CN106588045A - Tundish for continuous casting - Google Patents

Tundish for continuous casting Download PDF

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Publication number
CN106588045A
CN106588045A CN201611111527.7A CN201611111527A CN106588045A CN 106588045 A CN106588045 A CN 106588045A CN 201611111527 A CN201611111527 A CN 201611111527A CN 106588045 A CN106588045 A CN 106588045A
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CN
China
Prior art keywords
calcium
working lining
continuous casting
layer
magnesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611111527.7A
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Chinese (zh)
Inventor
林先桥
冯广
雷青云
丁良盛
康斌峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN WINNING TECHNOLOGY Co Ltd
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WUHAN WINNING TECHNOLOGY Co Ltd
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Application filed by WUHAN WINNING TECHNOLOGY Co Ltd filed Critical WUHAN WINNING TECHNOLOGY Co Ltd
Priority to CN201611111527.7A priority Critical patent/CN106588045A/en
Publication of CN106588045A publication Critical patent/CN106588045A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/02Linings

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention relates to tundish for continuous casting. The tundish comprises a first working layer, a second working layer, a third working layer, a permanent layer, a thermal-insulation layer and a steel shell which are sequentially stacked from inside to outside. The tundish has the advantages that the tundish adopts three working layers, the calcium content of the three working layers is different and changes in a stepped manner, molten steel can be purified effectively, scouring and corrosion by molten steel and slag can be resisted, slag adhering can be avoided, and tundish tilting can be performed easily; the permanent layer is high in strength and long in service life, and the thermal-insulation layer is good in thermal-insulation effect.

