CN105859132A - Colored high-strength heat insulation glass product and preparation technology thereof - Google Patents

Colored high-strength heat insulation glass product and preparation technology thereof Download PDF

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Publication number
CN105859132A
CN105859132A CN201610231938.3A CN201610231938A CN105859132A CN 105859132 A CN105859132 A CN 105859132A CN 201610231938 A CN201610231938 A CN 201610231938A CN 105859132 A CN105859132 A CN 105859132A
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China
Prior art keywords
goods
heat insulation
sent
carbonate
glass product
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Pending
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CN201610231938.3A
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Chinese (zh)
Inventor
曹学海
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Anhui Fengyang County Huaxia Glassware Co Ltd
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Anhui Fengyang County Huaxia Glassware Co Ltd
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Application filed by Anhui Fengyang County Huaxia Glassware Co Ltd filed Critical Anhui Fengyang County Huaxia Glassware Co Ltd
Priority to CN201610231938.3A priority Critical patent/CN105859132A/en
Publication of CN105859132A publication Critical patent/CN105859132A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B1/00Preparing the batches
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04Opacifiers, e.g. fluorides or phosphates; Pigments

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

A colored high-strength heat insulation glass product is characterized by being prepared from, by weight, 195.6 g of silicon dioxide, 1.2 g of beeswax, 29 g of lasurite, 6 g of tourmaline, 6.6 g of aluminum hydroxide, 1.5 g of niobium carbide, 15.4 g of roasted loess, 5 g of modified starch, 4 g of selenium powder, 0.5 g of cadmium yellow, 2 g of cadmium red, 23.6 g of calcite, 0.5 g of zinc oxide, 20 g of sodium carbonate, 1.3 g of potassium carbonate, 4.6 g of barium carbonate, 3 g of ferromolybdenum, 20 g of shells, 0.2 g of cobaltous oxide, 5 g of titanium carbide, 5 g of silicon carbide, 8 g of natural ocean jasper, 8 g of hauynite, 5 g of Huanglong Mountain green clay, 8 g of magnesite, 8 g of potassium feldspar, 5 g of sepiolite and 1 g of copper sulfate. By specially blending raw materials, the prepared product has a smooth surface, is beautiful in color and high in strength, has spots and does not scald the hands in use; compared with a traditional technology, the colored high-strength heat insulation glass product is low in time consumption and energy consumption, good in texture and free of toxic or harmful substance residues.

