CN106590805A - Coal desulfurization technology - Google Patents
Coal desulfurization technology Download PDFInfo
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- CN106590805A CN106590805A CN201611210308.4A CN201611210308A CN106590805A CN 106590805 A CN106590805 A CN 106590805A CN 201611210308 A CN201611210308 A CN 201611210308A CN 106590805 A CN106590805 A CN 106590805A
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- coal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/02—Combustion or pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/04—Gasification
Abstract
The invention belongs to the technical field of coal desulfurization, and provides a coal desulfurization technology. According to the coal desulfurization technology, biomass is added in the coal for co-pyrolysis between the biomass and the coal. The method of the coal desulfurization technology comprises the steps of S1, selecting a material; S2, smashing; S3, exhausting; S4, increasing temperature; S5, reacting; S6, cooling; S7, collecting. The added biomass makes the precipitation of H2S and COS advance. The biomass is beneficial to removal of sulfur and nitrogen in the coal pyrolysis process, can stop cohering among particles in the pyrolysis process of the strong cohesive coal, and promote sufficient pyrolysis and desulfurization of the coal. The addition of the biomass increases desulfurization degree and obtains high heat value semicoke, and rich alkali metal contained in the biomass can generate catalytic action in the gasification process so that remarkable reduction of gasification reaction activation energy of pyrolysis char can be caused. On one hand, the gasification reaction of the pyrolysis char is obviously higher than reactivity of coal char, on the other hand, the efficiency of the coal desulfurization is effectively improved, and the influence of the coal pyrolysis gasification process on the environment is reduced.
Description
Technical field
The present invention relates to Desulphurization Technology for Coal field, specially a kind of coal desulfurization technique.
Background technology
The energy resource structure feature of China's few gas rich in coal and poor in oil determines that the production of energy based on coal and consumptio are long-term
Will not change.But long-term extensive exploitation and poorly efficient utilization, not only waste of resource, and serious environment pollution.Wherein, sulphur is dirty
Dye one just can form " acid rain " while severe corrosion equipment.The latter causes forest decay, the ecosystem on a large scale
The one of the main reasons of destruction, the agriculture underproduction, building corrosion and many diseases.But from from the perspective of coal resources, sulfur-bearing
Sulphur coal of the amount more than 2% accounts for 30% or so of coal resources proved reserves, occupies critical role.Therefore sulphur in coal is understood
Sulphur removing sulfuldioxide in the effective coal of occurrence patterns, exploiting economy, the quality to improving coal, realizing the efficient clean utilization of coal has
Very important realistic meaning.
The removing of sulphur in coal is always the important topic of coal chemistry research, and many methods have been used to the removing of sulphur in coal.
Wherein, as coal clean and effective using important composition portion in one of effective means and the coal process such as gasification, burning and liquefaction
Point pyrolysis, cause the extensive concern of people because it has certain desulfidation.In pyrolytic process, inorganic sulfur and part have
Machine sulphur can be with the easy H for recycling2The form of S enters gas phase, and then is effectively removed.However, in more gentle heat
Under the conditions of solution, pyrolysis of coal desulfuration efficiency is relatively low, has some scholars to enter with biomass copyrolysis behavior to coal both at home and abroad at present
Go compared with system research, the burnt gasification activity of the transition behavior and copyrolysis to sulphur during copyrolysis has been also carried out tentatively examining
Examine.The content of sulphur and the survey of composition in the gas-solid-liquid three-phase product that result of study focuses mostly on after to coal and biomass copyrolysis
Examination, catalysis of the alkali metal to the burnt gasification reaction of copyrolysis in the impact and biomass after analysis addition biomass to sulphur transition
Effect.
The content of the invention
It is an object of the invention to provide a kind of coal desulfurization technique, to solve the problems, such as above-mentioned background technology in propose.
