CN106631572A - Anti-bacterial waste newspaper tea fertilizer and preparation method thereof - Google Patents

Anti-bacterial waste newspaper tea fertilizer and preparation method thereof Download PDF

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Publication number
CN106631572A
CN106631572A CN201611113080.7A CN201611113080A CN106631572A CN 106631572 A CN106631572 A CN 106631572A CN 201611113080 A CN201611113080 A CN 201611113080A CN 106631572 A CN106631572 A CN 106631572A
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China
Prior art keywords
parts
acid
fertilizer
old
gamma
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Application number
CN201611113080.7A
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Chinese (zh)
Inventor
周言明
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CHUZHOU SHIJI TEA PLANTATION
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CHUZHOU SHIJI TEA PLANTATION
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Priority to CN201611113080.7A priority Critical patent/CN106631572A/en
Publication of CN106631572A publication Critical patent/CN106631572A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00Fertilisers containing potassium
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses an anti-bacterial waste newspaper tea fertilizer. The anti-bacterial waste newspaper tea fertilizer is prepared from the following raw materials in parts by weight: 100 to 105 parts of waste newspaper, 10 to 11 parts of tofu skin, 5 to 6 parts of honeysuckle flower, 8 to 9 parts of houttuynia cordata, 20 to 22 parts of chestnut shell, 20 to 22 parts of fallen leaves, 1 to 2 parts of boric acid, 2 to 3 parts of potassium fulvic acid, 6 to 7 parts of plant ash, 8 to 9 parts of diatomaceous earth, 1,000 to 1,050 parts of 10 percent nitric acid solution, 165 to 175 parts of 10 percent phosphoric acid solution, a proper amount of potassium hydroxide, 1 to 1.5 part of ferroferric oxide, 1 to 1.5 parts of gamma-polyglutamic acid, 1 to 1.5 parts of polyvinyl alcohol, a proper amount of microorganism bacterial powder, 20 to 21 parts of bentonite and a proper amount of sulfuric acid. The fertilizer is prepared from the waste newspaper taken as the main raw materials, can play a role as a carrier, has a long-acting fertilizer effect, and is anti-bacterial.

