CN106564101A - Door body coating manufacturing process - Google Patents

Door body coating manufacturing process Download PDF

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Publication number
CN106564101A
CN106564101A CN201610995435.3A CN201610995435A CN106564101A CN 106564101 A CN106564101 A CN 106564101A CN 201610995435 A CN201610995435 A CN 201610995435A CN 106564101 A CN106564101 A CN 106564101A
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CN
China
Prior art keywords
timber
targets
door body
body coating
sand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610995435.3A
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Chinese (zh)
Inventor
刘侃
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Ofan Door Co Ltd
Original Assignee
Chongqing Ofan Door Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing Ofan Door Co Ltd filed Critical Chongqing Ofan Door Co Ltd
Priority to CN201610995435.3A priority Critical patent/CN106564101A/en
Publication of CN106564101A publication Critical patent/CN106564101A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • B27D1/08Manufacture of shaped articles; Presses specially designed therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D5/00Other working of veneer or plywood specially adapted to veneer or plywood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27MWORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M3/00Manufacture or reconditioning of specific semi-finished or finished articles
    • B27M3/18Manufacture or reconditioning of specific semi-finished or finished articles of furniture or of doors
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3464Sputtering using more than one target

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention discloses a door body coating manufacturing process, which comprises the following manufacturing process steps: (1) selecting a substrate; (2) sawing and cutting a wood door core according to the design size of the wood door; (3) hot-press forming; (4) drying treatment; (5) manufacturing a convex-concave model; (6) sputtering a coating; (7) inspecting the product; (8) and (6) packaging a finished product. Compared with the prior art, the sputtering coating is adopted in the coating step, so that the brightness of the coating of the coated wooden door formed by spraying can be kept to be more than 92 degrees according to the requirements of customers, and the coated wooden door can be resistant to scratch and deformation.

