CN106542575A - A kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material - Google Patents
A kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material Download PDFInfo
- Publication number
- CN106542575A CN106542575A CN201610929040.3A CN201610929040A CN106542575A CN 106542575 A CN106542575 A CN 106542575A CN 201610929040 A CN201610929040 A CN 201610929040A CN 106542575 A CN106542575 A CN 106542575A
- Authority
- CN
- China
- Prior art keywords
- nano
- titanium oxide
- powder material
- preparation
- nano titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/08—Drying; Calcining ; After treatment of titanium oxide
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
- C01G9/03—Processes of production using dry methods, e.g. vapour phase processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
Abstract
The invention belongs to technical field of nano material, and in particular to a kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material, which includes step：Step 1）：Zinc acetate and butyl titanate are dissolved in dehydrated alcohol, are stirred, mixed solution is obtained；Step 2）：By step 1）Water bath method is carried out in obtained mixed solution, is dried in being then put in baking oven, in placing into Muffle furnace, carry out high-temperature roasting, composite granule is obtained；Step 3）：By step 2）Obtained composite granule and stearic acid, carboxymethyl cellulose, hexamethylene mixing and ball milling 1～3 hour.After nano zine oxide and nano titanium oxide are organically combined by the present invention, the UVA and UVB in solar ultraviolet can be effectively shielded.
Description
Technical field
The invention belongs to technical field of nano material, and in particular to a kind of nano titanium oxide/nano zinc oxide compound powder
The preparation method of body material.
Background technology
Solar radiation ultraviolet out can be divided into by its wavelength：Wavelength is the long wave ultraviolet of 320～400nm
UVA, the short wave ultraviolet UVC that wavelength is the ultraviolet B radiation UVB of 290～320nm and wavelength is 200～290nm.Research knot
Fruit shows：Although the UVA for accounting for solar ultraviolet 91% will not cause as UVB fierce reaction, penetration is strong, its 35～
50% can reach corium, make intradermal fibrous tissue injured, cause twinge, cutis laxa and tanned, be to cause skin photoage
With the one of the main reasons of skin carcinoma.UVC is due to being absorbed substantially in air outer layer.
Nano zine oxide and nano titanium oxide are two kinds of important and widely used inorganic UV sunscreen, but which is right
The screening ability of UVA and UVB is discrepant, and the effect that nano titanium oxide intercepts UVB is very good, but the shielding to UVA is imitated
It is really not good enough；Nano zine oxide is undesirable to the shield effectiveness of UVB, but which intercepts UVA effects and is better than nano titanium oxide.
In order to effectively intercept UVA and UVB, overall protected purpose is reached, needed for this comprehensive in sun care preparationss
Close the characteristic using nano zine oxide and nano titanium oxide.Therefore, how to design one kind and have nano titanium oxide and nanometer concurrently
The composite powder material of Zinc Oxide advantage is study hotspot.
The content of the invention
It is an object of the invention to provide a kind of preparation side of nano titanium oxide/nano zinc oxide composite powder material
Method.
In order to realize the purpose of the present invention, the technical solution used in the present invention is as follows：
A kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material, which includes that step is as follows：
Step 1）：Zinc acetate and butyl titanate are dissolved in dehydrated alcohol, are stirred, mixed solution is obtained；
Step 2）：By step 1）Water bath method is carried out in obtained mixed solution, is dried in being then put in baking oven, is placed into
High-temperature roasting is carried out in Muffle furnace, composite granule is obtained；
Step 3）：By step 2）Obtained composite granule is little with stearic acid, carboxymethyl cellulose, hexamethylene mixing and ball milling 1～3
When.
Preferably, step 1）In, the amount ratio of described zinc acetate and the material of butyl titanate is 1：（1～3）, described vinegar
The mass volume ratio 1g of sour zinc and dehydrated alcohol：10mL.
Preferably, step 2）In, the high-temperature roasting condition is：Under excess oxygen, 500 DEG C are warming up to 5 DEG C/min
Roasting 1～3 hour.
Preferably, step 3）In, described composite granule and stearic acid, carboxymethyl cellulose, the quality volume of cyclohexane
Than for 1g：（0.5～0.8）g：（0.05～0.1）g：（5～10）mL.
Compared with prior art, the Advantageous Effects of technical solution of the present invention are：
1st, nano zine oxide of the invention/nano titanium oxide composite powder material preparation method, nano titanium oxide and nanometer
The UVA and UVB in solar ultraviolet can be effectively shielded after the combination of Zinc Oxide.
