CN105419155A - High-weather-resistance modified plastic - Google Patents

High-weather-resistance modified plastic Download PDF

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Publication number
CN105419155A
CN105419155A CN201510852604.3A CN201510852604A CN105419155A CN 105419155 A CN105419155 A CN 105419155A CN 201510852604 A CN201510852604 A CN 201510852604A CN 105419155 A CN105419155 A CN 105419155A
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CN
China
Prior art keywords
parts
weatherability
modified plastics
resol
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510852604.3A
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Chinese (zh)
Inventor
闫海玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bengbu Haiming Die Casting Machine Co Ltd
Original Assignee
Bengbu Haiming Die Casting Machine Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bengbu Haiming Die Casting Machine Co Ltd filed Critical Bengbu Haiming Die Casting Machine Co Ltd
Priority to CN201510852604.3A priority Critical patent/CN105419155A/en
Publication of CN105419155A publication Critical patent/CN105419155A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a high-weather-resistance modified plastic. The high-weather-resistance modified plastic is prepared from polyvinyl chloride, phenolic resin, aluminum powder, silica powder, a dispersing agent, a heat stabilizer and a plasticizing agent. Due to the fact that modified phenolic resin is added into the plastic and combined with silica powder and nano-aluminum particles, the structural property of the plastic can be improved, and the weather resistance of the plastic can be greatly improved. The production technology is simple and low in cost, and the prepared plastic has excellent heat stability.

Description

A kind of modified plastics of high-weatherability
Technical field
The present invention relates to plastic production field, particularly relate to a kind of modified plastics of high-weatherability.
Background technology
General igelite on market, the degree of branching is less, relative density about 1.4, second-order transition temperature 77 ~ 90 DEG C, about 170 DEG C start to decompose, to the poor stability of light and heat, more than 100 DEG C or through long-time exposure in sunshine, will decompose and produce hydrogenchloride, and autocatalytically is decomposed further, cause variable color, physical and mechanical properties also declines rapidly, the comparatively large and shock resistance of fragility, weathering resistance are poor, and these deficiencies make its application be restricted.
Summary of the invention
The object of this invention is to provide a kind of modified plastics of high-weatherability, be achieved through the following technical solutions:
A modified plastics for high-weatherability, is made up of following composition: polyvinyl chloride 40 parts, 30 parts, resol, aluminium powder 8 parts, silica flour 6 parts, dispersion agent 3 parts, thermo-stabilizer 2 parts, 2 parts, softening agent by weight.
Further, described aluminium powder adopts the heating in water bath process of 60-65 DEG C after 1-1.5 hour, dry.
Further, described dispersion agent is glyceryl monostearate.
Further, described thermo-stabilizer is calcium stearate.
Further, described softening agent is citrate.
Further, described resol is through modification: the dodecyltrimethoxysilane Homogeneous phase mixing under alkaline environment by resol and weight part being 5 parts, initial heating temperature to 300 DEG C, continue after 20 minutes, add the boric acid that weight part is 3 parts, continue slowly to heat, in 2 hours, temperature is increased to till 500 DEG C, start Slow cooling, when being cooled to 187 DEG C, keeping after 20 minutes, continuing to be cooled to 132 DEG C, keep 20 minutes, till last cool to room temperature.
Further, the resol through modification is heated to together with silica flour can Homogeneous phase mixing to together, then add the nano aluminum particle that weight part is 4 parts, mix; The granularity of described nano aluminum particle is 15-18nm.
The invention has the beneficial effects as follows: the present invention is directed to prior art above shortcomings, the present invention is by adding the resol through modification in the plastic and being combined with silica flour, nano aluminum granule by modified resol, the textural property of plastics can be improved, improve the weathering resistance of plastics greatly; Production technique of the present invention is simple, and cost is low, and the plastics of making have excellent thermostability.
Embodiment
A modified plastics for high-weatherability, is made up of following composition: polyvinyl chloride 40 parts, 30 parts, resol, aluminium powder 8 parts, silica flour 6 parts, dispersion agent 3 parts, thermo-stabilizer 2 parts, 2 parts, softening agent by weight.
Further, described aluminium powder adopts the heating in water bath process of 60-65 DEG C after 1-1.5 hour, dry.
Further, described dispersion agent is glyceryl monostearate.
Further, described thermo-stabilizer is calcium stearate.
Further, described softening agent is citrate.
Further, described resol is through modification: the dodecyltrimethoxysilane Homogeneous phase mixing under alkaline environment by resol and weight part being 5 parts, initial heating temperature to 300 DEG C, continue after 20 minutes, add the boric acid that weight part is 3 parts, continue slowly to heat, in 2 hours, temperature is increased to till 500 DEG C, start Slow cooling, when being cooled to 187 DEG C, keeping after 20 minutes, continuing to be cooled to 132 DEG C, keep 20 minutes, till last cool to room temperature.
Further, the resol through modification is heated to together with silica flour can Homogeneous phase mixing to together, then add the nano aluminum particle that weight part is 4 parts, mix; The granularity of described nano aluminum particle is 15-18nm.
A modified plastics for high-weatherability, comprising:
1) take respectively by weight, polyvinyl chloride 40 parts, 30 parts, resol, aluminium powder 8 parts, silica flour 6 parts, dispersion agent 3 parts, thermo-stabilizer 2 parts, 2 parts, softening agent.
2) by polyvinyl chloride, resol, aluminium powder, silica flour mixing, uniform stirring is after 30 minutes, remix dispersion agent, thermo-stabilizer and softening agent, add in forcing machine, extruding plasticizing and uniformly plastic grain, the processing condition extruding process are: a district temperature 210-220 DEG C, two district temperature 220-240 DEG C, three district temperature 240-260 DEG C, four district temperature 260-270 DEG C, the residence time is 2 minutes.
The performance parameters of plastics of the present invention:
Density g/cm3 Elongation at break % Dielectric strength MV/m Low-temperature impact embrittlement temperature DEG C
Plastics of the present invention 1.42 287.4 18.6 ≤-20
Table 1
Modified plastics performance test of the present invention:
Table 2
As can be seen from Table 2, plastics of the present invention are much more superior than general igelite in performance.

