CN106633693A - Color master batch for polylactic acid fiber pre-spinning dope dyeing - Google Patents
Color master batch for polylactic acid fiber pre-spinning dope dyeing Download PDFInfo
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- CN106633693A CN106633693A CN201611143792.3A CN201611143792A CN106633693A CN 106633693 A CN106633693 A CN 106633693A CN 201611143792 A CN201611143792 A CN 201611143792A CN 106633693 A CN106633693 A CN 106633693A
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- parts
- pigment
- acid fiber
- spins
- original liquid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a color master batch for polylactic acid fiber pre-spinning dope dyeing. The color master batch is composed of the following components in parts by weight: 40-95 parts of modified PET (polyethylene terephthalate) with the melting point of 180 DEG C, 0-50 parts of pigment A or dye a, 0-25 parts of pigment B or dye b, 0-15 parts of pigment C or dye c, 0-10 parts of pigment D or dye d, 0.3-1.0 part of heat stabilizer, 0-2.5 parts of dispersing aid and 0-2.5 parts of rheologic modifier. When the color master batch is added in the spinning process, the polylactic acid fibers, of which the color fastness to washing reaches Grade 3 or above and the color fastness to light reaches Grade 4 or above, can be obtained.
Description
Technical field
The present invention relates to acid fiber by polylactic spins front original liquid coloring Masterbatch.
Background technology
PLA（PLA ）Fiber is the fermented generation breast with the amyloid agricultural product such as corn, wheat, beet as raw material
After acid, then a kind of fiber made by Jing polycondensations and melt spinning, it is that a kind of raw material can be planted, easily planted, discarded object is in nature
In can natural degradation synthetic fibers.PLA fibers have good biodegradable, can be in nature completely after going out of use
Decompose.PLA（PLA ）If fiber is together buried with other organic wastes, carbon dioxide will be decomposed in some months
And water, its Jing microbial action in soil or seawater can be analyzed to carbon dioxide and water, during burning, will not distribute poison gas, no
Can pollute, be a kind of ecological fiber of sustainable development.PLA（PLA ）The fabric feel of fiber, drapability
Good, anti-ultraviolet property is excellent, with relatively low combustibility and excellent processing characteristics, suitable for various fashionable dresses, easy dress, body
Articles for use and amenities etc. are educated, is had broad application prospects.
The content of the invention
It is an object of the invention to provide a kind of acid fiber by polylactic spins front original liquid coloring Masterbatch, in spinning this is added
The Masterbatch of invention, is obtained that washing color fastness reaches more than 3 grades, that light shine color fastness reaches more than 4 grades of PLA is fine
Dimension.
For achieving the above object, the present invention provides original liquid coloring Masterbatch before a kind of acid fiber by polylactic spins, by weight
Meter is composed of the following components：
40～95 parts of fusing points are 180 DEG C of modified PET polyester,
0～50 part of pigment A or dyestuff a,
0～25 part of pigment B or dyestuff b,
0～15 part of pigment C or dyestuff c,
0～10 part of pigment D or dyestuff d,
0.3～1.0 part of thermally-stabilised auxiliary agent,
0～2.5 part of dispersing aid,
0～2.5 part of rheology modifier.
Preferably, the pigment A, pigment B, pigment C, pigment D are inorganic pigment or organic pigment；The dyestuff is solvent
Dyestuff.
Preferably, the inorganic pigment is selected from spinning-grade titanium dioxide, carbon black, spinning-grade iron oxide red.
Preferably, the organic pigment is selected from：P.R.214 、 P.R.142 、 P.Y.150 、 P.B.15:1 、
P.B.15:3 。
Preferably, the solvent dye is selected from：S.R.135 、 S.Y.176 、 S.B.104 .
Preferably, by weight, the thermally-stabilised auxiliary agent is composed of the following components：
70 parts of light rare earth-magnesium hydrotalcites,
7.5 parts of polytetrafluoroethylwax waxes,
29 parts of aliphatic carboxylic acids,
2.3 parts of ammonium dihydrogen phosphates,
2.8 parts of tributyltin chlorides,
3.1 parts of azelaic acid dibutyl esters,
4.6 parts of beta-diketons,
1.9 parts of 2-mercaptobenzothiazoles,
3.7 parts of sulfosuccinic acid Diisooctyl sodium,
2.4 parts of diisooctyl maleate sulfonate,
3.8 parts of calgons.
Preferably, by weight, the dispersing aid is composed of the following components：
12.1 parts of 1-METHYLPYRROLIDONEs,
7.6 parts of sodium tripolyphosphates,
13.4 parts of hexyl decyl alcohols,
2.7 parts of methylcellulose,
1.4 parts of 4 bromides,
2.6 parts of tributyl phosphates.