For achieving the above object, the present invention provides following technical scheme：A kind of coal desulfurization technique, it is characterised in that：Should
The method and step of coal desulfurization technique is as follows：
S1：Sorting：The appropriate coal that selection needs desulfurization and the biomass for reacting；
S2：Crush：The coal chosen is carried out into crushing operation by reducing mechanism, coal particles are obtained, taken and crush
Coal particles and corresponding quantitative biomass be put in the charging aperture on pyrolysis oven, be sent to by feed mechanism
In apparatus for placing in pyrolysis furnace chamber；
S3：Exhaust：After the apparatus for placing of coal particles and biomass is stable, inert gas tank is opened, in pyrolysis oven
Inert gas 30min is passed through, the air in pyrolysis furnace chamber is discharged；
S4：Heat up：After air is discharged, start electric heater unit, warming temperature is carried out to pyrolysis oven, 400 are warmed up to respectively
DEG C, 500 DEG C and 600 DEG C, when temperature reaches set value, open reaction gas tank, reaction gas and steady is passed through in pyrolysis oven
Determine 30min；
S5：Reaction：Apparatus for placing in pyrolysis oven is rapidly feeding into the thermal treatment zone of pyrolysis oven cause coal particles and
Biomass carry out pyrolytic reaction, while Jing gasifying agent vapor pipes are passed through vapor in pyrolysis oven, vapor is filled with electrical heating
While putting cooperation regulation pyrolysis oven pyrolysis temperature, the efficiency of pyrolytic reaction is improved, in the steam Jing pyrolysis ovens in simultaneous reactions
The layer of sand that filters of top of chamber is discharged from the top of pyrolysis oven, sequentially enters dust absorbing device, exhaust gas absorption device and blowing
Device, is again fed to heat energy in gasifying agent vapor pipe by blowing device, while realizing the recycling of heat, goes
Except dust and waste gas in pyrolysis course of reaction；
S6：Cooling：Close electric heater unit, gasifying agent vapor pipe, dust absorbing device, useless after the completion of question response successively
Aspiration receiving apparatus and blowing device, are passed through inert gas in pyrolysis oven again so that coal particles and biomass hold dress
Put and be cooled in the environment of inert gas room temperature；
S7：Collect：The gas Jing gas vents produced after reaction neutralization reaction are drained in gas filtration groove, are finally received
Collect and environmental protection treatment treated in gas collection bag, and the solid residue after cooling down in step S6 is preserved and backed up analysis use,
To the content and form that detect the sulphur of residual.
Preferably, hoisting mechanism is provided with the inner chamber of the pyrolysis oven in step S2, and the bottom peace of hoisting mechanism
Equipped with the quartzy apparatus for placing for holding coal particles and biomass.
Preferably, the biomass composition and property is C/H and C/O compounds, and biomass are included rich in alkali (alkaline earth)
Metal oxide and rich in nonmetal oxide.
Preferably, load in the reaction gas tank for CO, CO2、CH4Or H2Gas.
Preferably, one end of the gasifying agent vapor pipe extends to the inner chamber of pyrolysis oven, and gasifying agent vapor pipe is stretched
Enter the end being pyrolyzed in furnace chamber and taper steam shower nozzle is installed.
Compared with prior art, the invention has the beneficial effects as follows：The coal desulfurization technique is by adding life in coal
Material copyrolysis therewith, sequentially pass through sorting, crushing, exhaust, intensification, reaction, cooling and the step such as collect carrying out to coal
Desulfurization.The biomass of addition make H in coal2The precipitation of S and COS shifts to an earlier date.Biomass are the materials rich in H, and pyrolysis can generate more
H2, be conducive to the removing of sulphur and nitrogen during pyrolysis of coal, and biomass can prevent particle in heavy caking coal pyrolytic process
Between bonding, promote coal and be fully pyrolyzed.The addition of biomass improves desulfurization degree and obtains high heating value semicoke, biomass
In can produce catalytic action to coal gasification course containing more rich alkali metal, cause to be pyrolyzed burnt gasification reaction activation energy notable
Reduce, on the one hand, on the other hand its gasification activity, effectively raises coal desulfurization apparently higher than the reactivity of coal tar
Efficiency, reduces impact of the coal pyrolysis gasification to environment.
Description of the drawings
Fig. 1 is present invention process flow chart；
Fig. 2 is present configuration principle schematic.
