CN106620780B - Deodorant compositions and its application - Google Patents
Deodorant compositions and its application Download PDFInfo
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- CN106620780B CN106620780B CN201611012720.5A CN201611012720A CN106620780B CN 106620780 B CN106620780 B CN 106620780B CN 201611012720 A CN201611012720 A CN 201611012720A CN 106620780 B CN106620780 B CN 106620780B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a kind of deodorization composition and its applications, the deodorization composition contains amino acid complex, paraformaldehyde and/or Vanillin, stabilizer, bleeding agent, antibacterial agent and the antistatic agent of (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita；Wherein, the weight ratio of each component is 1:0.1-4.0:0.05-0.5:0.05-0.5:0.001-0.2:0.001-0.2.The method that the present invention carries out deodorization to foul odour includes contacting the aqueous solution containing above-mentioned deodorization composition with foul gas.Deodorization composition of the invention meets environmentally protective requirement, can be suitably used for the elimination of the stinks such as ammonia, hydrogen sulfide, methyl mercaptan, methyl sulfide.Deodorization composition of the invention can effectively mitigate pollution problem of the stench to environment, have excellent deodoriging properties, dosage is few, and treatment process is simple and effect is obvious, application easy to spread.
Description
Technical field
The invention belongs to technical field of fine, it is related to a kind of deodorant compositions and its application, and in particular, to a kind of
Deodorant compositions and its with fresh air, pet nursing, car care, sanitary ware nursing, toilet nurse, furniture nursing, rubbish
Application in deodorization.
Background technique
Odor pollution is to cause offending substance (odorant pollutant) bring by the olfactory organ of those stimulation people
A kind of feeling public hazards.Industrial production (such as industry of petrochemical industry, organic synthesis, plastics, rubber, printing, coating), poultry are supported
It grows, feed processing, during garbage disposal etc., a large amount of organic and inorganic exhaust gas discharged into atmosphere, serious shadow is caused to environment
It rings, wherein the most prominent with the gases affect with foul odour.Foreign countries have just started effluvium early in late 1950s
The research that body pollution is administered, has accumulated theoretical knowledge abundant and practical experience, and formulated the measurement of foul gas, evaluation,
A series of regulations such as control.Just carry out grinding in terms of the investigation of foul gas pollution, test and standard the 1980s in China
Study carefully, and to the research of deodorization technique carried out since the 1990s is just, has promulgated GB14554-93 " stench within 1993 years
Pollutant emission standard ", it is specified that ammonia, trimethylamine, hydrogen sulfide, methyl mercaptan, methyl sulfide, methyl disulfide, carbon disulfide, styrene
Deng 8 kinds of odorant pollutants and the emission limit and its measuring method of odor concentration.
Foul gas is very big to environmental hazard, and the harm to human body is also various.Being mainly manifested in it can influence
Respiratory system, the circulatory system, endocrine system, nervous system of human body etc..Reflexive inhibition is generated to human respiratory to make
With, or even hinder normal respiratory function；Lead to pulse and blood pressure, rises after falling before blood pressure；Often in contact with effluvium
Body easily makes one appetite stimulator, nausea is even vomitted, and also digestive function is caused to decline when serious；It can also make one to generate endocrine system
Dysfunction, some foul gas of Long Term Contact even easily cause fecundity to decline；Furthermore stench easily makes one mood agitation, the heart
Mind is not peaceful, and thought difficulty is concentrated, judgment and decrease of memory, and the regulatory function for even resulting in strata cerebrale excitement and inhibition is lacked of proper care,
Cause being mainly characterized by for chronic disease, acute disease and dead foul gas: first is that pollution sources are numerous, only human body smell can feel
Odorant just has more than 4000 kinds, pollutes wide, and it is more to be related to industry, is broadly divided into industry, life and organism and secretes 3 major class；
Second is that concentration is lower, or even down to 1 × 10-9mol/L, require its concentration lower after processing；Third is that foul gas ingredient is multiple
It is miscellaneous, often containing there are many pollutant components；Fourth is that the monitoring of odor pollution, analysis difficulty it is big, administer difficulty also than atmosphere dirt
It is bigger to contaminate difficulty of governance.