Description

Door body coating processing technology
Technical field
The invention belongs to the field of stratiform or coating, more particularly to a kind of door body coating processing technology.
Background technology
Now the coating class paint timber with highly dense plate HDF, MDF MDF, particieboard as substrate, is usually used in following five kinds of sides Method completes the processing and forming of product timber:
1st, using the modes such as artificial, electrostatic, airless spraying, machine showering Two-component polyurethane primer, finish paint (PU priming paint, Finish paint) it is taken up in order of priority and covers with paint, lacquer, colour wash, etc. on the timber surface with HDF, MDF or particieboard as substrate or in substrate veneer.Period, adopt 40-60 DEG C of heat drying method of room temperature surface drying is taken up in order of priority enforcement drying to covering with paint, lacquer, colour wash, etc. the PU priming paint on timber surface, top-coat paint film. All times are between 72-96 hours.The finished product finish paint paint film brightness that above-mentioned technique is covered with paint, lacquer, colour wash, etc. also can reach more than 92 °.
2nd, the Double-side hot moulding patch first on book size HDF, MDF or particieboard target plate face for 2440 × 1220mm The tripolycyanamide of white or other wood grain colors, urea-formaldehyde glue dipping paper, so as to make so-called dual platen, the dipping paper grammes per square metre 100g/m2To 120g/m2, postorder processing is carried out to dual platen by following operation again then:
(1) carry out the standing of one week balance period;
(2) cultivation plate, round are carried out to dual platen according to product design figure;
(3) hot-forming, the hot pressing mode using temperature control between 190-200 DEG C is being placed in timber upper and lower faces layer HDF or MDF vegetarian noodles plate or particieboard hot pressing, it is glued in the stile of timber core real-wood integrated material side;
(4) two component polyurethane finish paint (PU finish paints) is covered with paint, lacquer, colour wash, etc. using modes such as artificial, electrostatic, airless spraying, machine showerings On the surface of dual platen timber one side.Without the dual platen another side covered with paint, lacquer, colour wash, etc. directly as the finishing material of product parts, lead to It is often the inside of product timber, referred to as:The timber back side;
(5) successively reality is applied to covering with paint, lacquer, colour wash, etc. the PU top-coat paint films on timber surface in 35-40 DEG C of room temperature surface drying room heat drying room It is dried.All times are between 48-60 hours.
(6) artificial scraping is carried out to timber surrounding arris, is close to, is mended greasy, Xiu Se and cleaning.
The advantage of above-mentioned technique is reduction of the covering with paint cost of timber, but the following defective workmanship for existing equally is apparent 's:
(1) dual platen hot pressing is equilibration period long, and drying varniss speed is slow;
(2) health risk, pollutes environment, hand spray mode particularly therein;
Before covering with paint, the tripolycyanamide that overlays on timber surface, urea-formaldehyde glue dipping paper need to carry out Manual machine sand corase grind, artificial thin Mill and Manual machine sand fine grinding, Dust Capacity is big, it is time-consuming to take a lot of work;
(3) poor performances such as product surface coating is corrosion-resistant, color inhibition, anti-ultraviolet radiation line, wear-resisting anti scuffing, are particularly which In PU paint paint films based on pure white generally also there are at present easy loss of gloss, efflorescence, yellowing problems, affect product to use the longevity Life;
(4) fine work ability is weak, finished product timber back side generally existing edge sealing black glue line, artificial scraping, be close to, mend it is greasy, repair color The quality problems such as vestige and timber surrounding edge sealing arris " sharp cutting edge of a knife or a sword " needle-holding hand.
3rd, hot pressing sticker tripolycyanamide, urea-formaldehyde glue immersion-type facing paper (facing paper grammes per square metre 80g/m2To 120g/m2), or adopt With the binding agent hot pressing such as urea-formaldehyde glue, veneer is pasted, the then spraying nitro class colored varnish (NC) in veneer.Its defect for existing For:The adhesive such as pollution environment, urea-formaldehyde glue outwardly discharge free formaldehyde;NC paint in containing VOC, TDI, toluene and dimethylbenzene, The volatile material such as heavy metal, abnormal flavour, dust and other solid pollutants, the pollutant are constituted for the pollution of natural environment Source, is detrimental to health, and has increased water purification resource load.
4th, UV paints electrostatic spraying/leaching coating process.Using UV lamp drying mode to spraying/showering in timber HDF, MDF or plane UV priming paint on card real estate, finish paint are dried.When this method drastically reduce the area the drying varniss on timber surface Between, but equally exist surface layer cover with paint, lacquer, colour wash, etc. that cost is of a relatively high, finish paint easily produces paint film pin hole, it is dust granules, little orange peel, light The problems such as micro-pits, sagging, technique controlling difficulty is relatively large;It is also impossible to form heterochromatic on finished product timber edge and surface The covering with paint ability of layer.
