CN106751200A - Environmentally friendly bathroom floor and preparation method thereof - Google Patents
Environmentally friendly bathroom floor and preparation method thereof Download PDFInfo
- Publication number
- CN106751200A CN106751200A CN201611176305.3A CN201611176305A CN106751200A CN 106751200 A CN106751200 A CN 106751200A CN 201611176305 A CN201611176305 A CN 201611176305A CN 106751200 A CN106751200 A CN 106751200A
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- Prior art keywords
- parts
- bathroom floor
- agent
- environmentally friendly
- stabilizer
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/105—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of organic plastics with or without reinforcements or filling materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Floor Finish (AREA)
Abstract
The invention discloses a kind of environmentally friendly bathroom floor, the parts by weight comprising component and each component are：50 100 parts of PVC resin powder；150 250 parts of calcareous filler；15 parts of conditioning agent of plasticising；36 parts of stabilizer；13 parts of processing aid；13 parts of lubricant；0.1 0.5 parts of activator；5 20 parts of antishrinking agent；0.1 1 parts of environment friendly mildew resistant agent, 0.1 0.5 parts of tungsten-carbide powder.Environmentally friendly bathroom floor surface of the invention coated with superpower wear-resistant macromolecule PVC wearing layers, with case hardness very high；Mould proof anti-moth, is adapted to be used in bathroom；There is extremely low shrinkage factor under high humidity high-heat environment.
Description
Technical field
The present invention relates to a kind of bathroom floor, more precisely, being a kind of environmentally friendly bathroom floor and preparation method thereof.
Background technology
With the raising that people's life is required, traditional bathroom ceramics and marble floor is no longer satisfied with, compeled
Be essential want it is a kind of with attractive in appearance, low-carbon (LC), be easy to the new finishing material arranged.
The content of the invention
The present invention mainly solve prior art existing for technical problem so that provide a kind of environmentally friendly bathroom floor and its
Preparation method.
Above-mentioned technical problem of the invention is mainly what is be addressed by following technical proposals：
The invention discloses a kind of environmentally friendly bathroom floor, the parts by weight comprising component and each component are：
PVC resin powder 50-100 parts；
Calcareous filler 150-250 parts；
1-5 parts of conditioning agent of plasticising；
Stabilizer 3-6 parts；
Processing aid 1-3 parts；
Lubricant 1-3 parts；
Activator 0.1-0.5 parts；
Antishrinking agent 5-20 parts；
0.1-1 parts of environment friendly mildew resistant agent：
Tungsten-carbide powder 0.1-0.5 parts
As preferred embodiments of the present invention,
Described calcareous filler is the powdered whiting of 600-1200 mesh；
Described plasticising conditioning agent is double methyl esters；
Described stabilizer is at least one in calcium zinc stabilizer and organic tin stabilizer；
Described processing aid is styrene；
Described lubricant is stearic acid；
Described activator is aryl carboxylic acid metallic soap；
Described antishrinking agent is at least one in MBS and chliorinated polyvinyl chloride；
Described environment friendly mildew resistant agent is alkyl ammonium compounds；
Described tungsten-carbide powder is 200-300 mesh.
The invention also discloses a kind of preparation method for preparing environmental protection bathroom floor as the aforementioned, comprising step：
1) calcareous filler, is sent into high speed mixer, activator is added, 1-3 is activated at a temperature of 80~150 DEG C small
When；
2) remaining raw material, is heated to 100~150 DEG C by feeding high speed mixer, 45~85 DEG C is cooled to and is put into material
Cylinder；
3) mixed raw material, is added into extruder, 120~200 DEG C of extrusions, extruder barrel temperature 130~200 are heated to
DEG C, 130~220 DEG C of mold temperature, 8~30 turns/min of engine speed, 8~30 turns/min of feeding rotating speed；
4) through calendering formation, traction and cutting after, extruding.
Environmentally friendly bathroom floor of the invention and preparation method thereof has the following advantages that：
1st, surface coated with superpower wear-resistant macromolecule PVC wearing layers, with case hardness very high；
2nd, mould proof anti-moth, is adapted to be used in bathroom；
3rd, there is extremely low shrinkage factor under high humidity high-heat environment；
4th, with high-wearing feature, high resiliency and superpower shock resistance, and the cheap, production cycle is long, water proof fire retardant；
5th, 10-15 DEG C of processing temperature and die head temperature are reduced in process of production, continuous maching time is extended, and are reduced
Energy resource consumption, reduces mechanical wear, reduces the integrated cost of plastic processing, under the conditions of like products quality and energy resource consumption,
Can improve production efficiency 10%~30%；
6th, environmental protection, without formaldehyde, heavy metal, will not cause harm during production and use to environment, people；
7th, easy for installation, lightweight, good muffling effect, elasticity it is good, using after the several years can 100% reclaim；
8th, floor can simulate natural wood grain, bag, can also possess abundant geometrical pattern as ceramic tile, aesthetic property
It is good.
