CN106590486A - Phenolic resin adhesive and preparation method thereof - Google Patents
Phenolic resin adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106590486A CN106590486A CN201611171607.1A CN201611171607A CN106590486A CN 106590486 A CN106590486 A CN 106590486A CN 201611171607 A CN201611171607 A CN 201611171607A CN 106590486 A CN106590486 A CN 106590486A
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- CN
- China
- Prior art keywords
- parts
- phenolic resin
- acetone
- ethanol
- resin adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a phenolic resin adhesive and a preparation method thereof. The phenolic resin adhesive consists of the following components in parts by mass: 30-50 parts of phenolic resin, 6-10 parts of a polyacrylate salt, 7-11 parts of tricresyl phosphate, 20-40 parts of epoxy resin, 6-8 parts of acetone, 10-12 parts of ethanol, 1-3 parts of a cross-linking reinforcing agent, 4-6 parts of polyorganosiloxane, 2-4 parts of silane coupling agent, 16-18 parts of asbestos powder, 10-15 parts of natural latex and 3-4 parts of an anti-aging agent. By adopting the phenolic resin adhesive, the production cost of a phenolic resin type adhesive can be lowered, the comprehensive quality and the effect of an adhesive can be improved, and plywood made by using the adhesive in a pressing molding manner is relatively good in bonding quality.
Description
Technical field
The present invention relates to technical field of adhesive, in particular to a kind of phenolic resin adhesive and preparation method thereof.
Background technology
Phenolic resin is formed by phenols and aldehyde condensation polymer, and the adhesive has the performances such as good heat-resisting, media-resistant, but solid
After change, glue-line is crisp, needs temperature-pressure to solidify, and commonly uses other polymer chemistry things to improve performance, can expand application, end
Modified phenolic resin adhesive is mainly used in bonding timber, bubble and washes one's hair plastics and other porous materials, it is also possible to manufacture glue
Plywood.
The content of the invention
The invention provides a kind of phenolic resin adhesive and preparation method thereof, present invention reduces phenolic resin class gluing
The production cost of agent, improves the overall qualities and effect of adhesive, has with the compressing plywood of the adhesive higher
Glue performance.
For achieving the above object, the present invention provides following technical scheme：
A kind of phenolic resin adhesive and preparation method thereof, is made up of following mass fraction formula components：Phenolic resin 30-
50 parts, polyacrylate salts 6-10 parts, tricresyl phosphate 7-11 parts, epoxy resin 20-40 parts, acetone 6-8 parts, ethanol 10-12
Part, crosslinking enhancer 1-3 part, polysiloxane 4-6 parts, silane coupler 2-4 parts, flake asbestos 16-18 parts, natural emulsion
10-15 parts, age resistor 3-4 parts.
Further：It is made up of following mass fraction formula components：30 parts of phenolic resin, 6 parts of polyacrylate salts, tripotassium phosphate
It is 7 parts of phenolic ester, 20 parts of epoxy resin, 6 parts of acetone, 10 parts of ethanol, 1 part of crosslinking enhancer, 4 parts of polysiloxane, silane coupled
2 parts of agent, 16 parts of flake asbestos, 10 parts of natural emulsion, 3 parts of age resistor.
Further：It is made up of following mass fraction formula components：40 parts of phenolic resin, 8 parts of polyacrylate salts, tripotassium phosphate
It is 9 parts of phenolic ester, 30 parts of epoxy resin, 7 parts of acetone, 11 parts of ethanol, 2 parts of crosslinking enhancer, 5 parts of polysiloxane, silane coupled
3 parts of agent, 17 parts of flake asbestos, 12.5 parts of natural emulsion, 3.5 parts of age resistor.
Further：It is made up of following mass fraction formula components：50 parts of phenolic resin, 10 parts of polyacrylate salts, tricresyl phosphate
11 parts of cresol ester, 40 parts of epoxy resin, 8 parts of acetone, 12 parts of ethanol, 3 parts of crosslinking enhancer, 6 parts of polysiloxane, silane idol
4 parts of agent of connection, 18 parts of flake asbestos, 15 parts of natural emulsion, 4 parts of age resistor.
