CN106592324A - Release type glassine base paper and preparation method thereof - Google Patents

Release type glassine base paper and preparation method thereof Download PDF

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Publication number
CN106592324A
CN106592324A CN201611130902.2A CN201611130902A CN106592324A CN 106592324 A CN106592324 A CN 106592324A CN 201611130902 A CN201611130902 A CN 201611130902A CN 106592324 A CN106592324 A CN 106592324A
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parts
glassine paper
paper
pulp
mould release
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张日龙
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/06Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30Defibrating by other means
    • D21B1/34Kneading or mixing; Pulpers
    • D21B1/345Pulpers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10Bleaching ; Apparatus therefor
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36Inorganic fibres or flakes
    • D21H13/46Non-siliceous fibres, e.g. from metal oxides
    • D21H13/50Carbon fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/30Alginic acid or alginates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675Oxides, hydroxides or carbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2481/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2481/02Polythioethers; Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Paper (AREA)

Abstract

The invention discloses release type glassine base paper, which is made from glassine base paper and a release type film, wherein the glassine base paper is prepared from the following raw materials in parts by weight: 100 to 130 parts of cotton pulp, 80 to 110 parts of reed pulp, 70 to 90 parts of gulfweed, 40 to 46 parts of sodium alginate, 34 to 46 parts of carboxymethyl chitosan, 12 to 18 parts of aluminum nitride, 11 to15 parts of boron nitride, 9 to 13 parts of silicon carbide, 15 to 23 parts of magnesium oxide and 21 to 35 parts of carbon fiber; the release type film is prepared from the following raw materials in parts by weight: 26 to 38 parts of silica gel, 10 to 16 parts of nitrogen, 11 to 15 parts of acrylate, 14 to 20 parts of polyethylene, 11 to 15 parts of titanium dioxide and 9 to 11 parts of polyphenyl thioether. Such release type glassine base paper is environment-friendly in materials, is good in heat resistance and aging resistance, and has excellent waterproof and antibacterial effects at the same time.

Description

A kind of release glassine paper and preparation method thereof
Technical field
The present invention relates to a kind of release glassine paper and preparation method thereof.
Background technology
Lattice Racine paper is a kind of new body paper formed by multiple working procedure processing, and it is relatively common in industrial paper One kind, is to make bar coded sticker, adhesive sticker, adhesive tape or have a common used material of adhesive industrial goods, particularly suitable rotation and Flat bed die, it is also possible to for the outer package of the industries such as some food, medicine, now many things are all by way of postal delivery It is traded, more particularly needs the article for using wrapping paper, usually can causes because of a variety of causes during postal delivery Damage, particularly some rainwater weather, it is impossible to meet the demand of user.
Developed country forms series generally Ge Laxin paper for industries such as medicine, packaging for foodstuff and automatic labelings Product, Technical comparing is ripe.And in China, this paper more than 85% is relied on from foreign import before 2005, product price is high, Less, the plastic-coated leaching membrane paper of low price when at that time the country commonly uses, domestic only a small amount of enterprise starts the paper for imitating foreign countries to usage amount Sample is produced, and product specification is not high, without unified product standard.In recent years, the development with national economy and people's people's livelihood The flat raising of running water, the dynamics of Environmental protection is increasingly increased, and the adhesive sticker base stock of original employing film plastic-coated is due to it Not recuperability, products export is obstructed, and the adhesive sticker base stock of film plastic-coated is forced progressively to withdraw from the market, and the substitute is environmental protection The callable lattice Racine paper of type.As domestic usage amount is in rapid growth situation year by year, Development and Production producer also increases increasingly, And produce to large-scale production development from small processing.
But, existing glassine paper has that evenness is poor, cockling is whole, and cross direction ration is uneven, and water resistant, anti- The problems such as oily poor performance.
The content of the invention
In view of this, it is an object of the present invention to provide a kind of material environment friendly, heat resistance and ageing resistace are good, while having The release glassine paper of excellent water-proof antibiotic effect.
