CN103172965A - Matted oil-resistant elastomeric cable material and preparation method thereof - Google Patents
Matted oil-resistant elastomeric cable material and preparation method thereof Download PDFInfo
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- CN103172965A CN103172965A CN2013101371076A CN201310137107A CN103172965A CN 103172965 A CN103172965 A CN 103172965A CN 2013101371076 A CN2013101371076 A CN 2013101371076A CN 201310137107 A CN201310137107 A CN 201310137107A CN 103172965 A CN103172965 A CN 103172965A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- Engineering & Computer Science (AREA)
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Abstract
The invention provides a matted oil-resistant elastomeric cable material and a preparation method thereof. The cable material comprises the following components by weight percent: 20 to 45 percent of hydrogenated styrene-butadiene-styrene, 10 to 30 percent of polypropylene, 5 to 20 percent of paroline, 4 to 35 percent of ethylene propylene rubber, 5 to 15 percent of filler, 0.5 to 5 percent of a cross-linking agent, 0.5 to 5 percent of an antioxidant and 0.5 to 5 percent of a lubricant. The matted oil-resistant elastomeric cable material ensures that a cable has matted effect and also has good oil resistance and mechanical property, and can meet the requirements of oil resistant occasions.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS, relate in particular to a kind of cloudy surface oil resistant elastomer cable material and preparation method thereof.
Background technology
Now a lot of household electrical appliances and electronic cable product often require atomized surface effect to meet the new aesthetical standard of people.And cable as retardant cable of locomotives, often need be applied to the oil resistant occasion, and cable used need have certain oil resistance.The quality of oil resistance has material impact to work-ing life and the use properties of cable.At present, most cloudy surface cables only consider that adding the cloudy surface agent reaches atomized surface effect in research and development and production process, and have ignored the performance requriements such as oil resistant, make the over-all properties of cloudy surface cable be difficult to assurance.Therefore, developing a kind of electric wire with cloudy surface oil resistance, is the art problem demanding prompt solution.
Publication number is the Chinese patent application of CN101508806A, a kind of grease-proof low-smoke halogen-free flame-proof cable material is disclosed, this patent application is by compound with ethene-vinyl acetate multipolymer and paracril, and process to improve the oil resistance of material CABLE MATERIALS by inorganic powder surface, make the low-smoke halogen-free flame-proof cable material with better oil resistance.This cable material is from of the present invention different, and it does not possess atomized surface effect.
Summary of the invention
For making up the deficiencies in the prior art, the invention provides cloudy surface oil resistant elastomer cable material of a kind of nano modification and preparation method thereof, the objective of the invention is to make the cable with atomized surface effect to have simultaneously good oil resistance and mechanical property, make the cloudy surface cable satisfy the needs of oil resistant occasion.
To achieve the object of the present invention, cloudy surface oil resistant elastomer cable material provided by the invention is comprised of the each component of following weight percent:
A kind of cloudy surface oil resistant elastomer cable material is characterized in that, is comprised of the each component of following weight percent:
Hydrogenated styrene-butadiene-styrene 20-45%;
Polypropylene 10-30%;
Paraffin oil 5-20%;
Ethylene-propylene rubber(EPR) 4-35%;
Weighting material 5-15%;
Linking agent 0.5-5%;
Oxidation inhibitor 0.5-5%
Lubricant 0.5-5%
Preferably, the weight percent of ethylene-propylene rubber(EPR) is 16～24%, and the weight percent of linking agent is 4%, and further preferred, the weight percent of ethylene-propylene rubber(EPR) is 16%.
Further preferred, described cloudy surface oil resistant elastomer cable material is comprised of the each component of following weight percent: hydrogenated styrene-butadiene-styrene 28%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 16%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%.
Described hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～300,000, and as the virgin resin of weight-average molecular weight 12～200,000, more preferably weight-average molecular weight is at 50,000～100,000 virgin resin.
Described polypropylene is the acrylic resin of melt flow rate (MFR) 1g/10 minute to 40g/10 minute, as the acrylic resin of melt flow rate (MFR) 5～25g/10 minute, wherein melt flow rate (MFR) was to measure under the condition of 230 ℃/2.16KG according to ISO1133.Further, described polypropylene is preferably the acrylic resin of melt flow rate (MFR) 1～4g/10 minute.
