CN106589671A - Antibacterial plastic bottle and preparation method thereof - Google Patents
Antibacterial plastic bottle and preparation method thereof Download PDFInfo
- Publication number
- CN106589671A CN106589671A CN201611019208.3A CN201611019208A CN106589671A CN 106589671 A CN106589671 A CN 106589671A CN 201611019208 A CN201611019208 A CN 201611019208A CN 106589671 A CN106589671 A CN 106589671A
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- Prior art keywords
- parts
- plastic bottle
- raw material
- antioxidant
- antimicrobial plastic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/10—Applications used for bottles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses an antibacterial plastic bottle and a preparation method thereof. The antibacterial plastic bottle is prepared from, by mass, 35-45 parts of polyvinyl chloride, 6-11 parts of titanium dioxide, 5-8 parts of linalyl acetate, 4-6 parts of aniline, 1-5 parts of ethyl alcohol, 6-8 parts of titanate, 3-5 parts of dimethyl 2,2-thiobisacetate, 3-5 parts of cinnamamide sodium sulfovinate, 3-5 parts of sodium polyacrylate, 3-5 parts of ammonium nitrate, 0.5-0.8 part of silver-loaded zirconium phosphate, 3-5 parts of calcium phosphate, 1-3 parts of ammonium polyphosphate, 10-15 parts of antibacterial agent, 2-4 parts of antioxidant, 2-4 parts of plasticizer and 2-4 parts of flexibilizer. The antibacterial plastic bottle can effectively inhibit breeding of bacteria and germs, and is free of toxicity and peculiar smell at the same time.
Description
Technical field
The present invention relates to plastic bottle, more particularly to a kind of antimicrobial plastic bottle and preparation method thereof.
Background technology
With the extensive utilization of plastic bottle, the life of people is facilitated, especially in field of food, such as plastic bottle, oil bottle
Be loaded using plastic bottle, but, plastic bottle after uncapping using ingress of air, the bacterium of a part will take advantage of void and
Enter, enter in plastic bottle so that bacterium is produced in plastic bottle, the life of people is affected.
The information for being disclosed in the background section is merely intended to increase the understanding of the general background to the present invention, and should not
When the prior art for being considered to recognize or imply in any form the information structure well known to persons skilled in the art.
The content of the invention
It is an object of the invention to provide a kind of antimicrobial plastic bottle, so as to overcome existing plastic bottle scarce without antibacterial effect
Point.
For achieving the above object, the invention provides a kind of antimicrobial plastic bottle, in parts by mass, by following component raw material system
Into：Polyvinyl chloride 35-45 parts, titanium dioxide 6-11 parts, bergamio 5-8 parts, aniline 4-6 parts, ethanol 1-5 parts, titanate esters
6-8 parts, thiodiglycolic acid dimethyl ester 3-5 parts, osmanthus acyl aminoethyl sodium sulphate 3-5 parts, Sodium Polyacrylate 3-5 parts, ammonium nitrate 3-5
Part, silver-loaded zirconium phosphate 0.5-0.8 parts, calcium phosphate 3-5 parts, APP 1-3 parts, antiseptic 10-15 parts, antioxidant 2-4 parts, increasing
Modeling agent 2-4 parts and toughener 2-4 parts.
Preferably, antimicrobial plastic bottle in parts by mass, is made up of following component raw material：35 parts of polyvinyl chloride, titanium dioxide 6
Part, 5 parts of bergamio, 4 parts of aniline, 1 part of ethanol, 6 parts of titanate esters, 3 parts of thiodiglycolic acid dimethyl ester, osmanthus acyl aminoethyl sulfuric acid
3 parts of sodium, 3 parts of Sodium Polyacrylate, 3 parts of ammonium nitrate, 0.5 part of silver-loaded zirconium phosphate, 3 parts of calcium phosphate, 1 part of APP, antiseptic 10
Part, 2 parts of antioxidant, 2 parts of plasticizer and 2 parts of toughener.
Preferably, antimicrobial plastic bottle in parts by mass, is made up of following component raw material：45 parts of polyvinyl chloride, titanium dioxide
11 parts, 8 parts of bergamio, 6 parts of aniline, 5 parts of ethanol, 8 parts of titanate esters, 5 parts of thiodiglycolic acid dimethyl ester, osmanthus acyl aminoethyl sulphur
5 parts of sour sodium, 5 parts of Sodium Polyacrylate, 5 parts of ammonium nitrate, 0.8 part of silver-loaded zirconium phosphate, 5 parts of calcium phosphate, 3 parts of APP, antiseptic
4 parts of 15 parts, 4 parts of antioxidant, 4 parts of plasticizer and toughener.