In order to solve above-mentioned technical problem, the technical scheme is that:A kind of release glassine paper, it is former by Ge Laxin Paper and mould release membrance are made, and the glassine paper includes the raw material of following weight portion:Cotton pulp 100-130 parts, reed pulp 80-110 part, Alga Sgrgassi Enervess 70-90 parts, sodium alginate 40-46 parts, carboxymethyl chitosan 34-46 parts, aluminium nitride 12-18 parts, boron nitride 11-15 Part, carborundum 9-13 parts, magnesium oxide 15-23 parts and carbon fiber 21-35 parts, the mould release membrance includes the raw material of following weight portion: Silicon dioxide gel 26-38 parts, nitrogen 10-16 parts, acrylate 11-15 parts, polyethylene 14-20 parts, titanium dioxide 11-15 parts With polyphenylene sulfide 9-11 parts.
Further, the release glassine paper is made up of glassine paper and mould release membrance, the glassine paper bag Include the raw material of following weight portion:130 parts of cotton pulp, 80 parts of reed pulp, 70 parts of Alga Sgrgassi Enervess, 40 parts of sodium alginate, carboxymethyl chitosan 34 Part, 12 parts of aluminium nitride, 11 parts of boron nitride, 9 parts of carborundum, 15 parts of magnesium oxide and 21 parts of carbon fiber, the mould release membrance includes following The raw material of weight portion:26 parts of silicon dioxide gel, 10 parts of nitrogen, 11 parts of acrylate, 14 parts of polyethylene, 11 parts of titanium dioxide and 9 parts of polyphenylene sulfide.
Further, the release glassine paper is made up of glassine paper and mould release membrance, the glassine paper bag Include the raw material of following weight portion:100 parts of cotton pulp, 110 parts of reed pulp, 90 parts of Alga Sgrgassi Enervess, 46 parts of sodium alginate, carboxymethyl chitosan 46 Part, 18 parts of aluminium nitride, 15 parts of boron nitride, 13 parts of carborundum, 23 parts of magnesium oxide and 35 parts of carbon fiber, the mould release membrance includes following The raw material of weight portion:38 parts of silicon dioxide gel, 16 parts of nitrogen, 15 parts of acrylate, 20 parts of polyethylene, 15 parts of titanium dioxide and 11 parts of polyphenylene sulfide.
Further, the release glassine paper is made up of glassine paper and mould release membrance, the glassine paper bag Include the raw material of following weight portion:115 parts of cotton pulp, 95 parts of reed pulp, 80 parts of Alga Sgrgassi Enervess, 43 parts of sodium alginate, carboxymethyl chitosan 40 Part, 15 parts of aluminium nitride, 13 parts of boron nitride, 11 parts of carborundum, 19 parts of magnesium oxide and 28 parts of carbon fiber, the mould release membrance includes following The raw material of weight portion:32 parts of silicon dioxide gel, 13 parts of nitrogen, 13 parts of acrylate, 17 parts of polyethylene, 13 parts of titanium dioxide and 10 parts of polyphenylene sulfide.
