CN103467077A - Method for fabricating magnesia porcelain raw materials - Google Patents

Method for fabricating magnesia porcelain raw materials Download PDF

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Publication number
CN103467077A
CN103467077A CN2013104031822A CN201310403182A CN103467077A CN 103467077 A CN103467077 A CN 103467077A CN 2013104031822 A CN2013104031822 A CN 2013104031822A CN 201310403182 A CN201310403182 A CN 201310403182A CN 103467077 A CN103467077 A CN 103467077A
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China
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raw material
mixture
porcelain
less
raw materials
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CN2013104031822A
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Inventor
樊学民
贾培录
韩爱学
余晓虎
马富春
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SHANXI MINGHE CERAMIC Co Ltd
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SHANXI MINGHE CERAMIC Co Ltd
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Abstract

The invention belongs to the field of porcelain fabrication, and particularly relates to a method for fabricating magnesia porcelain raw materials. The method comprises the following steps: respectively crushing a first raw material containing Si, a second raw material containing Mg, and clay through a crusher after drying, so that granules are smaller than 0.25mm, and then mixing, so that the mass percent content of Si in the mixture is,more than 10% and is less than 30%, the mass percent content of Mg in the mixture is more than 9% and less than 16%, and the mass percent content AI in the mixture is more than 3% and less than 7%; adding 5% of water to the mixture and then adding phosphoric acid or barium carbonate or sodium silicate to adjust ph value to 7-9; and hermetically storing for 3-10 days, and then crushing into powder of which the granules are smaller than 0.25mm through the crusher. By adopting the method disclosed by the invention, local raw materials are effectively utilized; localized development of porcelain is achieved.

Description

A kind of magnesia porcelain raw material making method
Technical field
The invention belongs to a kind of porcelain and make field, specifically a kind of magnesia porcelain raw material making method.
Background technology
Magnesia porcelain characteristics: 1. fine and close, transparent, the whiteness of porcelain, attractive in appearance, fine and smooth aspect all far surpass the feldspathic porcelain.Roughly the same, 2. this product adopts firing with reductive flame for product whiteness, transparency, glaze glossiness and Bone China, and product appearance is identical with shellfish matter porcelain.3. facade, special-shaped product adopt that different ingredients is disposable to be burnt till, and hardness of glaze surface is far above Bone China.The dish bowl product adopts twice firing, and transparency, higher than Bone China, belongs to ceramic superfine product in the world.
But each is different for the material composition of different areas, and some is applicable to firing high-grade high ceramic whiteware device, and what have is not suitable for, the development that is not suitable for restricting China's porcelain localization of raw material.This patent is used unique formula, and the material of raw material commonly used and local raw material, according to certain ratio, is produced to magnesia porcelain, uses material respectively as following table.
Figure BDA0000378464830000011
The common raw material in Shanxi, Inner Mongolia is as following table
Figure BDA0000378464830000021
Summary of the invention
Technical problem to be solved by this invention is: how to utilize the local resource of various places to configure the raw material that is applicable to firing magnesia porcelain, the porcelain that is can localization.
The technical solution adopted in the present invention is: a kind of magnesia porcelain raw material making method, according to following step, carry out:
Step 1, pulverizing respectively by pulverizer after the first raw material containing Si, the second raw material that contains Mg and clay drying, make particle be less than 0.25mm, then mix, make 10%<Si mass percentage content<30% in mixture, 9%<Mg mass percentage content, 16%, 3%<AI mass percentage content<7%;
Step 2 adds 5% water then to add phosphoric acid or barium carbonate or water glass and adjusts ph value for 7-9 in mixture, sealing preservation 3-10 days, then be ground into by pulverizer the powder that particle is less than 0.25mm.
Almost there is the abundant raw material of Si in each area, contains abundant raw material and the clay of Mg, as long as the various elements in the configuration raw material are applicable to porcelain, just fires fire porcelain effectively.
The invention has the beneficial effects as follows: the present invention effectively utilizes the raw material of various places, has realized the localization development of porcelain.
Embodiment
Embodiment 1(be take the Shanxi area raw material as example)
The Changzhi feldspar is as the first raw material, the blast-furnace slag high containing magnesium is as the second raw material, the first raw material and the second raw material and clay respectively crushed after being dried make particle be less than 0.25mm, the composition of adjusting the first raw material, the second raw material and the 3rd raw material after mixing makes Si mass percentage content=25%, Mg mass percentage content=10%, 5%<=AI mass percentage content<7%; In mixture, add 5% water then to add phosphoric acid and adjust ph value for 7-9, sealing preservation 3-10 days, then be ground into by pulverizer the powder that particle is less than 0.25mm, this porcelain raw material completes.
In the mixing raw material process, often only need to be calculated for the first time, as long as after completing for the first time after measuring and calculating result according to measuring and calculating for the first time and measuring first raw material and the second raw material and clay drying and crushing of homogenous quantities ratio later, adding 5% water then to add phosphoric acid, to adjust ph value be 7-9,3-10 days is preserved in sealing, be ground into by pulverizer the powder that particle is less than 0.25mm again, raw material completes.
Embodiment 2(be take the Shanxi area raw material as example)
Yuanping City's quartz is as the first raw material, dolomite mineral through pyrolytic decomposition is the second raw material, the first raw material and the second raw material and clay respectively crushed after being dried make particle be less than 0.25mm, the composition of adjusting the first raw material, the second raw material and the 3rd raw material after mixing makes Si mass percentage content=15%, Mg mass percentage content=12%, 6%<=AI mass percentage content<7%; In mixture, add 5% water then to add phosphoric acid and adjust ph value for 7-9, sealing preservation 3-10 days, then be ground into by pulverizer the powder that particle is less than 0.25mm, this porcelain raw material completes.
In the mixing raw material process, often only need to be calculated for the first time, as long as after completing for the first time after measuring and calculating result according to measuring and calculating for the first time and measuring first raw material and the second raw material and clay drying and crushing of homogenous quantities ratio later, adding 5% water then to add phosphoric acid, to adjust ph value be 7-9,3-10 days is preserved in sealing, be ground into by pulverizer the powder that particle is less than 0.25mm again, raw material completes.
Magnesium is one of 10 kinds of non-ferrous metals commonly used, its standing stock are abundant, content in the earth's crust reaches 2.1%-2.7%, arranges the 8th in all elements, and the magnesium ore resources is mainly from seawater, mineral salt lake water, brine of oil field, dolomite, magnesite, brucite and peridotites etc.
Magnesite MgCO3, global stock number is about 13,000,000,000 tons, and China to nineteen ninety-five retained reserve be 3,000,000,000 tons, 80,000,000,000 tons of prognostic resourcess, rank first in the world.China's magnesite major part can be revealed and adopts, and impurity is few, and the content of MgO is between 46-47.6%.The above ore reserves of first grade (content of MgO is greater than 46%) accounts for 44% of national total amount, and sparry magnesite accounts for 93% of national total amount.Therefore very common as the high ore deposit containing Mg of the second raw material, development that can the porcelain localization by technical scheme of the present invention after, be easy to realization.

