CN106561697A - 一种福寿螺杀螺剂 - Google Patents

一种福寿螺杀螺剂 Download PDF

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CN106561697A
CN106561697A CN201610944902.XA CN201610944902A CN106561697A CN 106561697 A CN106561697 A CN 106561697A CN 201610944902 A CN201610944902 A CN 201610944902A CN 106561697 A CN106561697 A CN 106561697A
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陈卉
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Guangxi University
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

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Abstract

本发明公开了一种福寿螺杀螺剂，其由质量份的以下原料组成：硅藻土或高岭土1～20份、茶麸10～20份、乙酸仲丁酯30～40份、二甲基亚砜7～15份、蓖麻油聚氧乙烯醚1～15份、β‑环糊精3～20份、十二烷基苯磺酸钙3～8份、木质素磺酸钠1～10份、丙二醇5～15份、防冻剂1～10份、增稠剂1～10份、崩解剂1～10份、灭螺活性物质40～60份；所述的灭螺活性物质由五氯酚钠、槟榔碱、银杏酸、茶皂素、没食子酸、异槲皮素、益母草碱组成。本发明由植物活性物质与化学药物复配使用可降低化学药物的使用量，减少环境污染，各植物活性物质复配可增强灭螺剂的灭螺活性，与无害浓度的五氯酚钠复配，杀螺效果好。

Description

一种福寿螺杀螺剂
技术领域
本发明涉及农药技术领域，具体涉及一种福寿螺杀螺剂。
背景技术
福寿螺原产于南美洲亚马逊河流域，是世界100种恶性外来入侵生物之一，也是我国国家环保总局首批入侵中国的16种外来入侵物种“黑名单”之一的外来入侵物种。福寿螺是一种高蛋白商品而被引入养殖，但由于过度养殖、管理不善、和其口味不佳等原因被农民丢弃，由于其具有极强的环境适应能力，福寿螺繁殖泛滥，对农业生产造成严重的破坏。
灭螺的方法主要由生物灭螺、物理灭螺和药物灭螺。目前，在福寿螺的防治上主要采用药物灭螺，药物灭螺主要有化学灭螺药和植物灭螺药，但长期使用化学灭螺会对福寿螺产生耐药性，且易造成农药残留和农药污染，同时还会杀灭鱼类等有益物种。而植物灭螺药物主要是从以含有灭螺活性成分的植物中提取某些有效成分，用于灭螺。植物灭螺具有易降解等优点。但是植物药性较为缓慢，植物药物提取物有效成分的含量低，杂质多，提取成本高等缺点。这些缺点制约着植物灭螺的广泛应用。现阶段，人们已经将从单一的药物灭螺逐渐向植物药物灭螺研究，如专利号201510025184.1公布了一种复配杀螺剂，其主要利用甲氨基阿维菌素苯甲酸盐和茶枯粉复配作为灭螺活性成分制成灭螺剂，但其对化学药物的依赖还很高。
发明内容
本发明的目的在于，针对现有技术，提供一种植物活性物质与化学杀虫药物复配，降低化学杀虫药物使用量的一种福寿螺杀螺剂。
为实现上述目的，本发明采取以下技术方案：一种福寿螺杀螺剂其由质量份的以下原料组成：硅藻土或高岭土1～20份、茶麸10～20份、乙酸仲丁酯30～40份、二甲基亚砜7～15份、蓖麻油聚氧乙烯醚1～15份、β-环糊精3～20份、十二烷基苯磺酸钙3～8份、木质素磺酸钠1～10份、丙二醇5～15份、防冻剂1～10份、增稠剂1～10份、崩解剂1～10份、灭螺活性物质40～60份。
其中，所述的灭螺活性物质由五氯酚钠、槟榔碱、银杏酸、茶皂素、没食子酸、异槲皮素、益母草碱组成。
所述的增稠剂为黄原胶、阿拉伯胶的一种或其组合。
所述的崩解剂为硫酸铵、氯化钠或硫酸铵的一种或几种。
本发明中，没食子酸、异槲皮素、益母草碱可使螺的生物酶活力下降，新陈代谢受到破坏，从而导致螺的死亡。
本发明中，槟榔碱为杀螺剂的增效剂，与五氯酚钠、茶皂素、银杏酸的复配使用可减少灭螺药物的投放量，银杏酸具有很强的杀虫抑菌效果，但对农作物和鱼毒性较低，宜用于杀螺用药，但银杏酸本身水溶性较低，经β-环糊精包埋后与槟榔碱复配可显著提高银杏酸的水溶性。
本发明采用植物提取物与化学复配使用可减少化学药物的使用量，降低杀螺剂对环境的污染和对水中其他养殖鱼类的伤害。
本发明的有益效果是：本发明由植物活性物质与化学药物复配使用可降低化学药物的使用量，各植物活性物质复配可增强灭螺剂的灭螺活性，与无害浓度的五氯酚钠复配，杀螺效果好。
具体实施方式
下面结合具体实施例，对本发明进一步的说明。
实施例1
一种福寿螺杀螺剂由质量份的以下原料组成：硅藻土或高岭土10份、茶麸13份、乙酸仲丁酯35份、二甲基亚砜10份、蓖麻油聚氧乙烯醚12份、β-环糊精6份、十二烷基苯磺酸钙6份、木质素磺酸钠4份、丙二醇11份、防冻剂2份、黄原胶3份、硫酸铵9份、灭螺活性物质50份；所述的灭螺活性物质由五氯酚钠、槟榔碱、银杏酸、茶皂素、没食子酸、异槲皮素、益母草碱组成。
实施例2
一种福寿螺杀螺剂由质量份的以下原料组成：硅藻土或高岭土16份、茶麸18份、乙酸仲丁酯34份、二甲基亚砜14份、蓖麻油聚氧乙烯醚12份、β-环糊精18份、十二烷基苯磺酸钙5份、木质素磺酸钠8份、丙二醇8份、防冻剂8份、黄原胶和阿拉伯胶复合物4份、由硫酸铵、氯化钠和硫酸铵组成的崩解剂7份、灭螺活性物质55份；所述的灭螺活性物质由五氯酚钠、槟榔碱、银杏酸、茶皂素、没食子酸、异槲皮素、益母草碱组成。
实施例3
一种福寿螺杀螺剂由质量份的以下原料组成：硅藻土或高岭20份、茶麸10份、乙酸仲丁酯40份、二甲基亚砜7份、蓖麻油聚氧乙烯醚15份、β-环糊精3份、十二烷基苯磺酸钙8份、木质素磺酸钠1份、丙二醇15份、防冻剂1份、阿拉伯胶增稠剂10份、氯化钠和硫酸铵混合崩解剂1份、灭螺活性物质60份；所述的灭螺活性物质由五氯酚钠、槟榔碱、银杏酸、茶皂素、没食子酸、异槲皮素、益母草碱组成。
实施例4
一种福寿螺杀螺剂由质量份的以下原料组成：硅藻土或高岭土1份、茶麸20份、乙酸仲丁酯30份、二甲基亚砜15份、蓖麻油聚氧乙烯醚1份、β-环糊精20份、十二烷基苯磺酸钙3份、木质素磺酸钠10份、丙二醇5份、防冻剂10份、黄原胶增稠剂1份、硫酸铵和氯化钠混合崩解剂10份、灭螺活性物质40份；所述的灭螺活性物质由五氯酚钠、槟榔碱、银杏酸、茶皂素、没食子酸、异槲皮素、益母草碱组成。

