CN106589777A - High-performance environment-friendly outdoors-resistant wood-plastic material produced from recycled materials and preparation method of high-performance environment-friendly outdoors-resistant wood-plastic material - Google Patents
High-performance environment-friendly outdoors-resistant wood-plastic material produced from recycled materials and preparation method of high-performance environment-friendly outdoors-resistant wood-plastic material Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/04—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to rubbers
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- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2427/06—Homopolymers or copolymers of vinyl chloride
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- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/22—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers modified by chemical after-treatment
- C08J2427/24—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers modified by chemical after-treatment halogenated
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- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2451/04—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to rubbers
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2203/14—Applications used for foams
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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Abstract
The invention discloses a high-performance environment-friendly outdoors-resistant wood-plastic material produced from recycled materials. The high-performance environment-friendly outdoors-resistant wood-plastic material is prepared from, by weight, 10-50 parts of PVC resin powder, 150-300 parts of recycled abrasive powder materials, 1-4 parts of plasticizing modifier, 0.3-1.2 parts of foaming agent, 2-5 parts of environment-friendly stabilizer, 1-3 parts of processing agent, 2-7 parts of toughening and reinforcing agent, 10-20 parts of antishrinking agent and 0.1-0.5 part of tungsten carbide powder. The high-performance environment-friendly outdoors-resistant wood-plastic material produced from the recycled materials is processed by adopting the PVC resin and the recycled abrasive powder materials as a base and covering the surface of the base with a superstrong anti-aging polymer layer, the surface of the base is covered with the polymer material, the anti-aging performance and the surface hardness of the product are greatly improved, high abrasion resistance is achieved, the price is low, the production period is long, and the wood-plastic material is waterproof and retardant to flames.
Description
Technical field
The present invention relates to a kind of Wood-plastic material, more precisely, being that one kind produces the anti-room of high-performance environment-friendly using reclaimed materials
Outer Wood-plastic material and preparation method thereof.
Background technology
Traditional outdoor Wood-plastic material long-time is subject to wind, Exposure to Sunlight, drenches with rain etc. to affect, and easily occurs fading, physical property
The phenomenons such as energy reduction, can not meet the requirement of people, have the anti-outdoor wood moulding finishing of high-performance environment-friendly in the urgent need to a kind of
Material.
The content of the invention
The present invention mainly solves the technical problem existing for prior art, a kind of high using reclaimed materials production so as to provide
Anti- outdoor Wood-plastic material of performance environmental protection and preparation method thereof.
What the above-mentioned technical problem of the present invention was mainly addressed by following technical proposals：
The invention discloses it is a kind of using the anti-outdoor Wood-plastic material of reclaimed materials production high-performance environment-friendly, comprising component and each group
Point parts by weight be：
PVC resin powder 10-50 part；
Reclaim pulverizing material 150-300 parts；
Plasticising regulator 1-4 parts；
Foaming agent 0.3-1.2 parts；
Stabilizer 2-5 part；
Processing aid 1-3 parts；
Toughening and reinforcing agent 2-7 parts；
Antishrinking agent 10-20 parts；
Tungsten-carbide powder 0.1-0.5 parts.
As the preferred of the present invention,
Described recovery pulverizing material is 50-100 mesh；
Described plasticising regulator is at least one in double methyl ester and styrene；
Described foaming agent is at least one in sodium bicarbonate and azo amide；
Described stabilizer is at least one in calcium zinc stabilizer and organic tin stabilizer；
Described processing aid is at least one in dibutyl ester and adipic acid；
Described toughening and reinforcing agent is acrylate；
Described antishrinking agent is at least one in MBS and chliorinated polyvinyl chloride；
Described tungsten-carbide powder is 200-300 mesh.
The invention also discloses one kind is prepared as the aforementioned using the anti-outdoor Wood-plastic material of reclaimed materials production high-performance environment-friendly
Preparation method, comprising step：
1) surface co-extrusion material (ABS/ASA resins) is sent into into dehydrator, 1-3 is dried at a temperature of 80～120 DEG C little
When；
2) each group is distributed into into high speed mixer, 110～145 DEG C are heated to, 45～85 DEG C is cooled to and is put into barrel；
3) mixed raw material is added into extruder, 120～210 DEG C of extrusions, extruder barrel temperature 120～205 is heated to
DEG C, 125～220 DEG C of mold temperature, 10～30 turns/min of engine speed, 8～30 turns/min of feeding rotating speed, co-extrusion machine temperature 120-
230 DEG C, 5～13 turns/min of rotating speed；
4) Jing calendering formations, traction and cutting after, extruding.