Described paraffin oil is kinematic viscosity (40 ℃) 16～400mm
2The paraffin oil of/s.
Described ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～110, as the terpolymer EP rubber of Mooney viscosity 35～55.Preferably, ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～50.
Described ethylene-propylene rubber(EPR) is Mooney viscosity at 35～55 terpolymer EP rubber.
Described weighting material is one or more the mixture in talcum powder, wollastonite, calcium carbonate, kaolin, silicon-dioxide.
Described linking agent is cyanacrylate, sulphur, zinc oxide, magnesium oxide, dicumyl peroxide, benzoyl peroxide, 2, the mixture of one or more in 5-dimethyl-2,5 di-t-butyl hexane peroxide.
Described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, three (2,4-di-t-butyl) phenyl-phosphite, 4, the mixture of one or more in 4'-thiobis (the 6-tertiary butyl-3-methylphenol).
Described lubricant is one or more mixture in polyethylene wax, Zinic stearas, ethylene bis stearic acid amide.
The present invention also provides a kind of method for preparing cloudy surface oil resistant elastomer cable material as indicated above on the other hand, comprises the steps:
A: take each component by proportioning, each component is mixed;
B: the each component that mixes is placed in twin screw extruder plasticizing, granulation, and processing temperature is controlled at 180-220 ℃;
C: micelle after plastifying through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Technical scheme of the present invention has following beneficial effect:
1, the present invention effectively raises atomized surface effect and the oil resistance of material, also makes simultaneously the cable that makes have good mechanical property, and over-all properties is good.
2, CABLE MATERIALS of the present invention is the Halogen material, belongs to the environmental friendliness shaped material, can 100% recycling.
3, the cloudy surface oil resistant elastomer cable material of the nano modification developed of the present invention, can be used for computer data line, electric wire, earphone cord etc.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is further elaborated:
Embodiment 1:
Take as following weight percent each component: hydrogenated styrene-butadiene-styrene 40%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 4%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat is pre-mixed 10 minutes, mixing speed is controlled at 500 rev/mins; Afterwards the material that mixes is placed in that twin screw extruder plastifies, granulation, its processing temperature is controlled at 180-190 ℃; Micelle after plasticizing through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～100,000; Polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute to melt flow rate (MFR); Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 ℃) 16～400mm2/s; Ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is that four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant are Zinic stearas.
Embodiment 2:
Take as following weight percent each component: hydrogenated styrene-butadiene-styrene 36%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 8%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat is pre-mixed 20 minutes, mixing speed is controlled at 300 rev/mins; Afterwards the material that mixes is placed in that twin screw extruder plastifies, granulation, its processing temperature is controlled at 190-200 ℃; Micelle after plasticizing through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～100,000; Polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute to melt flow rate (MFR); Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 ℃) 16～400mm2/s; Ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is that four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant are Zinic stearas.
Embodiment 3:
Take as following weight percent each component: hydrogenated styrene-butadiene-styrene 32%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 12%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat is pre-mixed 30 minutes, mixing speed is controlled at 200 rev/mins; Afterwards the material that mixes is placed in that twin screw extruder plastifies, granulation, its processing temperature is controlled at 200-210 ℃; Micelle after plasticizing through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～100,000; Polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute to melt flow rate (MFR); Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 ℃) 16～400mm2/s; Ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is that four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant are Zinic stearas.
Embodiment 4:
Take as following weight percent each component: hydrogenated styrene-butadiene-styrene 28%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 16%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat is pre-mixed 30 minutes, mixing speed is controlled at 200 rev/mins; Afterwards the material that mixes is placed in that twin screw extruder plastifies, granulation, its processing temperature is controlled at 210-220 ℃; Micelle after plasticizing through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～100,000; Polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute to melt flow rate (MFR); Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 ℃) 16～400mm2/s; Ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is that four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant are Zinic stearas.