Preferably, antimicrobial plastic bottle in parts by mass, is made up of following component raw material：40 parts of polyvinyl chloride, titanium dioxide 8
Part, 6 parts of bergamio, 5 parts of aniline, 3 parts of ethanol, 7 parts of titanate esters, 4 parts of thiodiglycolic acid dimethyl ester, osmanthus acyl aminoethyl sulfuric acid
4 parts of sodium, 4 parts of Sodium Polyacrylate, 4 parts of ammonium nitrate, 0.7 part of silver-loaded zirconium phosphate, 4 parts of calcium phosphate, 2 parts of APP, antiseptic 12
Part, 3 parts of antioxidant, 3 parts of plasticizer and 3 parts of toughener.
Preferably, the plasticizer is ATBC.
Preferably, the antioxidant is phosphite ester kind antioxidant.
Preferably, the antiseptic is silver nitrate.
Preferably, the toughener is MBS.
The preparation method of above-mentioned radiation-proof plastic bottle, comprises the following steps：1) above-mentioned raw materials addition reactor is carried out
Premixing, stirring, and it is heated to fused raw material；2) fused raw material is passed through into extruding machine extrusion moulding raw material；3) by shaping raw material
Embryo is molded into by injection machine；4) by embryo's blow molding；5) bottle is taken off.
Preferably, blow molding pass sequentially through bottle blowing, prolong modeling, cooling and pressurize operation complete.
Compared with prior art, antimicrobial plastic bottle of the invention can effectively suppress bacterium, germ to grow, while anti-
Bacterium plastic bottle is nontoxic, free from extraneous odour.
Specific embodiment
The specific embodiment of the present invention is described in detail below, it is to be understood that protection scope of the present invention is not
Limited by specific embodiment.
Explicitly indicate that unless otherwise other, otherwise in entire disclosure and claims, term " including " or its change
Change such as "comprising" or " including " etc. and will be understood to comprise statement part, and do not exclude other parts.
Embodiment 1：
According to the antimicrobial plastic bottle of the specific embodiment of the invention, in parts by mass, it is made up of following component raw material：Polychlorostyrene
30 parts of ethene, 5 parts of sorbierite, 5 parts of titanium dioxide, 5 parts of phenyl silicone oil, 4 parts of aniline, 1 part of linalool, sub- 6 parts of olefin(e) acid copper, chlorination
3 parts of 3 parts of zinc, 3 parts of triethylene tetramine, 3 parts of tossa, 10 parts of antiseptic, 3 parts of antioxidant, 3 parts of plasticizer and toughener.
Wherein, plasticizer is ATBC；Antioxidant is phenolic antioxidant；Antiseptic is receiving for identical mass fraction
The mixture of rice silica, nano titanium oxide and silver nitrate；Toughener is MBS
Copolymer.
The preparation method of above-mentioned antimicrobial plastic bottle, it is comprised the following steps：
1) above-mentioned raw materials addition reactor is pre-mixed, is stirred；
2) raw material in reactor is heated to into melting；
3) raw material after melting in reactor is passed through into extruding machine extrusion moulding；
4) raw material of extrusion moulding is molded into embryo by injection machine again；
5) by embryo's blow molding；Blow molding pass sequentially through bottle blowing, prolong modeling, cooling, it is interior it is cold, deflate and pressurize operation it is complete
Into.
6) bottle is taken off.
The antimicrobial plastic bottle of the present invention can effectively suppress bacterium, germ to grow, while antimicrobial plastic bottle is nontoxic, nothing
Peculiar smell, and with excellent weatherability.
Embodiment 2：
According to the antimicrobial plastic bottle of the specific embodiment of the invention, in parts by mass, it is made up of following component raw material：Polychlorostyrene
50 parts of ethene, 10 parts of sorbierite, 10 parts of titanium dioxide, 8 parts of phenyl silicone oil, 6 parts of aniline, 5 parts of linalool, sub- 8 parts of olefin(e) acid copper, chlorine
Change 5 parts of 5 parts of zinc, 5 parts of triethylene tetramine, 5 parts of tossa, 15 parts of antiseptic, 5 parts of antioxidant, 5 parts of plasticizer and toughener.
Wherein, plasticizer is ATBC；Antioxidant is phenolic antioxidant；Antiseptic is receiving for identical mass fraction
The mixture of rice silica, nano titanium oxide and silver nitrate；Toughener is MBS
Copolymer.
