CN106633560A - Color masterbatch and manufacturing method - Google Patents

Color masterbatch and manufacturing method Download PDF

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Publication number
CN106633560A
CN106633560A CN201611231073.7A CN201611231073A CN106633560A CN 106633560 A CN106633560 A CN 106633560A CN 201611231073 A CN201611231073 A CN 201611231073A CN 106633560 A CN106633560 A CN 106633560A
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parts
masterbatch
agent
plasticizer
stabilizer
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李勇军
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C08J3/122—Pulverisation by spraying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention relates to a color masterbatch and a manufacturing method, specifically to pigmentation of a variety of plastics. The color masterbatch provided by the invention is composed of deionized water, polyvinyl butyral, ethanol, an antifoaming agent, a stabilizer, a plasticizer, a dispersant, polyethylene wax, ethylene oxide wax, a leveling agent, a coupling agent, plastic pigment powder, an anti-ultraviolet agent and an anti-ageing agent. The color masterbatch provided by the invention is prepared from a variety of raw materials in reasonable proportion, has excellent dispersion uniformity, smoothness, flexibility and low-temperature resistance, and significantly improves the quality of a product; the color masterbatch provided by the invention has two shapes of powder and granule, thereby meeting different addition requirements of powdered resins (like PVC) and granular resins (like PMMA) and achieving the effect of uniform pigmentation; and the color masterbatch provided by the invention is applicable to pigmentation of resins like PVC, ABS, PMMA, PS, polyurethane and epoxy resin.

