CN106626859A - Thermal dye sublimation transfer paper - Google Patents
Thermal dye sublimation transfer paper Download PDFInfo
- Publication number
- CN106626859A CN106626859A CN201611159012.4A CN201611159012A CN106626859A CN 106626859 A CN106626859 A CN 106626859A CN 201611159012 A CN201611159012 A CN 201611159012A CN 106626859 A CN106626859 A CN 106626859A
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- CN
- China
- Prior art keywords
- parts
- layer
- sublimation transfer
- thermal dye
- dye sublimation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses thermal dye sublimation transfer paper which comprises an ink holdout layer, a paper fiber bonding layer, a base paper layer and a back coating. The ink holdout layer comprises polyanionic cellulose and dry filler. The paper fiber bonding layer adopts a binder, namely water-base resin. The coating comprises 1-10 parts of saccharose, 1-15 parts of pentaerythritol, 1-10 parts of starch, 2-15 parts of cellulose, 2-10 parts of fumed silica, 2-16 parts of polyvinyl alcohol, 2-18 parts of glycerinum, 2-9 parts of barium sulfate, 2-15 parts of hydroxymethyl cellulose, 1-10 parts of a sterilizing agent, 2-15 parts of organic solvent, 2-15 parts of a surface active agent, 1-10 parts of a non-polar oxide, 1-15 parts of a thickening agent, 1-10 parts of a neutralizer, 2-15 parts of tall oil fatty acid, 1-15 parts of polyacrylamide, 1-10 parts of a polysaccharide derivative, 1-15 parts of a corrosion inhibitor, and 1-10 parts of a printing ink medium adsorbent. The preparation technique is simple, and obtained printing ink has great ink holdout capacity, corrosion resistance, abrasion resistance, oxidation resistance, water resistance and adhesive capacity.
Description
Technical field
The present invention relates to technical field of ink, specially a kind of thermal dye sublimation transfer printing paper.
Background technology
Thermal dye sublimation transfer printing is a kind of water-free dyeing technique, with higher environmental protection effect, the high energy advocated current country
Consumption industry energy-saving reduces discharging improvement project and has important value, has become study hotspot at present.The principle of thermal dye sublimation transfer printing is in height
Under temperature (usually more than 220 DEG C), the disperse dyes on thermal dye sublimation transfer printing medium are sublimed up on chemical fiber plus material and directly by fabric
Fiber is fixed, and the chemical fiber plus material printed and dyed can be with Non-water washing.It is believed that thermal dye sublimation transfer printing technique, especially digital heat sublimation
Transfer printing process, is a kind of high in environmental protection and practical reliable technique, is hopeful to substitute traditional dyeing and finishing technique.
And sublimation transfer paper improves printing exquisiteness degree, it is often more important that can easily realize the no-watermark of textile
Dye, ink-jet printer directly can print under computer control beautiful in colour, vivid forcing on ink-jet thermal dye sublimation transfer paper
Genuine effect and without the need for operations such as plate-making, then through simple heating process transferred object can be made to obtain the printing effect of exquisiteness.
However, because the trans-printing process that distils requires heat to higher temperature, therefore the binder of high temperature ink when shifting is necessary
Possess certain thermostability additionally, the ability of supporting ink well of existing transfer paper ink is poor, need the amount of coating relatively more, at present
It is less for heat sublimation transfer printing and preparation method thereof both at home and abroad.
The content of the invention
It is an object of the invention to provide a kind of thermal dye sublimation transfer printing paper, to solve the problems, such as above-mentioned background technology in propose.
For achieving the above object, the present invention provides following technical scheme：A kind of thermal dye sublimation transfer printing paper, including layer of supporting ink well, paper
Fibres bond layer, base paper layer and back coating, the layer of supporting ink well including polyanion cellulose and dry filler, glue by the paper fiber
Knot layer adopts binding agent, and the binding agent is water-base resin, and the coating includes sucrose 1-10 parts, tetramethylolmethane 1-15 parts, forms sediment
Powder 1-10 parts, cellulose 2-15 parts, aerosil 2-10 parts, polyvinyl alcohol 2-16 parts, glycerol 2-18 parts, barium sulfate 2-9
Part, hydroxymethyl cellulose 2-15 parts, antibacterial 1-10 parts, organic solvent 2-15 parts, surfactant 2-15 parts, electrodeless oxide
1-10 parts, thickening agent 1-15 parts, nertralizer 1-10 parts, tall oil fatty acid 2-15 parts, polyacrylamide 1-15 parts, polysaccharide derive
Thing 1-10 parts, corrosion inhibiter 1-15 parts, ink medium adsorbent 1-10 parts.
Preferably, the polysaccharide derivates include：Polydextrose, glucosan, arabic gum, agar, glycogen, hyalomitome
Acid.
