CN106587918A - High-grade strengthen magnesia porcelain - Google Patents

High-grade strengthen magnesia porcelain Download PDF

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Publication number
CN106587918A
CN106587918A CN201611155991.6A CN201611155991A CN106587918A CN 106587918 A CN106587918 A CN 106587918A CN 201611155991 A CN201611155991 A CN 201611155991A CN 106587918 A CN106587918 A CN 106587918A
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blank
glaze
magnesia porcelain
raw material
porcelain
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CN201611155991.6A
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Inventor
罗新甲
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Hunan Xinhui Ceramic Co Ltd
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Hunan Xinhui Ceramic Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9646Optical properties
    • C04B2235/9653Translucent or transparent ceramics other than alumina
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a high-grade strengthen magnesia porcelain. The high-grade strengthen magnesia porcelain is prepared by the following steps: S1, blank preparation: sieving after ball-milling of a blank material, and performing rolling molding after aging to obtain a blank; S2, glaze application: soaking the blank obtained in the step S1 in a glaze slip, then lifting out, and attaching a glaze layer onto the surface of the blank to obtain a glazed green body; and S3, sintering: drying the glazed green body obtained in the step S2, transferring into an oxidizing-atmosphere kiln for sintering, and cooling to obtain the magnesia porcelain. The blank material is prepared from white talc, black talc, soda feldspar, potassium feldspar, quartz, washing sludge and Inner Mongolia soil, and a glaze material in the glaze slip is prepared from magnesia porcelain waste porcelain powder, washing sludge, Inner Mongolia soil, white talc, barium carbonate, zinc oxide, soda feldspar, potassium feldspar, calcite and cesium carbonate. The high-grade strengthen magnesia porcelain prepared by the steps is ringing in sound, low in probability of breakage and high in transparency.

