CN106554598A - A kind of phenolic resin warming plate and preparation method thereof - Google Patents
A kind of phenolic resin warming plate and preparation method thereof Download PDFInfo
- Publication number
- CN106554598A CN106554598A CN201610985785.1A CN201610985785A CN106554598A CN 106554598 A CN106554598 A CN 106554598A CN 201610985785 A CN201610985785 A CN 201610985785A CN 106554598 A CN106554598 A CN 106554598A
- Authority
- CN
- China
- Prior art keywords
- phenolic resin
- warming plate
- inorganic filler
- fiber
- resin warming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 74
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 74
- 238000010792 warming Methods 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 46
- 239000011256 inorganic filler Substances 0.000 claims abstract description 31
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000011521 glass Substances 0.000 claims abstract description 19
- 239000004088 foaming agent Substances 0.000 claims abstract description 17
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960001149 dopamine hydrochloride Drugs 0.000 claims abstract description 14
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 239000011324 bead Substances 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 9
- 235000019362 perlite Nutrition 0.000 claims abstract description 8
- 239000010451 perlite Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 20
- 241000196324 Embryophyta Species 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 15
- -1 Hydrogen phthalic anhydride Chemical class 0.000 claims description 12
- 239000010902 straw Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 8
- 230000005070 ripening Effects 0.000 claims description 8
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical group CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 6
- 240000007594 Oryza sativa Species 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 6
- 240000008042 Zea mays Species 0.000 claims description 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 6
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 6
- 235000005822 corn Nutrition 0.000 claims description 6
- 235000009566 rice Nutrition 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 5
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 5
- 241000209140 Triticum Species 0.000 claims description 5
- 235000021307 Triticum Nutrition 0.000 claims description 5
- 229920002522 Wood fibre Polymers 0.000 claims description 5
- 239000011425 bamboo Substances 0.000 claims description 5
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 5
- 239000002025 wood fiber Substances 0.000 claims description 5
- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 claims description 4
- RYAIMSPHUVXLQI-UHFFFAOYSA-N 4-(aminomethyl)-2-(benzotriazol-2-yl)phenol Chemical compound NCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RYAIMSPHUVXLQI-UHFFFAOYSA-N 0.000 claims description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- 239000001384 succinic acid Substances 0.000 claims description 4
- 125000006158 tetracarboxylic acid group Chemical group 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 2
- SVBXGJUYERNFSM-UHFFFAOYSA-N phenyl-(4,5,6-trihydroxy-3-methylidenecyclohexa-1,5-dien-1-yl)methanone Chemical compound C=C1C(C(=C(C(C(=O)C2=CC=CC=C2)=C1)O)O)O SVBXGJUYERNFSM-UHFFFAOYSA-N 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N 1-dodecanol group Chemical group C(CCCCCCCCCCC)O LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims 1
- 244000025254 Cannabis sativa Species 0.000 claims 1
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- 238000005267 amalgamation Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- VYFYYTLLBUKUHU-UHFFFAOYSA-N dopamine Chemical compound NCCC1=CC=C(O)C(O)=C1 VYFYYTLLBUKUHU-UHFFFAOYSA-N 0.000 description 5
- 241001330002 Bambuseae Species 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
- 229960003638 dopamine Drugs 0.000 description 4
- 239000012774 insulation material Substances 0.000 description 4
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- HTQNYBBTZSBWKL-UHFFFAOYSA-N 2,3,4-trihydroxbenzophenone Chemical compound OC1=C(O)C(O)=CC=C1C(=O)C1=CC=CC=C1 HTQNYBBTZSBWKL-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- VGGRCVDNFAQIKO-UHFFFAOYSA-N formic anhydride Chemical compound O=COC=O VGGRCVDNFAQIKO-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920001690 polydopamine Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WTDRDQBEARUVNC-UHFFFAOYSA-N L-Dopa Natural products OC(=O)C(N)CC1=CC=C(O)C(O)=C1 WTDRDQBEARUVNC-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- MHUWZNTUIIFHAS-CLFAGFIQSA-N dioleoyl phosphatidic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(COP(O)(O)=O)OC(=O)CCCCCCC\C=C/CCCCCCCC MHUWZNTUIIFHAS-CLFAGFIQSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229960004502 levodopa Drugs 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2497/00—Characterised by the use of lignin-containing materials
- C08J2497/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of phenolic resin warming plate and preparation method thereof; the phenolic resin warming plate includes the phenolic resin of 50～80 weight portions; the resin fibre of 10～20 weight portions; the dopamine hydrochloride of 3～10 weight portions; the firming agent of 3～12 weight portions; the foaming agent of 2～5 weight portions; the surfactant of 0.5～3 weight portion; the inorganic filler of the heat stabilizer of 1～3 weight portion, 25～40 weight portions; one or more in hollow glass micropearl, glass bead, expanded perlite of inorganic filler, particle diameter is 80～100 μm.The present invention is with phenolic resin, Plant fiber, dopamine hydrochloride, firming agent, foaming agent, surfactant, heat stabilizer, inorganic filler as raw material, dopamine hydrochloride can improve inorganic filler and phenolic resin amalgamation, so that inorganic filler is dispersed in phenolic resin warming plate, it is to avoid scaling-off problem occur；Plant fiber enables to phenolic resin and is incubated while with excellent heat-insulating property, and intensity is high, good toughness.