Preferably, the dry filler is the mixture of one or more in hydrophobic starch, S iO2, CaCO3.
Preferably, the layer of supporting ink well can be with one layer of coating, it is also possible to divide multi-layer coated.
Preferably, the binding agent is water-base resin, using Biformyl, polyamide-based resin, potassium zirconium carbonate, polystyrene
Any one or a few mixture in thermoplastic elastomer (TPE).
Preferably, the coating optimum proportioning is 4 parts of sucrose, 8 parts of tetramethylolmethane, 5 parts of starch, 7 parts of cellulose, gas phase two
3 parts of silicon oxide, 8 parts of polyvinyl alcohol, 5 parts of glycerol, 3 parts of barium sulfate, 9 parts of hydroxymethyl cellulose, 3 parts of antibacterial, organic solvent 7
Part, 5 parts of surfactant, 9 parts of electrodeless oxide, 3 parts of thickening agent, 2 parts of nertralizer, 3 parts of tall oil fatty acid, polyacrylamide
2 parts, 3 parts of polysaccharide derivates, 2 parts of corrosion inhibiter, 3 parts of ink medium adsorbent.
Compared with prior art, the invention has the beneficial effects as follows：
(1) preparation process is simple of the present invention, is obtained thermal dye sublimation transfer printing paper and has good ability of supporting ink well, wearability, antioxygen
The property changed, resistance to water and adhesive ability；
(2) increasing in the present invention has anticorrosive, and coating can be made to have good anticorrosive property.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only it is a part of embodiment of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, ordinary skill
The every other embodiment that personnel are obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
The present invention provides a kind of technical scheme：A kind of thermal dye sublimation transfer printing paper, including layer of supporting ink well, paper fiber tack coat, base paper
Layer and back coating, including polyanion cellulose and dry filler, the paper fiber tack coat adopts binding agent to the layer of supporting ink well,
The binding agent is water-base resin, and the coating includes sucrose 1-10 parts, tetramethylolmethane 1-15 parts, starch 1-10 parts, cellulose
2-15 parts, aerosil 2-10 parts, polyvinyl alcohol 2-16 parts, glycerol 2-18 parts, barium sulfate 2-9 parts, hydroxymethyl cellulose
2-15 parts, antibacterial 1-10 parts, organic solvent 2-15 parts, surfactant 2-15 parts, electrodeless oxide 1-10 parts, thickening agent 1-
15 parts, nertralizer 1-10 parts, tall oil fatty acid 2-15 parts, polyacrylamide 1-15 parts, polysaccharide derivates 1-10 parts, corrosion inhibiter
1-15 parts, ink medium adsorbent 1-10 parts.
Embodiment one：
In the present embodiment, the coating optimum proportioning be 4 parts of sucrose, 8 parts of tetramethylolmethane, 5 parts of starch, 7 parts of cellulose,
It is 3 parts of aerosil, 8 parts of polyvinyl alcohol, 5 parts of glycerol, 3 parts of barium sulfate, 9 parts of hydroxymethyl cellulose, 3 parts of antibacterial, organic
7 parts of solvent, 5 parts of surfactant, 9 parts of electrodeless oxide, 3 parts of thickening agent, 2 parts of nertralizer, 3 parts of tall oil fatty acid, poly- third
2 parts of acrylamide, 3 parts of polysaccharide derivates, 2 parts of corrosion inhibiter, 3 parts of ink medium adsorbent.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucosan, arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the dry filler is the mixture of one or more in hydrophobic starch, SiO2, CaCO3.
In the present embodiment, the layer of supporting ink well can be with one layer of coating, it is also possible to divides multi-layer coated.
In the present embodiment, the binding agent is water-base resin, using Biformyl, polyamide-based resin, potassium zirconium carbonate, benzene
Any one or a few mixture in ethylene based thermoplastic elastomer.
Embodiment two：
In the present embodiment, the coating optimum proportioning be 5 parts of sucrose, 8 parts of tetramethylolmethane, 5 parts of starch, 7 parts of cellulose,
It is 3 parts of aerosil, 8 parts of polyvinyl alcohol, 5 parts of glycerol, 3 parts of barium sulfate, 9 parts of hydroxymethyl cellulose, 5 parts of antibacterial, organic
10 parts of solvent, 5 parts of surfactant, 9 parts of electrodeless oxide, 3 parts of thickening agent, 2 parts of nertralizer, 3 parts of tall oil fatty acid, poly- third
2 parts of acrylamide, 3 parts of polysaccharide derivates, 2 parts of corrosion inhibiter, 3 parts of ink medium adsorbent.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucosan, arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the dry filler is the mixture of one or more in hydrophobic starch, SiO2, CaCO3.
In the present embodiment, the layer of supporting ink well can be with one layer of coating, it is also possible to divides multi-layer coated.