Summary of the invention
The present invention is directed to solve at least some of the technical problems in related technologies.For this purpose, of the invention
Purpose be to propose a kind of deodorant compositions that chemical property is stable, environmental-friendly, adaptable and a kind of deodorant and its
With fresh air, pet nursing, car care, sanitary ware nursing, toilet are nursed, the application in furniture nursing, rubbish deodorization.
To achieve the above object, according to the first aspect of the invention, deodorant compositions provided by the invention, the composition
Amino acid complex, paraformaldehyde and/or 3- first containing (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita
Oxygroup -4- hydroxy benzaldehyde, stabilizer, bleeding agent, antibacterial agent and antistatic agent, wherein (9Z, the 12R) -12- hydroxyl -9-
The amino acid complex of octadecenic acid zinc salt and/or mantoquita, paraformaldehyde and/or Vanillin, stabilization
Agent, bleeding agent, antibacterial agent and antistatic agent weight ratio be 1:0.1-4.0:0.05-0.5:0.05-0.5:0.001-0.2:
0.001-0.2.Preferably 1:0.5-2.0:0.1-0.2:0.1-0.2:0.01-0.1:0.01-0.1.
According to one embodiment of present invention, described (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita
Amino acid complex is the compound with such as following formula (I):
Wherein: M is selected from Cu2+, at least one of Zn2+；R be selected from-H ,-CH3 ,-CH2COOH ,-CH2CONH2 ,-
CH2CH2COOH ,-CH2CH2NH2 ,-CH2CH2CONH2 ,-CH2OH ,-CH (CH3) OH, 4- imidazoles methylene ,-
At least one of CH2CH2CH2NHC (NH2) NH.
According to one embodiment of present invention, the stabilizer is selected from citric acid, lactic acid, hydroxy ethylene diphosphonic acid, ammonia
Base trimethylene phosphonic, 2- phosphinylidyne butane -1,2,4- tricarboxylic acids, ethylenediamine tetramethylene phosphonic acid, hexamethylene diamine tetramethylene phosphine
At least one of acid and its their sodium, sylvite.
According to one embodiment of present invention, the bleeding agent be selected from HLB value be 6-15 alkyl alcohol ethoxylates and/
Or polypropylene glycol polyethylene glycol block polyether, sodium 2-ethylhexyl sulfate, N-Methyl pyrrolidone, in N- dodecyl azone
It is at least one.
According to one embodiment of present invention, the antibacterial agent is selected from alkyldimethylbenzylammonium chlorine (bromine) change ammonium, alkyl three
Methyl chloride (bromine) changes ammonium, double alkyl dimethyl chlorine (bromine) change at least one of ammonium, wherein the alkyl is containing 8-18 carbon
The straight chained alkyl of atom.
According to one embodiment of present invention, it is double to be selected from alkyl double hydroxyethyl ammonio methacrylate, alkyl for the antistatic agent
At least one in hydroxyethyl methyl nitrification ammonium, alkyl hydroxyethyl alkyl dimethyl ammonium chloride and alkyl hydroxyethyl dimethyl nitrification ammonium
Kind, wherein the alkyl is the straight chained alkyl containing 8-18 carbon atom.
According to the second aspect of the invention, deodorant provided by the invention, the deodorant contain deodorant compositions and
Water, the deodorant compositions composition are deodorant compositions as described above.
According to one embodiment of present invention, the content of the deodorization composition is 0.5~30 weight %.
According to the third aspect of the present invention, the invention proposes deodorant as described above protects in fresh air, pet
Reason, car care, sanitary ware nursing, toilet are nursed, the application in furniture nursing, garbage disposal.
Through the above technical solutions, deodorization of the present invention can synergistically play mutually work with each component in composition
With therefore, deodorization of the invention is stablized with composition chemical property, is environmental-friendly Multi-use deodorizing composition, is met
Environmentally protective requirement；Deodorization composition of the invention can use with fresh air, pet nursing, car care, sanitary ware nursing,
Toilet nursing, furniture are nursed, in rubbish deodorisation process, and wide adaptability has excellent deodoriging properties, and bacteriostasis property resists quiet
Electrical property, dosage is few, and treatment process is simple and effect is obvious, application easy to spread.