The invention solves the problems that another technical problem be that a kind of preparation method of release glassine paper is provided, it is including following Step:
1) cotton pulp 100-130 parts are taken and reed pulp 80-110 part is put in pulper, run up by pulper, by cotton pulp It is beaten with reed pulp, mixed serum is obtained, then poured into obtained mixed serum in steam stove, is then heated to 300-380 DEG C so that serosity boils, standby;
2) by step 1) obtained in serosity pour in Bellmer and bleached, then by obtained serosity by pressurized screen and Vacuum is washed and starched machine and carries out washing and screening, obtains the cleaning serosity that concentration is 16~18%, standby;
3) Alga Sgrgassi Enervess 70-90 parts are taken to be crushed by Material disintegrator, then adds sodium alginate 40-46 parts, carboxymethyl shell Polysaccharide 34-46 parts mix with obtained Alga Sgrgassi Enervess particle, are then added to step 2) in obtained cleaning serosity, by blender With the rotating speed of 75r/min above-mentioned material is mixed rapidly so that Alga Sgrgassi Enervess particle is sufficiently mixed in serosity, standby;
4) aluminium nitride 12-18 parts, boron nitride 11-15 parts, carborundum 9-13 parts, magnesium oxide 15-23 parts and carbon fiber 21- are taken 35 parts are added in agitator, and by weight 1: 4 ratio addition water, then starting blender will be upper with the rotating speed of 65r/min State material to mix with water, serosity is obtained, it is standby;
5) by step 4) obtained in serosity be added to step 3) in obtained serosity, then by blender by serosity with Mixed pulp is stirred with the rotating speed of 35r/min, and body paper serosity is obtained, and then carries out copy paper, is scooped up paper pulp by scooping slurry, And uniformly out spread paper pulp on gauze with the frequency for swinging 30 times per minute by controlling to scoop to starch, being capable of effective control paper pulp stand The copy paper opened reaches the requirement of the uniform good toughness of thickness, is then extruded the copy paper on gauze by extruder so that Moisture extrusion and molding in copy paper, the copy paper after finally extruding is placed in low temp dryer and is carried out with 12-26 DEG C of low temperature Drying, is obtained body paper, standby;
6) take silicon dioxide gel 26-38 parts, nitrogen 10-16 parts, acrylate 11-15 parts, polyethylene 14-20 parts, two In titanium oxide 11-15 parts and polyphenylene sulfide 9-11 parts input smelting furnace, by being heated to 400-480 DEG C so that silicon dioxide gel, Acrylate, polyethylene, titanium dioxide and polyphenylene sulfide melt in the presence of nitrogen and release glue are obtained, standby;
7) by step 6) obtained in mould release membrance glue by inflation film manufacturing machine blow out mould release membrance, it is standby;
8) by step 7) in obtained mould release membrance be covered in step 6) on obtained copy paper surface, then by corona at Reason device is bonded mould release membrance and copy paper with the electric current of 6-8KV, is obtained final product.
The technology of the present invention effect major embodiment is in the following areas:By by cotton pulp, reed pulp, Alga Sgrgassi Enervess, sodium alginate, carboxylic first Copy paper obtained in base enclosure polysaccharide, aluminium nitride, boron nitride, carborundum, magnesium oxide and carbon fiber, with reference to by silicon dioxide gel, nitrogen Mould release membrance obtained in gas, acrylate, polyethylene, titanium dioxide and polyphenylene sulfide, then covers mould release membrance in copy paper, leads to Cross corona treatment plant causes mould release membrance and copy paper to bond in the presence of high-frequency high-voltage, so as to material environment friendly, heat-resisting is obtained The good release glassine paper of performance and ageing resistace, and with excellent water-proof antibiotic effect.
Specific embodiment
Embodiment 1
A kind of release glassine paper, is made up of glassine paper and mould release membrance, and the glassine paper includes following heavy The raw material of amount part:130 parts of cotton pulp, 80 parts of reed pulp, 70 parts of Alga Sgrgassi Enervess, 40 parts of sodium alginate, 34 parts of carboxymethyl chitosan, aluminium nitride 21 parts of 12 parts, 11 parts of boron nitride, 9 parts of carborundum, 15 parts of magnesium oxide and carbon fiber, the mould release membrance includes the original of following weight portion Material:26 parts of silicon dioxide gel, 10 parts of nitrogen, 11 parts of acrylate, 14 parts of polyethylene, 11 parts of titanium dioxide and polyphenylene sulfide 9 Part.