Embodiment 5:
Take as following weight percent each component: hydrogenated styrene-butadiene-styrene 24%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 20%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat is pre-mixed 30 minutes, mixing speed is controlled at 200 rev/mins; Afterwards the material that mixes is placed in that twin screw extruder plastifies, granulation, its processing temperature is controlled at 180-190 ℃; Micelle after plasticizing through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～100,000; Polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute to melt flow rate (MFR); Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 ℃) 16～400mm2/s; Ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is that four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant are Zinic stearas.
Embodiment 6:
Take as following weight percent each component: hydrogenated styrene-butadiene-styrene 20%, polypropylene 20%, paraffin oil 20%, ethylene-propylene rubber(EPR) 24%, weighting material 10%, linking agent 4%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat is pre-mixed 30 minutes, mixing speed is controlled at 200 rev/mins; Afterwards the material that mixes is placed in that twin screw extruder plastifies, granulation, its processing temperature is controlled at 190-195 ℃; Micelle after plasticizing through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～100,000; Polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute to melt flow rate (MFR); Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 ℃) 16～400mm2/s; Ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～50; Weighting material is the mixture of talcum powder, silicon-dioxide; Linking agent is 2,5-dimethyl-2,5 di-t-butyl hexane peroxide; Oxidation inhibitor is that four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant are Zinic stearas.
Comparative Examples
Take as following weight percent each component: hydrogenated styrene-butadiene-styrene 44%, polypropylene 20%, paraffin oil 20%, weighting material 14%, oxidation inhibitor 1%, lubricant 1%; Above material is placed in agitation vat is pre-mixed 30 minutes, mixing speed is controlled at 200 rev/mins; Afterwards the material that mixes is placed in that twin screw extruder plastifies, granulation, its processing temperature is controlled at 190-195 ℃; Micelle after plasticizing through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
Wherein, hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～100,000; Polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 4g/10 minute to melt flow rate (MFR); Paraffin oil is the paraffin oil of kinematic viscosity (temperature is 40 ℃) 16～400mm2/s; Weighting material is the mixture of talcum powder, silicon-dioxide; Oxidation inhibitor is that four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, lubricant are Zinic stearas.
Performance test:
Product to embodiment 1～6 and Comparative Examples carries out performance test, and test condition is: the particle that above-mentioned granulation is complete was dried 4 hours in the air dry oven of 60-80 ℃, then carried out the making moulding of test sample on injection moulding machine.The tensile property test sample is of a size of 150mm*10mm*4mm, and the draw speed test condition is 50mm/min.The specimen size of hardness performance test is 80mm*80mm*4mm.The oil resistance test sample is of a size of 150mm*10mm*4mm, according to JISK6301,166h*70 ℃, and it is immersed in JIS NO.1 and No. 3 oil, measure its with respect to experiment before increase and the elongation strengths conservation rate of weight.Flowing property is tested according to ISO1133, is the unified flowing property of weighing material, and adopting same test condition is 190 ℃ of temperature, and counterweight is 5KG.The condition of molding of material is weighed jointly by the flowing property of material, the processing temperature of material, the injection moulding temperature of material.
The prepared CABLE MATERIALS performance test results of embodiment 1-6 and Comparative Examples sees the following form 1:
Table 1
Do as one likes can detected result as can be known, CABLE MATERIALS of the present invention also has good oil resistance when possessing good atomized surface effect, and prepared cable has good mechanical property and over-all properties.Wherein, add in embodiment 4 ethylene-propylene rubber(EPR) 16% and linking agent 4% the time, the oil resistance of prepared material is improved significantly, and has also kept simultaneously the atomized surface effect of CABLE MATERIALS exquisiteness, and the mechanical and physical performance of material also increases.Find in practice, when the ethylene-propylene rubber(EPR) in formula continued to increase, in material, the compatible effect of each component can be a greater impact, and then has influence on the overall performance of CABLE MATERIALS.
The above, it is only preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, therefore all contents that does not break away from technical solution of the present invention,, all still belong in the scope of technical solution of the present invention any simple modification made for any of the above embodiments, equivalent variations and modification according to technical spirit of the present invention.
