CN106614717A - Composite herbicide - Google Patents
Composite herbicide Download PDFInfo
- Publication number
- CN106614717A CN106614717A CN201610866247.0A CN201610866247A CN106614717A CN 106614717 A CN106614717 A CN 106614717A CN 201610866247 A CN201610866247 A CN 201610866247A CN 106614717 A CN106614717 A CN 106614717A
- Authority
- CN
- China
- Prior art keywords
- amino acid
- ammonium
- glufosinate
- compound herbicide
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a composite herbicide, comprising glufosinate ammonium, amino acids and a pesticide-acceptable aid; the mass ratio of glufosinate ammonium to amino acids is 1:1 to 100:0.5, and the weight sum of glufosinate ammonium and amino acids accounts for 5-95% by weight of the herbicide. Compared with single agents of glufosinate ammonium, the composite herbicide can provide a significant increase of 5-15% in herbicidal bioactivity, and is suitable for controlling annual and perennial dicotylous and gramineous weeds and other weeds in orchards, grape gardens, potato fields, and uncultivated lands.
Description
Technical field
The present invention relates to biochemical pesticide technical field, and in particular to a kind of compound herbicide, can be used for orchard, grape
Garden, bare place weeding, it can also be used to prevent and kill off to potato annual or perennial dicotyledonous and grassy weed and nutgrass flatsedge etc..
Background technology
Glufosinate-ammonium also known as careless fourth phosphine, are a kind of organophosphorus herbicides of non-selective foliage-spray, belong to organic phosphates weeding
Agent, is glutamine synthetase inhibitor, non-selective contact weedicide.Have certain systemic action, can be used for orchard, vineyard,
Bare place weeding, can prevent and kill off annual or perennial dicotyledonous and grassy weed and nutgrass flatsedge etc., such as rat-tail amur foxtail, lady's-grass,
Barnyard grass, green bristlegrass, wild wheat, wild corn, orchardgrass, fescue grass, bent awns hairgrass, yorkshire fog grass, rye grass, reed, annual bluegrass, wild oat,
Bromegrass, clearvers, benbie, deaf nettle, black nightshade, chickweed, quackgrass, bent grass, stroke sub- grass, field scorpion grass, dog tooth
Root, Amaranthus retroflexus etc..Usage amount be regarded as thing, weeds and it is different, it is 1～2kg or more some more that glufosinate-ammonium per hectare is used alone, and is such as prevented and kill off
The raspberry and fern crop of forest and alpine pasture.Usage amount is 1.5～20kg/hm2。
Amino acid, particularly L-type amino acid can promote photosynthesis of plant, accelerate nutrition transhipment and accumulate, and strengthen plant
The anti-adversity ability such as cold-resistant, drought resisting, disease-resistant.To plant rooting, growth, reproduction and result, the growing stage such as expand and have significantly rush
Enter effect.
The content of the invention
Present invention aim at providing a kind of efficient compound herbicide and application thereof.
In in order to solve the problems, such as currently available technology, the technical scheme that first aspect present invention is provided is：One kind is compound
Type herbicide, it is made up of acceptable auxiliary agent in glufosinate-ammonium, amino acid and agricultural chemicals, the glufosinate-ammonium：The mass ratio of amino acid
For 1：5～100：0.5.
In a preferred technical scheme of the invention, the glufosinate-ammonium：The mass ratio of amino acid is 1：1～100：0.5.
In a preferred technical scheme of the invention, the glufosinate-ammonium：The mass ratio of amino acid is 10：1.
In an of the invention preferred technical scheme, the weight hundred of the weight summation of glufosinate-ammonium and amino acid in herbicide
Divide than being 5～95%.
In an of the invention preferred technical scheme, the weight hundred of the weight summation of glufosinate-ammonium and amino acid in herbicide
Divide than being 51～95%.
In a preferred technical scheme of the invention, the amino acid is L-type amino acid.