In the present embodiment, the binding agent is water-base resin, using Biformyl, polyamide-based resin, potassium zirconium carbonate, benzene
Any one or a few mixture in ethylene based thermoplastic elastomer.
Embodiment three：
In the present embodiment, the coating optimum proportioning is 4 parts of sucrose, 10 parts of tetramethylolmethane, 6 parts of starch, cellulose 7
Part, 3 parts of aerosil, 10 parts of polyvinyl alcohol, 5 parts of glycerol, 3 parts of barium sulfate, 9 parts of hydroxymethyl cellulose, 3 parts of antibacterial,
7 parts of organic solvent, 4 parts of surfactant, 9 parts of electrodeless oxide, 5 parts of thickening agent, 2 parts of nertralizer, 3 parts of tall oil fatty acid,
2 parts of polyacrylamide, 3 parts of polysaccharide derivates, 2 parts of corrosion inhibiter, 3 parts of ink medium adsorbent.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucosan, arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the dry filler is the mixture of one or more in hydrophobic starch, SiO2, CaCO3.
In the present embodiment, the layer of supporting ink well can be with one layer of coating, it is also possible to divides multi-layer coated.
In the present embodiment, the binding agent is water-base resin, using Biformyl, polyamide-based resin, potassium zirconium carbonate, benzene
Any one or a few mixture in ethylene based thermoplastic elastomer.
Example IV：
In the present embodiment, the coating optimum proportioning is 4 parts of sucrose, 8 parts of tetramethylolmethane, 10 parts of starch, cellulose 2
Part, 10 parts of aerosil, 8 parts of polyvinyl alcohol, 5 parts of glycerol, 3 parts of barium sulfate, 9 parts of hydroxymethyl cellulose, 3 parts of antibacterial,
10 parts of organic solvent, 5 parts of surfactant, 9 parts of electrodeless oxide, 3 parts of thickening agent, 2 parts of nertralizer, 3 parts of tall oil fatty acid,
2 parts of polyacrylamide, 3 parts of polysaccharide derivates, 2 parts of corrosion inhibiter, 3 parts of ink medium adsorbent.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucosan, arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the dry filler is the mixture of one or more in hydrophobic starch, SiO2, CaCO3.
In the present embodiment, the layer of supporting ink well can be with one layer of coating, it is also possible to divides multi-layer coated.
In the present embodiment, the binding agent is water-base resin, using Biformyl, polyamide-based resin, potassium zirconium carbonate, benzene
Any one or a few mixture in ethylene based thermoplastic elastomer.
Preparation process is simple of the present invention, be obtained thermal dye sublimation transfer printing paper have good ability of supporting ink well, anti-corrosive properties, wearability,
Non-oxidizability, resistance to water and adhesive ability；Add anticorrosive in the present invention, can make ink that there is good anticorrosive property.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (6)
1. a kind of thermal dye sublimation transfer printing paper, it is characterised in that：It is described including layer of supporting ink well, paper fiber tack coat, base paper layer and back coating
Layer of supporting ink well includes polyanion cellulose and dry filler, and the paper fiber tack coat adopts binding agent, and the binding agent is water
Property resin, the coating include sucrose 1-10 parts, tetramethylolmethane 1-15 parts, starch 1-10 parts, cellulose 2-15 parts, gas phase dioxy
SiClx 2-10 part, polyvinyl alcohol 2-16 parts, glycerol 2-18 parts, barium sulfate 2-9 parts, hydroxymethyl cellulose 2-15 parts, antibacterial 1-
10 parts, organic solvent 2-15 parts, surfactant 2-15 parts, electrodeless oxide 1-10 parts, thickening agent 1-15 parts, nertralizer 1-10
Part, tall oil fatty acid 2-15 parts, polyacrylamide 1-15 parts, polysaccharide derivates 1-10 parts, corrosion inhibiter 1-15 parts, ink medium
Adsorbent 1-10 parts.
2. thermal dye sublimation transfer printing paper according to claim 1, it is characterised in that：The polysaccharide derivates include：Polydextrose,
Glucosan, arabic gum, agar, glycogen, hyaluronic acid.
3. thermal dye sublimation transfer printing paper according to claim 1, it is characterised in that：The dry filler be hydrophobic starch, SiO2,
The mixture of one or more in CaCO3.
4. thermal dye sublimation transfer printing paper according to claim 1, it is characterised in that：The layer of supporting ink well can also may be used with one layer of coating
It is multi-layer coated with point.
5. thermal dye sublimation transfer printing paper according to claim 1, it is characterised in that：The binding agent is water-base resin, using second
Any one or a few mixture in dialdehyde, polyamide-based resin, potassium zirconium carbonate, styrene series thermoplastic elastomer.