Claims (7)

1. a modified plastics for high-weatherability, is characterized in that, is made up by weight of following composition: polyvinyl chloride 40 parts, 30 parts, resol, aluminium powder 8 parts, silica flour 6 parts, dispersion agent 3 parts, thermo-stabilizer 2 parts, 2 parts, softening agent.
2. the modified plastics of a kind of high-weatherability according to claim 1, is characterized in that, described aluminium powder adopts the heating in water bath process of 60-65 DEG C after 1-1.5 hour, dry.
3. the modified plastics of a kind of high-weatherability according to claim 1, is characterized in that, described dispersion agent is glyceryl monostearate.
4. the modified plastics of a kind of high-weatherability according to claim 1, is characterized in that, described thermo-stabilizer is calcium stearate.
5. the modified plastics of a kind of high-weatherability according to claim 1, is characterized in that, described softening agent is citrate.
6. the modified plastics of a kind of high-weatherability according to claim 1, it is characterized in that, described resol is through modification: the dodecyltrimethoxysilane Homogeneous phase mixing under alkaline environment by resol and weight part being 5 parts, initial heating temperature to 300 DEG C, continue after 20 minutes, add the boric acid that weight part is 3 parts, continue slowly heating, in 2 hours, temperature is increased to till 500 DEG C, starts Slow cooling, when being cooled to 187 DEG C, keep after 20 minutes, continue to be cooled to 132 DEG C, keep 20 minutes, till last cool to room temperature.
7. the modified plastics of a kind of high-weatherability according to claim 1 or 6, it is characterized in that, the resol through modification is heated to together with silica flour can Homogeneous phase mixing to together, then add the nano aluminum particle that weight part is 4 parts, mix; The granularity of described nano aluminum particle is 15-18nm.
CN201510852604.3A 2015-11-27 2015-11-27 High-weather-resistance modified plastic Pending CN105419155A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510852604.3A CN105419155A (en) 2015-11-27 2015-11-27 High-weather-resistance modified plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510852604.3A CN105419155A (en) 2015-11-27 2015-11-27 High-weather-resistance modified plastic

Publications (1)

Publication Number Publication Date
CN105419155A true CN105419155A (en) 2016-03-23

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Country Status (1)

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CN (1) CN105419155A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105820468A (en) * 2016-04-26 2016-08-03 界首市锦丰塑业有限公司 Durable plastic cloth
CN105820471A (en) * 2016-04-26 2016-08-03 界首市锦丰塑业有限公司 High-strength modified plastic
CN105820470A (en) * 2016-04-26 2016-08-03 界首市锦丰塑业有限公司 High-toughness antibacterial modified plastic
CN105837978A (en) * 2016-04-26 2016-08-10 界首市锦丰塑业有限公司 Waste plastic modified polyvinyl chloride
CN105860344A (en) * 2016-04-26 2016-08-17 界首市锦丰塑业有限公司 Heat resistant modified plastic granule
CN107778682A (en) * 2017-10-19 2018-03-09 界首市锦丰塑业有限公司 A kind of weatherability modified plastics

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2283073B1 (en) * 2008-04-30 2012-09-12 E. I. du Pont de Nemours and Company Plastic surfaces having improved surface characteristics
CN103396621A (en) * 2013-07-15 2013-11-20 安徽济峰节能材料有限公司 Modified PVC (polyvinyl chloride) foam wall panel and preparation method thereof
CN105038042A (en) * 2015-09-23 2015-11-11 界首市申发雨鞋有限责任公司 High-strength modified plastic
CN105061950A (en) * 2015-09-23 2015-11-18 界首市申发雨鞋有限责任公司 Modified heat-resistant plastic

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2283073B1 (en) * 2008-04-30 2012-09-12 E. I. du Pont de Nemours and Company Plastic surfaces having improved surface characteristics
CN103396621A (en) * 2013-07-15 2013-11-20 安徽济峰节能材料有限公司 Modified PVC (polyvinyl chloride) foam wall panel and preparation method thereof
CN105038042A (en) * 2015-09-23 2015-11-11 界首市申发雨鞋有限责任公司 High-strength modified plastic
CN105061950A (en) * 2015-09-23 2015-11-18 界首市申发雨鞋有限责任公司 Modified heat-resistant plastic

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105820468A (en) * 2016-04-26 2016-08-03 界首市锦丰塑业有限公司 Durable plastic cloth
CN105820471A (en) * 2016-04-26 2016-08-03 界首市锦丰塑业有限公司 High-strength modified plastic
CN105820470A (en) * 2016-04-26 2016-08-03 界首市锦丰塑业有限公司 High-toughness antibacterial modified plastic
CN105837978A (en) * 2016-04-26 2016-08-10 界首市锦丰塑业有限公司 Waste plastic modified polyvinyl chloride
CN105860344A (en) * 2016-04-26 2016-08-17 界首市锦丰塑业有限公司 Heat resistant modified plastic granule
CN107778682A (en) * 2017-10-19 2018-03-09 界首市锦丰塑业有限公司 A kind of weatherability modified plastics

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Application publication date: 20160323

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