A kind of preparation method of release glassine paper, comprises the following steps:
1) take 130 parts of cotton pulp and 80 parts of reed pulp is put in pulper, run up by pulper, cotton pulp and reed pulp are entered Row beating, is obtained mixed serum, then pours obtained mixed serum in steam stove into, is then heated to 300 DEG C so that serosity is boiled Boiling, it is standby;
2) by step 1) obtained in serosity pour in Bellmer and bleached, then by obtained serosity by pressurized screen and Vacuum is washed and starched machine and carries out washing and screening, obtains the cleaning serosity that concentration is 16~18%, standby;
3) 70 parts of Alga Sgrgassi Enervess are taken to be crushed by Material disintegrator, then adds 40 parts of sodium alginate, carboxymethyl chitosan 34 Part mix with obtained Alga Sgrgassi Enervess particle, is then added to step 2) obtained clean in serosity, by blender with 75r/min Rotating speed above-mentioned material is mixed rapidly so that Alga Sgrgassi Enervess particle is sufficiently mixed in serosity, standby;
4) 12 parts of aluminium nitride, 11 parts of boron nitride, 9 parts of carborundum, 15 parts of magnesium oxide and carbon fiber 21-35 parts are taken it is added to and stirs Mix in bucket, by weight 1: 4 ratio addition water, then start blender and mixed above-mentioned material with water with the rotating speed of 65r/min Close, serosity is obtained, it is standby;
5) by step 4) obtained in serosity be added to step 3) in obtained serosity, then by blender by serosity with Mixed pulp is stirred with the rotating speed of 35r/min, and body paper serosity is obtained, and then carries out copy paper, is scooped up paper pulp by scooping slurry, And uniformly out spread paper pulp on gauze with the frequency for swinging 30 times per minute by controlling to scoop to starch, being capable of effective control paper pulp stand The copy paper opened reaches the requirement of the uniform good toughness of thickness, is then extruded the copy paper on gauze by extruder so that Moisture extrusion and molding in copy paper, the copy paper after finally extruding is placed in low temp dryer is dried with 12 DEG C of low temperature It is dry, body paper is obtained, it is standby;
6) take 26 parts of silicon dioxide gel, 10 parts of nitrogen, 11 parts of acrylate, 14 parts of polyethylene, 11 parts of titanium dioxide and In 9 parts of input smelting furnaces of polyphenylene sulfide, by being heated to 400 DEG C so that silicon dioxide gel, acrylate, polyethylene, titanium dioxide Titanium and polyphenylene sulfide melt in the presence of nitrogen and release glue are obtained, standby;
7) by step 6) obtained in mould release membrance glue by inflation film manufacturing machine blow out mould release membrance, it is standby;
8) by step 7) in obtained mould release membrance be covered in step 6) on obtained copy paper surface, then by corona at Reason device is bonded mould release membrance and copy paper with the electric current of 6KV, is obtained final product.
Embodiment 2
A kind of release glassine paper, is made up of glassine paper and mould release membrance, and the glassine paper includes following heavy The raw material of amount part:100 parts of cotton pulp, 110 parts of reed pulp, 90 parts of Alga Sgrgassi Enervess, 46 parts of sodium alginate, 46 parts of carboxymethyl chitosan, nitridation 35 parts of 18 parts of aluminum, 15 parts of boron nitride, 13 parts of carborundum, 23 parts of magnesium oxide and carbon fiber, the mould release membrance includes following weight portion Raw material:38 parts of silicon dioxide gel, 16 parts of nitrogen, 15 parts of acrylate, 20 parts of polyethylene, 15 parts of titanium dioxide and polyphenylene sulfide 11 parts of ether.
