CN106566446B - A kind of gum paint and preparation method thereof - Google Patents
A kind of gum paint and preparation method thereof Download PDFInfo
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- CN106566446B CN106566446B CN201610997470.9A CN201610997470A CN106566446B CN 106566446 B CN106566446 B CN 106566446B CN 201610997470 A CN201610997470 A CN 201610997470A CN 106566446 B CN106566446 B CN 106566446B
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- rheology
- graphene oxide
- sebs
- mass ratio
- polyester
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of gum paints and preparation method thereof, belong to organic high molecular compound synthesis technical field.Formed including SEBS, high rheology PP, high viscosity graphene oxide and rheology polyester complexes, the SEBS, high rheology PP, high viscosity graphene oxide and rheology polyester complexes mass ratio be 100：（40‑50）：（5‑20）：（5‑15）.By the application be applied to carpet etc. household objects, have many advantages, such as viscosity height, it is environment friendly and pollution-free.
Description
Technical field
The present invention relates to a kind of gum paints and preparation method thereof, belong to organic high molecular compound synthesis technical field.
Background technology
Existing carpet back-adhesive, which generally uses, to be contained in the latex that latex-coating and lamination are rolled there are many auxiliary chemicals,
Thus inevitably residual fraction monomer, since carpet is chiefly used in household, this will be to environmental effects；Common material
Lamination calendering gum and various fibers cannot be made fully to bond, using and washing process in be easy to happen degumming, breakage,
Influence service life.
Based on this, the application is made.
Invention content
In order to overcome the drawbacks described above in the presence of existing carpet back-adhesive use, the application to provide first a kind of viscous various by force
Fiber, environmentally friendly on-slip carpet TPE gum paints.
To achieve the above object, the technical solution that the application takes is as follows：
A kind of gum paint, including SEBS, high rheology PP, high viscosity graphene oxide and rheology polyester complexes, it is described
SEBS, high rheology PP, high viscosity graphene oxide and rheology polyester complexes mass ratio be 100：(40-50)：(5-20)：
(5-15)。
Further, as preferred：
The rheological parameter of the PP ranging from 22-29.
The high viscosity graphene oxide be by epoxy silane coupling agent, oil terpene resin and graphene oxide according to
10-20：60-80：The mass ratio of 10-20 physics at a temperature of 100rpm or less, 40 DEG C is synthetically prepared.
The rheology polyester complexes are by rheological agent and polyester elastomer according to 20-30：The mass ratio of 70-80 exists
It is prepared by dual-screw-stem machine at 180-220 DEG C.It is furthermore preferred that the rheological agent refers to Rheological Index gathering in 80-110
Alkene rheological agent.
Further include having plasticiser in the gum paint, SEBS, high rheology PP, high viscosity graphene oxide, rheology polyester
Compound, plasticiser mass ratio be 100：(40-50)：(5-20)：(5-15)：(15-20).
Further include having plasticiser and additive in the gum paint, SEBS, high rheology PP, high viscosity graphene oxide,
Rheology polyester complexes, plasticiser, additive mass ratio be 100：(40-50)：(5-20)：(5-15)：(15-20)：(0.5-
1), wherein additive refers to the combination of antioxidant, anti ultraviolet agent, lubricant.
Meanwhile present invention also provides a kind of preparation method of gum paint as characterized above, by SEBS, high rheology PP,
It after high viscosity graphene oxide and rheology polyester complexes are mixed evenly in proportion, adds twin-screw extrude, heats up
To 180-220 DEG C of melting extrusion, after tie rod pelletizing or granulation, air-dry, drying.
Wherein, term SEBS refers to being copolymerized with the Ethylene/Butylene that polybutadiene plus hydrogen obtain using polystyrene as end segment
Object is the linear tri-block copolymer of intermediate elastic block.The high rheology PP of term refers to the PP being modified using rheological agent, rheology
For index between 90-110, rheological agent refers to the polyolefin rheological agent that Rheological Index is 80-110.
Specific implementation mode
The approximate term used in the present embodiment limits quantity, and expression is not limited to the specific data, further include with
The close amendment part acceptable and that related basic function a century will not be caused of the data, use accordingly " about ",
One data of modifications such as " about ", to be not limited to exact numerical for the present embodiment.
Wherein, in following embodiments, used SEBS refers to being obtained with polybutadiene plus hydrogen using polystyrene as end segment
The ethylene-butene copolymer arrived is the linear tri-block copolymer of intermediate elastic block, is not particularly limited, can be used commercially available or real
Test synthesis；High rheology PP refers to the PP being modified using rheological agent, and Rheological Index is between 90-110；Rheological agent refers to rheology
Index is the polyolefin rheological agent of 80-110.
High viscosity graphene oxide refers to being carried out at activation to graphene oxide according to 5-20 ‰ with epoxy silane coupling agent
Reason, then by the good graphene oxide of activation process according still further to 1：1 mass ratio and oil terpene resin (C5's or more) progress
The functional agglomerate being prepared by double screw extruder after height mixed (rotating speed 400rpm) stirring.It is not particularly limited, can be used commercially available
Or experiment synthesis.
In the present embodiment, rheology polyester complexes refer to using rheological agent modified poly ester elastomer or by rheological agent and polyester
The functional agglomerate being prepared after elastomer physical blending；Rheological agent therein refers to the polyene hydrocarbon stream that Rheological Index is 80-110
Become agent.
SEBS used herein is set as A, high rheology PP is set as B, and high viscosity maintenance graphene is set as C, and rheology is poly-
Ester complexes are set as D, and plasticiser is set as E, and additive is set as F.
Standard weights part refers to 100-500g.
Embodiment 1
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 40 parts by weight B, 5 parts by weight C, 5 parts by weight D, standard weights part E, standard weights part F
(antioxidant, anti ultraviolet agent, lubricant=1:1:2, mass ratio), stirred evenly at normal temperatures by blender.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 2
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 45 parts by weight B, 10 parts by weight C, 10 parts by weight D, standard weights part E, standard weights part F
(antioxidant, anti ultraviolet agent, lubricant=1:1:2, mass ratio), stirred evenly at normal temperatures by blender.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 3
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 50 parts by weight B, 15 parts by weight C, 15 parts by weight D, standard weights part E, standard weights part F
(antioxidant, anti ultraviolet agent, lubricant=1:1:2, mass ratio), stirred evenly at normal temperatures by blender.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 4
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 50 parts by weight B, 20 parts by weight C, 15 parts by weight D, standard weights part E, standard weights part F
(antioxidant, anti ultraviolet agent, lubricant=1:1:2, mass ratio), stirred evenly at normal temperatures by blender.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Carry out respectively with do not add F and while do not add E, F two kinds of ingredients progress Contrast on effect, specifically respectively referring to implementation
Example 5-8 and embodiment 9-12.
Embodiment 5
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 50 parts by weight B, 20 parts by weight C, 15 parts by weight D, 3 parts by weight E, at normal temperatures by stirring
The machine of mixing stirs evenly.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 6
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 50 parts by weight B, 20 parts by weight C, 15 parts by weight D, 5 parts by weight E, at normal temperatures by stirring
The machine of mixing stirs evenly.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 7
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 50 parts by weight B, 20 parts by weight C, 15 parts by weight D, 10 parts by weight E, pass through at normal temperatures
Blender stirs evenly.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 8
The present embodiment gum paint is prepared in accordance with the following steps：
(1) by 100 parts by weight A, 50 parts by weight B, 20 parts by weight C, 15 parts by weight D, 15 parts by weight E, pass through at normal temperatures
Blender stirs evenly.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 9
The present embodiment gum paint is prepared in accordance with the following steps：
(1) it by 100 parts by weight A, 50 parts by weight B, 20 parts by weight C, 15 parts by weight D, is stirred at normal temperatures by blender
Uniformly.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 10
The present embodiment gum paint is prepared in accordance with the following steps：
(1) it by 100 parts by weight A, 50 parts by weight B, 15 parts by weight C, 15 parts by weight D, is stirred at normal temperatures by blender
Uniformly.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 11
The present embodiment gum paint is prepared in accordance with the following steps：
(1) it by 100 parts by weight A, 45 parts by weight B, 10 parts by weight C, 10 parts by weight D, is stirred at normal temperatures by blender
Uniformly.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Embodiment 12
The present embodiment gum paint is prepared in accordance with the following steps：
(1) it by 100 parts by weight A, 40 parts by weight B, 5 parts by weight C, 5 parts by weight D, is stirred at normal temperatures by blender equal
It is even.
(2) the above-mentioned material stirred evenly is added in double screw extruder, is heated to 180-220 DEG C, squeezed out.
(3) cooling is squeezed out, pelletizing molding obtains single-size by vibrating screen.
(4) single-size of acquisition is dried so that particle moisture-free.
Comparative example 1
With commercially available 1 TPE carpet back-adhesives (Kunshan Ke Xin high molecular materials Co., Ltd) as a comparison case 1 carry out using pair
Than.
Comparative example 2
It 2 is carried out as a comparison case using comparison with commercially available 2 TPE carpet back-adhesives (Taizhou Sanming City plastic cement Co., Ltd).
The test table of comparisons of 1 different product of table
It can be seen that by the comparison of table 1 and the various embodiments described above：
(1) compared with commercial product, the tensile strength of the TPE carpet back-adhesive paints prepared by the application near 5.0MPa,
Bonding stretches slightly near 3MPa, is more than 0.5 with the friction coefficient of conventional floor tile, is superior to commercial product, is applied to
When various fiber (cotton, fiber crops, the chemical fibres such as terylene, acrylic fibers, polypropylene fibre), while there is preferable mechanical strength, also have
Powerful viscosity, bonding tearing strength is preferable, and is increased with the friction coefficient of floor tile, the flower effect that ensure that, and passes through ROHS
Environmental certification ensure that environment-friendly function, will not gum be made to fall off by washing, rinsing, and do not interfered to living environment.
(2) in the application, the main function ingredient of gum paint is SEBS, high rheology PP, high viscosity graphene oxide and stream
Become polyester complexes, high viscosity graphene oxide therein has good adherence；SEBS is free of unsaturated double-bond, has good
Good stability and resistance to ag(e)ing；High rheology PP and rheology polyester complexes have good rheological property, can be very good to adjust
With high viscosity graphene oxide and SEBS, and make up to effect reinforcing effect；And in the two kinds of auxiliary agents added, plasticiser
Plastication is primarily served, with the increase of its additive amount, plasticizing effect is reinforced, and antiskid property improves therewith, when being added to 15-
When 20% (mass percent), the raising of the non-skid property reaches best；Additive primarily serves ageing-resistant effect, with it
The increase of additive amount, antiageing effect are reinforced, and corresponding ageing-resistant performance improves therewith, when being added to 0.5-1% (quality percentages
Than) when, the raising of the ageing-resistant performance reaches best.
The above content is the preferred embodiments of combination the invention to further detailed made by provided technical solution
Describe in detail bright, and it cannot be said that the invention specific implementation is confined to these above-mentioned explanations, for the affiliated technology of the invention
For the those of ordinary skill in field, without departing from the concept of the premise of the invention, several simple deductions can also be made
Or replace, it all shall be regarded as belonging to the protection domain of the invention.
Claims (6)
1. a kind of gum paint, it is characterised in that：By SEBS, high rheology PP, high viscosity graphene oxide and rheology polyester complexes
Composition, the SEBS, high rheology PP, high viscosity graphene oxide and rheology polyester complexes mass ratio be 100：（40-
50）：（5-20）：（5-15）；The high viscosity graphene oxide is by epoxy silane coupling agent, oil terpene resin and oxidation
Graphene according to（10-20）：（60-80）：（10-20）Mass ratio 100rpm or less, physics synthesizes at a temperature of 40 DEG C；Described
Rheology polyester complexes be by rheological agent and polyester elastomer according to（20-30）：（70-80）Mass ratio at 180-220 DEG C
It is prepared.
2. a kind of gum paint as described in claim 1, it is characterised in that：The Rheological Index of the high rheology PP is in 90-110
Between.
3. a kind of gum paint, it is characterised in that：It is compound including SEBS, high rheology PP, high viscosity graphene oxide, rheology polyester
Object, the SEBS, high rheology PP, high viscosity graphene oxide and rheology polyester complexes mass ratio be 100：（40-50）：
（5-20）：（5-15）；The high viscosity graphene oxide is by epoxy silane coupling agent, oil terpene resin and graphite oxide
Alkene according to（10-20）：（60-80）：（10-20）Mass ratio 100rpm or less, physics synthesizes at a temperature of 40 DEG C；The high stream
Become the Rheological Index of PP between 90-110；The rheology polyester complexes be by rheological agent and polyester elastomer by（20-
30）：（70-80）Mass ratio compound at 180-220 DEG C be prepared.
4. a kind of gum paint as claimed in claim 3, it is characterised in that：Further include having plasticiser, SEBS, high rheology PP, height
Sticky graphene oxide, rheology polyester complexes, plasticiser mass ratio be 100：（40-50）：（5-20）：（5-15）：（15-
20）.
5. a kind of gum paint as claimed in claim 3, it is characterised in that：Further include having plasticiser and additive, SEBS, Gao Liu
Become the mass ratio of PP, high viscosity graphene oxide, rheology polyester complexes, plasticiser, additive as 100：（40-50）：（5-
20）：（5-15）：（15-20）：（0.5-1）, wherein additive refers to the combination of antioxidant, anti ultraviolet agent, lubricant.
6. the preparation method of gum paint as described in claim 1 or 3 any one, it is characterised in that：By SEBS, high rheology PP, height
After sticky graphene oxide and rheology polyester complexes are mixed evenly in proportion, pair having warmed up to 180-220 DEG C is added
After melting extrusion in screw extruder, tie rod pelletizing or granulation, it is drying to obtain.
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| CN201610997470.9A CN106566446B (en) | 2016-11-14 | 2016-11-14 | A kind of gum paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610997470.9A CN106566446B (en) | 2016-11-14 | 2016-11-14 | A kind of gum paint and preparation method thereof |
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| CN106566446A CN106566446A (en) | 2017-04-19 |
| CN106566446B true CN106566446B (en) | 2018-10-09 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497771A (en) * | 2009-02-27 | 2009-08-05 | 杨志 | Hot melt pressure-sensitive adhesive for post express back glue bag and preparation |
| CN102093837A (en) * | 2010-09-14 | 2011-06-15 | 抚顺哥俩好化学有限公司 | One-component high temperature-resistant gasket-free sealant and preparation method thereof |
| CN103436206A (en) * | 2012-09-18 | 2013-12-11 | 惠东伟康橡塑制品有限公司 | Glue as well as application of glue on PVC (Polyvinyl Chloride) floor and using method of glue |
| CN105111979A (en) * | 2015-09-07 | 2015-12-02 | 安徽雄亚塑胶科技有限公司 | Environment-friendly antimicrobial flame-retardant TPE (thermoplastic elastomer) carpet gum powder and preparation method thereof |
-
2016
- 2016-11-14 CN CN201610997470.9A patent/CN106566446B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497771A (en) * | 2009-02-27 | 2009-08-05 | 杨志 | Hot melt pressure-sensitive adhesive for post express back glue bag and preparation |
| CN102093837A (en) * | 2010-09-14 | 2011-06-15 | 抚顺哥俩好化学有限公司 | One-component high temperature-resistant gasket-free sealant and preparation method thereof |
| CN103436206A (en) * | 2012-09-18 | 2013-12-11 | 惠东伟康橡塑制品有限公司 | Glue as well as application of glue on PVC (Polyvinyl Chloride) floor and using method of glue |
| CN105111979A (en) * | 2015-09-07 | 2015-12-02 | 安徽雄亚塑胶科技有限公司 | Environment-friendly antimicrobial flame-retardant TPE (thermoplastic elastomer) carpet gum powder and preparation method thereof |
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| CN106566446A (en) | 2017-04-19 |
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