Specific embodiment
Below with reference to the specific embodiment technical solution that the present invention will be described in detail, to become apparent from, this is intuitively understood
The invention essence of invention.
Deodorization composition provided by the invention, the composition contain (9Z, 12R)-ricinoleic acid zinc salt
And/or amino acid complex, paraformaldehyde and/or the vanillic aldehyde of mantoquita, stabilizer, bleeding agent, antibacterial agent and antistatic agent.Its
In, amino acid complex, paraformaldehyde and/or the perfume (or spice) of (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita
Oxalaldehyde, stabilizer, bleeding agent, antibacterial agent and antistatic agent weight ratio be 1:0.1-4.0:0.05-0.5:0.05-0.5:
0.001-0.2:0.001-0.2, preferably 1:0.5-2.0:0.1-0.2:0.1-0.2:0.01-0.1:0.01-0.1.
Wherein, the amino acid complex of described (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita is deodorization
With the important composition ingredient in composition, it carries out complicated chemical bonding, to eliminate stench by the molecule with stink.
And (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita cannot obtain the work of deodorization due to insoluble in aqueous solution
Property.
The amino acid complex of (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita is with as follows
The compound of formula (I):
Wherein: M is selected from Cu2+, at least one of Zn2+；R be selected from-H ,-CH3 ,-CH2COOH ,-CH2CONH2 ,-
CH2CH2COOH ,-CH2CH2NH2 ,-CH2CH2CONH2 ,-CH2OH ,-CH (CH3) OH, 4- imidazoles methylene ,-
At least one of CH2CH2CH2NHC (NH2) NH, R preferably is selected from-H ,-CH2COOH ,-CH2CH2NH2 ,-CH2CH2CH2NHC
At least one of (NH2) NH,.
According to the present invention, used amino acid, can be with (9Z, 12R)-ricinoleic acid zinc salt and/or copper
Salt forms water-soluble complex compound, improves the deodorant activities of (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita.
Amino acid can be existing various synthesis or natural amino acid, such as alanine, valine, leucine, isoleucine, dried meat ammonia
Acid, phenylalanine, tryptophan, methionine, glycine, serine, threonine, cysteine, tyrosine, asparagine, paddy ammonia
Amide, lysine, arginine, histidine, aspartic acid, glutamic acid etc., preferably arginine, lysine, glycine and asparagus fern ammonia
At least one of acid.
According to the present invention, the paraformaldehyde and/or vanillic aldehyde are the important composition ingredient in deodorization composition, are passed through
Aldehyde radical in molecule is reacted with malodor molecules, to eliminate stink.It was found by the inventors of the present invention that currently preferred more
The amino-acid complex of polyformaldehyde and/or vanillic aldehyde and preferred (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita
Object has synergistic effect, can further increase the deodoriging properties of deodorization composition.
According to the present invention, the stabilizer is the important component of deodorization composition, can be to (9Z, 12R) -12- hydroxyl -
9- octadecenic acid zinc salt and/or mantoquita have the function of stable, can be selected from citric acid, lactic acid, hydroxy ethylene diphosphonic acid, ammonia
Base trimethylene phosphonic, 2- phosphinylidyne butane -1,2,4- tricarboxylic acids, ethylenediamine tetramethylene phosphonic acid, hexamethylene diamine tetramethylene phosphine
At least one of sour, iminodisuccinic acid and its their sodium, sylvite.
According to the present invention, the bleeding agent can improve the permeability of deodorant, improve the functioning efficiency of deodorization, and reduction connects
The surface tension of contacting surface is preferably selected from alkyl alcohol ethoxylates and/or polypropylene glycol polyethylene glycol block that HLB value is 6-15
Polyethers, sodium 2-ethylhexyl sulfate, N-Methyl pyrrolidone, at least one of N- dodecyl azone.
According to the present invention, the antibacterial agent can inhibit to produce the breeding of smelly bacterium algae, reduce the generation of stink, preferably be selected from alkyl two
Methylbenzyl chlorine (bromine) changes ammonium, alkyl trimethyl chlorine (bromine) changes ammonium, double alkyl dimethyl chlorine (bromine) change at least one of ammonium,
Described in alkyl be the straight chained alkyl containing 8-18 carbon atom.Such as common dodecyl alkyldimethylbenzylammonium chlorine in the market
(bromine) changes ammonium, trimethyl chlorine (bromine) changes ammonium, double decyl alkyl dimethyl chlorine (bromine) change ammonium etc..