A kind of preparation method of release glassine paper, comprises the following steps:
1) take 100 parts of cotton pulp and 110 parts of reed pulp is put in pulper, run up by pulper, by cotton pulp and reed pulp It is beaten, mixed serum is obtained, then poured into obtained mixed serum in steam stove, is then heated to 380 DEG C so that serosity Boil, it is standby;
2) by step 1) obtained in serosity pour in Bellmer and bleached, then by obtained serosity by pressurized screen and Vacuum is washed and starched machine and carries out washing and screening, obtains the cleaning serosity that concentration is 18%, standby;
3) 90 parts of Alga Sgrgassi Enervess are taken to be crushed by Material disintegrator, then adds 46 parts of sodium alginate, carboxymethyl chitosan 46 Part mix with obtained Alga Sgrgassi Enervess particle, is then added to step 2) obtained clean in serosity, by blender with 75r/min Rotating speed above-mentioned material is mixed rapidly so that Alga Sgrgassi Enervess particle is sufficiently mixed in serosity, standby;
4) 35 parts of 18 parts of aluminium nitride, 15 parts of boron nitride, 13 parts of carborundum, 23 parts of magnesium oxide and carbon fiber are taken and is added to stirring In bucket, by weight 1: 4 ratio addition water, then start blender and mixed above-mentioned material with water with the rotating speed of 65r/min, Prepared serosity, it is standby;
5) by step 4) obtained in serosity be added to step 3) in obtained serosity, then by blender by serosity with Mixed pulp is stirred with the rotating speed of 35r/min, and body paper serosity is obtained, and then carries out copy paper, is scooped up paper pulp by scooping slurry, And uniformly out spread paper pulp on gauze with the frequency for swinging 30 times per minute by controlling to scoop to starch, being capable of effective control paper pulp stand The copy paper opened reaches the requirement of the uniform good toughness of thickness, is then extruded the copy paper on gauze by extruder so that Moisture extrusion and molding in copy paper, the copy paper after finally extruding is placed in low temp dryer is dried with 26 DEG C of low temperature It is dry, body paper is obtained, it is standby;
6) take 38 parts of silicon dioxide gel, 16 parts of nitrogen, 15 parts of acrylate, 20 parts of polyethylene, 15 parts of titanium dioxide and In 11 parts of input smelting furnaces of polyphenylene sulfide, by being heated to 480 DEG C so that silicon dioxide gel, acrylate, polyethylene, dioxy Change titanium and polyphenylene sulfide melts in the presence of nitrogen and release glue is obtained, it is standby;
7) by step 6) obtained in mould release membrance glue by inflation film manufacturing machine blow out mould release membrance, it is standby;
8) by step 7) in obtained mould release membrance be covered in step 6) on obtained copy paper surface, then by corona at Reason device is bonded mould release membrance and copy paper with the electric current of 8KV, is obtained final product.
Embodiment 3
A kind of release glassine paper, is made up of glassine paper and mould release membrance, and the glassine paper includes following heavy The raw material of amount part:115 parts of cotton pulp, 95 parts of reed pulp, 80 parts of Alga Sgrgassi Enervess, 43 parts of sodium alginate, 40 parts of carboxymethyl chitosan, aluminium nitride 28 parts of 15 parts, 13 parts of boron nitride, 11 parts of carborundum, 19 parts of magnesium oxide and carbon fiber, the mould release membrance includes following weight portion Raw material:32 parts of silicon dioxide gel, 13 parts of nitrogen, 13 parts of acrylate, 17 parts of polyethylene, 13 parts of titanium dioxide and polyphenylene sulfide 10 parts.
A kind of preparation method of release glassine paper, comprises the following steps:
1) take 115 parts of cotton pulp and 95 parts of reed pulp is put in pulper, run up by pulper, cotton pulp and reed pulp are entered Row beating, is obtained mixed serum, then pours obtained mixed serum in steam stove into, is then heated to 340 DEG C so that serosity is boiled Boiling, it is standby;
2) by step 1) obtained in serosity pour in Bellmer and bleached, then by obtained serosity by pressurized screen and Vacuum is washed and starched machine and carries out washing and screening, obtains the cleaning serosity that concentration is 17%, standby;
3) 80 parts of Alga Sgrgassi Enervess are taken to be crushed by Material disintegrator, then adds 43 parts of sodium alginate, carboxymethyl chitosan 40 Part mix with obtained Alga Sgrgassi Enervess particle, is then added to step 2) obtained clean in serosity, by blender with 75r/min Rotating speed above-mentioned material is mixed rapidly so that Alga Sgrgassi Enervess particle is sufficiently mixed in serosity, standby;