The preparation method of above-mentioned antimicrobial plastic bottle, it is comprised the following steps：
1) above-mentioned raw materials addition reactor is pre-mixed, is stirred；
2) raw material in reactor is heated to into melting；
3) raw material after melting in reactor is passed through into extruding machine extrusion moulding；
4) raw material of extrusion moulding is molded into embryo by injection machine again；
5) by embryo's blow molding；Blow molding pass sequentially through bottle blowing, prolong modeling, cooling, it is interior it is cold, deflate and pressurize operation it is complete
Into.
6) bottle is taken off.
The antimicrobial plastic bottle of the present invention can effectively suppress bacterium, germ to grow, while antimicrobial plastic bottle is nontoxic, nothing
Peculiar smell, and with excellent weatherability.
Embodiment 3：
According to the antimicrobial plastic bottle of the specific embodiment of the invention, in parts by mass, it is made up of following component raw material：Polychlorostyrene
45 parts of ethene, 7 parts of sorbierite, 7 parts of titanium dioxide, 6 parts of phenyl silicone oil, 5 parts of aniline, 3 parts of linalool, sub- 7 parts of olefin(e) acid copper, chlorination
4 parts of 4 parts of zinc, 4 parts of triethylene tetramine, 4 parts of tossa, 12 parts of antiseptic, 4 parts of antioxidant, 4 parts of plasticizer and toughener.
Wherein, plasticizer is ATBC；Antioxidant is phenolic antioxidant；Antiseptic is receiving for identical mass fraction
The mixture of rice silica, nano titanium oxide and silver nitrate；Toughener is MBS
Copolymer.
The preparation method of above-mentioned antimicrobial plastic bottle, it is comprised the following steps：
1) above-mentioned raw materials addition reactor is pre-mixed, is stirred；
2) raw material in reactor is heated to into melting；
3) raw material after melting in reactor is passed through into extruding machine extrusion moulding；
4) raw material of extrusion moulding is molded into embryo by injection machine again；
5) by embryo's blow molding；Blow molding pass sequentially through bottle blowing, prolong modeling, cooling, it is interior it is cold, deflate and pressurize operation it is complete
Into.
6) bottle is taken off.
The antimicrobial plastic bottle of the present invention can effectively suppress bacterium, germ to grow, while antimicrobial plastic bottle is nontoxic, nothing
Peculiar smell, and with excellent weatherability.
It is aforementioned to the present invention specific illustrative embodiment description be in order to illustrate and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed
And change.The purpose of selecting and describing the exemplary embodiment is that explaining that the certain principles and its reality of the present invention should
With so that those skilled in the art can realize and using the present invention a variety of exemplaries and
A variety of selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (10)
1. a kind of antimicrobial plastic bottle, it is characterised in that in parts by mass, be made up of following component raw material：Polyvinyl chloride 35-45
Part, titanium dioxide 6-11 parts, bergamio 5-8 parts, aniline 4-6 parts, ethanol 1-5 parts, titanate esters 6-8 part, thiodiglycolic acid
Dimethyl ester 3-5 parts, osmanthus acyl aminoethyl sodium sulphate 3-5 parts, Sodium Polyacrylate 3-5 parts, ammonium nitrate 3-5 parts, silver-loaded zirconium phosphate 0.5-
0.8 part, calcium phosphate 3-5 parts, APP 1-3 parts, antiseptic 10-15 parts, antioxidant 2-4 parts, plasticizer 2-4 parts and toughener
2-4 parts.
2. antimicrobial plastic bottle according to claim 1, it is characterised in that in parts by mass, be made up of following component raw material：
35 parts of polyvinyl chloride, 6 parts of titanium dioxide, 5 parts of bergamio, 4 parts of aniline, 1 part of ethanol, 6 parts of titanate esters, thiodiglycolic acid two
3 parts of methyl esters, 3 parts of osmanthus acyl aminoethyl sodium sulphate, 3 parts of Sodium Polyacrylate, 3 parts of ammonium nitrate, 0.5 part of silver-loaded zirconium phosphate, calcium phosphate 3
Part, 1 part of APP, 10 parts of antiseptic, 2 parts of antioxidant, 2 parts of plasticizer and 2 parts of toughener.
3. antimicrobial plastic bottle according to claim 1, it is characterised in that in parts by mass, be made up of following component raw material：
45 parts of polyvinyl chloride, 11 parts of titanium dioxide, 8 parts of bergamio, 6 parts of aniline, 5 parts of ethanol, 8 parts of titanate esters, thiodiglycolic acid
5 parts of dimethyl ester, 5 parts of osmanthus acyl aminoethyl sodium sulphate, 5 parts of Sodium Polyacrylate, 5 parts of ammonium nitrate, 0.8 part of silver-loaded zirconium phosphate, calcium phosphate 5
Part, 3 parts of APP, 15 parts of antiseptic, 4 parts of antioxidant, 4 parts of plasticizer and 4 parts of toughener.