Further：Preparation method of the present invention has following steps：
Step one, by above-mentioned material according to aforementioned proportion proportioning, it is standby；
Step 2, by phenolic resin, polyacrylate salts, tricresyl phosphate, epoxy resin, acetone, ethanol, poly-organosilicon
During oxygen alkane, flake asbestos, natural emulsion mixing add reactor, in 70-80 DEG C of insulation reaction 1-1.5 hour；
Step 3, will obtained by step 2 add crosslinking enhancer and age resistor mixing；
Step 4, room temperature is cooled to, stirs and obtain final product the phenolic resin adhesive.
The invention has the beneficial effects as follows：Present invention reduces the production cost of phenolic resin class adhesive, improves gluing
The overall qualities and effect of agent, have higher glue performance with the compressing plywood of the adhesive.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of phenolic resin adhesive is made up of following mass fraction formula components：Phenolic resin 30-50 parts, polypropylene acid
Salt 6-10 parts, tricresyl phosphate 7-11 parts, epoxy resin 20-40 parts, acetone 6-8 parts, ethanol 10-12 parts, crosslinking enhancer
1-3 parts, polysiloxane 4-6 parts, silane coupler 2-4 parts, flake asbestos 16-18 parts, natural emulsion 10-15 parts, age resistor
3-4 parts.
Embodiment two：
A kind of phenolic resin adhesive is made up of following mass fraction formula components：30 parts of phenolic resin, polyacrylate salts 6
Part, 7 parts of tricresyl phosphate, 20 parts of epoxy resin, 6 parts of acetone, 10 parts of ethanol, 1 part of crosslinking enhancer, polysiloxane 4
Part, 2 parts of silane coupler, 16 parts of flake asbestos, 10 parts of natural emulsion, 3 parts of age resistor.
Embodiment three：
A kind of phenolic resin adhesive is made up of following mass fraction formula components：40 parts of phenolic resin, polyacrylate salts 8
Part, 9 parts of tricresyl phosphate, 30 parts of epoxy resin, 7 parts of acetone, 11 parts of ethanol, 2 parts of crosslinking enhancer, polysiloxane 5
Part, 3 parts of silane coupler, 17 parts of flake asbestos, 12.5 parts of natural emulsion, 3.5 parts of age resistor.
Example IV：
A kind of phenolic resin adhesive is made up of following mass fraction formula components：50 parts of phenolic resin, polyacrylate salts
10 parts, 11 parts of tricresyl phosphate, 40 parts of epoxy resin, 8 parts of acetone, 12 parts of ethanol, 3 parts of crosslinking enhancer, poly organo
6 parts of alkane, 4 parts of silane coupler, 18 parts of flake asbestos, 15 parts of natural emulsion, 4 parts of age resistor.
Embodiment five：
A kind of preparation method preparation method of phenolic resin adhesive comprises the steps：
Step one, by above-mentioned material according to aforementioned proportion proportioning, it is standby；
Step 2, by phenolic resin, polyacrylate salts, tricresyl phosphate, epoxy resin, acetone, ethanol, poly-organosilicon
During oxygen alkane, flake asbestos, natural emulsion mixing add reactor, in 70-80 DEG C of insulation reaction 1-1.5 hour；
Step 3, will obtained by step 2 add crosslinking enhancer and age resistor mixing；
Step 4, room temperature is cooled to, stirs and obtain final product the phenolic resin adhesive.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of description is only that those skilled in the art should for clarity
Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of phenolic resin adhesive, it is characterised in that：It is made up of following mass fraction formula components：
Phenolic resin 30-50 parts, polyacrylate salts 6-10 parts, tricresyl phosphate 7-11 parts, epoxy resin 20-40 parts, acetone
6-8 parts, ethanol 10-12 parts, crosslinking enhancer 1-3 part, polysiloxane 4-6 parts, silane coupler 2-4 parts, flake asbestos 16-
18 parts, natural emulsion 10-15 parts, age resistor 3-4 parts.
