CN106543564A - A kind of preparation method of the water plated material that can be roughened with water - Google Patents

A kind of preparation method of the water plated material that can be roughened with water Download PDF

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Publication number
CN106543564A
CN106543564A CN201611047548.7A CN201611047548A CN106543564A CN 106543564 A CN106543564 A CN 106543564A CN 201611047548 A CN201611047548 A CN 201611047548A CN 106543564 A CN106543564 A CN 106543564A
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water
plated material
roughened
preparation
resin
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CN201611047548.7A
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Chinese (zh)
Inventor
吴耀辉
周东波
黄贤明
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Xiamen Runner Industrial Corp
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Xiamen Runner Industrial Corp
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Priority to CN201611047548.7A priority Critical patent/CN106543564A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/02—Chemical treatment or coating of shaped articles made of macromolecular substances with solvents, e.g. swelling agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08J2371/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2429/02—Homopolymers or copolymers of unsaturated alcohols
    • C08J2429/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2439/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Derivatives of such polymers
    • C08J2439/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C08J2439/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2471/02—Polyalkylene oxides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemically Coating (AREA)

Abstract

The invention discloses a kind of preparation method of the water plated material that can be roughened with water, belongs to water power plating field of material preparation.After soluble oligomeric compound is taken using surfactant process, drying, then with resin agitating mixed processing, subsequently by double screw extruder pelletize, the water plated material is obtained；The soluble oligomeric compound can be dispersed in resin surface layer in granulation process, form 0.5 ~ 3 micron of particle.Water plated material obtained in of the invention can be directly roughened with water, 10 ~ 30min of certain hour is soaked in 50 ~ 80 DEG C of water, make to be dispersed in the soluble oligomer dissolving of resin surface, so as to " back-off " pit is formed in resin surface, reach effect of original ABS-like using the roughening of the strong acid such as chromic acid, so as to reach the target of Chrome-free roughening, the pollution to environment is reduced, and greatly reduces production cost.

Description

A kind of preparation method of the water plated material that can be roughened with water
Technical field
The invention belongs to water power plating field of material preparation, and in particular to a kind of water plated material that can be roughened with water Preparation method.
Background technology
Existing water plated material is mainly based on ABS and ABS/PC alloy material classes, and in its water electroplating process, roughening is Important step, its roughening principle are material to be corroded using the mixing of the strong acid such as chromic acid, the butadiene on surface wherein in material Composition is corroded completely by strong acid, so as to " back-off " pit is formed on surface, provides good combination power for follow-up plating.However, thick Change the Cr VI contained by the chromic acid in liquid and can cause severe contamination to environment, therefore, invent and a kind of can be roughened with water Water plated material has great significance.
The content of the invention
Present invention aims to prior art is not enough, there is provided a kind of water plated material that can be roughened with water Preparation method.
For achieving the above object, the present invention is adopted the following technical scheme that：
A kind of preparation method of the water plated material that can be roughened with water：Take soluble oligomeric compound and utilize surfactant After process, drying, then with resin agitating mixed processing, subsequently by double screw extruder pelletize, the water plated material is obtained； The soluble oligomeric compound, it is better than Resin Flow, and addition is low, and resin surface layer can be dispersed in granulation process, Form 0.5 ~ 3 micron of particle.
In double screw extruder granulation process, 140 ~ 270 DEG C of temperature control, rotating speed during screw rod shearing are 200 ~ 600r/ min。
The soluble oligomeric compound is any one in PVP, PEG and PVA.
The resin is any one in PP, PE, PA and PPO.
Resin is 100 with the mass ratio of soluble oligomeric compound:3~10.
The beneficial effects of the present invention is：Water plated material obtained in of the invention can be directly roughened with water, 50 ~ 10 ~ 30min of certain hour is soaked in 80 DEG C of water, makes to be dispersed in the soluble oligomer dissolving of resin surface, so as in resin Surface forms 0.5 ~ 3 micron " back-off " pit, reaches effect of original ABS-like using the roughening of the strong acid such as chromic acid, so as to reach To the target of Chrome-free roughening, the pollution to environment is reduced, and greatly reduces production cost.
Description of the drawings
SEM figures of the Fig. 1 for resin surface after water plated material immersion obtained in embodiment 1；
SEM figures of the Fig. 2 for resin surface after water plated material immersion obtained in embodiment 2；
SEM figures of the Fig. 3 for resin surface after water plated material immersion obtained in embodiment 3；
SEM figures of the Fig. 4 for resin surface after water plated material immersion obtained in embodiment 4.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
A kind of preparation method of the water plated material that can be roughened with water：After PVP is taken using surfactant process, dry It is dry, then with PP resin agitating mixed processing, PP resins are 100 with the mass ratio of PVP:3；Subsequently made by double screw extruder Grain, 160 DEG C of temperature control, rotating speed is 200r/min, and the water plated material is obtained；PVP can be dispersed in PP in granulation process Resin surface layer, forms 0.5 ~ 3 micron of particle.
Obtained water plated material is soaked into certain hour 30min in 50 DEG C of water, makes to be dispersed in PP resin surfaces Soluble oligomer PVP dissolvings, so as to " back-off " pit is formed in resin surface, reach roughening effect, roughening aperture is 0.5 ~ 3 microns.
Embodiment 2
A kind of preparation method of the water plated material that can be roughened with water：After PEG is taken using surfactant process, dry It is dry, then with PE resin agitating mixed processing, PE resins are 100 with the mass ratio of PEG:10；Subsequently made by double screw extruder Grain, 140 DEG C of temperature control, rotating speed is 600r/min, and the water plated material is obtained；PEG can be dispersed in PE in granulation process Resin surface layer, forms 0.5 ~ 3 micron of particle.
Obtained water plated material is soaked into certain hour 10min in 80 DEG C of water, makes to be dispersed in PE resin surfaces Soluble oligomer PEG dissolvings, so as to " back-off " pit is formed in resin surface, reach roughening effect, roughening aperture is 0.5 ~ 1.5 microns.
Embodiment 3
A kind of preparation method of the water plated material that can be roughened with water：After PVA is taken using surfactant process, dry It is dry, then with PA6 resin agitating mixed processing, PA6 resins are 100 with the mass ratio of PVA:5；Subsequently made by double screw extruder Grain, 200 DEG C of temperature control, rotating speed is 300r/min, and the water plated material is obtained；PVA can be dispersed in PA6 in granulation process Resin surface layer, forms 0.5 ~ 3 micron of particle.
Obtained water plated material is soaked into certain hour 25min in 60 DEG C of water, makes to be dispersed in PA resin surfaces Soluble oligomer PVA dissolvings, so as to " back-off " pit is formed in resin surface, reach roughening effect, roughening aperture is 0.5 ~ 2 microns.
Embodiment 4
A kind of preparation method of the water plated material that can be roughened with water：After PEG is taken using surfactant process, dry It is dry, then with PPO resin agitating mixed processing, PPO resins are 100 with the mass ratio of PEG:6；Subsequently made by double screw extruder Grain, 270 DEG C of temperature control, rotating speed is 400r/min, and the water plated material is obtained；PEG can be dispersed in PPO in granulation process Resin surface layer, forms 0.5 ~ 3 micron of particle.
Obtained water plated material is soaked into certain hour 20min in 70 DEG C of water, makes to be dispersed in PPO resin surfaces Soluble oligomer PEG dissolvings, so as to " back-off " pit is formed in resin surface, reach roughening effect, roughening aperture is 0.5 ~ 2 microns.
The roughening effect of water plated material obtained in 1 embodiment 1 ~ 4 of table
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with repair Decorations, should all belong to the covering scope of the present invention.