5th, electromagnetism paint Coating technology.Electromagnetism paint Coating technology is mainly using roller coat, Ga lamp wink-dry modes in timber HDF, MDF or wood shavings laminin plate (veneer) surface complete directly covering with paint.
In energy-saving and emission-reduction, Agile manufactruing, in terms of reducing production cost, raising product surface layer paint film scratch resistance, deformation resistant Performance, the Coating technology effect are more notable, but, when timber finished surface paint film brightness value is required up to more than 90 °, the work Skill process exist surface layer cover with paint, lacquer, colour wash, etc. that cost is of a relatively high, finish paint easily produces paint film pin hole, it is dust granules, little orange peel, slight The problems such as depression, sagging, is obvious.
The content of the invention
The invention is intended to provide a kind of door body coating processing technology, timber finished surface paint film brightness value is required to solve to work as During up to more than 90 °, technical process exist surface layer cover with paint, lacquer, colour wash, etc. that cost is of a relatively high, finish paint easily produces paint film pin hole, dust granules, The technical problems such as little orange peel, slight depression, sagging.
Door body coating processing technology in this programme, by following manufacturing process steps:
(1) choose substrate;
(2) substrate saw is cut into into timber core by timber design size;
(3) it is hot-forming:Hot pressing mode using temperature control between 190-200 DEG C is being placed in timber core upper and lower surface layer HDF vegetarian noodles or particieboard hot pressing, and be glued on timber core;
(4) drying and processing:By the timber core input baking room after gluing, baking room temperature is 130 DEG C, and keeps timber core Moisture content is 20%;(5) make convex-concave moulding:By priority on high speed belt sander with line, the face way of contact to timber table Face carries out fixed thick sanding, and timber surface passes sequentially through the first sand roller on high speed belt sander, the second sand in linear contact lay mode Roller carries out fixed thick sanding;
(6) splash coating:Splashed using Zr targets and Cu target lists, the material that Zr targets and Cu targets bombard out is fallen within into timber table On face, and deposit on timber surface, define layer protecting film;
(7) examination and test of products;
(8) finished product packing.
The beneficial effect of this programme is:
(1) compared with prior art, on coating step, using splash coating, which can allow injection according to the demand of client The coating of the coating timber of formation can keep brightness to reach more than 92 °, also can scratch resistance and deformation resistant;
(2) convex-concave moulding is made in this programme and adopts high speed belt sander, can sanding remain in the bar on timber surface Wire sand sheeter lines mark, and while reject the residue and pollutant on timber surface, it is more environmentally-friendly.
Further, the substrate of step (1) is chosen with vegetarian noodles HDF, MDF or particieboard as timber upper and lower surfaces.
Further, the substrate thickness size 5mm~12mm of step (1), 780-860Kg/m of density3;Substrate book size 2440mmX1220mm。
Further, the linear velocity of the first sand roller and the second sand roller in step (5) is 30 meter per seconds, first passes through plane formula sand Pillow carries out sanding to timber surface.Scale error specification present on timber thickness direction is made in the range of technological requirement.
Further, the Zr targets and Cu targets sputtering power in step (6) is respectively 45W and 46W.
Further, the working gas pressure of the Zr targets and Cu targets in step (6) strengthens successively.
Specific embodiment
The present invention is conducted further description below by embodiment, the present embodiment is served only for entering the present invention traveling one The explanation of step, but it is not intended that limiting the scope of the invention, those skilled in the art's content of the invention Make some nonessential modifications and adaptations and fall within the scope of protection of the invention.
Embodiment 1:Door body coating processing technology is comprised the following steps that:
1st, with vegetarian noodles HDF, MDF or particieboard as the substrate of timber upper and lower surfaces.Substrate thickness size 5mm~12mm, 780-860Kg/m of density3;Substrate book size 2440mmX1220mm (is attached to the veneer thickness on veneer substrate surface 0.30-0.80mm);
2nd, press timber design size saw and cut out substrate (HDF, MDF or particieboard) and timber core;
3rd, it is hot-forming:Hot pressing mode using temperature control between 190-200 DEG C is the HDF for being placed in timber upper and lower surface layer (or MDF) vegetarian noodles or particieboard hot pressing, and be glued on timber core;
4th, drying and processing:Timber is put into into baking room, baking room temperature is 130 DEG C, and holding timber core moisture content is 20%;