4. antimicrobial plastic bottle according to claim 1, it is characterised in that in parts by mass, be made up of following component raw material：
40 parts of polyvinyl chloride, 8 parts of titanium dioxide, 6 parts of bergamio, 5 parts of aniline, 3 parts of ethanol, 7 parts of titanate esters, thiodiglycolic acid two
4 parts of methyl esters, 4 parts of osmanthus acyl aminoethyl sodium sulphate, 4 parts of Sodium Polyacrylate, 4 parts of ammonium nitrate, 0.7 part of silver-loaded zirconium phosphate, calcium phosphate 4
Part, 2 parts of APP, 12 parts of antiseptic, 3 parts of antioxidant, 3 parts of plasticizer and 3 parts of toughener.
5. antimicrobial plastic bottle according to claim 1, it is characterised in that the plasticizer is ATBC.
6. antimicrobial plastic bottle according to claim 1, it is characterised in that the antioxidant is phosphite ester kind antioxidant.
7. antimicrobial plastic bottle according to claim 1, it is characterised in that the antiseptic is silver nitrate.
8. antimicrobial plastic bottle according to claim 1, it is characterised in that the toughener is methyl methacrylate-fourth
Diene-styrene copolymer.
9. a kind of preparation method of antimicrobial plastic bottle according to claim 1, it is characterised in that comprise the following steps：
1) above-mentioned raw materials addition reactor is pre-mixed, is stirred, and be heated to fused raw material；
2) fused raw material is passed through into extruding machine extrusion moulding raw material；
3) shaping raw material is molded into into embryo by injection machine；
4) by embryo's blow molding；
5) bottle is taken off.
10. preparation method according to claim 9, it is characterised in that blow molding passes sequentially through bottle blowing, prolongs modeling, cooling
Complete with pressurize operation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611019208.3A CN106589671A (en) | 2016-11-10 | 2016-11-10 | Antibacterial plastic bottle and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611019208.3A CN106589671A (en) | 2016-11-10 | 2016-11-10 | Antibacterial plastic bottle and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106589671A true CN106589671A (en) | 2017-04-26 |
Family
ID=58592246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611019208.3A Pending CN106589671A (en) | 2016-11-10 | 2016-11-10 | Antibacterial plastic bottle and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106589671A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107540984A (en) * | 2017-08-22 | 2018-01-05 | 安徽悦尔伟塑料机械有限公司 | Degradable plastic bottle and preparation method thereof |
| CN113354900A (en) * | 2021-06-29 | 2021-09-07 | 漳州市圣铭工贸股份有限公司 | Antibacterial plastic bottle ingredient and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102872653A (en) * | 2012-09-28 | 2013-01-16 | 上海交通大学 | Antibacterial filtering material for mask and method for manufacturing antibacterial filtering material |
| CN104804457A (en) * | 2015-04-17 | 2015-07-29 | 青岛康泰鑫环保科技有限公司 | Antimicrobial plastic |
| CN105086282A (en) * | 2015-09-01 | 2015-11-25 | 南宁市聚祥塑料制品有限责任公司 | Antibacterial plastic bottle and preparing method of antibacterial plastic bottle |
| CN105949643A (en) * | 2016-05-15 | 2016-09-21 | 淄博夸克医药技术有限公司 | Antibacterial plastic |
-
2016
- 2016-11-10 CN CN201611019208.3A patent/CN106589671A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102872653A (en) * | 2012-09-28 | 2013-01-16 | 上海交通大学 | Antibacterial filtering material for mask and method for manufacturing antibacterial filtering material |
| CN104804457A (en) * | 2015-04-17 | 2015-07-29 | 青岛康泰鑫环保科技有限公司 | Antimicrobial plastic |
| CN105086282A (en) * | 2015-09-01 | 2015-11-25 | 南宁市聚祥塑料制品有限责任公司 | Antibacterial plastic bottle and preparing method of antibacterial plastic bottle |
| CN105949643A (en) * | 2016-05-15 | 2016-09-21 | 淄博夸克医药技术有限公司 | Antibacterial plastic |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107540984A (en) * | 2017-08-22 | 2018-01-05 | 安徽悦尔伟塑料机械有限公司 | Degradable plastic bottle and preparation method thereof |
| CN113354900A (en) * | 2021-06-29 | 2021-09-07 | 漳州市圣铭工贸股份有限公司 | Antibacterial plastic bottle ingredient and preparation method thereof |
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Application publication date: 20170426 |
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