In an of the invention preferred technical scheme, the amino acid is selected from aliphatic amino acid, aromatic amino acid, miscellaneous
Ring race amino acid, heterocyclic imino acid.
In an of the invention preferred technical scheme, the compound herbicide be soluble powder, wettable powder, can
Dissolubility granula, water-dispersible granules, tablet.
In an of the invention preferred technical scheme, the auxiliary agent is selected from wetting agent, dispersant, defoamer, disintegrant, viscous
The mixing of one or more in knot agent, filler.
Described filler is selected from kaolin, precipitated calcium carbonate, ammonium sulfate (potassium, sodium), diammonium hydrogen phosphate (potassium, sodium), chlorination
In ammonium (potassium, sodium), ammonium nitrate (potassium, sodium), white carbon, sodium carbonate, sodium acid carbonate or sodium tripolyphosphate more than any one or both
Combination.
Second aspect present invention provide technical scheme be：A kind of purposes of compound herbicide, for carrying out to farmland
Spray, pesticide-clay mixture, spread fertilizer over the fields, the weeding of ditch spread.
Described auxiliary agent is selected from organic silicon polyether class, ox ester amine APEO, alkyl naphthalene sulfonic acid condensation polymer sodium salt, poly- carboxylic
Hydrochlorate and condensation product, aliphatic amine polyoxyethylene ether, lignosulfonates, ethylene oxide-propylene oxide block copolymer, alkyl phenol
Polyoxyethylene poly-oxygen propylene aether, polyoxyethylene fatty acid, AEO alkyl naphthalene sulfonic acid formaldehyde condensation products, dodecane
Combination in base sodium sulphate, polyethylene glycol, carboxymethylcellulose calcium or soluble starch more than any one or both.
Product of the present invention can be provided in the form of finished product preparation, and insecticide-applying way can be sprayed, pesticide-clay mixture, spread fertilizer over the fields, ditch spread
Etc. various.
Heretofore described amino acid according to structure include aliphatic amino acid, aromatic amino acid, heterocyclic amino acid,
Heterocyclic imino acid.The aliphatic amino acid is selected from third, figured silk fabrics, bright, different bright, egg, asparagus fern, paddy, bad, smart, sweet, silk, Soviet Union, partly
Guang, asparagine, glutamine；The aromatic amino acid includes phenylalanine, tyrosine, the heterocyclic amino acid group ammonia
Acid, tryptophan, the heterocyclic imino acid is proline.
To realize above-mentioned purpose of the present invention, the present invention provides a kind of effective ingredient by glufosinate-ammonium and the composition of amino acid,
Glufosinate-ammonium and amino acid weight summation percentage by weight in the composition is 5～95%, and preferred weight percent glufosinate-ammonium is
50～90%, amino acid is 1～20%；Glufosinate-ammonium：Amino acid=1：10～100：0.5 mass ratio compounding, is preferably in a proportion of
Glufosinate-ammonium：Amino acid=1：1～100：0.5 mass ratio compounding, it is optimal for glufosinate-ammonium：Amino acid=10：1, remaining is agriculture
Allow to use and acceptable auxiliary element in medicine.
The efficient compound herbicide of the present invention, can be used to prevent and treat orchard, vineyard, bare place weeding, it can also be used to horse
Prevent and kill off annual or perennial dicotyledonous and grassy weed and nutgrass flatsedge etc. bell potato.
Compared with prior art, the advantage of compound herbicide of the invention is：
1. weeding biologically active 5-15% can be significantly improved with comparing using glufosinate-ammonium single dose；
2. two kinds of active ingredient compoundings, reduce cost and the pollution to environment.
The compound herbicide of the present invention compounds in amino acid and glufosinate-ammonium, because amino acid can promote plant growth, strengthens
Plant Uptake and translocation, makes that glufosinate-ammonium is more faster to be absorbed by weeds, so as to significantly increase weeds poisoning speed, improves medicine
Effect.