Description

Colored heat insulation high strength glass goods and preparation technology thereof
Technical field
The present invention relates to technical field of living goods, be specifically related to a kind of colored heat insulation high strength glass goods And preparation technology.
Background technology
Domestic ceramics raw material is divided into three major types: have plastic one of clay raw materials, have nonplastic Quartz class raw material (non-plastic raw material) and flux raw material.One of clay raw materials is the most former of domestic ceramics raw material One of material.In fine porcelain dispensing, the consumption of one of clay raw materials often reaches 40~60%, consumption in pottery and stoneware Also can increase.Why clay as the primary raw material of ceramic, is owing to it has plasticity and burning Knot property.Essential mineral in ceramic industry clay has kaolinite class, smectites and illite (water cloud Female) class etc., then carry out the most rare allophane.The effect of quartz class raw material (non-plastic raw material) is to make Joining in ceramic batch for non-plastic raw material, it is one of Main Components in ceramic body, and it is at pottery Effect in production not only has important impact when body formation but also when burning till.Flux raw material master If the raw mineral materials of alkali metal containing oxide, Anhydrite is fluxed raw material the most frequently used in Ceramic Material. In addition, the mineral of some alkaline including earth metals also can use as flux raw material, the most oxygen-containing calcium and oxygen The carbonate mineral changing magnesium is relatively conventional.
From being analyzed above it can be seen that current primary raw material used by pottery is one of clay raw materials, but excellent Matter clay resource is the deficientest.As a example by Kaolin, according to Ministry of Geology and Mineral Resources, State Bureau of Building Materials Industry, " China builds Material nonmetal mineral resource was to development of the national economy guaranteed extent Demonstration Report in 2010 ", Chinese kaolin Mineral deposit is based on middle-size and small-size, and at 208 mineral products possessed, ceramic grade Kaolin accounts for 48%, China's Kaolin It is available for proved reserves only enough exploitations of exploitation at present to the year two thousand twenty.For the general layout in the whole nation, the pottery of old brand Porcelain industrial base, such as Foshan, Jing Dezhen, Chaozhou etc., during it develops, is all greatly benefited from Its abundant raw material resources.But through industrialized production for many years, adopt on a large scale raw-material Pick has made the ceramics base of these old brands coincidentally be faced with the predicament of resource exhaustion, Jing Dezhen, China clay raw material needed for the ground such as Zibo and Foshan depends almost entirely upon outward transport.Therefore, non-aluminosilicate is developed Domestic ceramics material system, change the dependence to clay of the present household porcelain production, find cheap, storage The alternate resources that amount is abundant becomes the strategic demand freeing domestic ceramics industry resource predicament.
Summary of the invention
The technical problem to be solved is to provide a kind of and uses safety, the colour of smooth texture every Hot high strength glass goods.
The technical problem to be solved realizes by the following technical solutions:
A kind of colored heat insulation high strength glass goods, are made up of the component of following weight: silicon dioxide 195.6g, Apis cerana Fabricius 1.2g, lazurite 29g, tourmaline 6g, aluminium hydroxide 6.6g, niobium carbide 1.5g, forge Burn loess 15.4g, modified starch 5g, selenium powder 4g, cadmium yellow 0.5g, cadmium red 2g, calcite 23.6g, oxygen Change zinc 0.5g, soda 20g, potassium carbonate 1.3g, brium carbonate 4.6g, molybdenum-iron 3g, shell 20g, cobalt oxide 0.2g, titanium carbide 5g, carborundum 5g, natural marine stone 8g, hauynite 8g, this mountain green mud 5g, magnesite Ore deposit 8g, potassium feldspar 8g, meerschaum 5g, copper sulfate 1g;
The preparation technology of a kind of colour heat insulation high strength glass goods, comprises the technical steps that,
(1) by silicon dioxide, Apis cerana Fabricius, lazurite, calcite, calcined loess, zinc oxide, soda, Aluminium hydroxide, potassium carbonate, brium carbonate, molybdenum-iron, shell, cobalt oxide, titanium carbide, carborundum, natural Ocean stone, hauynite, tourmaline, this mountain green mud, magnesite, potassium feldspar, meerschaum and copper sulfate Compound is put in nylon ball grinder, continuous ball milling 4-6 hour, crosses 120 eye mesh screens, collects and is mixed Powder is stand-by;
(2) compound is mixed homogeneously with modified starch, selenium powder, cadmium red and cadmium yellow, send into freezing Equipment, K cryogenic treatment 4 hours under-15 DEG C to-22 DEG C environment, the most again the material after freezing is sent into micro- In ripple processing equipment, being spaced microwave treatment under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, each microwave treatment 10 minutes, it is carried out continuously 3-4 time;By freezing and microwave treatment, improve Degrees of fusion between each material, improves the stability of goods;
(3) the material material after microwave treatment is sent into dehydrator, dry at 60 DEG C, be then fed into melting Stove, makes whole material carry out fusing mix homogeneously, obtains mother solution;
(4) mother solution is sent into forming machine, make the goods of the specification that varies in size, then goods are dropped naturally Temperature sends into annealing kiln with conveyer to 600 DEG C of hardening, anneals complete;
(5) goods after annealing are sent into tempering case, first goods are heated to 820 DEG C, stop heating, Immediately from all directions send into cold wind, after rapidly goods being cooled to room temperature, tempering terminates, by goods from Tempering case takes out, obtains finished product.The product strength obtained at a temperature of Gai is high, non-friable.
The invention has the beneficial effects as follows: the present invention is by the formulated to raw material, the goods mass color of preparation Sliding, beautiful in colour, spottiness, intensity is good, uses non-scald on hand, compared with traditional handicraft, institute of the present invention Taking time short, energy consumption is low, and goods texture is good, nonhazardous material residual.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of colored heat insulation high strength glass goods, are made up of the component of following weight: silicon dioxide 195.6g, Apis cerana Fabricius 1.2g, lazurite 29g, tourmaline 6g, aluminium hydroxide 6.6g, niobium carbide 1.5g, forge Burn loess 15.4g, modified starch 5g, selenium powder 4g, cadmium yellow 0.5g, cadmium red 2g, calcite 23.6g, oxygen Change zinc 0.5g, soda 20g, potassium carbonate 1.3g, brium carbonate 4.6g, molybdenum-iron 3g, shell 20g, cobalt oxide 0.2g, titanium carbide 5g, carborundum 5g, natural marine stone 8g, hauynite 8g, this mountain green mud 5g, magnesite Ore deposit 8g, potassium feldspar 8g, meerschaum 5g, copper sulfate 1g;
The preparation technology of a kind of colour heat insulation high strength glass goods, comprises the technical steps that,
(1) by silicon dioxide, Apis cerana Fabricius, lazurite, calcite, calcined loess, zinc oxide, soda, Aluminium hydroxide, potassium carbonate, brium carbonate, molybdenum-iron, shell, cobalt oxide, titanium carbide, carborundum, natural Ocean stone, hauynite, tourmaline, this mountain green mud, magnesite, potassium feldspar, meerschaum and copper sulfate Compound is put in nylon ball grinder, continuous ball milling 4-6 hour, crosses 120 eye mesh screens, collects and is mixed Powder is stand-by;
(2) compound is mixed homogeneously with modified starch, selenium powder, cadmium red and cadmium yellow, send into freezing Equipment, K cryogenic treatment 4 hours under-15 DEG C to-22 DEG C environment, the most again the material after freezing is sent into micro- In ripple processing equipment, being spaced microwave treatment under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, each microwave treatment 10 minutes, it is carried out continuously 3-4 time;By freezing and microwave treatment, improve Degrees of fusion between each material, improves the stability of goods;
(3) the material material after microwave treatment is sent into dehydrator, dry at 60 DEG C, be then fed into melting Stove, makes whole material carry out fusing mix homogeneously, obtains mother solution;
(4) mother solution is sent into forming machine, make the goods of the specification that varies in size, then goods are dropped naturally Temperature sends into annealing kiln with conveyer to 600 DEG C of hardening, anneals complete;
(5) goods after annealing are sent into tempering case, first goods are heated to 820 DEG C, stop heating, Immediately from all directions send into cold wind, after rapidly goods being cooled to room temperature, tempering terminates, by goods from Tempering case takes out, obtains finished product.The product strength obtained at a temperature of Gai is high, non-friable.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (2)