Description
Technical field
The present invention relates to building thermal insulation material field, more particularly to a kind of phenolic resin warming plate and preparation method thereof.
Background technology
Phenolic resin warming plate is made up of phenol formaldehyde foam resin, phenol formaldehyde foam resin be it is a kind of it is new do not fire, low cigarette of preventing fires
Insulation material, it is to add foaming agent, firming agent and closed pore rigid foam made by other auxiliary agents by phenolic resin.It is most
The characteristics of prominent be do not fire, low cigarette, high temperature resistance distortion, overcome inflammable original foam plasticss insulation material, thickness, heat deformation
Shortcoming, remain the features such as original foam plasticss type insulation material light weight, easy construction.But, phenolic resin warming plate
There are problems, such as poor toughness, intensity is low.
The content of the invention
It is an object of the invention to provide a kind of phenolic resin warming plate and preparation method thereof, can solve the problem that existing phenolic resin
The technical problem of warming plate poor toughness, low intensity.
To solve above-mentioned technical problem, the technical solution used in the present invention is：
A kind of phenolic resin warming plate, including the raw material of following parts by weight：
One or more in hollow glass micropearl, glass bead, expanded perlite of the inorganic filler；
The particle diameter of the inorganic filler is 80～100 μm.
Preferably, the Plant fiber is selected from rice hull cellulose, rice-straw fibre, wheat straw fiber, corn stalk fiber, Cotton Stalk
One or more in fiber, wood fiber, bamboo scraps fiber.
Preferably, the firming agent is phthalic anhydride, tetrabydrophthalic anhydride, chlordene methylene tetrahydrochysene benzene two
Penta tetracarboxylic dianhydride of formic anhydride or ring.
Preferably, the foaming agent is pentane, normal hexane, normal heptane, carborundum or Calcium Carbonate.
Preferably, the surfactant is sodium laurylsulfate, sodium lignin sulfonate or sodium stearate.
Preferably, the heat stabilizer is 2- (2 '-hydroxyl -5 '-aminomethyl phenyl) benzotriazole, methylene (trihydroxy two
Benzophenone) or poly- [(1- (β-ethyl) -2,2,6,6- tetramethyl -4- piperidyls) succinic acid] ester.
Present invention also offers a kind of preparation method of above-mentioned phenolic resin warming plate, comprises the following steps：
Weigh phenolic resin, Plant fiber, dopamine hydrochloride, foaming agent, heat stabilizer, surfactant, inorganic fill out
During material each component adds stirred tank, compound after stirring, is obtained；
To in the compound firming agent, depanning after foamed, solidification, ripening is added to obtain final product phenolic resin warming plate again.
Preferably, the particle diameter polydispersity index of inorganic filler described in the compound is less than 1.05.