According to the present invention, the antistatic agent is selected from alkyl double hydroxyethyl ammonio methacrylate, alkyl double hydroxyethyl methyl nitre
It is acidified at least one of ammonium, alkyl hydroxyethyl alkyl dimethyl ammonium chloride and alkyl hydroxyethyl dimethyl nitrification ammonium, wherein described
Alkyl be the straight chained alkyl containing 8-18 carbon atom.
According to the present invention, the deodorization composition can also contain low-carbon alcohols.The low-carbon alcohols mainly play the work of solvent
With, each component of deodorization composition can be promoted more uniformly to mix, so that deodorization performance is preferably played, because
This, does not require the dosage of the low-carbon alcohols particularly, as long as each component of deodorization composition can be made sufficiently to dissolve
?.Such as ethyl alcohol, ethylene glycol, propylene glycol etc..
According to the present invention, the deodorization composition can be obtained by existing various methods, such as can will be formed
The raw material of the deodorization composition according to aforementioned ratio be uniformly mixed and be made, therefore the step of present invention is to the mixing with
Condition is without particular/special requirement.For convenience of using and each component being promoted to be uniformly mixed, each component is mixed according to the above mentioned proportion it
Afterwards, a certain amount of dilution solvent (preferably water) can also be added, it is standby that deodorization with composition is configured to certain density medicament
With.
It is provided by the invention to air, pet, automobile interior decoration, sanitary ware, toilet, furniture, rubbish etc. carry out the side of deodorization
Method includes being sprayed onto deodorization on space and equipment to be processed with mist, and the deodorization contains above-mentioned deodorization group of the invention
Close object and water.
In the present invention, the content of the deodorization composition can be the amount of this field routine, it is preferable that with the deodorization
On the basis of the total weight of agent, the dosage of deodorization composition is 0.5-30 weight %.It should be noted that opposite not doing
In the case where explanation, the dosage of deodorization composition only relates to the weight of component (effective component) in addition to the solvents in the present invention
Amount.
The present invention will be described in detail by way of examples below.
In following embodiment, synthesis example 1-5 is used to illustrate (9Z, 12R)-ricinoleic acid zinc and/or copper
The synthesis of amino acid complex, embodiment 1-7 deodorization composition and preparation method thereof." effective content " used in embodiment
Refer to that the weight of the component in addition to solvent accounts for the percentage of total solution weight；The reagent used in embodiment and comparative example is as follows
It is shown:
(9Z, 12R)-ricinoleic acid zinc salt, (9Z, 12R)-ricinoleic acid mantoquita, smart ammonia
Acid, lysine, glycine, aspartic acid, citric acid, lactic acid, sodium 2-ethylhexyl sulfate, N-Methyl pyrrolidone, N- 12
Alkyl azone, paraformaldehyde, Vanillin (being above AR, Sinopharm Chemical Reagent Co., Ltd.),
Hydroxy ethylene diphosphonic acid sodium, aminotrimethylenephosphonic acid sodium, 2- phosphinylidyne butane -1,2,4- sodium tricarboxylate, ethylenediamine tetraacetic are sub-
Methylphosphonic acid sodium, hexamethylene diamine tetramethylene phosphonic acid sodium (being above industrial goods, the calm and peaceful water process Co., Ltd in Shandong), HLB value
Alkyl alcohol ethoxylates (such as trade name MOA-7, MOA-9), polypropylene glycol polyethylene glycol block polyether (such as quotient for 6-15
The name of an article is L61, L64), dodecyl dimethyl benzyl chloride (bromine) changes ammonium, Cocoalkyl double hydroxyethyl ammonio methacrylate, cocounut oil alkane
Base double hydroxyethyl methyl nitrification ammonium, Cocoalkyl hydroxyethyl dimethyl ammonium chloride and Cocoalkyl hydroxyethyl dimethyl nitrification
Ammonium (being above industrial goods, Jiangsu Hai'an petrochemical plant)
Synthesis example 1
The synthesis of (9Z, 12R)-ricinoleic acid zinc salt arginine complex:
In sub, the thermometer equipped with electromagnetic agitation, the three-necked flask of the 250ml of return pipe, it is added 0.01mol (6.603g)
(9Z, 12R)-ricinoleic acid zinc salt, the arginine of 0.01mol (1.742g), 100ml distilled water, in 70-80
It is reacted 24-48 hours at DEG C, reaction solution gradually becomes uniform single liquid phase by solid-liquid two-phase, is evaporated under reduced pressure out moisture, dry
Obtain white solid (9Z, 12R)-ricinoleic acid zinc salt arginine complex, referred to as A-I.