In figure：1 coal particles, 2 biomass, 3 pyrolysis ovens, 4 charging apertures, 5 inert gas tanks, 6 reaction gas tanks, 7 gasifying agents
Layer of sand, 9 dust absorbing devices, 10 blowing devices, 11 exhaust gas absorption devices, 12 gas filtration grooves, 13 gas are filtered in vapor pipe, 8
Body collecting bag, 14 electric heater units, 15 gas vents.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.It is based on
Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Fig. 1-2 is referred to, the present invention provides a kind of technical scheme：
Embodiment 1
A kind of coal desulfurization technique, it is characterised in that：The method and step of the coal desulfurization technique is as follows：
S1：Sorting：The appropriate coal that selection needs desulfurization and the biomass 2 for reacting, the composition and property of the biomass 2
Include rich in alkali (alkaline earth) metal oxide and rich in nonmetal oxide for C/H and C/O compounds, and biomass；
S2：Crush：The coal chosen is carried out into crushing operation by reducing mechanism, coal particles 1 are obtained, taken and crush
Coal particles 1 and corresponding quantitative biomass 2 be put in the charging aperture 4 on pyrolysis oven 3, sent by feed mechanism
Enter in the apparatus for placing in the inner chamber of pyrolysis oven 3, hoisting mechanism, and the bottom of hoisting mechanism are provided with the inner chamber of pyrolysis oven 3
The quartzy apparatus for placing for holding coal particles 1 and biomass 2 is installed；
S3：Exhaust：After the apparatus for placing of coal particles 1 and biomass 2 is stable, inert gas tank 5 is opened, to pyrolysis oven
Inert gas 30min is passed through in 3, the air in the inner chamber of pyrolysis oven 3 is discharged；
S4：Heat up：After air is discharged, start electric heater unit 14, warming temperature is carried out to pyrolysis oven 3, heating rate is
10 DEG C/min, 400 DEG C are warmed up to, when temperature reaches set value, open reaction gas tank 6, in pyrolysis oven 3 reaction is passed through
Gas and stably 30min, state load in reaction gas tank 6 for CO, CO2、CH4Or H2Gas；
S5：Reaction：Apparatus for placing in pyrolysis oven 3 is rapidly feeding the thermal treatment zone of pyrolysis oven 3 to cause coal particles
1 and biomass 2 carry out pyrolytic reaction, while Jing gasifying agent vapor pipe 7 is passed through vapor in pyrolysis oven 3, vapor and electricity
While heater 14 coordinates regulation 3 pyrolysis temperature of pyrolysis oven, the efficiency of pyrolytic reaction, the steam Jing in simultaneous reactions are improved
The layer of sand 8 that filters of the inner cavity top of pyrolysis oven 3 is discharged from the top of pyrolysis oven 3, sequentially enters the suction of dust absorbing device 9, waste gas
Receiving apparatus 11 and blowing device 10, are again fed to heat energy in gasifying agent vapor pipe 7 by blowing device 10, the gas
One end of agent vapor pipe 7 extends to the inner chamber of pyrolysis oven 3, and gasifying agent vapor pipe 7 stretches into the end in the inner chamber of pyrolysis oven 3
Portion is provided with taper steam jet, while realizing the recycling of heat, removes the dust and waste gas during pyrolytic reaction；
S6：Cooling：Close electric heater unit 14, gasifying agent vapor pipe 7, dust absorbing device after the completion of question response successively
9th, exhaust gas absorption device 11 and blowing device 10, are passed through inert gas in pyrolysis oven 3 again so that coal particles 1 and biology
The apparatus for placing of matter 2 is cooled to room temperature in the environment of inert gas；
S7：Collect：The gas Jing gas vents 15 produced after reaction neutralization reaction are drained in gas filtration groove 12, most
After collect environmental protection treatment treated in gas collection bag 13, and the solid residue after cooling down in step S6 is preserved and backed up
Analysis is used, to the content and form that detect the sulphur of residual.