The advantages of the present invention are：Original liquid coloring Masterbatch before a kind of acid fiber by polylactic spins is provided,
During spinning add the present invention Masterbatch, be obtained washing color fastness reach more than 3 grades, light shine color fastness reach 4 grades with
On acid fiber by polylactic.
The present invention especially optimizes the component proportion of dispersing aid and heat stabilizer, can be effectively improved the dye of acid fiber by polylactic
The color fastness of color performance and the acid fiber by polylactic for improving.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following examples are only used for more
Plus technical scheme is clearly demonstrated, and can not be limited the scope of the invention with this.
The technical scheme that the present invention is embodied as is：
The present invention provides original liquid coloring Masterbatch before a kind of acid fiber by polylactic spins, composed of the following components by weight：
40～95 parts of fusing points are 180 DEG C of modified PET polyester,
0～50 part of pigment A or dyestuff a,
0～25 part of pigment B or dyestuff b,
0～15 part of pigment C or dyestuff c,
0～10 part of pigment D or dyestuff d,
0.3～1.0 part of thermally-stabilised auxiliary agent,
0～2.5 part of dispersing aid,
0～2.5 part of rheology modifier.
Preferably, the pigment A, pigment B, pigment C, pigment D are inorganic pigment or organic pigment；The dyestuff is solvent
Dyestuff.
Preferably, the inorganic pigment is selected from spinning-grade titanium dioxide, carbon black, spinning-grade iron oxide red.
Preferably, the organic pigment is selected from：P.R.214 、 P.R.142 、 P.Y.150 、 P.B.15:1 、
P.B.15:3 。
Preferably, the solvent dye is selected from：S.R.135 、 S.Y.176 、 S.B.104 .
Preferably, by weight, the thermally-stabilised auxiliary agent is composed of the following components：
70 parts of light rare earth-magnesium hydrotalcites,
7.5 parts of polytetrafluoroethylwax waxes,
29 parts of aliphatic carboxylic acids,
2.3 parts of ammonium dihydrogen phosphates,
2.8 parts of tributyltin chlorides,
3.1 parts of azelaic acid dibutyl esters,
4.6 parts of beta-diketons,
1.9 parts of 2-mercaptobenzothiazoles,
3.7 parts of sulfosuccinic acid Diisooctyl sodium,
2.4 parts of diisooctyl maleate sulfonate,
3.8 parts of calgons.
Preferably, by weight, the dispersing aid is composed of the following components：
12.1 parts of 1-METHYLPYRROLIDONEs,
7.6 parts of sodium tripolyphosphates,
13.4 parts of hexyl decyl alcohols,
2.7 parts of methylcellulose,
1.4 parts of 4 bromides,
2.6 parts of tributyl phosphates.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, on the premise of without departing from the technology of the present invention principle, some improvements and modifications can also be made, these improvements and modifications
Also should be regarded as protection scope of the present invention.
Claims (7)
1. original liquid coloring Masterbatch before acid fiber by polylactic spins, it is characterised in that composed of the following components by weight：
40～95 parts of fusing points are 180 DEG C of modified PET polyester,
0～50 part of pigment A or dyestuff a,
0～25 part of pigment B or dyestuff b,
0～15 part of pigment C or dyestuff c,
0～10 part of pigment D or dyestuff d,
0.3～1.0 part of thermally-stabilised auxiliary agent,
0～2.5 part of dispersing aid,
0～2.5 part of rheology modifier.
2. original liquid coloring Masterbatch before acid fiber by polylactic according to claim 1 spins, it is characterised in that the pigment A,
Pigment B, pigment C, pigment D are inorganic pigment or organic pigment；The dyestuff is solvent dye.
3. original liquid coloring Masterbatch before acid fiber by polylactic according to claim 2 spins, it is characterised in that the inorganic face
Material is selected from spinning-grade titanium dioxide, carbon black, spinning-grade iron oxide red.
4. original liquid coloring Masterbatch before acid fiber by polylactic according to claim 3 spins, it is characterised in that organic face
Material is selected from：P.R.214 、 P.R.142 、 P.Y.150 、 P.B.15:1 、 P.B.15:3 .
5. original liquid coloring Masterbatch before acid fiber by polylactic according to claim 4 spins, it is characterised in that the solvent dye
Material is selected from：S.R.135 、 S.Y.176 、 S.B.104 .