Description

A kind of Masterbatch and manufacture method
Technical field
The present invention relates to a kind of new Masterbatch and manufacture method, and in particular to the coloring of various plastics.
Background technology
At present the manufacture method of domestic enterprise's Masterbatch is that resin-oatmeal and toner blending are granulated, the Masterbatch of the method production There are two weak points, 1. in 15-40 microns, toner particle is irregular to cause dispersion uneven to toner particle diameter distribution, produces plastics Easily go out fisheye during film and have obvious aberration；2. when using powdex article of manufacture, Masterbatch can not be blended with powdex Uniformly, thus color masterbatch can not can only be used using toner with during powdex article of manufacture；The Masterbatch particle diameter of the present invention is in 1-3 Micron, is uniformly dispersed, and without fisheye, consumption is few and good luster, and no color differnece, applicability is extensive.
The content of the invention
The invention mainly solves the technical problem of providing a kind of plastic products Masterbatch and manufacture new method, overcome existing Masterbatch technological deficiency, with being uniformly dispersed, without fisheye, consumption is few and good luster, no color differnece, the advantage of resistance to discoloration.
The present invention Masterbatch, by deionized water, polyvinyl butyral resin, ethanol, defoamer, stabilizer, plasticizer, point Powder, Tissuemat E, ethylene oxide wax, levelling agent, coupling agent, plastic cement toner, UV resistant agent, age resister composition；
Described polyvinyl butyral resin 10-30 parts；
Described deionized water 10-30 part；
Described ethanol 20-40 parts；
The defoamer 0,5-5 parts；
Described stabilizer 0.1-3 parts；
Described plasticizer 1-5 parts；
Described dispersant 0.1-3 parts；
Described Tissuemat E 0.1-3 parts；
Described ethylene oxide wax 0.1-3 parts；
Described levelling agent 0.1-3 parts；
Described coupling agent 0.1-5 parts；
Described plastic cement toner 10-40 parts；
Described UV resistant agent 0.5-5 parts；
Described age resister 0,5-5 parts；
Described number is parts by weight.
It is one of preferable to be：
17 parts of the polyvinyl butyral resin；
17 parts of the deionized water；
35 parts of the ethanol；
1 part of the defoamer；
0.5 part of the stabilizer；
2.8 parts of the plasticizer；
1 part of the dispersant；
0.2 part of the Tissuemat E；
0.5 part of the ethylene oxide wax；
0.5 part of the levelling agent；
1 part of the coupling agent；
21 parts of the plastic cement toner；
1 part of the UV resistant agent；
1.5 parts of the age resister；
Described number is weight fraction.
Preferably two are：
10 parts of the polyvinyl butyral resin;
10 parts of the deionized water;
20 parts of the ethanol;
1.5 parts of the defoamer;
1 part of the stabilizer;
4.5 parts of the plasticizer;
2 parts of the dispersant;
3 parts of the Tissuemat E;
3 parts of the ethylene oxide wax；
3 parts of the coupling agent;
2 parts of the levelling agent;
35 parts of the plastic cement toner；
2 parts of the UV resistant agent;
3 parts of the age resister;
Described number is weight fraction.
The preparation method of above-mentioned Masterbatch, is carried out as steps described below：
During the first, ethanol, deionized water, polyvinyl butyral resin to be poured into the reactor of external pipe formula sand mill, in 40 ° of constant temperature Lower stirring 120 minutes；
2nd, be cooled to after room temperature, successively in the reactor in step one add defoamer, stabilizer, plasticizer, dispersant, Tissuemat E, ethylene oxide wax, coupling agent, levelling agent, plastic cement toner, UV resistant agent, age resister, grind while stirring 600 minutes；
3rd, take liquid in the reactor after implementation steps two to be spray-dried with spray drying tower, obtain powder Masterbatch Or be vacuum dried with vacuum drying chamber, sheet Masterbatch is obtained, then it is ground into graininess Masterbatch with pulverizer.
The invention has the beneficial effects as follows：The Masterbatch of the present invention is formed by plurality of raw materials rational proportion, is divided with splendid Scattered uniformity, smoothness, pliability, lower temperature resistance, significantly improve product quality；The Masterbatch of the present invention has powder and particle Two kinds of shapes of shape require come the different additions for meeting powdex (such as PVC) and particulate resins (such as PMMA), reach and colour Even effect；The present invention it is widely applicable, can be used for PVC, ABS, PMMA, PS, polyurethane, epoxy resin, pollopas, ketone resin, Melamine resin, natural resin, polyethyleneimine, the coloring of polyisocyanate resin.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of specification, described in detail as after with presently preferred embodiments of the present invention below.
Embodiment 1：The present invention Masterbatch, by deionized water, polyvinyl butyral resin, ethanol, defoamer, stabilizer, Plasticizer, dispersant, Tissuemat E, ethylene oxide wax, levelling agent, coupling agent, plastic cement toner, UV resistant agent, age resister Composition composition；
17 parts of the polyvinyl butyral resin；
17 parts of the deionized water；
35 parts of the ethanol；
1 part of the defoamer；
0.5 part of the stabilizer；
2.8 parts of the plasticizer；
1 part of the dispersant；
0.2 part of the Tissuemat E；
0.5 part of the ethylene oxide wax；
0.5 part of the levelling agent；
1 part of the coupling agent；
21 parts of the plastic cement toner；
1 part of the UV resistant agent；
1.5 parts of the age resister；
Described number is weight fraction.
Embodiment 2：The present invention Masterbatch, by deionized water, polyvinyl butyral resin, ethanol, defoamer, stabilizer, Plasticizer, dispersant, Tissuemat E, ethylene oxide wax, levelling agent, coupling agent, plastic cement toner, UV resistant agent, age resister Composition；
10 parts of the polyvinyl butyral resin；
10 parts of the deionized water;
20 parts of the ethanol;
1.5 parts of the defoamer;
1 part of the stabilizer;
4.5 parts of the plasticizer;
2 parts of the dispersant;
3 parts of the Tissuemat E;
3 parts of the ethylene oxide wax；
3 parts of the coupling agent;
2 parts of the levelling agent;
35 parts of the plastic cement toner；
2 parts of the UV resistant agent;
3 parts of the age resister;
Described number is weight fraction.
The preparation method of the Masterbatch of above example 1 and embodiment 2, is carried out as steps described below：
During the first, ethanol, deionized water, polyvinyl butyral resin to be poured into the reactor of external pipe formula sand mill, in 40 ° of constant temperature Lower stirring 120 minutes；
2nd, be cooled to after room temperature, successively in the reactor in step one add defoamer, stabilizer, plasticizer, dispersant, Tissuemat E, ethylene oxide wax, coupling agent, levelling agent, plastic cement toner, UV resistant agent, age resister, grind while stirring 600 minutes；
3rd, take liquid in the reactor after implementation steps two to be spray-dried with spray drying tower, obtain powder Masterbatch Or be vacuum dried with vacuum drying chamber, sheet Masterbatch is obtained, then it is ground into graininess Masterbatch with pulverizer.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every to be said using the present invention Equivalent structure or equivalent flow conversion that bright book content is made, or other related technical fields are directly or indirectly used in, It is included within the scope of the present invention in the same manner.

Claims (5)