Description

A kind of continuous casting tundish
Technical field
The present invention relates to field of steel-making, and in particular to a kind of continuous casting tundish.
Background technology
Tundish is the refractory material containers used in mini-mill steelmaking, receives from ladle to pour the steel for getting off first Water, is then assigned in each crystallizer by middle water containing opening again.Tundish is the intermediate link of STEELMAKING PRODUCTION flow process, and It is the connecting points that continuous operation is turned to by intermittently operated.Tundish is improve output of steel and quality important as metallurgical reaction One ring.With Tapping Temperature of Bof raising, the application of various ladle refining techniques, and middle continuous cast crystallizer number pour the time with even Improve constantly, the pressure that middle ladle-lining is subject to constantly increases, and working environment becomes more severe.Effect in view of middle bag (subtracts Pressure, current stabilization, go to be mingled with, store and shunt molten steel), it is necessary to centering ladle-lining is optimized design, reasonable selection refractory material.Mesh Before, it is all using traditional heat-insulation layer+permanent layer+working lining or permanent layer+working lining that domestic existing tundish liner body is most of Build form by laying bricks or stones, heat-insulation layer typically adopts refractory fibre, permanent layer to adopt magnesia painting using clay or high alumina castable, working lining Material.The combination of these materials be present, if do not adopted heat-insulation layer, liner body heat insulation effect is poor, and thermal loss is big;Using resistance to The heat-insulation layer of fiery fiber, the easy efflorescence of life-time service, causes cavity, there is potential safety hazard;Permanent layer service life is low;Working lining is used Magnesia coating have that smear is bad, have the problem of secondary pollution to molten steel.
The content of the invention
The technical problem to be solved is to provide a kind of high insulating effect, can purify molten steel and long-lived company Casting tundish.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:A kind of continuous casting tundish, including from the inside to the outside according to First working lining of secondary stacking, the second working lining, the 3rd working lining, permanent layer, heat-insulation layer and box hat,
First working lining is built by laying bricks or stones by high-calcium type calcium and magnesium matter skinning loam and is formed, and high-calcium type calcium and magnesium matter skinning loam includes following Each composition of percentage by weight:10%~20% calcium oxide, 50%~70% magnesium oxide, 15%~20% resinoid bond, 3% ~5% paper fiber and 2%~5% carbon fiber;
Second working lining is built by laying bricks or stones by middle calcium type calcium and magnesium matter skinning loam and is formed, and middle calcium type calcium and magnesium matter skinning loam includes following Each composition of percentage by weight:5%~10% calcium oxide, 60%~80% magnesium oxide, 10%~15% silicon powder, 0%~5% Explosion-proof fiber and 5%~10% phenol-formaldehyde resin modified;
3rd working lining is built by laying bricks or stones by low calcium type calcium and magnesium matter skinning loam and is formed, and low calcium type calcium and magnesium matter skinning loam includes following Each composition of percentage by weight:1%~5% calcium oxide, 90%~95% magnesium oxide, 1%~3% boron oxide, 2%~3% aluminum Powder and 1%~2% sodium tripolyphosphate;
The permanent layer is formed by high alumina castable cast, and the high alumina castable includes following percentage by weight Each composition:85%~90% aluminium sesquioxide, 5%~8% silicon dioxide, 2%~3% organic fiber, 3%~5% hydration silicon Hydrochlorate and 0%~2% other impurities;
The heat-insulation layer is made up of aluminosilicate property fiber felt.
The invention has the beneficial effects as follows:A kind of continuous casting of present invention tundish adopts three layers of working lining, and three layers of working lining Calcareous content it is different, in stepped change, can effectively purify molten steel, be resistant to washing away and corroding for molten steel and slag, together When non-sticky slag, be easy to turn over bag;Permanent layer intensity is high, long service life, the high insulating effect of heat-insulation layer.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the thickness of the heat-insulation layer is 10~20mm.
Further, the bulk density of the permanent layer is more than or equal to 2.45g/cm under the conditions of 110 DEG C × 24h3
Further, the compressive resistance of the permanent layer is more than or equal to 20MPa under the conditions of 110 DEG C × 24h.
Further, the compressive resistance of the permanent layer is more than or equal to 60MPa under the conditions of 1350 DEG C × 3h.
Further, the rupture strength of the permanent layer is more than or equal to 6MPa under the conditions of 110 DEG C × 24h.
Further, the rupture strength of the permanent layer is more than or equal to 12MPa under the conditions of 1350 DEG C × 3h.
Further, the thickness of first working lining is more than the thickness of second working lining, second working lining Thickness more than the 3rd working lining thickness.
Description of the drawings
Fig. 1 is a kind of structural representation of continuous casting tundish of the invention.
In accompanying drawing, the list of parts representated by each label is as follows:
1st, a working lining, the 2, second working lining, the 3, the 3rd working lining, 4, permanent layer, 5, heat-insulation layer, 6, box hat.
Specific embodiment
The principle and feature of the present invention are described below in conjunction with accompanying drawing, example is served only for explaining the present invention, and It is non-for limiting the scope of the present invention.
As shown in figure 1, a kind of continuous casting tundish, works including the first working lining 1, second for stacking gradually from the inside to the outside The 2, the 3rd working lining 3 of layer, permanent layer 4, heat-insulation layer 5 and box hat 6,