Claims (5)

1. a kind of preparation method of the water plated material that can be roughened with water, it is characterised in that：Take soluble oligomeric compound After surfactant process, drying, then with resin agitating mixed processing, subsequently by double screw extruder pelletize, be obtained The water plated material；The soluble oligomeric compound can be dispersed in resin surface layer in granulation process, form 0.5 ~ 3 micron Particle.
2. a kind of preparation method of the water plated material that can be roughened with water as claimed in claim 1, it is characterised in that： In double screw extruder granulation process, 140 ~ 270 DEG C of temperature control, rotating speed during screw rod shearing are 200 ~ 600r/min.
3. a kind of preparation method of the water plated material that can be roughened with water as claimed in claim 1, it is characterised in that： The soluble oligomeric compound is any one in PVP, PEG and PVA.
4. a kind of preparation method of the water plated material that can be roughened with water as claimed in claim 1, it is characterised in that： The resin is any one in PP, PE, PA and PPO.
5. a kind of preparation method of the water plated material that can be roughened with water as claimed in claim 1, it is characterised in that： Resin is 100 with the mass ratio of soluble oligomeric compound:3~10.
CN201611047548.7A 2016-11-25 2016-11-25 A kind of preparation method of the water plated material that can be roughened with water Pending CN106543564A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117195A (en) * 2019-12-30 2020-05-08 上海普利特复合材料股份有限公司 Low-internal-stress electroplating-grade PC/ABS alloy material and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1300877A (en) * 1999-12-21 2001-06-27 伊藤亮 Local electroplating method for substrate
CN101501245A (en) * 2006-08-04 2009-08-05 大赛璐高分子株式会社 Plated resin molded body
CN102296332A (en) * 2011-09-05 2011-12-28 厦门华戎能源科技有限公司 Method for directly plating conductive metal on surface of polyethylene
CN102409320A (en) * 2011-11-29 2012-04-11 沈阳工业大学 Electroplating pretreatment method for acrylonitrile butadiene styrene (ABS) plastic surface
CN102418090A (en) * 2011-11-07 2012-04-18 深圳市欣天科技有限公司 Method for surface metallization of resin-based composite material compressed by mold
CN103132024A (en) * 2013-03-12 2013-06-05 太仓协乐高分子材料有限公司 Surface metallization process for plastic products

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1300877A (en) * 1999-12-21 2001-06-27 伊藤亮 Local electroplating method for substrate
CN101501245A (en) * 2006-08-04 2009-08-05 大赛璐高分子株式会社 Plated resin molded body
CN102296332A (en) * 2011-09-05 2011-12-28 厦门华戎能源科技有限公司 Method for directly plating conductive metal on surface of polyethylene
CN102418090A (en) * 2011-11-07 2012-04-18 深圳市欣天科技有限公司 Method for surface metallization of resin-based composite material compressed by mold
CN102409320A (en) * 2011-11-29 2012-04-11 沈阳工业大学 Electroplating pretreatment method for acrylonitrile butadiene styrene (ABS) plastic surface
CN103132024A (en) * 2013-03-12 2013-06-05 太仓协乐高分子材料有限公司 Surface metallization process for plastic products

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117195A (en) * 2019-12-30 2020-05-08 上海普利特复合材料股份有限公司 Low-internal-stress electroplating-grade PC/ABS alloy material and preparation method thereof

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