Embodiment 2
A kind of coal desulfurization technique, it is characterised in that：The method and step of the coal desulfurization technique is as follows：
S1：Sorting：The appropriate coal that selection needs desulfurization and the biomass 2 for reacting, the composition and property of the biomass 2
Include rich in alkali (alkaline earth) metal oxide and rich in nonmetal oxide for C/H and C/O compounds, and biomass；
S2：Crush：The coal chosen is carried out into crushing operation by reducing mechanism, coal particles 1 are obtained, taken and crush
Coal particles 1 and corresponding quantitative biomass 2 be put in the charging aperture 4 on pyrolysis oven 3, sent by feed mechanism
Enter in the apparatus for placing in the inner chamber of pyrolysis oven 3, hoisting mechanism, and the bottom of hoisting mechanism are provided with the inner chamber of pyrolysis oven 3
The quartzy apparatus for placing for holding coal particles 1 and biomass 2 is installed；
S3：Exhaust：After the apparatus for placing of coal particles 1 and biomass 2 is stable, inert gas tank 5 is opened, to pyrolysis oven
Inert gas 30min is passed through in 3, the air in the inner chamber of pyrolysis oven 3 is discharged；
S4：Heat up：After air is discharged, start electric heater unit 14, warming temperature is carried out to pyrolysis oven 3, heating rate is
10 DEG C/min, 400 DEG C are warmed up to, when temperature reaches set value, open reaction gas tank 6, in pyrolysis oven 3 reaction is passed through
Gas and stably 30min, state load in reaction gas tank 6 for CO, CO2、CH4Or H2Gas；
S5：Reaction：Apparatus for placing in pyrolysis oven 3 is rapidly feeding the thermal treatment zone of pyrolysis oven 3 to cause coal particles
1 and biomass 2 carry out pyrolytic reaction, while Jing gasifying agent vapor pipe 7 is passed through vapor in pyrolysis oven 3, vapor and electricity
While heater 14 coordinates regulation 3 pyrolysis temperature of pyrolysis oven, the efficiency of pyrolytic reaction, the steam Jing in simultaneous reactions are improved
The layer of sand 8 that filters of the inner cavity top of pyrolysis oven 3 is discharged from the top of pyrolysis oven 3, sequentially enters the suction of dust absorbing device 9, waste gas
Receiving apparatus 11 and blowing device 10, are again fed to heat energy in gasifying agent vapor pipe 7 by blowing device 10, the gas
One end of agent vapor pipe 7 extends to the inner chamber of pyrolysis oven 3, and gasifying agent vapor pipe 7 stretches into the end in the inner chamber of pyrolysis oven 3
Portion is provided with taper steam shower nozzle, while realizing the recycling of heat, removes the dust and waste gas during pyrolytic reaction；
S6：Cooling：Close electric heater unit 14, gasifying agent vapor pipe 7, dust absorbing device after the completion of question response successively
9th, exhaust gas absorption device 11 and blowing device 10, are passed through inert gas in pyrolysis oven 3 again so that coal particles 1 and biology
The apparatus for placing of matter 2 is cooled to room temperature in the environment of inert gas；
S7：Collect：The gas Jing gas vents 15 produced after reaction neutralization reaction are drained in gas filtration groove 12, most
After collect environmental protection treatment treated in gas collection bag 13, and the solid residue after cooling down in step S6 is preserved and backed up
Analysis is used, to the content and form that detect the sulphur of residual.
Embodiment 3
A kind of coal desulfurization technique, it is characterised in that：The method and step of the coal desulfurization technique is as follows：
S1：Sorting：The appropriate coal that selection needs desulfurization and the biomass 2 for reacting, the composition and property of the biomass 2
Include rich in alkali (alkaline earth) metal oxide and rich in nonmetal oxide for C/H and C/O compounds, and biomass；
S2：Crush：The coal chosen is carried out into crushing operation by reducing mechanism, coal particles 1 are obtained, taken and crush
Coal particles 1 and corresponding quantitative biomass 2 be put in the charging aperture 4 on pyrolysis oven 3, sent by feed mechanism
Enter in the apparatus for placing in the inner chamber of pyrolysis oven 3, hoisting mechanism, and the bottom of hoisting mechanism are provided with the inner chamber of pyrolysis oven 3
The quartzy apparatus for placing for holding coal particles 1 and biomass 2 is installed；