4) take 15 parts of aluminium nitride, 13 parts of boron nitride, 11 parts of carborundum, 19 parts of magnesium oxide and carbon fiber 21-35 parts to be added to In agitator, by weight 1: 4 ratio addition water, then start blender with the rotating speed of 65r/min by above-mentioned material and water Mixing, is obtained serosity, standby;
5) by step 4) obtained in serosity be added to step 3) in obtained serosity, then by blender by serosity with Mixed pulp is stirred with the rotating speed of 35r/min, and body paper serosity is obtained, and then carries out copy paper, is scooped up paper pulp by scooping slurry, And uniformly out spread paper pulp on gauze with the frequency for swinging 30 times per minute by controlling to scoop to starch, being capable of effective control paper pulp stand The copy paper opened reaches the requirement of the uniform good toughness of thickness, is then extruded the copy paper on gauze by extruder so that Moisture extrusion and molding in copy paper, the copy paper after finally extruding is placed in low temp dryer is dried with 19 DEG C of low temperature It is dry, body paper is obtained, it is standby;
6) take 32 parts of silicon dioxide gel, 13 parts of nitrogen, 13 parts of acrylate, 17 parts of polyethylene, 13 parts of titanium dioxide and In 10 parts of input smelting furnaces of polyphenylene sulfide, by being heated to 410 DEG C so that silicon dioxide gel, acrylate, polyethylene, dioxy Change titanium and polyphenylene sulfide melts in the presence of nitrogen and release glue is obtained, it is standby;
7) by step 6) obtained in mould release membrance glue by inflation film manufacturing machine blow out mould release membrance, it is standby;
8) by step 7) in obtained mould release membrance be covered in step 6) on obtained copy paper surface, then by corona at Reason device is bonded mould release membrance and copy paper with the electric current of 7KV, is obtained final product.
Experimental example
Following table is the technical requirements of release lattice Racine paper:
Above table is the technical requirements of glassine paper, according to the data of upper table, by the glassine paper of the present invention Contrasted with other glassine papers, and record data.
Experimental products:Made using the glassine paper of common glassine paper, special glassine paper and the application Contrast, and concrete numerical value is recorded, it is as shown in the table:
With reference to upper table, the glassine paper of common glassine paper, special glassine paper and the application is contrasted, only The glassine paper all technical for having the present invention reaches the standard of high-class product, therefore, compare common glassine paper, spy The glassine paper of system, the glassine paper of the present invention more can be projected in the material environment friendly of glassine paper, heat resistance and anti- The good release glassine paper of ageing properties, and with excellent water-proof antibiotic effect.
The technology of the present invention effect major embodiment is in the following areas:By by cotton pulp, reed pulp, Alga Sgrgassi Enervess, sodium alginate, carboxylic first Copy paper obtained in base enclosure polysaccharide, aluminium nitride, boron nitride, carborundum, magnesium oxide and carbon fiber, with reference to by silicon dioxide gel, nitrogen Mould release membrance obtained in gas, acrylate, polyethylene, titanium dioxide and polyphenylene sulfide, then covers mould release membrance in copy paper, leads to Cross corona treatment plant causes mould release membrance and copy paper to bond in the presence of high-frequency high-voltage, so as to material environment friendly, heat-resisting is obtained The good release glassine paper of performance and ageing resistace, and with excellent water-proof antibiotic effect.
Certainly, the above is the representative instance of the present invention, and in addition, the present invention can also have other various to be embodied as The technical scheme that mode, all employing equivalents or equivalent transformation are formed, all falls within the scope of protection of present invention.

Claims (4)

1. a kind of release glassine paper, it is characterised in that:It is made up of glassine paper and mould release membrance, the glassine paper bag Include the raw material of following weight portion:Cotton pulp 100-130 parts, reed pulp 80-110 part, Alga Sgrgassi Enervess 70-90 parts, sodium alginate 40-46 parts, Carboxymethyl chitosan 34-46 parts, aluminium nitride 12-18 parts, boron nitride 11-15 parts, carborundum 9-13 parts, magnesium oxide 15-23 parts and Carbon fiber 21-35 parts, the mould release membrance includes the raw material of following weight portion:Silicon dioxide gel 26-38 parts, nitrogen 10-16 parts, Acrylate 11-15 parts, polyethylene 14-20 parts, titanium dioxide 11-15 parts and polyphenylene sulfide 9-11 parts.