1. colour heat insulation high strength glass goods, it is characterised in that be made up of the component of following weight: Silica 1 95.6g, Apis cerana Fabricius 1.2g, lazurite 29g, tourmaline 6g, aluminium hydroxide 6.6g, niobium carbide 1.5g, calcined loess 15.4g, modified starch 5g, selenium powder 4g, cadmium yellow 0.5g, cadmium red 2g, calcite 23.6g, Zinc oxide 0.5g, soda 20g, potassium carbonate 1.3g, brium carbonate 4.6g, molybdenum-iron 3g, shell 20g, oxidation Cobalt 0.2g, titanium carbide 5g, carborundum 5g, natural marine stone 8g, hauynite 8g, this mountain green mud 5g, Pedicellus et Pericarpium Trapae Magnesium ore deposit 8g, potassium feldspar 8g, meerschaum 5g, copper sulfate 1g.
2. a preparation technology for colored heat insulation high strength glass goods described in claim 1, its feature exists In, comprise the technical steps that,
(1) by silicon dioxide, Apis cerana Fabricius, lazurite, calcite, calcined loess, zinc oxide, soda, Aluminium hydroxide, potassium carbonate, brium carbonate, molybdenum-iron, shell, cobalt oxide, titanium carbide, carborundum, natural Ocean stone, hauynite, tourmaline, this mountain green mud, magnesite, potassium feldspar, meerschaum and copper sulfate Compound is put in nylon ball grinder, continuous ball milling 4-6 hour, crosses 120 eye mesh screens, collects and is mixed Powder is stand-by;
(2) compound is mixed homogeneously with modified starch, selenium powder, cadmium red and cadmium yellow, send into freezing Equipment, K cryogenic treatment 4 hours under-15 DEG C to-22 DEG C environment, the most again the material after freezing is sent into micro- In ripple processing equipment, being spaced microwave treatment under microwave frequency 2450MHz, power 500W, interval time is 5 minutes, each microwave treatment 10 minutes, it is carried out continuously 3-4 time;
(3) the material material after microwave treatment is sent into dehydrator, dry at 60 DEG C, be then fed into melting Stove, makes whole material carry out fusing mix homogeneously, obtains mother solution;
(4) mother solution is sent into forming machine, make the goods of the specification that varies in size, then goods are dropped naturally Temperature sends into annealing kiln with conveyer to 600 DEG C of hardening, anneals complete;
(5) goods after annealing are sent into tempering case, first goods are heated to 820 DEG C, stop heating, Immediately from all directions send into cold wind, after rapidly goods being cooled to room temperature, tempering terminates, by goods from Tempering case takes out, obtains finished product.
CN201610231938.3A 2016-04-14 2016-04-14 Colored high-strength heat insulation glass product and preparation technology thereof Pending CN105859132A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107858858A (en) * 2017-11-04 2018-03-30 舒城宏峰纸板有限公司 For the buffer fillings agent in corrugated layer in high-strength corrugated board
CN110002751A (en) * 2019-04-15 2019-07-12 安徽省凤阳县华夏玻璃制品有限公司 A kind of heat-insulated high-strength colour glassware and its preparation process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101148317A (en) * 2007-08-22 2008-03-26 东营力诺玻璃制品有限责任公司 Formulation for medicinal neutral boron silicate glass
CN104150773A (en) * 2014-07-17 2014-11-19 安徽省含山民生瓷业有限责任公司 Purple sand glass ceramic bowl and preparation process thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101148317A (en) * 2007-08-22 2008-03-26 东营力诺玻璃制品有限责任公司 Formulation for medicinal neutral boron silicate glass
CN104150773A (en) * 2014-07-17 2014-11-19 安徽省含山民生瓷业有限责任公司 Purple sand glass ceramic bowl and preparation process thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107858858A (en) * 2017-11-04 2018-03-30 舒城宏峰纸板有限公司 For the buffer fillings agent in corrugated layer in high-strength corrugated board
CN110002751A (en) * 2019-04-15 2019-07-12 安徽省凤阳县华夏玻璃制品有限公司 A kind of heat-insulated high-strength colour glassware and its preparation process

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Application publication date: 20160817