Claims (1)

1. a magnesia porcelain raw material making method is characterized in that carrying out according to following step:
Step 1, pulverizing respectively by pulverizer after the first raw material containing Si, the second raw material that contains Mg and clay drying, make particle be less than 0.25mm, then mix, make 10%<Si mass percentage content<30% in mixture, 9%<Mg mass percentage content, 16%, 3%<AI mass percentage content<7%;
Step 2 adds 5% water then to add phosphoric acid or barium carbonate or water glass and adjusts ph value for 7-9 in mixture, sealing preservation 3-10 days, then be ground into by pulverizer the powder that particle is less than 0.25mm.
CN2013104031822A 2013-09-06 2013-09-06 Method for fabricating magnesia porcelain raw materials Pending CN103467077A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587920A (en) * 2016-12-15 2017-04-26 湖南新辉陶瓷有限责任公司 Preparation method of improved strengthened magnesia porcelain
CN106587919A (en) * 2016-12-15 2017-04-26 湖南新辉陶瓷有限责任公司 Magnesia porcelain with high transparency
CN106587918A (en) * 2016-12-15 2017-04-26 湖南新辉陶瓷有限责任公司 High-grade strengthen magnesia porcelain

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
林绍贤 等: "镁质瓷泥浆流变性能的改进", 《大连轻工业学院学报》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587920A (en) * 2016-12-15 2017-04-26 湖南新辉陶瓷有限责任公司 Preparation method of improved strengthened magnesia porcelain
CN106587919A (en) * 2016-12-15 2017-04-26 湖南新辉陶瓷有限责任公司 Magnesia porcelain with high transparency
CN106587918A (en) * 2016-12-15 2017-04-26 湖南新辉陶瓷有限责任公司 High-grade strengthen magnesia porcelain

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Application publication date: 20131225