5th, make convex-concave moulding:Timber is formed into the door-plate with three-dimensional contouring through saw sanction, plane, milling, by a high speed Fixed thick sanding is carried out with line, the face way of contact to timber surface successively on belt sander, timber surface with linear contact lay mode according to Secondary the first sand roller by high speed belt sander, the second sand roller carry out the line of fixed thick sanding, the first sand roller and the second sand roller Speed is 30 meter per seconds, then carries out again sanding operation to timber surface by plane formula sand pillow with the face way of contact, makes to remain in Bar wire sand sheeter lines mark on timber surface is completely eliminated, and scale error moment present on timber thickness direction is advised Model is in the range of technological requirement, and while rejects residue and pollutant on timber surface;
6th, splash coating:Metal film is prepared using three target Sputting film-plating apparatus of JGP450 types fine vacuum, on timber surface Sputtering sedimentation film layer, is splashed using Zr targets and Cu target lists, the sputtering current and sputtering voltage of both respectively be 0.1A, The sputtering power of 0.45kV and 0.1A, 0.46kV, Zr targets and Cu targets is respectively 45W and 46W, the Zr target and Cu targets film layer when singly splashing The pressure of deposition is set to 7x10-2, the material that Zr targets and Cu targets bombard out is fallen within timber surface, and on timber surface It is upper to deposit, define layer protecting film.
7th, the examination and test of products;
8th, finished product packing;
9th, finished product warehouse-in, delivery.
Embodiment 2:Door body coating processing technology is comprised the following steps that:
2 step 1-5 of embodiment, 7,8 and 9 are consistent with embodiment 1, its step 6:
Splash coating:Metal film is prepared using three target Sputting film-plating apparatus of JGP450 types fine vacuum, is splashed on timber surface Depositional coating is penetrated, is splashed using Zr targets and Cu target lists, the sputtering current and sputtering voltage of both respectively is 0.1A, 0.45kV 45W and 46W, the Zr target and Cu targets film deposition when singly splashing is respectively with the sputtering power of 0.1A, 0.46kV, Zr targets and Cu targets Pressure is set to 2.4x10-1, the material that Zr targets and Cu targets bombard out is fallen within timber surface, and is sunk on timber surface Accumulate, define layer protecting film.
Embodiment 3:Door body coating processing technology is comprised the following steps that:
3 step 1-5 of embodiment, 7,8 and 9 are consistent with embodiment 1, its step 6:
Splash coating:Metal film is prepared using three target Sputting film-plating apparatus of JGP450 types fine vacuum, is splashed on timber surface Depositional coating is penetrated, is splashed using Zr targets and Cu target lists, the sputtering current and sputtering voltage of both respectively is 0.1A, 0.45kV 45W and 46W, the Zr target and Cu targets film deposition when singly splashing is respectively with the sputtering power of 0.1A, 0.46kV, Zr targets and Cu targets Pressure is set to 3.4, and the material that Zr targets and Cu targets bombard out is fallen within timber surface, and under depositing on timber surface Come, define layer protecting film.
Experiment test:
1st, use AB104- N-type electronic balance is weighed to the timber before splash coating, and its weight is initial mass M0
2nd, use AB104- N-type electronic balance is weighed to the timber after splash coating, and its weight is mass M after plating1
3rd, metal film deposition amount M2=M1-M0
Experimental data:
Embodiment 1 Embodiment 2 Embodiment 3
Working gas pressure/Pa 7x10-2 2.4x10-1 3.4
Initial mass M0/g 32.2158 32.522 33.2521
Mass M after plating1/g 32.2168 32.545 33.2687
Metal film deposition amount M2/g 0.001 0.023 0.0166
Experimental result:
When working gas pressure is 7x10-2During Pa, its metal film deposition amount M2For 0.001g, can determine whether out in working gas When pressure is low, its three target Sputting film-plating apparatus of JGP450 types fine vacuum pounds Zr targets and the material of Cu targets is less, and sputtering is uniform, Therefore, the coating brightness of program timber can reach more than 92 °.
When working gas pressure is 2.4x10-1During Pa, its metal deposition capability M2For 0.023g, can determine whether out that JGP450 types are high Three target Sputting film-plating apparatus of vacuum pound Zr targets and the material of Cu targets is more, the coating scratch resistance of program timber and resistance to change Shape.
When working gas pressure is 3.4Pa, its metal deposition capability M2For 0.0166g, though working gas pressure is than front two Individual embodiment is high, but its three target Sputting film-plating apparatus of JGP450 types fine vacuum pounds Zr targets and the material of Cu targets compares embodiment 2 is less, and which can determine whether it should not is that working gas pressure is higher, and the material of Zr targets and the bombardment of Cu targets is more, the painting of program timber Layer can both keep brightness to reach more than 92 °, also can scratch resistance and deformation resistant.
Above-described is only embodiments of the invention, and in scheme, the known general knowledge here such as concrete structure and characteristic is not made It is excessive to describe.It should be pointed out that for a person skilled in the art, on the premise of without departing from present configuration, can be with Some deformations and improvement are made, these should also be considered as protection scope of the present invention, these are implemented all without the impact present invention Effect and practical applicability.This application claims protection domain should be defined by the content of its claim, in description Specific embodiment etc. records the content that can be used for explaining claim.