Specific embodiment
Such scheme is described further below in conjunction with specific embodiment.It should be understood that these embodiments are for illustrating
The present invention and be not limited to limit the scope of the present invention.The implementation condition adopted in embodiment can be done according to the condition of concrete producer
Further adjustment, not marked implementation condition is usually the condition in normal experiment.
Introduce and summarize
The present invention by way of example rather than provides the mode of restriction illustrating.It should be noted that in present disclosure
Described " one " or " one kind " embodiment is not necessarily referring to same specific embodiment, and refers at least a kind of.
Various aspects of the invention are described below.However, as will be readily apparent to one of skill in the art, can
Only some or all of aspects of the invention are implementing the present invention.For purposes of illustration, be given herein specific numbering, material and
Configuration, enables one to thoroughly understand the present invention.However, for those of skill in the art are evident that,
The present invention can be implemented without the need for concrete details.In other examples, not make, the present invention is obscure to be omitted or simplified many institutes
Known feature.
By according to the reactant of type species illustrating various embodiments.To show for those of skill in the art and
It is clear to, the present invention can be implemented using any number of different types of reactant, and is more than those for the purpose of illustration
And the reactant for being given here.Additionally, being also evident that, the invention is not limited in that any specific mixing is shown
Example.
Embodiment 1：Glufosinate-ammonium and amino acid compound and the synergy that barnyard grass is killed are determined
Test method：In man-made chamber case, 25 × 25 cm dishes are put into, select and remain in every culture dish 100 plants and grow
Normal 2 leaf phase barnyard grass, adds a small amount of sterilized water, keeps culture 3 days under the conditions of normal illumination, 25 DEG C of constant temperature, 50% constant humidity, often
Finally select and remain 50 plants in culture dish and grow normal barnyard grass, it is standby.
Test scope：Glufosinate-ammonium：Amino acid=100：0.5～1：10 setting 1 glufosinate-ammonium single dose, 7 glufosinate-ammonium+L-types
8 groups of amino acid different proportion, carrying out variable concentrations gradient carries out spraying treatment (diluent is distilled water) to barnyard grass, another distillation
Water blank, each process sprays 2 culture dishes, and checkout facility effect is observed after 7 days, completely withered and yellow with more than two leaves
It is dead for plant, calculate the death rate and corrected mortality.
According to survey data, the corrected mortality of each process is calculated.And adopt the abundant methods of Sun Yun with reference to NY/T1154.1-2006
Calculate the co-toxicity coefficient (CTC values) of mixture.Co-toxicity coefficient (CTC values) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC values)
≤ 80 show as antagonism；80<Co-toxicity coefficient (CTC values)<120 show as summation action.Measurement result is shown in Table one.
Table one：The synergy that glufosinate-ammonium and amino acid different ratio are killed to barnyard grass is determined
According to glufosinate-ammonium：Amino acid=100：0.5～1：10 mass ratio determines and the co-toxicity coefficient that barnyard grass is killed is determined
Show：
1. glufosinate-ammonium is worked as：Amino acid=100：0.5～1：CTC value >=120 are killed to barnyard grass when 1, glufosinate-ammonium and ammonia is illustrated
Base acid compounding has synergistic effect, optimal glufosinate-ammonium to the synergy that barnyard grass is killed：Amino acid=10：1 show it is excellent
Preventive effect, illustrate that glufosinate-ammonium and amino acid compounding have reasonability and feasibility；
2. but with amino acid ratio increase on the contrary preventive effect declines, and shows amino acid effect increase, has protection to plant
Effect.
Embodiment 2：The preparation of the amino acid wettable powder of 59% glufosinate-ammonium 1% and water dispersible granules
Weigh 59 grams of glufosinate-ammonium, L-type amino acid/11 gram, 6 grams of alkyl naphthalene sulfonic acid condensation polymer sodium salt, polycarboxylate condensation product 2
Gram, 3 grams of white carbon, kaolin trim is to 100 grams.Above-mentioned material is well mixed, 325 mesh are crushed in airslide disintegrating mill with
On, the amino acid wettable powder of 59% glufosinate-ammonium 1% is obtained.