Synthesis example 2 is according to 1 step of synthesis example, and in addition to replacing arginine with lysine, product is referred to as A-II.
Synthesis example 3 is according to 1 step of synthesis example, and in addition to replacing arginine with glycine, product is referred to as A-III.
Synthesis example 4 is according to 1 step of synthesis example, in addition to replacing zinc salt with (9Z, 12R)-ricinoleic acid mantoquita,
Product is referred to as B-I.
Synthesis example 5 is according to 4 step of synthesis example, and in addition to replacing arginine with aspartic acid, product is referred to as B-II.
Embodiment 1
Weigh 1.0g A-I, 1.25g paraformaldehyde, 0.15g hydroxy ethylene diphosphonic acid sodium, 0.15g MOA-7,0.05g
Dodecyl benzyl dimethyl ammonium chloride, 0.05g Cocoalkyl hydroxyethyl dimethyl nitrification ammonium, is finally diluted with distilled water into
30% solution, stirs evenly.
Embodiment 2
Weigh 1.0g A-I, 0.25g Vanillin, 0.25g paraformaldehyde, 0.2g lactic acid, 0.2g
N-Methyl pyrrolidone, 0.1g dodecyl dimethyl benzyl ammonium bromide, 0.1g Cocoalkyl double hydroxyethyl methyl nitrification ammonium,
It is finally diluted with distilled water into 30% solution, is stirred evenly.
Embodiment 3
Weigh 1.0g B-I, 2.0g Vanillin, 0.1g citric acid, 0.1g 2- ethylhexyl sulphur
Sour sodium, 0.01g dodecyl benzyl dimethyl ammonium chloride, 0.01g Cocoalkyl double hydroxyethyl ammonio methacrylate, 3.0g ethyl alcohol,
It is finally diluted with distilled water into 30% solution, is stirred evenly.
Embodiment 4
Weigh 0.5g A-II, 0.5g B-I, 3.0g paraformaldehyde, 1.0g Vanillin,
0.05g2- phosphinylidyne butane -1,2,4- sodium tricarboxylate, 0.05g L64,0.001g dodecyl dimethyl benzyl ammonium bromide,
0.2g Cocoalkyl hydroxyethyl dimethyl ammonium chloride, is finally diluted with distilled water into 30% solution, stirs evenly.
Embodiment 5
Weigh 0.2g A-I, 0.8g B-II, 0.1g paraformaldehyde, 0.5g aminotrimethylenephosphonic acid sodium, 0.5g N- ten
Dialkyl group azone, 0.2g dodecyl dimethyl benzyl ammonium bromide, 0.001g Cocoalkyl double hydroxyethyl methyl nitrification ammonium, most
It is diluted with distilled water into 30% solution afterwards, stirs evenly.
Embodiment 6
Weigh 0.8g A-II, 0.2g B-I, 3.0g Vanillin, 0.3g ethylenediamine tetramethylene
Alendronate, 0.075g MOA-9,0.15g dodecyl benzyl dimethyl ammonium chloride, 0.15g Cocoalkyl double hydroxyethyl methyl chloride
Change ammonium, 5.0g ethyl alcohol is finally diluted with distilled water into 30% solution, stirs evenly.
Embodiment 7
Weigh 0.5A-I, 0.25g A-III, 0.25g B-I, 0.3g paraformaldehyde, 0.075g hexamethylene diamine tetramethylene phosphine
Sour sodium, 0.4g L61,0.005g dodecyl benzyl dimethyl ammonium chloride, 0.005g Cocoalkyl double hydroxyethyl methyl nitrification
Ammonium is finally diluted with distilled water into 30% solution, stirs evenly.