2. a kind of release glassine paper as claimed in claim 1, it is characterised in that:By glassine paper and mould release membrance system Into the glassine paper includes the raw material of following weight portion:130 parts of cotton pulp, 80 parts of reed pulp, 70 parts of Alga Sgrgassi Enervess, sodium alginate 21 parts of 40 parts, 34 parts of carboxymethyl chitosan, 12 parts of aluminium nitride, 11 parts of boron nitride, 9 parts of carborundum, 15 parts of magnesium oxide and carbon fiber, The mould release membrance includes the raw material of following weight portion:26 parts of silicon dioxide gel, 10 parts of nitrogen, 11 parts of acrylate, polyethylene 9 parts of 14 parts, 11 parts of titanium dioxide and polyphenylene sulfide.
3. a kind of release glassine paper as claimed in claim 1, it is characterised in that:By glassine paper and mould release membrance system Into the glassine paper includes the raw material of following weight portion:100 parts of cotton pulp, 110 parts of reed pulp, 90 parts of Alga Sgrgassi Enervess, sodium alginate 46 parts, 46 parts of carboxymethyl chitosan, 18 parts of aluminium nitride, 15 parts of boron nitride, 13 parts of carborundum, 23 parts of magnesium oxide and carbon fiber 35 Part, the mould release membrance includes the raw material of following weight portion:38 parts of silicon dioxide gel, 16 parts of nitrogen, 15 parts of acrylate, poly- second 11 parts of 20 parts of alkene, 15 parts of titanium dioxide and polyphenylene sulfide.
4. a kind of release glassine paper as claimed in claim 1, it is characterised in that:By glassine paper and mould release membrance system Into the glassine paper includes the raw material of following weight portion:115 parts of cotton pulp, 95 parts of reed pulp, 80 parts of Alga Sgrgassi Enervess, sodium alginate 43 parts, 40 parts of carboxymethyl chitosan, 15 parts of aluminium nitride, 13 parts of boron nitride, 11 parts of carborundum, 19 parts of magnesium oxide and carbon fiber 28 Part, the mould release membrance includes the raw material of following weight portion:32 parts of silicon dioxide gel, 13 parts of nitrogen, 13 parts of acrylate, poly- second 10 parts of 17 parts of alkene, 13 parts of titanium dioxide and polyphenylene sulfide.
CN201611130902.2A 2016-12-09 2016-12-09 Release type glassine base paper and preparation method thereof Pending CN106592324A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108894051A (en) * 2018-07-02 2018-11-27 温州新意特种纸业有限公司 A kind of high ultra-thin lattice Racine silicone oil paper
CN109796888A (en) * 2019-02-19 2019-05-24 王秀云 A kind of adhesive waterproof tape

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CN102587192A (en) * 2012-03-14 2012-07-18 江南大学 High temperature resistant release paper and preparation method thereof
CN202969151U (en) * 2012-12-31 2013-06-05 温州市新丰装饰材料有限公司 Glassine release paper
US20130186548A1 (en) * 2010-09-29 2013-07-25 Nitto Denko Corporation Method for producing laminated film
CN106012659A (en) * 2016-05-17 2016-10-12 湖南省和祥润新材料有限公司 High-temperature-resistant release paper and preparation method thereof

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US20130186548A1 (en) * 2010-09-29 2013-07-25 Nitto Denko Corporation Method for producing laminated film
CN202208868U (en) * 2011-09-09 2012-05-02 苏州斯迪克电子胶粘材料有限公司 Release paper
CN102587192A (en) * 2012-03-14 2012-07-18 江南大学 High temperature resistant release paper and preparation method thereof
CN202969151U (en) * 2012-12-31 2013-06-05 温州市新丰装饰材料有限公司 Glassine release paper
CN106012659A (en) * 2016-05-17 2016-10-12 湖南省和祥润新材料有限公司 High-temperature-resistant release paper and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108894051A (en) * 2018-07-02 2018-11-27 温州新意特种纸业有限公司 A kind of high ultra-thin lattice Racine silicone oil paper
CN109796888A (en) * 2019-02-19 2019-05-24 王秀云 A kind of adhesive waterproof tape

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