The beneficial effects of the present invention is：
The invention provides a kind of phenolic resin warming plate and preparation method thereof, the phenolic resin warming plate includes 50～
The phenolic resin of 80 weight portions, the resin fibre of 10～20 weight portions, the dopamine hydrochloride of 3～10 weight portions, 3～12 weight
The firming agent of part, the foaming agent of 2～5 weight portions, the surfactant of 0.5～3 weight portion, the heat stabilizer of 1～3 weight portion,
The inorganic filler of 25～40 weight portions, inorganic filler selected from hollow glass micropearl, glass bead, the one kind in expanded perlite or
Various, particle diameter is 80～100 μm.The present invention is with phenolic resin, Plant fiber, dopamine hydrochloride, firming agent, foaming agent, table
Face activating agent, heat stabilizer, inorganic filler prepare phenolic resin warming plate for raw material, and dopamine hydrochloride can make inorganic filler
Merge with phenolic resin so that inorganic filler is dispersed in phenolic resin warming plate, it is to avoid scaling-off asking occurs in warming plate
Topic, fire protecting performance are high；Plant fiber can improve the intensity and toughness of phenolic resin warming plate, so that phenolic resin insulation
While with excellent heat-insulating property, intensity is high, good toughness.
Specific embodiment
The invention discloses a kind of phenolic resin warming plate and preparation method thereof, those skilled in the art can use for reference herein
Content, is suitably modified technological parameter realization.Specifically, the similar replacement and change are to people in the art
It is it will be apparent that they are considered as being included in the present invention for member.The method of the present invention and reference have passed through preferably real
Apply example to be described, related personnel substantially can be in without departing from present invention, spirit and scope to method described herein
It is modified with application or suitably changes and combine, realizes and apply the technology of the present invention.
A kind of phenolic resin warming plate that the present invention is provided, including the raw material of following parts by weight：
One or more in hollow glass micropearl, glass bead, expanded perlite of inorganic filler；
The particle diameter of inorganic filler is 80～100 μm.
The present invention is steady with phenolic resin, Plant fiber, dopamine hydrochloride, firming agent, foaming agent, surfactant, heat
Determining agent, inorganic filler and phenolic resin warming plate being prepared for raw material, dopamine hydrochloride can improve inorganic filler and phenolic resin
Amalgamation so that inorganic filler is dispersed in phenolic resin warming plate, it is to avoid scaling-off problem occur, fire protecting performance is high；Plant
Fibres can improve the intensity and toughness of phenolic resin warming plate, so that phenolic resin is incubated with excellent insulation
While performance, intensity is high, good toughness.
In the present invention, the parts by weight of phenolic resin are 50～80 parts；In an embodiment of the present invention, phenolic resin
Parts by weight are 60～70 parts.
Plant fiber is used for the compressive strength for increasing phenolic resin；In an embodiment of the present invention, Plant fiber is selected from rice
One kind in case fibre, rice-straw fibre, wheat straw fiber, corn stalk fiber, Cotton Gossypii stalk fiber, wood fiber, bamboo scraps fiber or
It is various；In other embodiments, Plant fiber is selected from rice hull cellulose, rice-straw fibre, wheat straw fiber, corn stalk fiber, Cotton Gossypii
Two kinds in stalk fiber, wood fiber, bamboo scraps fiber.
In the present invention, the parts by weight of Plant fiber are 10～20 parts；In an embodiment of the present invention, Plant fiber
Parts by weight are 13～17 parts.
Inorganic filler is easily wrapped up in water by dopamine hydrochloride so that inorganic filler surface covers poly-dopamine film,
Between poly-dopamine and phenolic resin, the compatibility is good, so that filler preferably can be dispersed in phenolic resin warming plate.
In the present invention, the parts by weight of dopamine hydrochloride are 3～10 parts；In an embodiment of the present invention, dopamine
The parts by weight of hydrochlorate are 5～8 parts.
In order to improve the dimensional stability of phenolic resin warming plate, in an embodiment of the present invention, firming agent is adjacent benzene two
Formic anhydride, tetrabydrophthalic anhydride, penta tetracarboxylic dianhydride of chlordene methylene tetrahydrochysene phthalate anhydride or ring.
In the present invention, the parts by weight of firming agent are 3～12 parts；In an embodiment of the present invention, the weight of firming agent
Number is 6～9 parts.