Description

A kind of top grade strengthens magnesia porcelain
Technical field
The present invention relates to domestic ceramics technical field, and in particular to a kind of top grade strengthens magnesia porcelain.
Background technology
Ceramics have counted the history in dry year in the history of human being's production, and domestic ceramics is in ceramic various in style Most ancient and most traditional ceramics.At present porcelain species very abundant, develops in terms of type, decoration and even more makes rapid progress, skill Art innovation achievement emerges in an endless stream.With the continuous improvement of people's living standard, the practicality of ceramic product and appreciation are needed Ask more urgent.Ceramic art moulding, artistic decoration, carving product very abundant, various products are constantly brought forth new ideas, are enriched, and enrich The artistic demand of people.But the art pottery be only limitted to furnishings with decoration, only for the leisure after appreciate it, please it.Practicality and The ceramic of appreciating one could meet and enrich the material life of people and culture life intension, make people food and drink, After work, leisure, the Ceramics Culture and Chinese civilization history of China can be appreciated, savoured everywhere.
Magnesia porcelain (reinforcing porcelain) is also a kind of high-grade porcelain, and Britain just makes magnesium early in 18 end of the centurys by primary raw material of Talcum Matter porcelain, so magnesia porcelain is also known as steatite ceramic.Magnesia porcelain porcelain exquisiteness is milky white, thin tire is translucent, have greasy luster.Talcum is magnesium Hydrosilicate mineral, handss touch with soapy feeling, and slabbing structure, easy slabbing when crushing is difficult to crush.Magnesia porcelain was making Cheng Zhong, because its blank is mainly based on poor material, accounts for 80-88%, and plasticity bentonite is less, burns in reducing atmosphere condition More than 1350 DEG C, to be that base substrate has significantly different for its contraction change and common " clay, Anhydrite, quartz " in sintering process.According to Known technology cannot be solved at all, and the not high defect of frangible, transparency easily occur in magnesia ceramic products.
The content of the invention
The technical problem to be solved is to provide a kind of high-grade for the problems of existing magnesia porcelain Strengthen magnesia porcelain, its is clear, it is not easy to broken, transparency is high.
The technical problem to be solved can be achieved through the following technical solutions:
A kind of top grade strengthens magnesia porcelain, is prepared from by following steps:
S1, body preparation:To sieve after blank ball milling, old rear roll forming obtains base substrate;
S2, glazing:In the base substrate immersion glaze slip that step S1 is obtained, then propose, in billet surface glaze layer is adhered to, obtain Glazing green compact;
S3, sintering:The glazing green compact that step S2 is obtained are dried, and proceed to sintering in the kiln of oxidizing atmosphere, after cooling To the magnesia porcelain, it is characterised in that
The blank, is made up of the following raw material according to mass percent:
Above each component sum is 100%;
The preparation method of above-mentioned blank be will whiten stone, black talc, albite, potassium feldspar, quartz, wash mud, Inner Mongol soil point 200-400 mesh sieves, Fen Sui not be crossed, water stirring after weighing according to mass percent plus appropriate is made.
Glaze in the glaze slip, is made up of the following raw material according to mass percent:
The preparation method of above-mentioned glaze slip, comprises the following steps:
(1) pretreatment of raw material:Stone matter raw material is whitened into stone, albite, potassium feldspar and calcite and is processed at least 8 mesh excessively The powder of sieve;
(2) manufacture:All raw materials are added in the ball mill equipped with abrasive body by formula ratio, adds a certain amount of water to make glaze In 1.57~1.61g/100ml, more than 240 mesh, i.e., particle diameter is less than ball milling glaze slip to fineness slurry specific gravity control 0.061mm, detects, screen over-size is in 0.03-0.04% for qualified with 320 mesh sieves, you can blowing-mistake screens out ferrum-store for future use.
In a preferred embodiment of the invention, the blank, is made up of the following raw material according to mass percent:
In a preferred embodiment of the invention, the glaze in the glaze slip, by the following original according to mass percent Material composition:
The magnesia porcelain prepared using said method is clear, it is not easy to broken, and transparency is high.
Specific embodiment
Embodiment 1
The top grade of the embodiment strengthens magnesia porcelain, is prepared from by following steps:
S1, body preparation:To sieve after blank ball milling, old rear roll forming obtains base substrate;
S2, glazing:In the base substrate immersion glaze slip that step S1 is obtained, then propose, in billet surface glaze layer is adhered to, obtain Glazing green compact;
S3, sintering:The glazing green compact that step S2 is obtained are dried, and proceed to sintering in the kiln of oxidizing atmosphere, after cooling To the magnesia porcelain, wherein:
Above-mentioned blank, is made up of the following raw material according to mass percent:
It is will to whiten stone, black talc, albite, potassium feldspar, stone that the embodiment strengthens the preparation method of the blank of magnesia porcelain English, wash mud, Inner Mongol soil and crush respectively, cross 200-400 mesh sieves, after weighing according to mass percent plus appropriate water stirring is made.
Glaze in above-mentioned glaze slip, is made up of the following raw material according to mass percent:
The preparation method of above-mentioned glaze slip, comprises the following steps:
(1) pretreatment of raw material:Stone matter raw material is whitened into stone, albite, potassium feldspar and calcite and is processed at least 8 mesh excessively The powder of sieve;
(2) manufacture:All raw materials are added in the ball mill equipped with abrasive body by formula ratio, adds a certain amount of water to make glaze In 1.57g/100ml, more than 240 mesh, i.e., particle diameter is less than 0.061mm to ball milling glaze slip to fineness to slurry specific gravity control, uses 320 Mesh sieve detects that screen over-size is 0.03% for qualified, you can blowing-mistake screens out ferrum-store for future use.
Embodiment 2
The top grade of the embodiment strengthens magnesia porcelain, is prepared from by following steps:
S1, body preparation:To sieve after blank ball milling, old rear roll forming obtains base substrate;
S2, glazing:In the base substrate immersion glaze slip that step S1 is obtained, then propose, in billet surface glaze layer is adhered to, obtain Glazing green compact;
S3, sintering:The glazing green compact that step S2 is obtained are dried, and proceed to sintering in the kiln of oxidizing atmosphere, after cooling To the magnesia porcelain, wherein:
Above-mentioned blank, is made up of the following raw material according to mass percent:
It is will to whiten stone, black talc, albite, potassium feldspar, stone that the embodiment strengthens the preparation method of the blank of magnesia porcelain English, wash mud, Inner Mongol soil and crush respectively, cross 200-400 mesh sieves, after weighing according to mass percent plus appropriate water stirring is made.
Glaze in above-mentioned glaze slip, is made up of the following raw material according to mass percent:
The preparation method of above-mentioned glaze slip, comprises the following steps:
(1) pretreatment of raw material:Stone matter raw material is whitened into stone, albite, potassium feldspar and calcite and is processed at least 8 mesh excessively The powder of sieve;
(2) manufacture:All raw materials are added in the ball mill equipped with abrasive body by formula ratio, adds a certain amount of water to make glaze In 1.57g/100ml, more than 240 mesh, i.e., particle diameter is less than 0.061mm to ball milling glaze slip to fineness to slurry specific gravity control, uses 320 Mesh sieve detects that screen over-size is 0.03% for qualified, you can blowing-mistake screens out ferrum-store for future use.
Embodiment 3
The top grade of the embodiment strengthens magnesia porcelain, is prepared from by following steps:
S1, body preparation:To sieve after blank ball milling, old rear roll forming obtains base substrate;
S2, glazing:In the base substrate immersion glaze slip that step S1 is obtained, then propose, in billet surface glaze layer is adhered to, obtain Glazing green compact;
S3, sintering:The glazing green compact that step S2 is obtained are dried, and proceed to sintering in the kiln of oxidizing atmosphere, after cooling To the magnesia porcelain, wherein:
Above-mentioned blank, is made up of the following raw material according to mass percent:
It is will to whiten stone, black talc, albite, potassium feldspar, stone that the embodiment strengthens the preparation method of the blank of magnesia porcelain English, wash mud, Inner Mongol soil and crush respectively, cross 200-400 mesh sieves, after weighing according to mass percent plus appropriate water stirring is made.
Glaze in above-mentioned glaze slip, is made up of the following raw material according to mass percent:
The preparation method of above-mentioned glaze slip, comprises the following steps:
(1) pretreatment of raw material:Stone matter raw material is whitened into stone, albite, potassium feldspar and calcite and is processed at least 8 mesh excessively The powder of sieve;
(2) manufacture:All raw materials are added in the ball mill equipped with abrasive body by formula ratio, adds a certain amount of water to make glaze In 1.57g/100ml, more than 240 mesh, i.e., particle diameter is less than 0.061mm to ball milling glaze slip to fineness to slurry specific gravity control, uses 320 Mesh sieve detects that screen over-size is 0.03% for qualified, you can blowing-mistake screens out ferrum-store for future use.