Specific embodiment
It is carried out according to the following table and gets the raw materials ready：
Part is respectively adopted in four embodiments:
Above-mentioned four embodiments for getting material ready are carried out into following processing respectively：
1) calcareous filler, is sent into high speed mixer, activator is added, 1-3 is activated at a temperature of 80~150 DEG C small
When；
2) remaining raw material, is heated to 100~150 DEG C by feeding high speed mixer, 45~85 DEG C is cooled to and is put into material
Cylinder；
3) mixed raw material, is added into extruder, 120~200 DEG C of extrusions, extruder barrel temperature 130~200 are heated to
DEG C, 130~220 DEG C of mold temperature, 8~30 turns/min of engine speed, 8~30 turns/min of feeding rotating speed；
4) through calendering formation, traction and cutting after, extruding.
Following table is the mechanics testing result of embodiment 4：
Due to increased tungsten-carbide powder, the wearability of Wood-plastic material is effectively increased.
In order to improve the intensity on floor of the invention, Graphene can be added in dispensing, addition is PVC resin powder weight
The 0.1%-0.5% of amount, obtained sheet material hardness can at least improve 10%, and the modulus of elasticity in static bending can at least improve 5%.
Additionally, intensity and corrosion resistance in order to further improve material, can add and break into metal foam
The material of powder, metal foam can be nickel foam, foam copper, titanium foam, foam iron-nickel etc., preferred foams titanium.
Titanium foam is crushed into the powder for 30 to 50 mesh, according to 1~embodiment of embodiment 4, add 0.3 respectively, 0.6,
0.9th, 1.2 weight portion is added, and remaining preparation technology is ibid.
Due to titanium foam crush after, powder has irregular shape, can well with substrate with therefore, it is possible to more preferable
Be cured in matrix.Intensity is with without compared with, it is possible to increase 10~15%.And titanium has good corrosion-resistant energy in itself
Power such that it is able to further improve the decay resistance of wood plastic composite.
In order to improve the anti-microbial property of wood and plastic composite of the invention, Nano Silver can be added in dispensing, Nano Silver
Between 25-50 nanometers, addition is the 1%-5% of PVC resin powder weight to particle diameter, after adding Nano Silver, obtained sheet material
Antibiotic property effectively improves, and by the Escherichia coli antibacterial test of ASTME2180 standards, sterilizing rate reaches more than 90%.
Environmentally friendly bathroom floor of the invention and preparation method thereof has the following advantages that：
1st, surface coated with superpower wear-resistant macromolecule PVC wearing layers, with case hardness very high；
2nd, mould proof anti-moth, is adapted to be used in bathroom；
3rd, there is extremely low shrinkage factor under high humidity high-heat environment；
4th, with high-wearing feature, high resiliency and superpower shock resistance, and the cheap, production cycle is long, water proof fire retardant；
5th, 10-15 DEG C of processing temperature and die head temperature are reduced in process of production, continuous maching time is extended, and are reduced
Energy resource consumption, reduces mechanical wear, reduces the integrated cost of plastic processing, under the conditions of like products quality and energy resource consumption,
Can improve production efficiency 10%~30%；
6th, environmental protection, without formaldehyde, heavy metal, will not cause harm during production and use to environment, people；
7th, easy for installation, lightweight, good muffling effect, elasticity it is good, using after the several years can 100% reclaim；
8th, floor can simulate natural wood grain, bag, can also possess abundant geometrical pattern as ceramic tile, aesthetic property
It is good.
This is not limited to, any change or replacement expected without creative work should all be covered in guarantor of the invention
Within the scope of shield.Therefore, protection scope of the present invention should be determined by the scope of protection defined in the claims.
Claims (3)
1. a kind of environmentally friendly bathroom floor, the parts by weight comprising component and each component are：
PVC resin powder 50-100 parts；
Calcareous filler 150-250 parts；
1-5 parts of conditioning agent of plasticising；
Stabilizer 3-6 parts；
Processing aid 1-3 parts；
Lubricant 1-3 parts；
Activator 0.1-0.5 parts；
Antishrinking agent 5-20 parts；
0.1-1 parts of environment friendly mildew resistant agent,
Tungsten-carbide powder 0.1-0.5 parts.