S3：Exhaust：After the apparatus for placing of coal particles 1 and biomass 2 is stable, inert gas tank 5 is opened, to pyrolysis oven
Inert gas 30min is passed through in 3, the air in the inner chamber of pyrolysis oven 3 is discharged；
S4：Heat up：After air is discharged, start electric heater unit 14, warming temperature is carried out to pyrolysis oven 3, heating rate is
10 DEG C/min, 400 DEG C are warmed up to, when temperature reaches set value, open reaction gas tank 6, in pyrolysis oven 3 reaction is passed through
Gas and stably 30min, state load in reaction gas tank 6 for CO, CO2、CH4Or H2Gas；
S5：Reaction：Apparatus for placing in pyrolysis oven 3 is rapidly feeding the thermal treatment zone of pyrolysis oven 3 to cause coal particles
1 and biomass 2 carry out pyrolytic reaction, while Jing gasifying agent vapor pipe 7 is passed through vapor in pyrolysis oven 3, vapor and electricity
While heater 14 coordinates regulation 3 pyrolysis temperature of pyrolysis oven, the efficiency of pyrolytic reaction, the steam Jing in simultaneous reactions are improved
The layer of sand 8 that filters of the inner cavity top of pyrolysis oven 3 is discharged from the top of pyrolysis oven 3, sequentially enters the suction of dust absorbing device 9, waste gas
Receiving apparatus 11 and blowing device 10, are again fed to heat energy in gasifying agent vapor pipe 7 by blowing device 10, the gas
One end of agent vapor pipe 7 extends to the inner chamber of pyrolysis oven 3, and gasifying agent vapor pipe 7 stretches into the end in the inner chamber of pyrolysis oven 3
Portion is provided with taper steam jet, while realizing the recycling of heat, removes the dust and waste gas during pyrolytic reaction；
S6：Cooling：Close electric heater unit 14, gasifying agent vapor pipe 7, dust absorbing device after the completion of question response successively
9th, exhaust gas absorption device 11 and blowing device 10, are passed through inert gas in pyrolysis oven 3 again so that coal particles 1 and biology
The apparatus for placing of matter 2 is cooled to room temperature in the environment of inert gas；
S7：Collect：The gas Jing gas vents 15 produced after reaction neutralization reaction are drained in gas filtration groove 12, most
After collect environmental protection treatment treated in gas collection bag 13, and the solid residue after cooling down in step S6 is preserved and backed up
Analysis is used, to the content and form that detect the sulphur of residual.
Wherein, the early stage of pyrolysis, tar is quickly separated out, the hydroperoxyl radical in biomass simultaneously with gas phase and condensed phase
In free radical react, after, after tar and gas are produced in a large number, biomass occur with the active component in residual semicoke
Reaction；
Vapor is blown in pyrolysis oven 3 by Conic nozzle, coordinates regulation pyrolysis oven 3 to be pyrolyzed temperature with electric heater unit 14
Also the efficiency for improving pyrolytic reaction of degree, filtering layer of sand 8 can filter off most tar and dust, while coordinating dust absorbing
Device 9 and exhaust gas absorption device 11 are further absorbed to dust and waste gas, environmental protection and cause testing crew exempt from
Injured by dust and waste gas.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (5)
1. a kind of coal desulfurization technique, it is characterised in that：The method and step of the coal desulfurization technique is as follows：
S1：Sorting：The appropriate coal that selection needs desulfurization and the biomass (2) for reacting；
S2：Crush：The coal chosen is carried out into crushing operation by reducing mechanism, coal particles (1) are obtained, take what is crushed
Coal particles (1) and corresponding quantitative biomass (2) are put in the charging aperture (4) on pyrolysis oven (3), by feeding
Mechanism is sent in the apparatus for placing in pyrolysis oven (3) inner chamber；
S3：Exhaust：After the apparatus for placing of coal particles (1) and biomass (2) is stable, inert gas tank (5) is opened, to pyrolysis
Inert gas 30min is passed through in stove (3), the air in pyrolysis oven (3) inner chamber is discharged；
S4：Heat up：After air is discharged, start electric heater unit (14), warming temperature is carried out to pyrolysis oven (3), be warmed up to respectively
400 DEG C, 500 DEG C and 600 DEG C, when temperature reaches set value, reaction gas tank (6) is opened, be passed through in pyrolysis oven (3) anti-