Description

A kind of antibacterial old and useless newspaper tea fertilizer and preparation method thereof
Technical field
The present invention relates to fertilizer processing technique field, more particularly to a kind of antibacterial old and useless newspaper tea fertilizer and its preparation side Method.
Background technology
Paper has purposes widely, and the species of waste paper is also varied, with the continuous enhancing of environmental consciousness, this
A bit the recycling problem of " waste product " is increasingly paid close attention to by people.Paper after losing using function, usually burn, Reproduce it and use or recycle manufacture paper, so as to reach the effect of waste process or twice laid.Burning will necessarily bring dioxy Change discharge and the problem of environmental pollution of carbon, discarded paper recycling papermaking also brings along new pollution problem, not can realize clear It is clean to recycle.The daily old and useless newspaper amount of China is very big, if can be recycled that little, low cost is not only invested, produces effects fast, And industrial chemicals and the energy can be saved, mitigate the pollution to environment.Cellulose is the main component of newspaper, is put into In soil, improved can soil physics condition and arable layer.Therefore, old and useless newspaper is made into fertilizer can be to the growth of plant Play a positive role, this opens new approach for the process of old and useless newspaper, and provides a kind of economical and effective for agricultural Fertilizer.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of antibacterial old and useless newspaper tea fertilizer and its system Preparation Method.
The present invention is achieved by the following technical solutions:
A kind of antibacterial old and useless newspaper tea fertilizer, is prepared by the raw materials in:
Old and useless newspaper 100-105, skin of beancurd 10-11, honeysuckle 5-6, cordate houttuynia 8-9, chestnut shell 20-22, fallen leaves 20-22, boric acid 1-2, potassium fulvate 2-3, plant ash 6-7, diatomite 8-9,10% salpeter solution 1000-1050,10% phosphoric acid solution 165- 175th, appropriate potassium hydroxide, ferroso-ferric oxide 1-1.5, gamma-polyglutamic acid 1-1.5, polyvinyl alcohol 1-1.5, microbial germ powder are fitted Amount, bentonite 20-21, appropriate sulfuric acid.
The preparation method of described antibacterial old and useless newspaper tea fertilizer, comprises the following steps:
(3)Polyvinyl alcohol is added water the solution for being configured to that concentration is 5%, adds ferroso-ferric oxide, is stirred 30-35 minutes, plus sulfuric acid PH is adjusted to 4, gamma-polyglutamic acid is added, 40-50 minutes are stirred, gained is precipitated drying by centrifugation, obtain magnetic γ-poly- Glutamic acid;
(2)Old and useless newspaper is crushed, adds 10% salpeter solution and 10% phosphoric acid solution, reaction to add hydroxide after one hour Potassium adjusts pH to 8, adds magnetic gamma-polyglutamic acid, reacts one hour on the oscillator of 180r/min, then in additional magnetic Magnetic gamma-polyglutamic acid is separated off field is removed, resulting material heating is concentrated into thick, is dried in 107 DEG C of drying ovens, Crush, cross 20 mesh sieves;
(3)Skin of beancurd, honeysuckle, cordate houttuynia, chestnut shell, fallen leaves co-grinding, regulation to the water content that adds water are reached into 40-45%, so After add microbial germ powder, heap vexed fermentation 25-30 days, the turning of 5-6 days period is once;
(4)By step(2)、(3)Resulting material and leftover materials mix, and granulation is dried to constant weight at 40 DEG C, is obtained final product.
It is an advantage of the invention that:Using old and useless newspaper as primary raw material, it can play the work of carrier to the fertilizer of the present invention With, make chemical composition be attached to its surface, it is retained in for a long time in soil, with prolonged fertilizer efficiency, and newspaper is main Composition is cellulose, can strengthen the moisture retention of soil, and the physical condition or arable layer for making soil is improved, and is risen to reconciling soil Good effect has been arrived, the purpose of the fertilizer efficiency for increasing fertilizer has been served, it is contemplated that newspaper is to use letter press, the fertilizer being fabricated to Wherein lead tolerance may affect soil and plant and then affect health, add gamma-polyglutamic acid, and it can be complexed with lead, carry The high security of fertilizer, and polyvinyl alcohol can form coating film on ferroso-ferric oxide surface, the hydroxyl of polyvinyl alcohol and γ-poly- The carboxyl of glutamic acid carries out esterification and forms covalent bond, so that gamma-polyglutamic acid is coated on ferroso-ferric oxide surface, outward Plus magnetic field makes it easily separate from newspaper slurries, additionally, the honeysuckle of present invention addition, cordate houttuynia, plant ash have sterilization Effect, crop can be avoided to be bacterial contamination.
Specific embodiment
A kind of antibacterial old and useless newspaper tea fertilizer, by following weight portion(Kilogram)Raw material make:
Old and useless newspaper 100, skin of beancurd 10, honeysuckle 5, cordate houttuynia 8, chestnut shell 20, fallen leaves 20, boric acid 1, potassium fulvate 2, plant ash 6th, the phosphoric acid solution 165, appropriate potassium hydroxide of the salpeter solution 1000,10% of diatomite 8,10%, ferroso-ferric oxide 1, γ-poly- paddy Propylhomoserin 1, polyvinyl alcohol 1, appropriate microbial germ powder, bentonite 20, appropriate sulfuric acid.
The preparation method of described antibacterial old and useless newspaper tea fertilizer, comprises the following steps:
(3)Polyvinyl alcohol is added water the solution for being configured to that concentration is 5%, adds ferroso-ferric oxide, is stirred 30 minutes, plus sulfuric acid is adjusted Section pH adds gamma-polyglutamic acid to 4, stirs 40 minutes, and gained is precipitated drying by centrifugation, obtains magnetic γ-polyglutamic Acid;
(2)Old and useless newspaper is crushed, adds 10% salpeter solution and 10% phosphoric acid solution, reaction to add hydroxide after one hour Potassium adjusts pH to 8, adds magnetic gamma-polyglutamic acid, reacts one hour on the oscillator of 180r/min, then in additional magnetic Magnetic gamma-polyglutamic acid is separated off field is removed, resulting material heating is concentrated into thick, is dried in 107 DEG C of drying ovens, Crush, cross 20 mesh sieves;
(3)Skin of beancurd, honeysuckle, cordate houttuynia, chestnut shell, fallen leaves co-grinding, regulation to the water content that adds water are reached into 40%, then Microbial germ powder is added, heap is vexed to ferment 25 days, and the turning of 5 days periods is once;
(4)By step(2)、(3)Resulting material and leftover materials mix, and granulation is dried to constant weight at 40 DEG C, is obtained final product.
The fertilizer of the present invention is used to plant tea tree experiment, 5 mu of planting bases are selected, the fertilizer of the present invention is applied, as Experimental group, routinely planting requirement applies common fertilizer in 5 mu of bases of control group, and other conditions are identical, it is demonstrated experimentally that experimental group kind The tea tree of plant greatly reduces Fertilizer application amount in the case where equal production volume is reached, while raw material is easy to get, cost of material compares It is low, labour is saved, environmental protection is economical on year-on-year basis to improve 19.3%.