Above-mentioned powder is added in kneader, adds 12 grams of stirrings of water to mediate 15 minutes, use rotary pelleting machine extruder grain,
Wet grain is obtained the amino acid water dispersible granules of 59% glufosinate-ammonium 1% less than 1.5% in 80 DEG C of dryings to moisture.
Embodiment 3：The preparation of the amino acid solvent accessibility pulvis of 88% glufosinate-ammonium 2% and granula
Weigh 88 grams of glufosinate-ammonium, 2 grams of L-type amino acid, 1 gram of organic silicon polyether, 4 grams of ox ester amine APEO, carboxymethyl
1 gram of cellulose, 0.5 gram of soluble starch, ammonium sulfate trim are to 100 grams.Above-mentioned material is well mixed, in airslide disintegrating mill
It is crushed to more than 325 mesh, as by the amino acid solvent accessibility pulvis of 88% glufosinate-ammonium 2%.
Above-mentioned powder is added in kneader, adds 10 grams of stirrings of water to mediate 15 minutes, use rotary pelleting machine extruder grain,
Wet grain is obtained the amino acid solvent accessibility granula of 88% glufosinate-ammonium 2% less than 1.5% in 80 DEG C of dryings to moisture.
Embodiment 4：The preparation of the amino acid dry suspending agent of 88% glufosinate-ammonium 2%
Weigh 88 grams of glufosinate-ammonium, 2 grams of L-type amino acid, 0.5 gram of organic silicon polyether, 5 grams of lignosulfonates, polyethylene glycol 1
Gram, kaolin trim is to 100 grams.Add 80 grams of water.Above-mentioned material is well mixed, it is finely ground to 5um in sand mill, in spraying
Drying machine spraying granulation obtains the amino acid dry suspending agent of 88% glufosinate-ammonium 2%.
Embodiment 5：The preparation of the amino acid tablet of 45% glufosinate-ammonium 5%
Weigh 45 grams of glufosinate-ammonium, 5 grams of L-type amino acid, 2 grams of calcium dodecyl benzene sulfonate, alkyl polyoxyethylene ether butanedioic acid
4 grams of fat sodium sulfonate, 2 grams of Fatty alcohol polyoxyethylene polyoxypropylene ether, 15 grams of sodium tripolyphosphate, 5 grams of white carbon, kaolin trim are extremely
100 grams.Above-mentioned material is well mixed, is crushed to more than 150 mesh with beater grinder, 45% careless ammonium is obtained with tabletting machine
The amino acid tablet of phosphine 5%.
The embodiment of the present invention is used to prevent and kill off the test of bare place weeds, and total preventive effect is investigated after 15 days, as a result shows that effect is higher than
Commercially available aqua, see the table below：
Table two：Prevention effect of the different preparations to weeds
Result of the test shows：The composition pesticide of the present invention has obvious synergistic effect, can reduce dosage, reduce into
Originally the pollution to environment, is reduced.
The above specific embodiment is only the preferred embodiment of the present invention, it is noted that for the art
For those of ordinary skill, under the premise without departing from the principles of the invention, some improvement or replacement can also be made, these improvement
Or replacement should also be as being considered as protection scope of the present invention.
Claims (10)
1. a kind of compound herbicide, it is characterised in that it is made up of acceptable auxiliary agent in glufosinate-ammonium, amino acid and agricultural chemicals,
The glufosinate-ammonium：The mass ratio of amino acid is 1：5～100：0.5.
2. compound herbicide according to claim 1, it is characterised in that the glufosinate-ammonium：The mass ratio of amino acid is
1：1～100：0.5.