2. a kind of phenolic resin adhesive according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
30 parts of phenolic resin, 6 parts of polyacrylate salts, 7 parts of tricresyl phosphate, 20 parts of epoxy resin, 6 parts of acetone, 10 parts of ethanol,
1 part of crosslinking enhancer, 4 parts of polysiloxane, 2 parts of silane coupler, 16 parts of flake asbestos, 10 parts of natural emulsion, age resistor 3
Part.
3. a kind of phenolic resin adhesive according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
40 parts of phenolic resin, 8 parts of polyacrylate salts, 9 parts of tricresyl phosphate, 30 parts of epoxy resin, 7 parts of acetone, 11 parts of ethanol,
2 parts of crosslinking enhancer, 5 parts of polysiloxane, 3 parts of silane coupler, 17 parts of flake asbestos, 12.5 parts of natural emulsion, age resistor
3.5 part.
4. a kind of phenolic resin adhesive according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
50 parts of phenolic resin, 10 parts of polyacrylate salts, 11 parts of tricresyl phosphate, 40 parts of epoxy resin, 8 parts of acetone, ethanol 12
Part, 3 parts of crosslinking enhancer, 6 parts of polysiloxane, 4 parts of silane coupler, 18 parts of flake asbestos, 15 parts of natural emulsion, age resistor
4 parts.
5. a kind of a kind of preparation method of phenolic resin adhesive according to claim 1, it is characterised in that：Including as follows
Step：
Step one, by above-mentioned material according to aforementioned proportion proportioning, it is standby；
Step 2, by phenolic resin, polyacrylate salts, tricresyl phosphate, epoxy resin, acetone, ethanol, poly organo
During alkane, flake asbestos, natural emulsion mixing add reactor, in 70-80 DEG C of insulation reaction 1-1.5 hour；
Step 3, will obtained by step 2 add crosslinking enhancer and age resistor mixing；
Step 4, room temperature is cooled to, stirs and obtain final product the phenolic resin adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171607.1A CN106590486A (en) | 2016-12-17 | 2016-12-17 | Phenolic resin adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171607.1A CN106590486A (en) | 2016-12-17 | 2016-12-17 | Phenolic resin adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106590486A true CN106590486A (en) | 2017-04-26 |
Family
ID=58599746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611171607.1A Pending CN106590486A (en) | 2016-12-17 | 2016-12-17 | Phenolic resin adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106590486A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384280A (en) * | 2017-08-31 | 2017-11-24 | 成都卡美奇鞋业有限公司 | A kind of adhesive for shoe-making process |
| CN107858132A (en) * | 2017-11-29 | 2018-03-30 | 广西众昌树脂有限公司 | Resin dedicated adhesive of bamboo flooring and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1821334A (en) * | 2006-04-05 | 2006-08-23 | 北京林业大学 | Phenolic resin glue for veneer board and its preparing method |
| CN102994027A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Phenolic resin adhesive |
| CN105950062A (en) * | 2016-05-19 | 2016-09-21 | 合肥庭索环保材料有限公司 | Efficient waterproof binder and production method thereof |
-
2016
- 2016-12-17 CN CN201611171607.1A patent/CN106590486A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1821334A (en) * | 2006-04-05 | 2006-08-23 | 北京林业大学 | Phenolic resin glue for veneer board and its preparing method |
| CN102994027A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Phenolic resin adhesive |
| CN105950062A (en) * | 2016-05-19 | 2016-09-21 | 合肥庭索环保材料有限公司 | Efficient waterproof binder and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李广宇等: "《胶粘与密封新技术》", 31 January 2006, 国防工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384280A (en) * | 2017-08-31 | 2017-11-24 | 成都卡美奇鞋业有限公司 | A kind of adhesive for shoe-making process |
| CN107858132A (en) * | 2017-11-29 | 2018-03-30 | 广西众昌树脂有限公司 | Resin dedicated adhesive of bamboo flooring and preparation method thereof |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170426 |
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