Claims (10)
1. a cloudy surface oil resistant elastomer cable material, is characterized in that, is comprised of the each component of following weight percent:
Hydrogenated styrene-butadiene-styrene 20-45%;
Polypropylene 10-30%;
Paraffin oil 5-20%;
Ethylene-propylene rubber(EPR) 4-35%;
Weighting material 5-15%;
Linking agent 0.5-5%;
Oxidation inhibitor 0.5-5%;
Lubricant 0.5-5%.
2. cloudy surface oil resistant elastomer cable material according to claim 1, is characterized in that, described hydrogenated styrene-butadiene-styrene is the virgin resin of weight-average molecular weight 50,000～300,000.
3. cloudy surface oil resistant elastomer cable material according to claim 1, is characterized in that, described polypropylene is that (test condition is the 230 ℃/2.16KG) acrylic resin of 1g/10 minute to 40g/10 minute to melt flow rate (MFR).
4. cloudy surface oil resistant elastomer cable material according to claim 1, is characterized in that, described paraffin oil is the paraffin oil of kinematic viscosity (40 ℃) 16～400mm2/s.
5. cloudy surface oil resistant elastomer cable material according to claim 1, is characterized in that, described ethylene-propylene rubber(EPR) is the terpolymer EP rubber of Mooney viscosity (ML1+4,125 ℃) 25～110.
6. cloudy surface oil resistant elastomer cable material according to claim 1, is characterized in that, described weighting material is one or more the mixture in talcum powder, wollastonite, calcium carbonate, kaolin, silicon-dioxide.
7. cloudy surface oil resistant elastomer cable material according to claim 1, it is characterized in that, described linking agent is cyanacrylate, sulphur, zinc oxide, magnesium oxide, dicumyl peroxide, benzoyl peroxide, 2, the mixture of one or more in 5-dimethyl-2,5 di-t-butyl hexane peroxide.
8. cloudy surface oil resistant elastomer cable material according to claim 1, it is characterized in that, described oxidation inhibitor is four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, three (2, the 4-di-t-butyl) phenyl-phosphite, 4, the mixture of one or more in 4'-thiobis (the 6-tertiary butyl-3-methylphenol).
9. cloudy surface oil resistant elastomer cable material according to claim 1, is characterized in that, described lubricant is one or more mixture in polyethylene wax, Zinic stearas, ethylene bis stearic acid amide.
10. a method for preparing the described cloudy surface oil resistant of claim 1～9 any one elastomer cable material, is characterized in that, comprises the steps:
A: take each component by proportioning, each component is mixed;
B: the each component that mixes is placed in twin screw extruder plasticizing, granulation, and processing temperature is controlled at 180-220 ℃;
C: micelle after plastifying through the head tie rod, cross water, cooling, air-dry, pelletizing and packing.
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| CN103509308A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆（集团）有限公司 | Matte oil-resistant elastomer cable material |
| CN105185449A (en) * | 2015-09-22 | 2015-12-23 | 晋源电气集团股份有限公司 | Oil resistant and high and low temperature resistant mine cable |
| CN105968676A (en) * | 2016-05-12 | 2016-09-28 | 广州市番禺旭升合成材料有限公司 | Plastic modifier with copying function and preparation method of plastic modifier |
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| CN101654530A (en) * | 2009-09-18 | 2010-02-24 | 清华大学 | Negative temperature coefficient polymer composite material for temperature sensing cable and preparation method |
| CN101838436A (en) * | 2010-06-17 | 2010-09-22 | 深圳职业技术学院 | SEBS thermoplastic elastomer cable insulation material and preparation method thereof |
| CN101921437A (en) * | 2010-10-11 | 2010-12-22 | 天龙伟业线缆有限公司 | Low smoke zero halogen thermoplastic elastomer flame-retardant cable material and production method thereof |
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| CN105968676A (en) * | 2016-05-12 | 2016-09-28 | 广州市番禺旭升合成材料有限公司 | Plastic modifier with copying function and preparation method of plastic modifier |
| CN105968676B (en) * | 2016-05-12 | 2019-07-12 | 广州市番禺旭升合成材料有限公司 | A kind of plastic modifier and preparation method thereof with copy function |
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