3. compound herbicide according to claim 1, it is characterised in that the glufosinate-ammonium：The mass ratio of amino acid is
10：1.
4. compound herbicide according to claim 1, it is characterised in that the weight summation of glufosinate-ammonium and amino acid is being removed
Percentage by weight in careless agent is 5～95%.
5. compound herbicide according to claim 1, it is characterised in that the amino acid is L-type amino acid.
6. compound herbicide according to claim 1, it is characterised in that the amino acid selected from aliphatic amino acid,
Aromatic amino acid, heterocyclic amino acid, heterocyclic imino acid.
7. compound herbicide according to claim 1, it is characterised in that the compound herbicide is soluble powder
Agent, wettable powder, soluble granula, water-dispersible granules, tablet.
8. compound herbicide according to claim 1, it is characterised in that the auxiliary agent selected from wetting agent, dispersant, disappear
The mixing of one or more in infusion, disintegrant, binding agent, filler.
9. compound herbicide according to claim 8, it is characterised in that described filler is selected from kaolin, lightweight carbon
Sour calcium, ammonium-potassium sulfate, ammonium sulfate sodium, diammonium hydrogen phosphate potassium, diammonium hydrogen phosphate sodium, ammonium chloride potassium, ammonium chloride sodium, potassium ammonium nitrate,
Combination in nitrope, white carbon, sodium carbonate, sodium acid carbonate or sodium tripolyphosphate more than any one or both.
10. the compound herbicide as described in claim 1-9 is used to spray farmland, pesticide-clay mixture, spreads fertilizer over the fields, the weeding of ditch spread
Purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610866247.0A CN106614717A (en) | 2016-09-30 | 2016-09-30 | Composite herbicide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610866247.0A CN106614717A (en) | 2016-09-30 | 2016-09-30 | Composite herbicide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106614717A true CN106614717A (en) | 2017-05-10 |
Family
ID=58854020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610866247.0A Pending CN106614717A (en) | 2016-09-30 | 2016-09-30 | Composite herbicide |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108271782A (en) * | 2018-03-12 | 2018-07-13 | 张轶翔 | A kind of technical method improving inner-adsorption conduction-type herbicide efficiency |
| WO2019007393A1 (en) * | 2017-07-06 | 2019-01-10 | Rhodia Operations | Pesticide compositions |
| WO2019006726A1 (en) * | 2017-07-06 | 2019-01-10 | Rhodia Operations | Herbicidal compositions |
| CN112167262A (en) * | 2020-11-11 | 2021-01-05 | 浙江新安化工集团股份有限公司 | Weeding composition and herbicide |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001060160A1 (en) * | 2000-02-16 | 2001-08-23 | Chemia S.P.A. | Herbicidal composition |
| CN1625337A (en) * | 2002-04-01 | 2005-06-08 | 瓦伦特生物科学公司 | Enhanced herbicide composition |
-
2016
- 2016-09-30 CN CN201610866247.0A patent/CN106614717A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001060160A1 (en) * | 2000-02-16 | 2001-08-23 | Chemia S.P.A. | Herbicidal composition |
| CN1625337A (en) * | 2002-04-01 | 2005-06-08 | 瓦伦特生物科学公司 | Enhanced herbicide composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019007393A1 (en) * | 2017-07-06 | 2019-01-10 | Rhodia Operations | Pesticide compositions |
| WO2019006726A1 (en) * | 2017-07-06 | 2019-01-10 | Rhodia Operations | Herbicidal compositions |
| CN110831439A (en) * | 2017-07-06 | 2020-02-21 | 罗地亚经营管理公司 | Pesticide composition |
| CN108271782A (en) * | 2018-03-12 | 2018-07-13 | 张轶翔 | A kind of technical method improving inner-adsorption conduction-type herbicide efficiency |
| CN112167262A (en) * | 2020-11-11 | 2021-01-05 | 浙江新安化工集团股份有限公司 | Weeding composition and herbicide |
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