In order to improve the intensity of phenolic resin warming plate, in an embodiment of the present invention, foaming agent be pentane, just oneself
Alkane, normal heptane, carborundum or Calcium Carbonate；In other embodiments, foaming agent is normal hexane, carborundum or Calcium Carbonate.
In the present invention, the parts by weight of foaming agent are 2～5 parts；In an embodiment of the present invention, the weight portion of foaming agent
Number is 3～4 parts.
In an embodiment of the present invention, surfactant is sodium laurylsulfate, sodium lignin sulfonate or sodium stearate.
In the present invention, the parts by weight of surfactant are 0.5～3 part；In an embodiment of the present invention, surface activity
The parts by weight of agent are 1.2～2.4 parts.
In order to improve the heat stability of phenolic resin warming plate, in an embodiment of the present invention, heat stabilizer be 2- (2 '-
Hydroxyl -5 '-aminomethyl phenyl) benzotriazole, methylene (trihydroxybenzophenone) or poly- [(1- (β-ethyl) -2,2,6,6- tetramethyls
Base -4- piperidyls) succinic acid] ester.
In the present invention, the parts by weight of heat stabilizer are 1～3 part；In an embodiment of the present invention, the weight of heat stabilizer
Amount number is 1.6～2.4 parts.
In order to improve the heat-insulating property and crushing resistance of phenolic resin warming plate, in an embodiment of the present invention, inorganic filler
One or more in hollow glass micropearl, glass bead, expanded perlite, the particle diameter of inorganic filler is 80～100 μm.
In the present invention, the parts by weight of inorganic filler are 25～40 parts；In an embodiment of the present invention, inorganic filler
Parts by weight are 30～35 parts.
Present invention also offers a kind of preparation method of phenolic resin warming plate, comprises the following steps：
Weigh phenolic resin, Plant fiber, dopamine hydrochloride, foaming agent, heat stabilizer, surfactant, inorganic fill out
During material each component adds stirred tank, compound after stirring, is obtained；
To in compound firming agent, depanning after foamed, solidification, ripening is added to obtain final product phenolic resin warming plate again.
Wherein, phenolic resin, Plant fiber, dopamine hydrochloride, foaming agent, heat stabilizer, surfactant, inorganic fill out
Material and firming agent are same as above, will not be described here.
Above-mentioned technology preparation method is simple, it is easy to operate, and the phenolic resin warming plate for preparing has excellent resisting
Pressure performance, heat-insulating property, intensity and toughness.
In an embodiment of the present invention, in compound, the particle diameter polydispersity index of inorganic filler is less than 1.05.
In an embodiment of the present invention, step a) is specially and inorganic filler is added to the water, and is stirring evenly and then adding into many
Bar amine hydrochlorate；After lucifuge stands 18～36h, phenolic resin, Plant fiber, foaming agent, heat stabilizer, surface activity are added
During agent each component adds stirred tank, compound after stirring, is obtained.
In other embodiments, water and the mass ratio of inorganic filler are (4～6)：1.
In order to further illustrate the present invention, with reference to embodiments to the present invention provide a kind of phenolic resin warming plate and
Its preparation method is described in detail.
Embodiment 1
25kg hollow glass micropearls are added in 150kg water, 3kg dopamine hydrochlorides are stirring evenly and then adding into；Lucifuge
Stand 18h after, add 50kg phenolic resin, 10kg corn stalk fibers, 2kg pentanes, 1kg 2- (2 '-hydroxyl -5 '-first
Base phenyl) benzotriazole, 0.5kg sodium laurylsulfates, compound is obtained after stirring；
To in compound 3kg tetrabydrophthalic anhydrides, depanning after foamed, solidification, ripening is added to obtain final product phenolic aldehyde tree again
Fat warming plate.
The phenolic resin warming plate that embodiment 1 is prepared has excellent heat stability, can be in 150 DEG C of life-time service.