2nd, nano zine oxide/nano titanium oxide composite powder material prepared by the present invention, its Jing stearic acid, carboxymethyl are fine
The ball-milling reaction of dimension element, changes the surface nature of composite powder material, nano zine oxide/nano titanium oxide composite granule material
Material is with preferably dispersive property.
3rd, raw material of the invention is easy to get, and low cost, reaction are easily controlled.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
1）Weigh 18.35g zinc acetates and 34.03g butyl titanates are dissolved in 183.5mL dehydrated alcohol, stir, mixing is obtained
Solution.
2）By mixed solution at 80 DEG C water bath method, be dried in being then put in baking oven, place in Muffle furnace,
Under excess oxygen, 500 DEG C of roastings 2 hours are warming up to 5 DEG C/min, composite granule is obtained.
3）5g composite granules and 3g stearic acid, 0.04g carboxymethyl celluloses, 40mL cyclohexanes mixing and ball milling 2 hours are weighed,
.
Embodiment 2
1）Weigh 18.35g zinc acetates and 34.03g butyl titanates are dissolved in 183.5mL dehydrated alcohol, stir, mixing is obtained
Solution.
2）By mixed solution at 65 DEG C water bath method, be dried in being then put in baking oven, place in Muffle furnace,
Under excess oxygen, 500 DEG C of roastings 1 hour are warming up to 5 DEG C/min, composite granule is obtained.
3）Weigh 5g composite granules little with 2.5g stearic acid, 0.25g carboxymethyl celluloses, 25mL cyclohexanes mixing and ball milling 1
When, you can.
Embodiment 3
1）Weigh 18.35g zinc acetates and 34.03g butyl titanates are dissolved in 183.5mL dehydrated alcohol, stir, mixing is obtained
Solution.
2）By mixed solution at 95 DEG C water bath method, be dried in being then put in baking oven, place in Muffle furnace,
Under excess oxygen, 500 DEG C of roastings 3 hours are warming up to 5 DEG C/min, composite granule is obtained.
3）5g composite granules and 4g stearic acid, 0.5g carboxymethyl celluloses, 50mL cyclohexanes mixing and ball milling 3 hours are weighed,
.
Embodiment 4
Nano titanium oxide obtained in step 1～3/nano zinc oxide composite powder material is carried out into mean diameter and light transmittance
Test.Wherein, T308 represents the transmitance at 308nm, and reflection is screening ability of the composite granule to UVB, and T308 values are got over
It is little, illustrate that shielding UVB abilities are better；T360 represents the transmitance at 360nm, and reflection is shielding of the composite granule to UVA
Ability, T360 values are less, illustrate that shielding UVA abilities are better.Test result shows, the mean diameter of composite granule in 100nm,
T308 values are that 0, T360 values are not more than 2.Nano titanium oxide obtained in the inventive method-average grain of zinc oxide composite powder material
Degree is little, strong to the absorbability of UVA and UVB.
Claims (4)
1. the preparation method of a kind of nano titanium oxide/nano zinc oxide composite powder material, it is characterised in that：Including step such as
Under：
Step 1）：Zinc acetate and butyl titanate are dissolved in dehydrated alcohol, are stirred, mixed solution is obtained；
Step 2）：By step 1）Water bath method is carried out in obtained mixed solution, is dried in being then put in baking oven, is placed into
High-temperature roasting is carried out in Muffle furnace, composite granule is obtained；
Step 3）：By step 2）Obtained composite granule is little with stearic acid, carboxymethyl cellulose, hexamethylene mixing and ball milling 1～3
When.
2. the preparation method of a kind of nano titanium oxide/nano zinc oxide composite powder material according to claim 1, its
It is characterised by：Step 1）In, the amount ratio of described zinc acetate and the material of butyl titanate is 1：（1～3）, described zinc acetate with
The mass volume ratio 1g of dehydrated alcohol：10mL.
3. the preparation method of a kind of nano titanium oxide/nano zinc oxide composite powder material according to claim 1, its
It is characterised by：Step 2）In, the high-temperature roasting condition is：Under excess oxygen, 500 DEG C of roastings 1 are warming up to 5 DEG C/min
～3 hours.