2. environmentally friendly bathroom floor according to claim 1, it is characterised in that
Described calcareous filler is the powdered whiting of 600-1200 mesh；
Described plasticising conditioning agent is double methyl esters；
Described stabilizer is at least one in calcium zinc stabilizer and organic tin stabilizer；
Described processing aid is styrene；
Described lubricant is stearic acid；
Described activator is aryl carboxylic acid metallic soap；
Described antishrinking agent is at least one in MBS and chliorinated polyvinyl chloride；
Described environment friendly mildew resistant agent is alkyl ammonium compounds；
Described tungsten-carbide powder is 200-300 mesh.
3. a kind of preparation method for preparing environmental protection bathroom floor as claimed in claim 1 or 2, comprising step：
1) calcareous filler, is sent into high speed mixer, activator is added, is activated 1-3 hours at a temperature of 80~150 DEG C；
2) remaining raw material, is heated to 100~150 DEG C by feeding high speed mixer, 45~85 DEG C is cooled to and is put into barrel；
3) mixed raw material, is added into extruder, 120~200 DEG C is heated to and is extruded, 130~200 DEG C of extruder barrel temperature,
130~220 DEG C of mold temperature, 8~30 turns/min of engine speed, 8~30 turns/min of feeding rotating speed；
4) through calendering formation, traction and cutting after, extruding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611176305.3A CN106751200A (en) | 2016-12-19 | 2016-12-19 | Environmentally friendly bathroom floor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611176305.3A CN106751200A (en) | 2016-12-19 | 2016-12-19 | Environmentally friendly bathroom floor and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106751200A true CN106751200A (en) | 2017-05-31 |
Family
ID=58889750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611176305.3A Pending CN106751200A (en) | 2016-12-19 | 2016-12-19 | Environmentally friendly bathroom floor and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106751200A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141649A (en) * | 2017-06-05 | 2017-09-08 | 浙江巨美家科技有限公司 | The preparation method of the bed of material in a kind of hard multi-layer composite PVC floor |
| CN107418086A (en) * | 2017-06-05 | 2017-12-01 | 浙江巨美家科技有限公司 | A kind of preparation method of hard multi-layer composite PVC floor initial bed |
| CN109093969A (en) * | 2018-08-06 | 2018-12-28 | 丰县正标卫浴有限公司 | A kind of wallboard of unitary bathroom substrate and preparation method thereof |
| CN109968736A (en) * | 2019-02-19 | 2019-07-05 | 滁州卷烟材料厂 | A kind of fungus-resistant type corrugated case |
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| CN103642148A (en) * | 2013-11-04 | 2014-03-19 | 孔祥利 | Stone plastic floor |
| CN104710711A (en) * | 2015-03-24 | 2015-06-17 | 陕西金禾农业科技有限公司 | PVC (polyvinyl chloride) artificial marble board |
| CN104945782A (en) * | 2015-07-21 | 2015-09-30 | 河南圣美阳光装饰材料有限公司 | Stone-plastic board, manufacturing method thereof and stone-plastic door casing |
| CN105647051A (en) * | 2014-11-12 | 2016-06-08 | 吉林吉瑞莱板材科技有限公司 | Diatomite calcified plastic board and production method therefor |
-
2016
- 2016-12-19 CN CN201611176305.3A patent/CN106751200A/en active Pending
Patent Citations (4)
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|---|---|---|---|---|
| CN103642148A (en) * | 2013-11-04 | 2014-03-19 | 孔祥利 | Stone plastic floor |
| CN105647051A (en) * | 2014-11-12 | 2016-06-08 | 吉林吉瑞莱板材科技有限公司 | Diatomite calcified plastic board and production method therefor |
| CN104710711A (en) * | 2015-03-24 | 2015-06-17 | 陕西金禾农业科技有限公司 | PVC (polyvinyl chloride) artificial marble board |
| CN104945782A (en) * | 2015-07-21 | 2015-09-30 | 河南圣美阳光装饰材料有限公司 | Stone-plastic board, manufacturing method thereof and stone-plastic door casing |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141649A (en) * | 2017-06-05 | 2017-09-08 | 浙江巨美家科技有限公司 | The preparation method of the bed of material in a kind of hard multi-layer composite PVC floor |
| CN107418086A (en) * | 2017-06-05 | 2017-12-01 | 浙江巨美家科技有限公司 | A kind of preparation method of hard multi-layer composite PVC floor initial bed |
| CN109093969A (en) * | 2018-08-06 | 2018-12-28 | 丰县正标卫浴有限公司 | A kind of wallboard of unitary bathroom substrate and preparation method thereof |
| CN109968736A (en) * | 2019-02-19 | 2019-07-05 | 滁州卷烟材料厂 | A kind of fungus-resistant type corrugated case |
| CN109968736B (en) * | 2019-02-19 | 2021-09-14 | 滁州卷烟材料厂 | Mould proof type corrugated box that suppresses bacteria |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
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