Comparative example 1
Deodorization composition is prepared according to embodiment 1, unlike, with (9Z, 12R)-ricinoleic acid zinc
Salt replaces complex compound A-I.
Comparative example 2
Deodorization composition is prepared according to embodiment 1, unlike, with (9Z, 12R)-ricinoleic acid copper
Salt replaces A-I.
Comparative example 3
Deodorization composition is prepared according to embodiment 1, unlike, do not use A-I.
Comparative example 4
Deodorization composition is prepared according to embodiment 1, unlike, do not use paraformaldehyde.
Comparative example 5
Deodorization composition is prepared according to embodiment 1, unlike, do not use MOA-7.
Test case 1
The deodoriging properties of embodiment 1-7 and comparative example 1-5 resulting deodorization composition are evaluated respectively, wherein
Odor eliminating rate is higher, illustrates that the deodoriging properties of deodorization composition are higher.
In table 1, "-" indicates odor removal efficient of the deodorization composition in the stink made from undetermined.
Test condition: the concentration of odorant is 100mg/L, is injected in the Taide pulling bag of 5L, and quantitative deodorization is injected
Composition, after 1 hour, remaining odorant concentration is analyzed in sampling.
Deodorizing rate %=100 × (concentration after odorant initial concentration-odorant test)/odorant starting is dense
Degree.
Elimination factor % of 1 odorant of table after 1 hour
Can be seen that deodorization of the invention composition from the evaluation experimental result of table 1 has good deodoriging properties, adds
After adding deodorization composition of the invention, 90%, therefore, deodorization of the invention are greater than to the stench elimination factor of representative malodor substance
The requirement eliminated with foul odour of the composition to a variety of odorants.
From the above it can also be seen that deodorization of the invention is low using concentration with composition, sour foul odour is being handled
When only need to add 0.5-5 weight % relative to total weight, good deodoriging properties can be obtained.
In addition, by embodiment 1 as can be seen that deodorization composition of the invention compared with the measurement result of comparative example 1-5
Each ingredient can play the deodorization preferably cooperateed with when being used cooperatively with specific quantity.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail within the scope of the technical concept of the present invention can be with various simple variants of the technical solution of the present invention are made, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case where shield, can be combined in any appropriate way, in order to avoid unnecessary repetition, the present invention to it is various can
No further explanation will be given for the combination of energy.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (9)
1. a kind of deodorant compositions, which is characterized in that the composition contains (9Z, 12R)-ricinoleic acid zinc salt
And/or amino acid complex, paraformaldehyde and/or the Vanillin of mantoquita, stabilizer, bleeding agent, antibacterial
Agent and antistatic agent, wherein the amino acid complex of (9Z, 12R)-ricinoleic acid zinc salt and/or mantoquita,
Paraformaldehyde and/or Vanillin, stabilizer, bleeding agent, antibacterial agent and antistatic agent weight ratio be 1:
0.1-4.0:0.05-0.5:0.05-0.5:0.001-0.2:0.001-0.2.
2. deodorant compositions according to claim 1, which is characterized in that (9Z, the 12R) -12- hydroxyl -9- octadecylene
The amino acid complex of sour zinc salt and/or mantoquita is the compound with such as following formula (I):
Wherein: M is selected from Cu2+, at least one of Zn2+；R be selected from-H ,-CH3 ,-CH2COOH ,-CH2CONH2 ,-
CH2CH2COOH ,-CH2CH2NH2 ,-CH2CH2CONH2 ,-CH2OH ,-CH (CH3) OH, 4- imidazoles methylene ,-
At least one of CH2CH2CH2NHC (NH2) NH.
3. deodorant compositions according to claim 1, which is characterized in that the stabilizer is selected from citric acid, lactic acid, hydroxyl
Ethylidene diphosphonic acid, aminotrimethylenephosphonic acid, 2- phosphinylidyne butane -1,2,4- tricarboxylic acids, ethylenediamine tetramethylene phosphonic acid, oneself
At least one of diamines tetramethylene phosphonic acid and its their sodium, sylvite.
4. deodorant compositions according to claim 1, which is characterized in that the bleeding agent is selected from the alkane that HLB value is 6-15
Base alcohol polyoxyethylene ether and/or polypropylene glycol polyethylene glycol block polyether, sodium 2-ethylhexyl sulfate, N-Methyl pyrrolidone,
At least one of N- dodecyl azone.