Claims (3)

1. a kind of magnesia porcelain of high-grade reinforcing, is prepared from by following steps:
The preparation method of magnesia porcelain, comprises the following steps:
S1, body preparation:To sieve after blank ball milling, old rear roll forming obtains base substrate;
S2, glazing:In the base substrate immersion glaze slip that step S1 is obtained, then propose, in billet surface glaze layer is adhered to, obtain glazing Green compact;
S3, sintering:The glazing green compact that step S2 is obtained are dried, and proceed to sintering in the kiln of oxidizing atmosphere, and institute is obtained after cooling State magnesia porcelain, it is characterised in that
The blank, is made up of the following raw material according to mass percent:
The preparation method of above-mentioned blank is will to whiten stone, black talc, albite, potassium feldspar, quartz, wash mud, Inner Mongol soil respectively powder Broken, mistake 200-400 mesh sieves, water stirring after weighing according to mass percent plus appropriate is made;
Glaze in the glaze slip, is made up of the following raw material according to mass percent:
The preparation method of above-mentioned glaze slip, comprises the following steps:
(1) pretreatment of raw material:Stone matter raw material is whitened into stone, albite, potassium feldspar and calcite it is processed into and at least cross 8 mesh sieves Powder;
(2) manufacture:All raw materials are added in the ball mill equipped with abrasive body by formula ratio, adds a certain amount of water to make glaze slip ratio Control again in 1.57~1.61g/100ml, more than 240 mesh, i.e., particle diameter is less than 0.061mm to ball milling glaze slip to fineness, uses 320 mesh sieves detect that screen over-size is in 0.03-0.04% for qualified, you can blowing-mistake screens out ferrum-store for future use.
2. top grade as claimed in claim 1 strengthens magnesia porcelain, it is characterised in that the blank, by following according to quality percentage The raw material composition of ratio:
3. the magnesia porcelain of reinforcing as claimed in claim 1 high-grade, it is characterised in that the glaze in the glaze slip, by it is following according to The raw material composition of mass percent:
CN201611155991.6A 2016-12-15 2016-12-15 High-grade strengthen magnesia porcelain Pending CN106587918A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111533548A (en) * 2020-06-05 2020-08-14 广东创潮流瑜格科技有限公司 Steatite porcelain

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101544498A (en) * 2009-04-17 2009-09-30 广东长城集团股份有限公司 Production method for solving porcelain explosion of magnesia porcelain under natural condition
CN102786298A (en) * 2012-08-22 2012-11-21 湖南仙凤瓷业有限公司 Magnesian ceramic blank, magnesian ceramic and preparation method thereof
CN103467077A (en) * 2013-09-06 2013-12-25 山西明禾陶瓷有限责任公司 Method for fabricating magnesia porcelain raw materials
CN104591709A (en) * 2014-12-24 2015-05-06 景德镇陶瓷学院 High-strength magnesia porcelain ultrathin plate and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101544498A (en) * 2009-04-17 2009-09-30 广东长城集团股份有限公司 Production method for solving porcelain explosion of magnesia porcelain under natural condition
CN102786298A (en) * 2012-08-22 2012-11-21 湖南仙凤瓷业有限公司 Magnesian ceramic blank, magnesian ceramic and preparation method thereof
CN103467077A (en) * 2013-09-06 2013-12-25 山西明禾陶瓷有限责任公司 Method for fabricating magnesia porcelain raw materials
CN104591709A (en) * 2014-12-24 2015-05-06 景德镇陶瓷学院 High-strength magnesia porcelain ultrathin plate and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111533548A (en) * 2020-06-05 2020-08-14 广东创潮流瑜格科技有限公司 Steatite porcelain

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