1. a kind of Masterbatch, it is characterised in that：The Masterbatch of the present invention, by deionized water, polyvinyl butyral resin, ethanol, disappears Infusion, stabilizer, plasticizer, dispersant, Tissuemat E, ethylene oxide wax, levelling agent, coupling agent, plastic cement toner, uvioresistant Agent, age resister composition；Described polyvinyl butyral resin 10-30 parts；Described deionized water 10-30 part；The ethanol 20-40 Part；Described defoamer 0.5-5 parts；Described stabilizer 0.1-3 parts；Described plasticizer 1-5 parts；Described dispersant 0.1-3 parts；It is described Tissuemat E 0.1-3 parts；Described ethylene oxide wax 0.1-3 parts；Described levelling agent 0.1-3 parts；Described coupling 0.1-5 parts；It is described Plastic cement toner 10-40 parts；Described UV resistant agent 0.5-5 parts；Described age resister 0.5-5 parts；Described number is weight portion Number.
2. Masterbatch preparation method according to claim 1, it is characterised in that carry out as steps described below：
During the first, ethanol, deionized water, polyvinyl butyral resin to be poured into the reactor of external pipe formula sand mill, in 40 ° of constant temperature Lower stirring 120 minutes；
2nd, be cooled to after room temperature, successively in the reactor in step one add defoamer, stabilizer, plasticizer, dispersant, Tissuemat E, ethylene oxide wax, coupling agent, levelling agent, plastic cement toner, UV resistant agent, age resister, grind while stirring 600 minutes；
3rd, take liquid in the reactor after implementation steps two to be spray-dried with spray drying tower, obtain powder Masterbatch Or be vacuum dried with vacuum drying chamber, sheet Masterbatch is obtained, then it is ground into graininess Masterbatch with pulverizer.
3. Masterbatch according to claim 1, it is characterised in that：17 parts of the polyvinyl butyral resin；The deionization 17 parts of water；35 parts of the ethanol；1 part of the defoamer；0.5 part of the stabilizer；2.8 parts of the plasticizer；The dispersant 1 Part；0.2 part of the Tissuemat E；0.5 part of the ethylene oxide wax；0.5 part of the levelling agent；1 part of the coupling agent；The modeling 21 parts of glue toner；1 part of the UV resistant agent；1.5 parts of the age resister；Described number is weight fraction.
4. Masterbatch according to claim 1, it is characterised in that：10 parts of the polyvinyl butyral resin；The deionization 10 parts of water;20 parts of the ethanol；1.5 parts of the defoamer；1 part of the stabilizer;4.5 parts of the plasticizer;The dispersant 2 Part;3 parts of the Tissuemat E；3 parts of the ethylene oxide wax；3 parts of the coupling agent；2 parts of the levelling agent；The plastic cement toner 35 parts；2 parts of the UV resistant agent；3 parts of the age resister；Described number is weight fraction.
5. the Masterbatch preparation method according to claim 3 and claim 4, it is characterised in that enter as steps described below OK：
During the first, ethanol, deionized water, polyvinyl butyral resin to be poured into the reactor of external pipe formula sand mill, in 40 ° of constant temperature Lower stirring 120 minutes；
2nd, be cooled to after room temperature, successively in the reactor in step one add defoamer, stabilizer, plasticizer, dispersant, Tissuemat E, ethylene oxide wax, coupling agent, levelling agent, plastic cement toner, UV resistant agent, age resister, grind while stirring 600 minutes；
3rd, take liquid in the reactor after implementation steps two to be spray-dried with spray drying tower, obtain powder Masterbatch Or be vacuum dried with vacuum drying chamber, sheet Masterbatch is obtained, then it is ground into graininess Masterbatch with pulverizer.
CN201611231073.7A 2016-12-28 2016-12-28 Color masterbatch and manufacturing method Pending CN106633560A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107732530A (en) * 2017-10-27 2018-02-23 深圳市和宏实业股份有限公司 The manufacture method of the connector of temperature sensing color changing, new temperature sensing color changing data wire and temperature sensing color changing material
CN112250976A (en) * 2020-10-19 2021-01-22 济南金彩阳新材料科技有限公司 High-concentration ammonia-removing color cake and application thereof
CN112280228A (en) * 2020-10-19 2021-01-29 济南金彩阳新材料科技有限公司 PVB high-concentration color cake and preparation method and application thereof
US20220145078A1 (en) * 2019-04-26 2022-05-12 Thai Polyethylene Co., Ltd. Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same, a product comprising the color masterbatch and the use of the color masterbatch

Citations (1)

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CN1051920A (en) * 1990-11-27 1991-06-05 西安无线电一厂 High safety of color base and preparation method thereof

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李青山主编: "《着色配色技术手册》", 31 January 2016, 中国纺织出版社 *
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107732530A (en) * 2017-10-27 2018-02-23 深圳市和宏实业股份有限公司 The manufacture method of the connector of temperature sensing color changing, new temperature sensing color changing data wire and temperature sensing color changing material
US20220145078A1 (en) * 2019-04-26 2022-05-12 Thai Polyethylene Co., Ltd. Composition comprising an oxidized polyethylene wax, a color masterbatch comprising the same, a product comprising the color masterbatch and the use of the color masterbatch
CN112250976A (en) * 2020-10-19 2021-01-22 济南金彩阳新材料科技有限公司 High-concentration ammonia-removing color cake and application thereof
CN112280228A (en) * 2020-10-19 2021-01-29 济南金彩阳新材料科技有限公司 PVB high-concentration color cake and preparation method and application thereof
CN112280228B (en) * 2020-10-19 2021-06-22 济南金彩阳新材料科技有限公司 PVB high-concentration color cake and preparation method and application thereof
CN112250976B (en) * 2020-10-19 2023-01-20 济南金彩阳新材料科技有限公司 High-concentration ammonia-removing color cake and application thereof

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Application publication date: 20170510