Embodiment 2
40kg glass beads are added in 160kg water, 10kg dopamine hydrochlorides are stirring evenly and then adding into；Lucifuge stands
After 24h, the poly- [(1- (β-second of 80kg phenolic resin, 10kg rice hull celluloses, 10kg rice-straw fibres, 5kg normal heptane, 3kg are added
Base) -2,2,6,6- tetramethyl -4- piperidyls) succinic acid] ester, 3kg sodium lignin sulfonates, compound is obtained after stirring；
To in compound penta tetracarboxylic dianhydride of 12kg rings, depanning after foamed, solidification, ripening is added to obtain final product phenolic resin again
Warming plate.
The phenolic resin warming plate that embodiment 2 is prepared has excellent heat stability, can be in 150 DEG C of life-time service.
Embodiment 3
16kg hollow glass micropearls, 16kg glass beads are added in 144kg water, 7kg DOPA is stirring evenly and then adding into
Amine hydrochlorate；After lucifuge stands 28h, 60kg phenolic resin, 6kg Cotton Gossypii stalk fibers, 7kg wood fibers, 3.5kg carbonic acid are added
Calcium, 1.6kg methylene (trihydroxybenzophenone), 1.2kg sodium stearates, obtain compound after stirring；
Add 6kg chlordene methylene tetrahydrochysene phthalate anhydrides again in compound, foamed, solidification, depanning after ripening,
Obtain final product phenolic resin warming plate.
The phenolic resin warming plate that embodiment 3 is prepared has excellent heat stability, can be in 150 DEG C of life-time service.
Embodiment 4
15kg hollow glass micropearls, 20kg expanded perlites are added in 180kg water, 5kg is stirring evenly and then adding into many
Bar amine hydrochlorate；After lucifuge stands 36h, 65kg phenolic resin, 7kg wheat straw fibers, 10kg bamboo scraps fibers, 4kg carbonizations are added
Silicon, 2kg methylene (trihydroxybenzophenone), 1.8kg sodium stearates, obtain compound after stirring；
To in compound 3kg tetrabydrophthalic anhydrides, depanning after foamed, solidification, ripening is added to obtain final product phenolic aldehyde tree again
Fat warming plate.
The phenolic resin warming plate that embodiment 4 is prepared has excellent heat stability, can be in 150 DEG C of life-time service.
Embodiment 5
10kg hollow glass micropearls, 10kg glass beads, 10kg expanded perlites are added in 165kg water, stirring is equal
7kg dopamine hydrochlorides are added after even；After lucifuge stands 32h, 70kg phenolic resin, 7kg corn stalk fibers, 8kg are added
Cotton Gossypii stalk fiber, 3kg normal hexane, 2.4kg 2- (2 '-hydroxyl -5 '-aminomethyl phenyl) benzotriazole, 2.4kg sodium lignin sulfonates,
Compound is obtained after stirring；
To in compound 3kg phthalic anhydrides, depanning after foamed, solidification, ripening is added to obtain final product phenolic resin guarantor again
Warm plate.
The phenolic resin warming plate that embodiment 5 is prepared has excellent heat stability, can be in 150 DEG C of life-time service.
The phenolic resin warming plate that embodiment 1～5 is prepared is carried out tensile strength, elongation at break, comprcssive strength,
The test of heat conductivity, the results are shown in Table 1.
The test result of 1 embodiment 1～5 of table
Disclosed above is only specific implementation of the patent example, but this patent is not limited to this, general for this area
For logical technical staff, under the premise without departing from the principles of the invention, the deformation made should be regarded as belonging to the scope of the present invention.
Claims (8)
1. a kind of phenolic resin warming plate, it is characterised in that including the raw material of following parts by weight：
One or more in hollow glass micropearl, glass bead, expanded perlite of the inorganic filler；
The particle diameter of the inorganic filler is 80～100 μm.
2. phenolic resin warming plate as claimed in claim 1, it is characterised in that the Plant fiber is selected from rice hull cellulose, rice
One or more in grass fiber, wheat straw fiber, corn stalk fiber, Cotton Gossypii stalk fiber, wood fiber, bamboo scraps fiber.
3. phenolic resin warming plate as claimed in claim 1, it is characterised in that the firming agent be phthalic anhydride, four
Hydrogen phthalic anhydride, penta tetracarboxylic dianhydride of chlordene methylene tetrahydrochysene phthalate anhydride or ring.