Anti- outdoor Wood-plastic material of utilization reclaimed materials production high-performance environment-friendly of the present invention and preparation method thereof has following excellent
Point：
1st, the anti-outdoor Wood-plastic material of utilization reclaimed materials of the invention production high-performance environment-friendly is using polyvinyl chloride resin, recovery pulverizing
Expect for substrate, surface is processed coated with superpower age resistant polymer layer, and macromolecular material is covered on surface, substantially increases product
Ageing-resistant performance and case hardness, with high-wearing feature and cheap, long the production cycle, water proof fire retardant；
2nd, environmental protection, without formaldehyde, heavy metal, will not work the mischief to environment, people during production and use；
3rd, with high resiliency and superpower shock resistance, in an outdoor environment with extremely low shrinkage factor；
4th, easy for installation, lightweight, good muffling effect, elasticity it is good, using after the several years can 100% reclaim.
Specific embodiment
It is carried out according to the following table and gets the raw materials ready：
In four embodiments, part is respectively adopted:
Above-mentioned four embodiments for getting material ready are carried out into following processing respectively：
1) surface co-extrusion material (ABS/ASA resins) is sent into into dehydrator, 1-3 is dried at a temperature of 80～120 DEG C little
When；
2) each group is distributed into into high speed mixer, 110～145 DEG C are heated to, 45～85 DEG C is cooled to and is put into barrel；
3) mixed raw material is added into extruder, 120～210 DEG C of extrusions, extruder barrel temperature 120～205 is heated to
DEG C, 125～220 DEG C of mold temperature, 10～30 turns/min of engine speed, 8～30 turns/min of feeding rotating speed, co-extrusion machine temperature 120-
230 DEG C, 5～13 turns/min of rotating speed；
4) Jing calendering formations, traction and cutting after, extruding.
Following table is the Mechanical test results on floor obtained in embodiment 4：
Due to increased tungsten-carbide powder, the wearability of Wood-plastic material is effectively increased.
In order to improve the intensity of the wood plastic composite of the present invention, Graphene can be added in dispensing, addition is PVC
The 0.1%-0.5% of resin-oatmeal weight, obtained sheet material hardness can at least improve 10%, and the modulus of elasticity in static bending can at least be improved
5%.
Additionally, the intensity and corrosion resistance in order to further improve material, can add and break into metal foam
The material of powder body, metal foam can be nickel foam, foam copper, titanium foam, foam iron-nickel etc., preferred foams titanium.
Titanium foam is crushed into the powder body for 30 to 50 mesh, according to 1～embodiment of embodiment 4, respectively addition 0.3,0.6,
0.9th, 1.2 weight portion is added, and remaining preparation technology is ibid.
Due to titanium foam crush after, powder body has irregular shape, can well with substrate with therefore, it is possible to more preferable
Be cured in matrix.Intensity is with without compared with, it is possible to increase 10～15%.And titanium itself has good corrosion-resistant energy
Power such that it is able to further improve the decay resistance of wood plastic composite.
In order to improve the anti-microbial property of the wood and plastic composite of the present invention, nanometer silver can be added in dispensing, nanometer silver
Between 25-50 nanometers, addition is the 1%-5% of PVC resin powder weight to particle diameter, after adding nanometer silver, obtained sheet material
Antibiotic property effectively improves, and through the escherichia coli antibacterial test of ASTME2180 standards, sterilizing rate reaches more than 90%.
Anti- outdoor Wood-plastic material of utilization reclaimed materials production high-performance environment-friendly of the present invention and preparation method thereof has following excellent
Point：
1st, the anti-outdoor Wood-plastic material of utilization reclaimed materials of the invention production high-performance environment-friendly is using polyvinyl chloride resin, recovery pulverizing
Expect for substrate, surface is processed coated with superpower age resistant polymer layer, and macromolecular material is covered on surface, substantially increases product
Ageing-resistant performance and case hardness, with high-wearing feature and cheap, long the production cycle, water proof fire retardant；
2nd, environmental protection, without formaldehyde, heavy metal, will not work the mischief to environment, people during production and use；
3rd, with high resiliency and superpower shock resistance, in an outdoor environment with extremely low shrinkage factor；
4th, easy for installation, lightweight, good muffling effect, elasticity it is good, using after the several years can 100% reclaim.