Claims (2)

1. a kind of antibacterial old and useless newspaper tea fertilizer, it is characterised in that be prepared by the raw materials in:
Old and useless newspaper 100-105, skin of beancurd 10-11, honeysuckle 5-6, cordate houttuynia 8-9, chestnut shell 20-22, fallen leaves 20-22, boric acid 1-2, potassium fulvate 2-3, plant ash 6-7, diatomite 8-9,10% salpeter solution 1000-1050,10% phosphoric acid solution 165- 175th, appropriate potassium hydroxide, ferroso-ferric oxide 1-1.5, gamma-polyglutamic acid 1-1.5, polyvinyl alcohol 1-1.5, microbial germ powder are fitted Amount, bentonite 20-21, appropriate sulfuric acid.
2. the preparation method of antibacterial old and useless newspaper tea fertilizer according to claim 1, it is characterised in that comprise the following steps:
(3)Polyvinyl alcohol is added water the solution for being configured to that concentration is 5%, adds ferroso-ferric oxide, is stirred 30-35 minutes, plus sulfuric acid PH is adjusted to 4, gamma-polyglutamic acid is added, 40-50 minutes are stirred, gained is precipitated drying by centrifugation, obtain magnetic γ-poly- Glutamic acid;
(2)Old and useless newspaper is crushed, adds 10% salpeter solution and 10% phosphoric acid solution, reaction to add hydroxide after one hour Potassium adjusts pH to 8, adds magnetic gamma-polyglutamic acid, reacts one hour on the oscillator of 180r/min, then in additional magnetic Magnetic gamma-polyglutamic acid is separated off field is removed, resulting material heating is concentrated into thick, is dried in 107 DEG C of drying ovens, Crush, cross 20 mesh sieves;
(3)Skin of beancurd, honeysuckle, cordate houttuynia, chestnut shell, fallen leaves co-grinding, regulation to the water content that adds water are reached into 40-45%, so After add microbial germ powder, heap vexed fermentation 25-30 days, the turning of 5-6 days period is once;
(4)By step(2)、(3)Resulting material and leftover materials mix, and granulation is dried to constant weight at 40 DEG C, is obtained final product.
CN201611113080.7A 2016-12-07 2016-12-07 Anti-bacterial waste newspaper tea fertilizer and preparation method thereof Withdrawn CN106631572A (en)

Priority Applications (1)

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CN201611113080.7A CN106631572A (en) 2016-12-07 2016-12-07 Anti-bacterial waste newspaper tea fertilizer and preparation method thereof

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829298A (en) * 2015-04-11 2015-08-12 铜陵家宴生态农业发展有限公司 Adsorption fertilizer prepared by charing waste paper and preparation method thereof
CN106588326A (en) * 2016-12-07 2017-04-26 滁州市施集茶场 Waste newspaper fertilizer capable of improving soil aeration for tea tree and preparation method of waste newspaper fertilizer for tea tree
CN106748436A (en) * 2016-12-07 2017-05-31 滁州市施集茶场 A kind of solid root old and useless newspaper tea fertilizer and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829298A (en) * 2015-04-11 2015-08-12 铜陵家宴生态农业发展有限公司 Adsorption fertilizer prepared by charing waste paper and preparation method thereof
CN106588326A (en) * 2016-12-07 2017-04-26 滁州市施集茶场 Waste newspaper fertilizer capable of improving soil aeration for tea tree and preparation method of waste newspaper fertilizer for tea tree
CN106748436A (en) * 2016-12-07 2017-05-31 滁州市施集茶场 A kind of solid root old and useless newspaper tea fertilizer and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
"废纸做肥料可防植物病", 《江苏环境科技》 *
,白山松水环保世纪行执委会: "《2006年白山松水环保世纪行作品集》", 31 December 2006 *
张娟等: "新型磁性聚谷氨酸吸附剂对水中Pb2+的吸附去除", 《环境科学》 *

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