6. original liquid coloring Masterbatch before acid fiber by polylactic according to claim 5 spins, it is characterised in that by weight
Meter, the thermally-stabilised auxiliary agent is composed of the following components：
70 parts of light rare earth-magnesium hydrotalcites,
7.5 parts of polytetrafluoroethylwax waxes,
29 parts of aliphatic carboxylic acids,
2.3 parts of ammonium dihydrogen phosphates,
2.8 parts of tributyltin chlorides,
3.1 parts of azelaic acid dibutyl esters,
4.6 parts of beta-diketons,
1.9 parts of 2-mercaptobenzothiazoles,
3.7 parts of sulfosuccinic acid Diisooctyl sodium,
2.4 parts of diisooctyl maleate sulfonate,
3.8 parts of calgons.
7. original liquid coloring Masterbatch before acid fiber by polylactic according to claim 6 spins, it is characterised in that by weight
Meter, the dispersing aid is composed of the following components：
12.1 parts of 1-METHYLPYRROLIDONEs,
7.6 parts of sodium tripolyphosphates,
13.4 parts of hexyl decyl alcohols,
2.7 parts of methylcellulose,
1.4 parts of 4 bromides,
2.6 parts of tributyl phosphates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611143792.3A CN106633693A (en) | 2016-12-13 | 2016-12-13 | Color master batch for polylactic acid fiber pre-spinning dope dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611143792.3A CN106633693A (en) | 2016-12-13 | 2016-12-13 | Color master batch for polylactic acid fiber pre-spinning dope dyeing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633693A true CN106633693A (en) | 2017-05-10 |
Family
ID=58825820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611143792.3A Pending CN106633693A (en) | 2016-12-13 | 2016-12-13 | Color master batch for polylactic acid fiber pre-spinning dope dyeing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106633693A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108864666A (en) * | 2018-07-26 | 2018-11-23 | 苏州宝丽迪材料科技股份有限公司 | The preparation method of PET fiber master batch |
| CN108864669A (en) * | 2018-07-26 | 2018-11-23 | 苏州宝丽迪材料科技股份有限公司 | The preparation method of PLA Biodegradable fibers master batch |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6096822A (en) * | 1998-04-21 | 2000-08-01 | Alliedsignal Inc. | Low molecular weight polyester or polyamide pigment dispersing composition and color concentrate for the manufacture of colored polymers |
| CN1544748A (en) * | 2003-11-28 | 2004-11-10 | 中国人民解放军总后勤部军需装备研究 | High color stability stock solution dyeing synthetic leather and process for making same |
| CN101024719A (en) * | 2006-02-23 | 2007-08-29 | 东丽纤维研究所（中国）有限公司 | Metod and apparatus for continuously producing clouring polyester |
| CN104861561A (en) * | 2014-10-17 | 2015-08-26 | 青岛欣展塑胶有限公司 | PET spinning color master batch and preparation method therefor |
| CN105199183A (en) * | 2015-10-23 | 2015-12-30 | 揭东巴黎万株纱华纺织有限公司 | Color masterbatch formula |
-
2016
- 2016-12-13 CN CN201611143792.3A patent/CN106633693A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6096822A (en) * | 1998-04-21 | 2000-08-01 | Alliedsignal Inc. | Low molecular weight polyester or polyamide pigment dispersing composition and color concentrate for the manufacture of colored polymers |
| CN1544748A (en) * | 2003-11-28 | 2004-11-10 | 中国人民解放军总后勤部军需装备研究 | High color stability stock solution dyeing synthetic leather and process for making same |
| CN101024719A (en) * | 2006-02-23 | 2007-08-29 | 东丽纤维研究所（中国）有限公司 | Metod and apparatus for continuously producing clouring polyester |
| CN104861561A (en) * | 2014-10-17 | 2015-08-26 | 青岛欣展塑胶有限公司 | PET spinning color master batch and preparation method therefor |
| CN105199183A (en) * | 2015-10-23 | 2015-12-30 | 揭东巴黎万株纱华纺织有限公司 | Color masterbatch formula |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108864666A (en) * | 2018-07-26 | 2018-11-23 | 苏州宝丽迪材料科技股份有限公司 | The preparation method of PET fiber master batch |
| CN108864669A (en) * | 2018-07-26 | 2018-11-23 | 苏州宝丽迪材料科技股份有限公司 | The preparation method of PLA Biodegradable fibers master batch |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 215000 Shiqiao Road, Shiqiao, Xiangcheng District, Suzhou, Jiangsu Applicant after: Suzhou Baoli Di material Polytron Technologies Inc Address before: 215000 Shiqiao Road, Shiqiao, Xiangcheng District, Suzhou, Jiangsu Applicant before: POLY PLASTIC MASTERBATCH (SUZHOU) CO., LTD. |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |