CN103172965B - A kind of Matte oil-resistant elastomer cable material and preparation method thereof - Google Patents
A kind of Matte oil-resistant elastomer cable material and preparation method thereof Download PDFInfo
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- CN103172965B CN103172965B CN201310137107.6A CN201310137107A CN103172965B CN 103172965 B CN103172965 B CN 103172965B CN 201310137107 A CN201310137107 A CN 201310137107A CN 103172965 B CN103172965 B CN 103172965B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of Matte oil-resistant elastomer cable material and preparation method thereof, this CABLE MATERIALS is made up of each component of following weight percent: hydrogenated styrene-butadiene-styrene 20-45%; Polypropylene 10-30%; Paraffin oil 5-20%; Ethylene-propylene rubber(EPR) 4-35%; Weighting material 5-15%; Linking agent 0.5-5%; Oxidation inhibitor 0.5-5%; Lubricant 0.5-5%.While Matte oil-resistant elastomer cable material provided by the invention makes cable have atomized surface effect, also there is good oil resistance and mechanical property, make cloudy surface cable meet the needs of oil resistant occasion.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS, particularly relate to a kind of Matte oil-resistant elastomer cable material and preparation method thereof.
Background technology
A lot of household electrical appliances and electronic cable product, often require that atomized surface effect is to meet the new aesthetical standard of people now.And cable, as retardant cable of locomotives, often need be applied to oil resistant occasion, cable used need have certain oil resistance.The quality of oil resistance has material impact to the work-ing life of cable and use properties.At present, most cloudy surface cable, in research and development and production process, is only considered and is added cloudy surface agent to reach atomized surface effect, and have ignored the performance requriements of resistance to wet goods, make the over-all properties of cloudy surface cable be difficult to ensure.Therefore, developing a kind of electric wire with cloudy surface oil resistance, is the art problem demanding prompt solution.
Publication number is the Chinese patent application of CN101508806A, disclose a kind of grease-proof low-smoke halogen-free flame-proof cable material, this patent application is passed through vinyl-ester acid ethylene copolymer and paracril compound, and improved the oil resistance of material CABLE MATERIALS by inorganic powder surface process, the obtained low-smoke halogen-free flame-proof cable material with better oil resistance.This cable material is different from of the present invention, and it does not possess atomized surface effect.
Summary of the invention
For making up the deficiencies in the prior art, the invention provides Matte oil-resistant elastomer cable material of a kind of nano modification and preparation method thereof, the cable that the object of the invention is to make to have atomized surface effect has good oil resistance and mechanical property simultaneously, makes cloudy surface cable meet the needs of oil resistant occasion.
To achieve the object of the present invention, Matte oil-resistant elastomer cable material provided by the invention, is made up of each component of following weight percent:
A kind of Matte oil-resistant elastomer cable material, is characterized in that, be made up of each component of following weight percent:
Hydrogenated styrene-butadiene-styrene 20-45%;
Polypropylene 10-30%;
Paraffin oil 5-20%;
Ethylene-propylene rubber(EPR) 4-35%;
Weighting material 5-15%;
Linking agent 0.5-5%;
Oxidation inhibitor 0.5-5%
Lubricant 0.5-5%
Preferably, the weight percent of ethylene-propylene rubber(EPR) is 16 ~ 24%, and the weight percent of linking agent is 4%, and further preferably, the weight percent of ethylene-propylene rubber(EPR) is 16%.
Preferred further, described Matte oil-resistant elastomer cable material is made up of each component of following weight percent: hydrogenated styrene-butadiene-styrene 28%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 16%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%.
Described hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 300,000, as the virgin resin of weight-average molecular weight 12 ~ 200,000, be more preferably weight-average molecular weight 50,000 ~ 100,000 virgin resin.
Described polypropylene is the acrylic resin of melt flow rate (MFR) 1g/10 minute to 40g/10 minute, as the acrylic resin of melt flow rate (MFR) 5 ~ 25g/10 minute, wherein melt flow rate (MFR) carries out measuring under the condition of 230 DEG C/2.16KG according to ISO1133.Further, described polypropylene is preferably the acrylic resin of melt flow rate (MFR) 1 ~ 4g/10 minute.
Described paraffin oil is kinematic viscosity (40 DEG C) 16 ~ 400mm
2the paraffin oil of/s.
Described ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 DEG C) 25 ~ 110, as the terpolymer EP rubber of Mooney viscosity 35 ~ 55.Preferably, ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 DEG C) 25 ~ 50.
Described ethylene-propylene rubber(EPR) be Mooney viscosity 35 ~ 55 terpolymer EP rubber.
Described weighting material is the mixture of one or more in talcum powder, wollastonite, calcium carbonate, kaolin, silicon-dioxide.
Described linking agent is the mixture of one or more in cyanacrylate, sulphur, zinc oxide, magnesium oxide, dicumyl peroxide, benzoyl peroxide, 2,5-dimethyl-2,5 di-t-butyl hexane peroxides.
Described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, three (2,4-di-t-butyl) phenyl-phosphite, one or more mixture in 4,4'-thiobiss (the 6-tertiary butyl-3-methylphenol).
Described lubricant is one or more mixture in polyethylene wax, Zinic stearas, ethylene bis stearic acid amide.
The present invention also provides on the other hand a kind of method preparing Matte oil-resistant elastomer cable material as described above, comprises the steps:
A: take each component by proportioning, mixes each component;
B: each component mixed is placed in twin screw extruder plasticizing, granulation, processing temperature controls at 180-220 DEG C;
C: by the micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Technical scheme of the present invention has following beneficial effect:
1, the present invention effectively raises atomized surface effect and the oil resistance of material, and also make the cable obtained have good mechanical property, over-all properties is good simultaneously.
2, CABLE MATERIALS of the present invention is halogen-free material, belongs to environmental friendliness shaped material, can 100% recycling.
3, the Matte oil-resistant elastomer cable material of nano modification developed of the present invention, can be used for computer data line, electric wire, earphone cord etc.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is further elaborated:
Embodiment 1:
Take each component as following weight percent: hydrogenated styrene-butadiene-styrene 40%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 4%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat and is pre-mixed 10 minutes, mixing speed controls at 500 revs/min; Afterwards the material mixed is placed in that twin screw extruder carries out plastifying, granulation, its processing temperature controls at 180-190 DEG C; Micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000; Polypropylene is melt flow rate (MFR) (test condition the is 230 DEG C/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute; Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 DEG C) 16 ~ 400mm2/s; Ethylene-propylene rubber(EPR) is Mooney viscosity (ML1+4, the 125 DEG C) terpolymer EP rubber 25 ~ 50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant is Zinic stearas.
Embodiment 2:
Take each component as following weight percent: hydrogenated styrene-butadiene-styrene 36%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 8%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat and is pre-mixed 20 minutes, mixing speed controls at 300 revs/min; Afterwards the material mixed is placed in that twin screw extruder carries out plastifying, granulation, its processing temperature controls at 190-200 DEG C; Micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000; Polypropylene is melt flow rate (MFR) (test condition the is 230 DEG C/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute; Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 DEG C) 16 ~ 400mm2/s; Ethylene-propylene rubber(EPR) is Mooney viscosity (ML1+4, the 125 DEG C) terpolymer EP rubber 25 ~ 50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant is Zinic stearas.
Embodiment 3:
Take each component as following weight percent: hydrogenated styrene-butadiene-styrene 32%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 12%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat and is pre-mixed 30 minutes, mixing speed controls at 200 revs/min; Afterwards the material mixed is placed in that twin screw extruder carries out plastifying, granulation, its processing temperature controls at 200-210 DEG C; Micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000; Polypropylene is melt flow rate (MFR) (test condition the is 230 DEG C/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute; Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 DEG C) 16 ~ 400mm2/s; Ethylene-propylene rubber(EPR) is Mooney viscosity (ML1+4, the 125 DEG C) terpolymer EP rubber 25 ~ 50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant is Zinic stearas.
Embodiment 4:
Take each component as following weight percent: hydrogenated styrene-butadiene-styrene 28%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 16%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat and is pre-mixed 30 minutes, mixing speed controls at 200 revs/min; Afterwards the material mixed is placed in that twin screw extruder carries out plastifying, granulation, its processing temperature controls at 210-220 DEG C; Micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000; Polypropylene is melt flow rate (MFR) (test condition the is 230 DEG C/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute; Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 DEG C) 16 ~ 400mm2/s; Ethylene-propylene rubber(EPR) is Mooney viscosity (ML1+4, the 125 DEG C) terpolymer EP rubber 25 ~ 50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant is Zinic stearas.
Embodiment 5:
Take each component as following weight percent: hydrogenated styrene-butadiene-styrene 24%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 20%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat and is pre-mixed 30 minutes, mixing speed controls at 200 revs/min; Afterwards the material mixed is placed in that twin screw extruder carries out plastifying, granulation, its processing temperature controls at 180-190 DEG C; Micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000; Polypropylene is melt flow rate (MFR) (test condition the is 230 DEG C/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute; Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 DEG C) 16 ~ 400mm2/s; Ethylene-propylene rubber(EPR) is Mooney viscosity (ML1+4, the 125 DEG C) terpolymer EP rubber 25 ~ 50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant is Zinic stearas.
Embodiment 6:
Take each component as following weight percent: hydrogenated styrene-butadiene-styrene 20%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 24%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat and is pre-mixed 30 minutes, mixing speed controls at 200 revs/min; Afterwards the material mixed is placed in that twin screw extruder carries out plastifying, granulation, its processing temperature controls at 190-195 DEG C; Micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000; Polypropylene is melt flow rate (MFR) (test condition the is 230 DEG C/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute; Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 DEG C) 16 ~ 400mm2/s; Ethylene-propylene rubber(EPR) is Mooney viscosity (ML1+4, the 125 DEG C) terpolymer EP rubber 25 ~ 50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant is Zinic stearas.
Comparative example
Take each component as following weight percent: hydrogenated styrene-butadiene-styrene 44%, polypropylene 20%, paraffin oil 20%, weighting material 14%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat and is pre-mixed 30 minutes, mixing speed controls at 200 revs/min; Afterwards the material mixed is placed in that twin screw extruder carries out plastifying, granulation, its processing temperature controls at 190-195 DEG C; Micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000; Polypropylene is melt flow rate (MFR) (test condition the is 230 DEG C/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute; Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 DEG C) 16 ~ 400mm2/s; Weighting material is the mixture of talcum powder, silicon-dioxide; Oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant is Zinic stearas.
Performance test:
Carry out performance test to the product of embodiment 1 ~ 6 and comparative example, test condition is: dried 4 hours in the air dry oven of 60-80 DEG C by particle complete for above-mentioned granulation, the making then carrying out test sample on injection moulding machine is shaping.Tensile property test sample is of a size of 150mm*10mm*4mm, and draw speed test condition is 50mm/min.The specimen size of hardness performance test is 80mm*80mm*4mm.Oil resistance test sample is of a size of 150mm*10mm*4mm, according to JISK6301,166h*70 DEG C, and is immersed in JIS NO.1 and No. 3 oil, measures its increase relative to weight before experiment and elongation strengths conservation rate.Flowing property is tested according to ISO1133, and be the unified flowing property weighing material, adopt same test condition to be temperature 190 DEG C, counterweight is 5KG.The condition of molding of material is weighed jointly by the flowing property of material, the processing temperature of material, the injection moulding temperature of material.
Embodiment 1-6 and the CABLE MATERIALS performance test results prepared by comparative example see the following form 1:
Table 1
From performance test results, CABLE MATERIALS of the present invention, while possessing good atomized surface effect, also has good oil resistance, and obtained cable has good mechanical property and over-all properties.Wherein, in embodiment 4 add ethylene-propylene rubber(EPR) 16% and linking agent 4% time, the oil resistance of prepared material is improved significantly, and also maintains the atomized surface effect of CABLE MATERIALS exquisiteness simultaneously, and the mechanical and physical performance of material also increases.Find in practice, when the ethylene-propylene rubber(EPR) in filling a prescription continues to increase, in material, the com-patibilising effect of each component can be a greater impact, and then has influence on the overall performance of CABLE MATERIALS.
The above, it is only preferred embodiment of the present invention, not any pro forma restriction is done to the present invention, therefore all contents not departing from technical solution of the present invention, according to technical spirit of the present invention to any simple modification made for any of the above embodiments, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (5)
1. a Matte oil-resistant elastomer cable material, is characterized in that, is made up of each component of following weight percent:
Described hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000 ~ 100,000;
Described polypropylene to be melt flow rate (MFR) the be acrylic resin of 1g/10 minute to 40g/10 minute, its test condition of described melt flow rate (MFR) is probe temperature is 230 DEG C, test pressure is 2.16KG;
Described paraffin oil is kinematic viscosity 16 ~ 400mm under 40 DEG C of test conditions
2the paraffin oil of/s;
Described ethylene-propylene rubber(EPR) is ML 1+4, the terpolymer EP rubber of Mooney viscosity 25 ~ 110 under 125 DEG C of test conditions;
Described weighting material is the mixture of one or more in talcum powder, wollastonite, calcium carbonate, kaolin, silicon-dioxide.
2. Matte oil-resistant elastomer cable material according to claim 1, it is characterized in that, described linking agent is cyanacrylate, sulphur, zinc oxide, magnesium oxide, dicumyl peroxide, benzoyl peroxide, 2, the mixture of one or more in 5-dimethyl-2,5 di-t-butyl hexane peroxide.
3. Matte oil-resistant elastomer cable material according to claim 1, it is characterized in that, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, three (2,4-di-t-butyl) phenyl-phosphite, one or more mixture in 4,4'-thiobiss (the 6-tertiary butyl-3-methylphenol).
4. Matte oil-resistant elastomer cable material according to claim 1, is characterized in that, described lubricant is one or more mixture in polyethylene wax, Zinic stearas, ethylene bis stearic acid amide.
5. prepare a method for the Matte oil-resistant elastomer cable material described in any one of Claims 1 to 4, it is characterized in that, comprise the steps:
A: take each component by proportioning, mixes each component;
B: each component mixed is placed in twin screw extruder plasticizing, granulation, processing temperature controls at 180-220 DEG C;
C: by the micelle after plasticizing through head tie rod, cross water, cooling, air-dry, pelletizing and packaging.
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| CN103509308B (en) * | 2013-10-12 | 2016-05-25 | 绿宝电缆（集团）有限公司 | A kind of cloudy surface oil resistant elastomer cable material |
| CN105185449A (en) * | 2015-09-22 | 2015-12-23 | 晋源电气集团股份有限公司 | Oil resistant and high and low temperature resistant mine cable |
| CN105968676B (en) * | 2016-05-12 | 2019-07-12 | 广州市番禺旭升合成材料有限公司 | A kind of plastic modifier and preparation method thereof with copy function |
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| JP2002226643A (en) * | 2001-02-06 | 2002-08-14 | Sumitomo Bakelite Co Ltd | Heat-resistant, flexible and flame-retardant resin composition of non-halogen type and its application product |
| CN101654530A (en) * | 2009-09-18 | 2010-02-24 | 清华大学 | Negative temperature coefficient polymer composite material for temperature sensing cable and preparation method |
| CN101838436A (en) * | 2010-06-17 | 2010-09-22 | 深圳职业技术学院 | SEBS thermoplastic elastomer cable insulation material and preparation method thereof |
| CN101921437A (en) * | 2010-10-11 | 2010-12-22 | 天龙伟业线缆有限公司 | Low smoke zero halogen thermoplastic elastomer flame-retardant cable material and production method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP1221464B1 (en) * | 2001-01-09 | 2007-09-26 | Sumitomo Wiring Systems, Ltd. | Resin composition, method of making it and electrical wire covered with it |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002226643A (en) * | 2001-02-06 | 2002-08-14 | Sumitomo Bakelite Co Ltd | Heat-resistant, flexible and flame-retardant resin composition of non-halogen type and its application product |
| CN101654530A (en) * | 2009-09-18 | 2010-02-24 | 清华大学 | Negative temperature coefficient polymer composite material for temperature sensing cable and preparation method |
| CN101838436A (en) * | 2010-06-17 | 2010-09-22 | 深圳职业技术学院 | SEBS thermoplastic elastomer cable insulation material and preparation method thereof |
| CN101921437A (en) * | 2010-10-11 | 2010-12-22 | 天龙伟业线缆有限公司 | Low smoke zero halogen thermoplastic elastomer flame-retardant cable material and production method thereof |
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