Should gas and stable 30min；
S5：Reaction：Apparatus for placing in pyrolysis oven (3) is rapidly feeding the thermal treatment zone of pyrolysis oven (3) to cause coal particles
(1) and biomass (2) carry out pyrolytic reaction, while Jing gasifying agents vapor pipe (7) is passed through vapor, water in pyrolysis oven (3)
While steam coordinates regulation pyrolysis oven (3) pyrolysis temperature with electric heater unit (14), the efficiency of pyrolytic reaction is improved, while instead
The filtration layer of sand (8) of steam Jing pyrolysis ovens (3) inner cavity top in answering is discharged from the top of pyrolysis oven (3), sequentially enters powder
Dirt absorption plant (9), exhaust gas absorption device (11) and blowing device (10), are again fed to heat energy by blowing device (10)
In gasifying agent vapor pipe (7), while realizing the recycling of heat, the dust and waste gas during pyrolytic reaction is removed；
S6：Cooling：Close electric heater unit (14), gasifying agent vapor pipe (7), dust absorbing device after the completion of question response successively
(9), exhaust gas absorption device (11) and blowing device (10), are passed through inert gas so that coal particles in pyrolysis oven (3) again
And the apparatus for placing of biomass (2) is cooled to room temperature in the environment of inert gas (1)；
S7：Collect：Gas Jing gas vents (15) produced after reaction neutralization reaction is drained in gas filtration groove (12), most
After collect environmental protection treatment treated in gas collection bag (13), and the solid residue after cooling down in step S6 is preserved and standby
Part analysis is used, to the content and form that detect the sulphur of residual.
2. a kind of coal desulfurization technique according to claim 1, it is characterised in that：Pyrolysis oven (3) in step S2
Inner chamber in be provided with hoisting mechanism, and the bottom of hoisting mechanism is provided with the quartz for holding coal particles (1) and biomass (2)
Apparatus for placing.
3. a kind of coal desulfurization technique according to claim 1, it is characterised in that：Biomass (2) composition and property is
C/H and C/O compounds, and biomass include rich in alkali (alkaline earth) metal oxide and rich in nonmetal oxide.
4. a kind of coal desulfurization technique according to claim 1, it is characterised in that：Load in reaction gas tank (6)
For CO, CO2、CH4Or H2Gas.
5. a kind of coal desulfurization technique according to claim 1, it is characterised in that：The gasifying agent vapor pipe (7)
One end extends to the inner chamber of pyrolysis oven (3), and the end that gasifying agent vapor pipe (7) is stretched in pyrolysis oven (3) inner chamber is provided with
Taper steam jet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210308.4A CN106590805A (en) | 2016-12-24 | 2016-12-24 | Coal desulfurization technology |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210308.4A CN106590805A (en) | 2016-12-24 | 2016-12-24 | Coal desulfurization technology |
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| CN106590805A true CN106590805A (en) | 2017-04-26 |
Family
ID=58603548
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| CN201611210308.4A Pending CN106590805A (en) | 2016-12-24 | 2016-12-24 | Coal desulfurization technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109554537A (en) * | 2018-11-19 | 2019-04-02 | 北京汉唐环保科技股份有限公司 | Iron ore Special desulfurizing equipment |
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| CN104974772A (en) * | 2014-04-04 | 2015-10-14 | 北京中矿科能煤炭地下气化技术研究中心 | Heat pipe heating fluidized bed biomass and coal co-pyrolysis system |
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2016
- 2016-12-24 CN CN201611210308.4A patent/CN106590805A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104974772A (en) * | 2014-04-04 | 2015-10-14 | 北京中矿科能煤炭地下气化技术研究中心 | Heat pipe heating fluidized bed biomass and coal co-pyrolysis system |
Non-Patent Citations (2)
| Title |
|---|
| 中国煤炭学会青年工作委员会: "《中国煤炭学会第六届青年科技学术研讨会论文集》", 30 November 2000, 煤炭工业出版社 * |
| 黄怡等: "《有机摩擦材料实验》", 31 August 2016, 天津大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109554537A (en) * | 2018-11-19 | 2019-04-02 | 北京汉唐环保科技股份有限公司 | Iron ore Special desulfurizing equipment |
| CN109554537B (en) * | 2018-11-19 | 2020-05-05 | 北京汉唐环保科技股份有限公司 | Special desulfurization equipment for iron ore |
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