Claims (6)

1. door body coating processing technology, it is characterised in that by following manufacturing process steps:
(1)Choose substrate;
(2)Press timber design size saw and cut out timber core;
(3)It is hot-forming:Hot pressing mode using temperature control between 190-200 DEG C is the HDF for being placed in timber upper and lower surface layer plain Face or particieboard hot pressing, and be glued on timber core;
(4)Drying and processing:Timber is put into into baking room, baking room temperature is 130 DEG C, and keep timber core moisture content to be 20%; (5)Make convex-concave moulding:By fixed thick sand is carried out to timber surface with line, the face way of contact successively on high speed belt sander Light, timber surface are passed sequentially through the first sand roller on high speed belt sander, the second sand roller and carry out fixed thick sand in linear contact lay mode Light;
(6)Splash coating:Splashed using Zr targets and Cu target lists, the material that Zr targets and Cu targets bombard out is fallen within into timber surface On, and deposit on timber surface, define layer protecting film;
(7)The examination and test of products;
(8)Finished product packing.
2. door body coating processing technology according to claim 1, it is characterised in that:Step(1)Substrate choose with vegetarian noodles HDF, MDF or particieboard are timber upper and lower surfaces.
3. door body coating processing technology according to claim 1, it is characterised in that:Step(1)Substrate thickness size 5mm ~12mm, 780-860Kg/m of density3;Substrate book size 2440mmX1220mm.
4. door body coating processing technology according to claim 1, it is characterised in that:Step(5)In the first sand roller and The linear velocity of two sand rollers is 30 meter per seconds, carries out again sanding operation to timber surface by plane formula sand pillow with the face way of contact.
5. door body coating processing technology according to claim 1, it is characterised in that:Step(6)In Zr targets and Cu targets splash Penetrate power and be respectively 45W and 46W.
6. door body coating processing technology according to claim 1, it is characterised in that:Step(6)In Zr targets and Cu targets Working gas pressure strengthens successively.
CN201610995435.3A 2016-11-11 2016-11-11 Door body coating manufacturing process Pending CN106564101A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610995435.3A CN106564101A (en) 2016-11-11 2016-11-11 Door body coating manufacturing process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610995435.3A CN106564101A (en) 2016-11-11 2016-11-11 Door body coating manufacturing process

Publications (1)

Publication Number Publication Date
CN106564101A true CN106564101A (en) 2017-04-19

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11117453A (en) * 1997-10-14 1999-04-27 Noda Corp Construction board
CN101091125A (en) * 2004-12-03 2007-12-19 空气化工产品公司 Sun protection film which absorbs infrared radiation
KR20100131458A (en) * 2008-03-28 2010-12-15 다이니폰 인사츠 가부시키가이샤 Damp-proof membrane, anti-warping wooden board, and veneer
CN103659954A (en) * 2014-01-02 2014-03-26 王梁 Wear-resistant steel template and manufacturing method thereof
CN103722603A (en) * 2014-01-11 2014-04-16 昆明三德木门制造有限公司 Wooden door manufacturing technology
CN105803413A (en) * 2016-05-31 2016-07-27 东北林业大学 Method for preparing super-amphiphobic wood through magnetron sputtering

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11117453A (en) * 1997-10-14 1999-04-27 Noda Corp Construction board
CN101091125A (en) * 2004-12-03 2007-12-19 空气化工产品公司 Sun protection film which absorbs infrared radiation
KR20100131458A (en) * 2008-03-28 2010-12-15 다이니폰 인사츠 가부시키가이샤 Damp-proof membrane, anti-warping wooden board, and veneer
CN101980866A (en) * 2008-03-28 2011-02-23 大日本印刷株式会社 Damp-proof membrane, anti-warping wooden board, and veneer
CN103659954A (en) * 2014-01-02 2014-03-26 王梁 Wear-resistant steel template and manufacturing method thereof
CN103722603A (en) * 2014-01-11 2014-04-16 昆明三德木门制造有限公司 Wooden door manufacturing technology
CN105803413A (en) * 2016-05-31 2016-07-27 东北林业大学 Method for preparing super-amphiphobic wood through magnetron sputtering

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Application publication date: 20170419