CN106553295A - A kind of releasing agent of polyurethane elastomer material - Google Patents

A kind of releasing agent of polyurethane elastomer material Download PDF

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Publication number
CN106553295A
CN106553295A CN201610934114.2A CN201610934114A CN106553295A CN 106553295 A CN106553295 A CN 106553295A CN 201610934114 A CN201610934114 A CN 201610934114A CN 106553295 A CN106553295 A CN 106553295A
Authority
CN
China
Prior art keywords
parts
releasing agent
polyurethane elastomer
elastomer material
paraffin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610934114.2A
Other languages
Chinese (zh)
Inventor
黎茜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201610934114.2A priority Critical patent/CN106553295A/en
Publication of CN106553295A publication Critical patent/CN106553295A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • B29C33/62Releasing, lubricating or separating agents based on polymers or oligomers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • B29C33/62Releasing, lubricating or separating agents based on polymers or oligomers
    • B29C33/64Silicone
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

The invention discloses a kind of releasing agent of polyurethane elastomer material, which is made up of the following raw material of mass parts:25~35 parts of paraffin, 5~10 parts of silicone grease, 3~10 parts of stearic acid, 20~25 parts of vegetable oil, 10~20 parts of polyoxyethylene fatty acid ester, 5~10 parts of glyceryl monostearate, 1~5 part of lauryl alcohol, 1~10 part of potassium hydroxide, 100~200 parts of deionized water.The releasing agent of the polyurethane elastomer material of the present invention has good isolation effect, and also with the good easy mold release of lubricity, stability is high, do not pollute smooth easy cleaning of grinding tool, abrasive surface and other effects.

Description

A kind of releasing agent of polyurethane elastomer material
Technical field
The present invention relates to technical field of mold release, and in particular to a kind of releasing agent of polyurethane elastomer material.
Background technology
, in molding, because the isocyanide ester of polyurethane has caking property, when causing the demoulding, product is easily and model for polyurethane material Bonding, in order to preferably make formed product, needs to isolate model and product with releasing agent.At present, there is system in many releasing agents Product are easily bondd with grinding tool, and after the demoulding, product appearance is bad, pollute the phenomenon such as big, unstable.The direct shadow of quality of releasing agent quality Ring the quality of product.Thus develop that lubricity is good, stability is high, do not pollute the demoulding of the smooth easy cleaning of grinding tool, abrasive surface Agent is particularly important.
The content of the invention
It is an object of the present invention to be directed to prior art, there is provided a kind of releasing agent of polyurethane elastomer material.
For achieving the above object, the present invention takes technical scheme below:A kind of releasing agent of polyurethane elastomer material by The following raw material composition of mass parts:It is 25~35 parts of paraffin, 5~10 parts of silicone grease, 3~10 parts of stearic acid, 20~25 parts of vegetable oil, poly- 10~20 parts of oxygen ethylene fatty acid ester, 5~10 parts of glyceryl monostearate, 1~5 part of lauryl alcohol, 1~10 part of potassium hydroxide, go 100~200 parts of ionized water.
Preferably, a kind of releasing agent of polyurethane elastomer material is made up of the following raw material of mass parts:Paraffin 25~30 Part, 5~8 parts of silicone grease, 3~5 parts of stearic acid, 20~22 parts of vegetable oil, 10~15 parts of polyoxyethylene fatty acid ester, monostearate are sweet 5~7 parts of grease, 3~5 parts of lauryl alcohol, 1~5 part of potassium hydroxide, 150~200 parts of deionized water.
Further, a kind of preparation method of the releasing agent of polyurethane elastomer material of the invention is comprised the following steps: Paraffin, silicone grease, stearic acid, vegetable oil heating and melting are obtained into mixed material A, then just polyoxyethylene fatty acid ester, single hard acid fat Mixed material B is slowly added to mixture by glyceride, lauryl alcohol, potassium hydroxide, the mixed material B of deionized water heating and melting In material A, stirring and emulsifying obtains final product the releasing agent obtained by the present invention.
Wherein, paraffin, silicone grease, stearic acid, vegetable oil are the oil phase of the present invention, polyoxyethylene fatty acid ester, single hard acid fat Glyceride, lauryl alcohol, potassium hydroxide, deionized water are the water phase of the present invention, polyoxyethylene fatty acid ester, single hard acid fat glycerol Ester, lauryl alcohol are with the use of with good emulsifying effectiveness, releasing agent good stability obtained in emulsifying.
The invention has the beneficial effects as follows:A kind of releasing agent of polyurethane elastomer material of the present invention has isolation well Effect, the good easy mold release of lubricity, stability are high, do not pollute smooth easy cleaning of grinding tool, abrasive surface and other effects.
Specific embodiment
With reference to specific embodiment, to further instruction of the present invention.
Embodiment 1
A kind of releasing agent of polyurethane elastomer material is made up of the following raw material of mass parts:25 parts of paraffin, 5 parts of silicone grease, 3 parts of stearic acid, 20 parts of vegetable oil, 10 parts of polyoxyethylene fatty acid ester, 5 parts of glyceryl monostearate, 1 part of lauryl alcohol, hydroxide 1 part of potassium, 100 parts of deionized water.
Its preparation method is:Paraffin, silicone grease, stearic acid, vegetable oil heating and melting are obtained into mixed material A, then just polyoxy Ethylene fatty acid ester, single hard acid fat glyceride, lauryl alcohol, potassium hydroxide, the mixed material B of deionized water heating and melting, will be mixed During compound material B is slowly added to mixed material A, stirring and emulsifying obtains final product the releasing agent obtained by the present invention.
Embodiment 2
A kind of releasing agent of polyurethane elastomer material is made up of the following raw material of mass parts:35 parts of paraffin, 10 parts of silicone grease, 10 parts of stearic acid, 25 parts of vegetable oil, 20 parts of polyoxyethylene fatty acid ester, 10 parts of glyceryl monostearate, 5 parts of lauryl alcohol, hydrogen-oxygen Change 10 parts of potassium, 200 parts of deionized water.
Its preparation method is with embodiment 1.
Embodiment 3
A kind of releasing agent of polyurethane elastomer material is made up of the following raw material of mass parts:30 parts of paraffin, 8 parts of silicone grease, 5 parts of stearic acid, 22 parts of vegetable oil, 15 parts of polyoxyethylene fatty acid ester, 7 parts of glyceryl monostearate, 5 parts of lauryl alcohol, hydroxide 5 parts of potassium, 200 parts of deionized water.
Its preparation method is with embodiment 1.
Embodiment 4
A kind of releasing agent of polyurethane elastomer material is made up of the following raw material of mass parts:25 parts of paraffin, 5 parts of silicone grease, 3 parts of stearic acid, 20 parts of vegetable oil, 10 parts of polyoxyethylene fatty acid ester, 5 parts of glyceryl monostearate, 3 parts of lauryl alcohol, hydroxide 1 part of potassium, 150 parts of deionized water.
Its preparation method is with embodiment 1.
Embodiment 5
A kind of releasing agent of polyurethane elastomer material is made up of the following raw material of mass parts:27 parts of paraffin, 6 parts of silicone grease, 4 parts of stearic acid, 21 parts of vegetable oil, 13 parts of polyoxyethylene fatty acid ester, 6 parts of glyceryl monostearate, 4 parts of lauryl alcohol, hydroxide 3 parts of potassium, 170 parts of deionized water.
Its preparation method is with embodiment 1.