First working lining 1 is built by laying bricks or stones by high-calcium type calcium and magnesium matter skinning loam and is formed, the high-calcium type calcium and magnesium matter skinning loam include with Each composition of lower percentage by weight:10%~20% calcium oxide, 50%~70% magnesium oxide, 15%~20% resinoid bond, 3%~5% paper fiber and 2%~5% carbon fiber;
Second working lining 2 is built by laying bricks or stones by middle calcium type calcium and magnesium matter skinning loam and is formed, the middle calcium type calcium and magnesium matter skinning loam include with Each composition of lower percentage by weight:5%~10% calcium oxide, 60%~80% magnesium oxide, 10%~15% silicon powder, 0%~ 5% explosion-proof fiber and 5%~10% phenol-formaldehyde resin modified;
3rd working lining 3 is built by laying bricks or stones by low calcium type calcium and magnesium matter skinning loam and is formed, the low calcium type calcium and magnesium matter skinning loam include with Each composition of lower percentage by weight:1%~5% calcium oxide, 90%~95% magnesium oxide, 1%~3% boron oxide, 2%~3% Aluminium powder and 1%~2% sodium tripolyphosphate;
The permanent layer 4 is formed by high alumina castable cast, and the high alumina castable includes following percentage by weight Each composition:85%~90% aluminium sesquioxide, 5%~8% silicon dioxide, 2%~3% organic fiber, 3%~5% hydration Silicate, 0%~2% other impurities;
The heat-insulation layer 5 is made up of aluminosilicate property fiber felt.
The thickness of the heat-insulation layer 5 be 10~20mm, you can think 10mm, can be 20mm, can also for 10 to 20 it Between any value, such as 15mm.
The bulk density of the permanent layer 4 is more than or equal to 2.45g/cm under the conditions of 110 DEG C × 24h3
The compressive resistance of the permanent layer 4 is more than or equal to 20MPa under the conditions of 110 DEG C × 24h.
The compressive resistance of the permanent layer 4 is more than or equal to 60MPa under the conditions of 1350 DEG C × 3h.
The rupture strength of the permanent layer 4 is more than or equal to 6MPa under the conditions of 110 DEG C × 24h.
The rupture strength of the permanent layer 4 is more than or equal to 12MPa under the conditions of 1350 DEG C × 3h.
The thickness of first working lining 1 is more than the thickness of second working lining 2, the thickness of second working lining 2 Thickness of the degree more than the 3rd working lining 3.
In specific examples below:
First working lining 1 is built by laying bricks or stones by high-calcium type calcium and magnesium matter skinning loam and is formed, the high-calcium type calcium and magnesium matter skinning loam include with Each composition of lower percentage by weight:
The content of calcium oxide can be 10%, or 20%, can also be any value between 10% to 20%, example Such as 15%;
The content of magnesium oxide can be 50%, or 70%, can also be any value between 50% to 70%, example Such as 60%;
The content of resinoid bond can be 15%, or 20%, can also be arbitrary between 15% to 20% Value, such as 18%;
The content of paper fiber can be 3%, or 5%, can also be any value between 3% to 5%, for example 4%;
The content of carbon fiber can be 2%, or 5%, can also be any value between 2% to 5%, for example 3%.
Second working lining 2 is built by laying bricks or stones by middle calcium type calcium and magnesium matter skinning loam and is formed, the middle calcium type calcium and magnesium matter skinning loam include with Each composition of lower percentage by weight:
The content of calcium oxide can be 5%, or 10%, can also be any value between 5% to 10%, for example 7.5%;
The content of magnesium oxide can be 60%, or 80%, can also be any value between 60% to 80%, example Such as 70%;
The content of silicon powder can be 10%, or 15%, can also be any value between 10% to 15%, example Such as 12.5%;
The content of explosion-proof fiber can be 0%, or 5%, can also be any value between 0% to 5%, for example 2.5%;
The content of phenol-formaldehyde resin modified can be 5%, or 10%, can also be arbitrary between 5% to 10% Value, such as 7.5%.
3rd working lining 3 is built by laying bricks or stones by low calcium type calcium and magnesium matter skinning loam and is formed, the low calcium type calcium and magnesium matter skinning loam include with Each composition of lower percentage by weight:
The content of calcium oxide can be 1%, or 5%, can also be any value between 1% to 5%, for example 2%;
The content of magnesium oxide can be 90%, or 95%, can also be any value between 90% to 95%, example Such as 92%;
The content of boron oxide can be 1%, or 3%, can also be any value between 1% to 3%, for example 2%;
The content of aluminium powder can be 2%, or 3%, can also be any value between 2% to 3%, for example 2.5%;
The content of sodium tripolyphosphate can be 1%, or 2%, can also be any value between 1% to 2%, example Such as 1.5%.
The permanent layer 4 is formed by high alumina castable cast, and the high alumina castable includes following percentage by weight Each composition:
The content of aluminium sesquioxide can be 85%, or 90%, can also be arbitrary between 85% to 90% Value, such as 87%;
The content of silicon dioxide can be 5%, or 8%, can also be any value between 5% to 8%, for example 6%;
The content of organic fiber can be 2%, or 3%, can also be any value between 2% to 3%, for example 2%;
The content of hydrosilicate can be 3%, or 5%, can also be any value between 3% to 5%, example Such as 4%;
The content of other impurities can be 0%, or 3%, can also be any value between 0% to 2%, for example 1%.
A kind of continuous casting of present invention tundish adopts three layers of working lining, and the calcareous content of three layers of working lining is different, in rank The change of ladder type, can effectively purify molten steel, be resistant to washing away and corroding for molten steel and slag, while non-sticky slag, being easy to turn over bag;Forever Long layer intensity is high, long service life, the high insulating effect of heat-insulation layer.
The foregoing is only presently preferred embodiments of the present invention, not to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.