4. phenolic resin warming plate as claimed in claim 1, it is characterised in that the foaming agent is pentane, normal hexane, just
Heptane, carborundum or Calcium Carbonate.
5. phenolic resin warming plate as claimed in claim 1, it is characterised in that the surfactant is lauryl alcohol sulphuric acid
Sodium, sodium lignin sulfonate or sodium stearate.
6. phenolic resin warming plate as claimed in claim 1, it is characterised in that the heat stabilizer be 2- (2 '-hydroxyl -5 ' -
Aminomethyl phenyl) benzotriazole, methylene (trihydroxybenzophenone) or poly- [(1- (β-ethyl) -2,2,6,6- tetramethyl -4- piperazines
Piperidinyl) succinic acid] ester.
7. a kind of preparation method of phenolic resin warming plate as claimed in claim 1, it is characterised in that comprise the following steps：
A) phenolic resin, Plant fiber, dopamine hydrochloride, foaming agent, heat stabilizer, surfactant, inorganic filler are weighed
During each component adds stirred tank, compound after stirring, is obtained；
B) in the compound firming agent, depanning after foamed, solidification, ripening is added to obtain final product phenolic resin warming plate again.
8. preparation method as claimed in claim 7, it is characterised in that many points of the particle diameter of inorganic filler described in the compound
Scattered index is less than 1.05.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610985785.1A CN106554598A (en) | 2016-11-09 | 2016-11-09 | A kind of phenolic resin warming plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610985785.1A CN106554598A (en) | 2016-11-09 | 2016-11-09 | A kind of phenolic resin warming plate and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106554598A true CN106554598A (en) | 2017-04-05 |
Family
ID=58443761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610985785.1A Pending CN106554598A (en) | 2016-11-09 | 2016-11-09 | A kind of phenolic resin warming plate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106554598A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107090186A (en) * | 2017-06-25 | 2017-08-25 | 北京林业大学 | A kind of preparation method based on the enhanced bamboo-plastic composite material of dopamine |
| CN107325479A (en) * | 2017-07-18 | 2017-11-07 | 合肥广能新材料科技有限公司 | Plasticizing phenol formaldehyde warming plate and preparation method thereof |
| CN107418236A (en) * | 2017-06-22 | 2017-12-01 | 合肥励仙电力工程有限公司 | A kind of insulation Wood plastic composite for being used to decorate and preparation method thereof |
| CN107459830A (en) * | 2017-09-10 | 2017-12-12 | 北京林业大学 | One kind is based on the bionical interface modifier enhancing bamboo fibre of poly-dopamine and poly butylene succinate interface compatibility technology |
| CN107746544A (en) * | 2017-11-21 | 2018-03-02 | 南宁可煜能源科技有限公司 | A kind of phenol-formaldehyde foam composite thermal-insulating materials and preparation method thereof |
| CN108485178A (en) * | 2018-04-04 | 2018-09-04 | 肖锦 | A kind of antibacterial and mouldproof wood plastics composite thermal insulation board and preparation method thereof |
| CN108641279A (en) * | 2018-05-30 | 2018-10-12 | 合肥智慧龙图腾知识产权股份有限公司 | A kind of thermal insulation board that flame retardant property is good |
| CN108774074A (en) * | 2018-08-03 | 2018-11-09 | 深圳市金鑫城纸品有限公司 | A kind of light sound-proof high-strength panel and preparation method thereof |
| CN114276629A (en) * | 2021-11-19 | 2022-04-05 | 东台市豪威节能科技有限公司 | Preparation method of bamboo-wood fiber heat-insulation composite decorative plate |
| CN114854084A (en) * | 2022-03-31 | 2022-08-05 | 化学与精细化工广东省实验室揭阳分中心 | Sponge with nanoparticle coating and preparation method and application thereof |
| CN117087259A (en) * | 2023-08-21 | 2023-11-21 | 江苏科技大学 | Mail wheel shutter with heat preservation and noise reduction functions |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531769A (en) * | 2009-04-17 | 2009-09-16 | 上海应用技术学院 | Method for preparing high temperature resistance phenolic aldehyde foam insulating composite material |