Claims (3)

1. a kind of releasing agent of polyurethane elastomer material, it is characterised in which is made up of the following raw material of mass parts:Paraffin 25 ~35 parts, it is 5~10 parts of silicone grease, 3~10 parts of stearic acid, 20~25 parts of vegetable oil, 10~20 parts of polyoxyethylene fatty acid ester, single hard 5~10 parts of glycerol, 1~5 part of lauryl alcohol, 1~10 part of potassium hydroxide, 100~200 parts of deionized water.
2. the releasing agent of a kind of polyurethane elastomer material according to claim 1, it is characterised in which is by mass parts Following raw material composition:25~30 parts of paraffin, 5~8 parts of silicone grease, 3~5 parts of stearic acid, 20~22 parts of vegetable oil, Polyoxyethylene fatty 10~15 parts of acid esters, 5~7 parts of glyceryl monostearate, 3~5 parts of lauryl alcohol, 1~5 part of potassium hydroxide, deionized water 150~ 200 parts.
3. a kind of releasing agent of polyurethane elastomer material according to claim 1 and 2, it is characterised in that its preparation side Method is comprised the following steps:Paraffin, silicone grease, stearic acid, vegetable oil heating and melting are obtained into mixed material A, then just Polyethylene oxide fat Fat acid esters, single hard acid fat glyceride, lauryl alcohol, potassium hydroxide, the mixed material B of deionized water heating and melting, by mixed material B In being slowly added to mixed material A, stirring and emulsifying obtains final product the releasing agent obtained by the present invention.
CN201610934114.2A 2016-11-01 2016-11-01 A kind of releasing agent of polyurethane elastomer material Pending CN106553295A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610934114.2A CN106553295A (en) 2016-11-01 2016-11-01 A kind of releasing agent of polyurethane elastomer material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610934114.2A CN106553295A (en) 2016-11-01 2016-11-01 A kind of releasing agent of polyurethane elastomer material

Publications (1)

Publication Number Publication Date
CN106553295A true CN106553295A (en) 2017-04-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610934114.2A Pending CN106553295A (en) 2016-11-01 2016-11-01 A kind of releasing agent of polyurethane elastomer material

Country Status (1)

Country Link
CN (1) CN106553295A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403737A (en) * 2014-09-25 2015-03-11 安徽华盛科技控股股份有限公司 Production process of CIT capsule demoulding agent
CN105252678A (en) * 2015-11-06 2016-01-20 沈阳化工大学 High-temperature-resistant wax-system environment-friendly polyurethane release agents and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403737A (en) * 2014-09-25 2015-03-11 安徽华盛科技控股股份有限公司 Production process of CIT capsule demoulding agent
CN105252678A (en) * 2015-11-06 2016-01-20 沈阳化工大学 High-temperature-resistant wax-system environment-friendly polyurethane release agents and preparation method thereof

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Application publication date: 20170405