Claims (8)

1. a kind of continuous casting tundish, it is characterised in that:Including the first working lining for stacking gradually from the inside to the outside, the second work Layer, the 3rd working lining, permanent layer, heat-insulation layer and box hat,
First working lining is built by laying bricks or stones by high-calcium type calcium and magnesium matter skinning loam and is formed, and high-calcium type calcium and magnesium matter skinning loam includes following weight Each composition of percentage ratio:10%~20% calcium oxide, 50%~70% magnesium oxide, 15%~20% resinoid bond, 3%~ 5% paper fiber and 2%~5% carbon fiber;
Second working lining is built by laying bricks or stones by middle calcium type calcium and magnesium matter skinning loam and is formed, and middle calcium type calcium and magnesium matter skinning loam includes following weight Each composition of percentage ratio:5%~10% calcium oxide, it is 60%~80% magnesium oxide, 10%~15% silicon powder, 0%~5% explosion-proof Fiber and 5%~10% phenol-formaldehyde resin modified;
3rd working lining is built by laying bricks or stones by low calcium type calcium and magnesium matter skinning loam and is formed, and low calcium type calcium and magnesium matter skinning loam includes following weight Each composition of percentage ratio:1%~5% calcium oxide, 90%~95% magnesium oxide, 1%~3% boron oxide, 2%~3% aluminium powder and 1%~2% sodium tripolyphosphate;
The permanent layer by high alumina castable cast form, the high alumina castable include following percentage by weight it is each into Point:85%~90% aluminium sesquioxide, 5%~8% silicon dioxide, 2%~3% organic fiber, 3%~5% hydrosilicate With 0%~2% other impurities;
The heat-insulation layer is made up of aluminosilicate property fiber felt.
2. a kind of continuous casting tundish according to claim 1, it is characterised in that:The thickness of the heat-insulation layer be 10~ 20mm。
3. a kind of continuous casting tundish according to claim 1 and 2, it is characterised in that:The bulk density of the permanent layer It is more than or equal to 2.45g/cm under the conditions of 110 DEG C × 24h3
4. a kind of continuous casting tundish according to claim 1 and 2, it is characterised in that:The compressive resistance of the permanent layer It is more than or equal to 20MPa under the conditions of 110 DEG C × 24h.
5. a kind of continuous casting tundish according to claim 1 and 2, it is characterised in that:The compressive resistance of the permanent layer It is more than or equal to 60MPa under the conditions of 1350 DEG C × 3h.
6. a kind of continuous casting tundish according to claim 1 and 2, it is characterised in that:The rupture strength of the permanent layer It is more than or equal to 6MPa under the conditions of 110 DEG C × 24h.
7. a kind of continuous casting tundish according to claim 1 and 2, it is characterised in that:The rupture strength of the permanent layer It is more than or equal to 12MPa under the conditions of 1350 DEG C × 3h.
8. a kind of continuous casting tundish according to claim 1 and 2, it is characterised in that:The thickness of first working lining Degree is more than the thickness of second working lining, and the thickness of second working lining is more than the thickness of the 3rd working lining.
CN201611111527.7A 2016-12-06 2016-12-06 Tundish for continuous casting Pending CN106588045A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201611111527.7A CN106588045A (en) 2016-12-06 2016-12-06 Tundish for continuous casting

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CN106588045A true CN106588045A (en) 2017-04-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111644607A (en) * 2020-07-07 2020-09-11 鞍钢股份有限公司 Method for preventing molten steel from recarburizing in ultra-low carbon steel production process

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CN202683999U (en) * 2012-05-04 2013-01-23 苏州罗卡节能科技有限公司 Continuous casting tundish
CN104193354A (en) * 2014-08-08 2014-12-10 上海利尔耐火材料有限公司 Permanent layer casting material of tundish and preparation method of permanent layer casting material
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111644607A (en) * 2020-07-07 2020-09-11 鞍钢股份有限公司 Method for preventing molten steel from recarburizing in ultra-low carbon steel production process
CN111644607B (en) * 2020-07-07 2021-12-24 鞍钢股份有限公司 Method for preventing molten steel from recarburizing in ultra-low carbon steel production process

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