| CN102061059A (en) * | 2010-12-22 | 2011-05-18 | 中国林业科学研究院林产化学工业研究所 | Wood fiber reinforced inflaming retarding foam material and machining method thereof |
| CN102321279A (en) * | 2011-09-29 | 2012-01-18 | 北京化工大学 | Dopamine modified carbon nanotube/rubber composite material and preparation method thereof |
| CN102964772A (en) * | 2012-12-05 | 2013-03-13 | 福建天利高新材料有限公司 | Chopped fiber reinforced phenolic resin foam material and preparation method thereof |
| CN103087344A (en) * | 2013-01-18 | 2013-05-08 | 南京航空航天大学 | Preparation method of hollow glass microbead-reinforced phenolic foam composite material |
| CN104004319A (en) * | 2014-06-16 | 2014-08-27 | 北京航空航天大学 | Plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material and preparing method thereof |
| CN104030309A (en) * | 2014-06-26 | 2014-09-10 | 淮阴工学院 | Fiber-type clay organic modification method based on dopamine modification |
| CN104098860A (en) * | 2014-07-30 | 2014-10-15 | 四川大学 | Preparation method for polyvinylidene fluoride/poly-dopamine-coated graphene nanocomposite |
| CN105440583A (en) * | 2015-12-04 | 2016-03-30 | 武汉理工大学 | Dopamine compound modified or coated nano particle modified polymer composite material and preparation method thereof |
-
2016
- 2016-11-09 CN CN201610985785.1A patent/CN106554598A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531769A (en) * | 2009-04-17 | 2009-09-16 | 上海应用技术学院 | Method for preparing high temperature resistance phenolic aldehyde foam insulating composite material |
| CN102061059A (en) * | 2010-12-22 | 2011-05-18 | 中国林业科学研究院林产化学工业研究所 | Wood fiber reinforced inflaming retarding foam material and machining method thereof |
| CN102321279A (en) * | 2011-09-29 | 2012-01-18 | 北京化工大学 | Dopamine modified carbon nanotube/rubber composite material and preparation method thereof |
| CN102964772A (en) * | 2012-12-05 | 2013-03-13 | 福建天利高新材料有限公司 | Chopped fiber reinforced phenolic resin foam material and preparation method thereof |
| CN103087344A (en) * | 2013-01-18 | 2013-05-08 | 南京航空航天大学 | Preparation method of hollow glass microbead-reinforced phenolic foam composite material |
| CN104004319A (en) * | 2014-06-16 | 2014-08-27 | 北京航空航天大学 | Plant fiber reinforcing type heat-preservation inflaming-retarding phenolic foam material and preparing method thereof |
| CN104030309A (en) * | 2014-06-26 | 2014-09-10 | 淮阴工学院 | Fiber-type clay organic modification method based on dopamine modification |
| CN104098860A (en) * | 2014-07-30 | 2014-10-15 | 四川大学 | Preparation method for polyvinylidene fluoride/poly-dopamine-coated graphene nanocomposite |
| CN105440583A (en) * | 2015-12-04 | 2016-03-30 | 武汉理工大学 | Dopamine compound modified or coated nano particle modified polymer composite material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 唐黎明等: "《高分子化学》", 30 September 2016, 清华大学出版社 * |
| 焦宝祥: "《土木工程材料》", 31 January 2009, 高等教育出版社 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418236A (en) * | 2017-06-22 | 2017-12-01 | 合肥励仙电力工程有限公司 | A kind of insulation Wood plastic composite for being used to decorate and preparation method thereof |
| CN107090186A (en) * | 2017-06-25 | 2017-08-25 | 北京林业大学 | A kind of preparation method based on the enhanced bamboo-plastic composite material of dopamine |
| CN107325479A (en) * | 2017-07-18 | 2017-11-07 | 合肥广能新材料科技有限公司 | Plasticizing phenol formaldehyde warming plate and preparation method thereof |
| CN107459830A (en) * | 2017-09-10 | 2017-12-12 | 北京林业大学 | One kind is based on the bionical interface modifier enhancing bamboo fibre of poly-dopamine and poly butylene succinate interface compatibility technology |
| CN107746544A (en) * | 2017-11-21 | 2018-03-02 | 南宁可煜能源科技有限公司 | A kind of phenol-formaldehyde foam composite thermal-insulating materials and preparation method thereof |
| CN108485178A (en) * | 2018-04-04 | 2018-09-04 | 肖锦 | A kind of antibacterial and mouldproof wood plastics composite thermal insulation board and preparation method thereof |