6. thermal dye sublimation transfer printing paper according to claim 1, it is characterised in that：The coating optimum proportioning is 4 parts of sucrose, season
Penta 8 parts of tetrol, 5 parts of starch, 7 parts of cellulose, 3 parts of aerosil, 8 parts of polyvinyl alcohol, 5 parts of glycerol, 3 parts of barium sulfate, hydroxyl
9 parts of methylcellulose, 3 parts of antibacterial, 7 parts of organic solvent, 5 parts of surfactant, 9 parts of electrodeless oxide, 3 parts of thickening agent, in
2 parts of mediating recipe, 3 parts of tall oil fatty acid, 2 parts of polyacrylamide, 3 parts of polysaccharide derivates, 2 parts of corrosion inhibiter, ink medium adsorbent 3
Part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611159012.4A CN106626859A (en) | 2016-12-15 | 2016-12-15 | Thermal dye sublimation transfer paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611159012.4A CN106626859A (en) | 2016-12-15 | 2016-12-15 | Thermal dye sublimation transfer paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106626859A true CN106626859A (en) | 2017-05-10 |
Family
ID=58822217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611159012.4A Pending CN106626859A (en) | 2016-12-15 | 2016-12-15 | Thermal dye sublimation transfer paper |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109624541A (en) * | 2018-12-24 | 2019-04-16 | 苏州吉谷新材料有限公司 | A kind of ultra-thin thermal dye sublimation transfer printing paper and preparation method thereof |
| CN110168165A (en) * | 2017-01-12 | 2019-08-23 | 奥斯龙-明士克公司 | Sublimation printing transfer paper containing alkali salt |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1115284A (en) * | 1993-12-28 | 1996-01-24 | 佳能株式会社 | Recording medium and image-forming method employing the same |
| JP2011207169A (en) * | 2010-03-30 | 2011-10-20 | Fujifilm Corp | Image forming method |
| CN103538386A (en) * | 2012-07-16 | 2014-01-29 | 苏州市全佳涂布制品有限公司 | Quick-drying ink-jet thermal dye sublimation transfer printing medium and preparation method thereof |
| CN203713283U (en) * | 2013-11-25 | 2014-07-16 | 中国制浆造纸研究院 | High-transfer-rate quick-dry thermal sublimation transfer paper |
| US20150091974A1 (en) * | 2013-10-02 | 2015-04-02 | Seiko Epson Corporation | Recording method |
| CN104553431A (en) * | 2014-12-30 | 2015-04-29 | 杭州华大海天科技有限公司 | Self-adhesive quick-drying thermal sublimation transfer printing digital cloth |
| CN105711280A (en) * | 2014-12-04 | 2016-06-29 | 全斯福新材料（苏州）有限公司 | Easy-to-use ink-jet heat sublimation transfer paper |
| CN106042701A (en) * | 2015-04-03 | 2016-10-26 | 佳能精技股份有限公司 | Transfer material, recorded matter, method of manufacturing recorded matter, image-recording apparatus, and apparatus for manufacturing recorded matter |
-
2016
- 2016-12-15 CN CN201611159012.4A patent/CN106626859A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1115284A (en) * | 1993-12-28 | 1996-01-24 | 佳能株式会社 | Recording medium and image-forming method employing the same |
| JP2011207169A (en) * | 2010-03-30 | 2011-10-20 | Fujifilm Corp | Image forming method |
| CN103538386A (en) * | 2012-07-16 | 2014-01-29 | 苏州市全佳涂布制品有限公司 | Quick-drying ink-jet thermal dye sublimation transfer printing medium and preparation method thereof |
| US20150091974A1 (en) * | 2013-10-02 | 2015-04-02 | Seiko Epson Corporation | Recording method |
| CN203713283U (en) * | 2013-11-25 | 2014-07-16 | 中国制浆造纸研究院 | High-transfer-rate quick-dry thermal sublimation transfer paper |
| CN105711280A (en) * | 2014-12-04 | 2016-06-29 | 全斯福新材料（苏州）有限公司 | Easy-to-use ink-jet heat sublimation transfer paper |
| CN104553431A (en) * | 2014-12-30 | 2015-04-29 | 杭州华大海天科技有限公司 | Self-adhesive quick-drying thermal sublimation transfer printing digital cloth |
| CN106042701A (en) * | 2015-04-03 | 2016-10-26 | 佳能精技股份有限公司 | Transfer material, recorded matter, method of manufacturing recorded matter, image-recording apparatus, and apparatus for manufacturing recorded matter |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110168165A (en) * | 2017-01-12 | 2019-08-23 | 奥斯龙-明士克公司 | Sublimation printing transfer paper containing alkali salt |
| CN109624541A (en) * | 2018-12-24 | 2019-04-16 | 苏州吉谷新材料有限公司 | A kind of ultra-thin thermal dye sublimation transfer printing paper and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |
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