5. deodorant compositions according to claim 1, which is characterized in that the antibacterial agent is selected from alkyldimethylbenzylammonium chlorine
Change ammonium, Alkyl dimethyl benzyl ammonium bromide, alkyl trimethyl ammonium chloride, alkyl trimethyl ammonium bromide, double alkyl dimethyl chlorinations
At least one of ammonium, double alkyl dimethyl ammonium bromides, wherein the alkyl is the straight chained alkyl containing 8-18 carbon atom.
6. deodorant compositions according to claim 1, which is characterized in that the antistatic agent is selected from alkyl double hydroxyethyl first
Ammonium chloride, alkyl double hydroxyethyl methyl nitrification ammonium, alkyl hydroxyethyl alkyl dimethyl ammonium chloride and alkyl hydroxyethyl dimethyl nitre
It is acidified at least one of ammonium, wherein the alkyl is the straight chained alkyl containing 8-18 carbon atom.
7. a kind of deodorant, the deodorant contains deodorant compositions and water, which is characterized in that the deodorant compositions combination
Object is deodorant compositions described in any one in claim 1-6.
8. deodorant according to claim 7, which is characterized in that the content of the deodorization composition is 0.5~30 weight
Measure %.
9. deodorant described in any one of claim 7-8 with fresh air, pet nursing, car care, sanitary ware nursing,
Toilet is nursed, the application in furniture nursing, garbage disposal.
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| TWI626058B (en) * | 2017-07-18 | 2018-06-11 | Guo jin long | Dye / perm agent deodorant preparation and deodorant hair conditioner |
| CN108159865A (en) * | 2017-12-20 | 2018-06-15 | 苏州禾川化学技术服务有限公司 | A kind of environment-friendly deodorant agent containing active zinc atom |
| CN109173556A (en) * | 2018-09-25 | 2019-01-11 | 深圳市爱康泉水处理服务有限公司 | Environment-friendly type deodorant composition and deodorant and its application |
| CN111345296A (en) * | 2018-12-21 | 2020-06-30 | 南京科翼新材料有限公司 | Glyphosate aqueous agent synergistic auxiliary agent with formaldehyde removing function and preparation method thereof |
| CN111349113B (en) * | 2018-12-21 | 2023-06-30 | 南京科翼新材料有限公司 | Composition capable of removing formaldehyde in glyphosate mother liquor and preparation method thereof |
| CN110810434A (en) * | 2019-08-01 | 2020-02-21 | 广州博能能源科技有限公司 | Odor-removing and sterilizing AB agent |
| CN110624388B (en) * | 2019-10-28 | 2022-04-15 | 深圳市爱康泉水处理服务有限公司 | Deodorant composition, deodorant and application thereof |
| CN112827471B (en) * | 2020-12-29 | 2023-10-31 | 南京凯创微锌环境技术有限公司 | Preparation method of deodorant for sheep farm |
| CN114452430A (en) * | 2022-03-11 | 2022-05-10 | 深圳市爱康泉水处理服务有限公司 | Air filter screen, air filter device and manufacturing method |
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| CN101036801A (en) * | 2005-11-18 | 2007-09-19 | 施拖克豪森有限公司 | Deodorizing super-absorbent composition |
| CN104448540A (en) * | 2013-09-21 | 2015-03-25 | 青岛博研达工业技术研究所(普通合伙) | Multifunctional polypropylene material |
| CN105647060A (en) * | 2016-02-03 | 2016-06-08 | 轩脉家居科技（上海）有限公司 | Medical antibacterial low-odor PVC plastics and preparation method thereof |
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| CN101036801A (en) * | 2005-11-18 | 2007-09-19 | 施拖克豪森有限公司 | Deodorizing super-absorbent composition |
| CN104448540A (en) * | 2013-09-21 | 2015-03-25 | 青岛博研达工业技术研究所(普通合伙) | Multifunctional polypropylene material |
| CN105647060A (en) * | 2016-02-03 | 2016-06-08 | 轩脉家居科技（上海）有限公司 | Medical antibacterial low-odor PVC plastics and preparation method thereof |
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