| CN108641279A (en) * | 2018-05-30 | 2018-10-12 | 合肥智慧龙图腾知识产权股份有限公司 | A kind of thermal insulation board that flame retardant property is good |
| CN108774074A (en) * | 2018-08-03 | 2018-11-09 | 深圳市金鑫城纸品有限公司 | A kind of light sound-proof high-strength panel and preparation method thereof |
| CN114276629A (en) * | 2021-11-19 | 2022-04-05 | 东台市豪威节能科技有限公司 | Preparation method of bamboo-wood fiber heat-insulation composite decorative plate |
| CN114854084A (en) * | 2022-03-31 | 2022-08-05 | 化学与精细化工广东省实验室揭阳分中心 | Sponge with nanoparticle coating and preparation method and application thereof |
| CN114854084B (en) * | 2022-03-31 | 2023-08-18 | 化学与精细化工广东省实验室揭阳分中心 | Sponge with nanoparticle coating and preparation method and application thereof |
| CN117087259A (en) * | 2023-08-21 | 2023-11-21 | 江苏科技大学 | Mail wheel shutter with heat preservation and noise reduction functions |
| CN117087259B (en) * | 2023-08-21 | 2024-04-19 | 江苏科技大学 | Mail wheel shutter with heat preservation and noise reduction functions |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106554598A (en) | A kind of phenolic resin warming plate and preparation method thereof | |
| CN104058630A (en) | Novel heat insulating plate and manufacturing method thereof | |
| US20140158927A1 (en) | Composition for manufacturing a tannin-based foam material, foam material obtainable from it, and manufacturing process thereof | |
| CN105347769A (en) | Two-component efficient and light external wall insulation material and preparation method thereof | |
| CN104876629A (en) | Silicate fireproof thermal insulation material and preparation method thereof | |
| CN104446130A (en) | Composite nanometer heat-preservation and thermal-insulation sheet and preparation method thereof | |
| CN107474536A (en) | A kind of construction and decoration light flame-retardant acoustic material | |
| CN103254565A (en) | Preparation method of toughened modified phenolic foams | |
| CN106966661A (en) | A kind of fretting map technique of assembled architecture Light trabses | |
| CN109535614A (en) | The preparation method of fiber reinforcement porous fluoropolymer polymer | |
| CN106046671A (en) | Modified phenolic resin composite thermal insulation material and preparation method thereof | |
| CN107674332A (en) | A kind of environmental protection flame retardant master batch and preparation method thereof, application, fire proofing | |
| CN103450434B (en) | A kind of plant polyatomic alcohol polyurethane rigid foam material and preparation method thereof | |
| CN106243303A (en) | Environmentally-friepolyurethane polyurethane foam heat-insulation material | |
| CN107474204A (en) | A kind of modified phenolic foam insulation material and preparation method thereof | |
| CN106145855B (en) | A kind of siliceous polymer heat preserving plate of fiber reinforcement and preparation method thereof | |
| CN101781114B (en) | Preparation method for inorganic fire-resistant foam filling material for door core board | |
| CN105541260A (en) | Inorganic thermal-insulation plate and preparation method thereof | |
| CN102863252B (en) | Foaming-stabilizing dispersion agent for foamed cement insulation board | |
| CN106832680A (en) | A kind of ultralow cold-resistant PVC expanded material and preparation method | |
| CN106279631A (en) | Polyurethane foam heat insulation material | |
| CN104987581A (en) | Polythene alloy material and preparation method therefor | |
| CN109293295A (en) | A kind of homogeneous complex material heat preservation template and its production method | |
| CN112646106A (en) | Composite polyether for environment-friendly flame-retardant polyurethane commercial beverage barrel and preparation method thereof | |
| WO2010108340A2 (en) | Fireproof inflaming retarding plate core, fireproof colored steel with core and corresponding producing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170405 |