Claims (3)

1.一种福寿螺杀螺剂，其特征在于，其由质量份的以下原料组成：硅藻土或高岭土1～20份、茶麸10～20份、乙酸仲丁酯30～40份、二甲基亚砜7～15份、蓖麻油聚氧乙烯醚1～15份、β-环糊精3～20份、十二烷基苯磺酸钙3～8份、木质素磺酸钠1～10份、丙二醇5～15份、防冻剂1～10份、增稠剂1～10份、崩解剂1～10份、灭螺活性物质40～60份；
所述的灭螺活性物质由五氯酚钠、槟榔碱、银杏酸、茶皂素、没食子酸、异槲皮素、益母草碱组成。
2.根据权利要求1所述的一种福寿螺灭螺剂，其特征在于，所述的增稠剂为黄原胶、阿拉伯胶的一种或其组合。
3.根据权利要求1所述的一种福寿螺灭螺剂，其特征在于，所述的崩解剂为硫酸铵、氯化钠或硫酸铵的一种或几种。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108423774A (zh) * 2018-04-10 2018-08-21 上海海洋大学 一种水体除螺和净化双重作用剂及其用途
CN108812716A (zh) * 2018-08-03 2018-11-16 普定县顺和水果苗木种植有限公司 一种生物杀螺剂及其制备方法

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* Cited by examiner, † Cited by third party
Title
吴俊等: ""益母草碱灭螺活性研究"", 《湖北大学学报（自然科学版）》 *
常连举等: ""没食子酸的制备与应用综述"", 《生物质化学工程》 *
杨丽敏等主编: "《有机化学》", 30 December 2012 *
田启建等主编: "《湘西主要特色药用植物栽培与利用》", 30 December 2015 *
钱久李等: ""福寿螺植物源杀螺剂绿色农药的研究进展"", 《农药》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108423774A (zh) * 2018-04-10 2018-08-21 上海海洋大学 一种水体除螺和净化双重作用剂及其用途
CN108812716A (zh) * 2018-08-03 2018-11-16 普定县顺和水果苗木种植有限公司 一种生物杀螺剂及其制备方法

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