This is not limited to, the guarantor in the present invention should be all covered in any change or replacement expected without creative work
Within the scope of shield.Therefore, the protection domain that protection scope of the present invention should be limited by claims is defined.
Claims (3)
1. a kind of using the anti-outdoor Wood-plastic material of reclaimed materials production high-performance environment-friendly, the parts by weight comprising component and each component
For：
PVC resin powder 10-50 part；
Reclaim pulverizing material 150-300 parts；
Plasticising regulator 1-4 parts；
Foaming agent 0.3-1.2 parts；
Stabilizer 2-5 part；
Processing aid 1-3 parts；
Toughening and reinforcing agent 2-7 parts；
Antishrinking agent 10-20 parts；
Tungsten-carbide powder 0.1-0.5 parts.
2. utilization reclaimed materials according to claim 1 produce the anti-outdoor Wood-plastic material of high-performance environment-friendly, it is characterised in that
Described recovery pulverizing material is 50-100 mesh；
Described plasticising regulator is at least one in double methyl ester and styrene；
Described foaming agent is at least one in sodium bicarbonate and azo amide；
Described stabilizer is at least one in calcium zinc stabilizer and organic tin stabilizer；
Described processing aid is at least one in dibutyl ester and adipic acid；
Described toughening and reinforcing agent is acrylate；
Described antishrinking agent is at least one in MBS and chliorinated polyvinyl chloride；
Described tungsten-carbide powder is 200-300 mesh.
3. it is a kind of to prepare the system that the anti-outdoor Wood-plastic material of high-performance environment-friendly is produced using reclaimed materials as claimed in claim 1 or 2
Preparation Method, comprising step：
1) surface co-extrusion material (ABS/ASA resins) is sent into into dehydrator, 1-3 hours is dried at a temperature of 80～120 DEG C；
2) each group is distributed into into high speed mixer, 110～145 DEG C are heated to, 45～85 DEG C is cooled to and is put into barrel；
3) mixed raw material is added into extruder, 120～210 DEG C is heated to and is extruded, 120～205 DEG C of extruder barrel temperature,
125～220 DEG C of mold temperature, 10～30 turns/min of engine speed, 8～30 turns/min of feeding rotating speed, co-extrusion machine temperature 120-230
DEG C, 5～13 turns/min of rotating speed；
4) Jing calendering formations, traction and cutting after, extruding.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611176349.6A CN106589777A (en) | 2016-12-19 | 2016-12-19 | High-performance environment-friendly outdoors-resistant wood-plastic material produced from recycled materials and preparation method of high-performance environment-friendly outdoors-resistant wood-plastic material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611176349.6A CN106589777A (en) | 2016-12-19 | 2016-12-19 | High-performance environment-friendly outdoors-resistant wood-plastic material produced from recycled materials and preparation method of high-performance environment-friendly outdoors-resistant wood-plastic material |
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| CN106589777A true CN106589777A (en) | 2017-04-26 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103665636A (en) * | 2013-11-27 | 2014-03-26 | 江阴匡时建材有限公司 | PVC (polyvinyl chloride) plastic building template |
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2016
- 2016-12-19 CN CN201611176349.6A patent/CN106589777A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103665636A (en) * | 2013-11-27 | 2014-03-26 | 江阴匡时建材有限公司 | PVC (polyvinyl chloride) plastic building template |
Non-Patent Citations (6)
| Title |
|---|
| 周殿明: "《塑料管挤出成型》", 31 October 2011, 机械工业出版社 * |
| 徐同考: "《塑料改性实用技术》", 31 October 2012, 中国轻工业出版社 * |
| 朱元庆: "《聚氯乙烯管材制造和应用》", 30 September 2009, 化学工业出版社 * |
| 王文广: "《塑料配方大全 第二版》", 31 January 2009, 化学工业出版社 * |
| 蒋民华: "《神奇的新材料》", 31 October 2013, 山东科学技术出版社 * |
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