4. the preparation method of a kind of nano titanium oxide/nano zinc oxide composite powder material according to claim 1, its
It is characterised by：Step 3）In, described composite granule is 1g with the mass volume ratio of stearic acid, carboxymethyl cellulose, cyclohexane：
（0.5～0.8）g：（0.05～0.1）g：（5～10）mL.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610929040.3A CN106542575B (en) | 2016-10-31 | 2016-10-31 | A kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610929040.3A CN106542575B (en) | 2016-10-31 | 2016-10-31 | A kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106542575A true CN106542575A (en) | 2017-03-29 |
| CN106542575B CN106542575B (en) | 2018-01-16 |
Family
ID=58392645
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610929040.3A Active CN106542575B (en) | 2016-10-31 | 2016-10-31 | A kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106542575B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110184596A (en) * | 2019-06-20 | 2019-08-30 | 佛山市众之助新材料科技有限公司 | A method of black phosphating film is covered in metal surface |
| CN116082893A (en) * | 2022-12-29 | 2023-05-09 | 广东涂百年新型材料有限公司 | Antibacterial dry powder coating and construction method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1785817A (en) * | 2005-12-21 | 2006-06-14 | 四川大学 | Preparation of shielding ultra violest ray nano-ZnO/TiO2 composite powder |
| CN101224418A (en) * | 2008-02-15 | 2008-07-23 | 哈尔滨工业大学 | Preparing method of core-shell TiO2/ZnO photocatalyst and applications thereof |
| CN102274129A (en) * | 2011-08-08 | 2011-12-14 | 陈家轲 | Nano-sized core-shell composite material used for cosmetics and preparation method thereof |
| CN102618109A (en) * | 2012-02-27 | 2012-08-01 | 浙江吉利汽车研究院有限公司 | Preparation method and application of ZnO/TiO2 composite powder |
| CN103566921A (en) * | 2012-07-24 | 2014-02-12 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of zinc oxide/titanium dioxide composite material with network structure |
| CN103977756A (en) * | 2014-05-28 | 2014-08-13 | 东北林业大学 | High-crystallinity nano-zinc oxide-titanium dioxide adsorbing agent and preparation method thereof |
-
2016
- 2016-10-31 CN CN201610929040.3A patent/CN106542575B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1785817A (en) * | 2005-12-21 | 2006-06-14 | 四川大学 | Preparation of shielding ultra violest ray nano-ZnO/TiO2 composite powder |
| CN101224418A (en) * | 2008-02-15 | 2008-07-23 | 哈尔滨工业大学 | Preparing method of core-shell TiO2/ZnO photocatalyst and applications thereof |
| CN102274129A (en) * | 2011-08-08 | 2011-12-14 | 陈家轲 | Nano-sized core-shell composite material used for cosmetics and preparation method thereof |
| CN102618109A (en) * | 2012-02-27 | 2012-08-01 | 浙江吉利汽车研究院有限公司 | Preparation method and application of ZnO/TiO2 composite powder |
| CN103566921A (en) * | 2012-07-24 | 2014-02-12 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of zinc oxide/titanium dioxide composite material with network structure |
| CN103977756A (en) * | 2014-05-28 | 2014-08-13 | 东北林业大学 | High-crystallinity nano-zinc oxide-titanium dioxide adsorbing agent and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 唐文韬等: "纳米ZnO/TiO2 复合广谱紫外屏蔽粉体的制备", 《日用化学品科学》 * |
| 李哲等: "屏蔽紫外线纳米ZnO/TiO2复合粉体的制备与性能研究", 《化工新型材料》 * |
| 林元华等: "纳米级ZnO一TiO2复合粉体的制备及其性能表征", 《功能材料》 * |
| 王国宏等: "纳米TiO2/ZnO的表面改性及表征", 《功能材料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110184596A (en) * | 2019-06-20 | 2019-08-30 | 佛山市众之助新材料科技有限公司 | A method of black phosphating film is covered in metal surface |
| CN116082893A (en) * | 2022-12-29 | 2023-05-09 | 广东涂百年新型材料有限公司 | Antibacterial dry powder coating and construction method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106542575B (en) | 2018-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ren et al. | Ce and Er Co-doped TiO2 for rapid bacteria-killing using visible light | |
| CN106491377B (en) | A kind of preparation method of composite nano-powder material | |
| CN106361584B (en) | A kind of nano-titanium dioxide-zinc oxide composite powder material | |
| CN106542575B (en) | A kind of preparation method of nano titanium oxide/nano zinc oxide composite powder material | |
| Adhikari et al. | Synthesis of Er3+ loaded barium molybdate nanoparticles: A new approach for harvesting solar energy | |
| Xie et al. | A novel Ag2O-TiO2-Bi2WO6/polyvinyl alcohol composite film with ethylene photocatalytic degradation performance towards banana preservation | |
| CN101787147B (en) | Method for preparing ultra-high rare earth composite oxide ultraviolet screening agent | |
| CN108420751A (en) | A kind of preparation method of the nano lignin particle with uvioresistant effect | |
| CN105111483A (en) | Sun-proof heat-insulating automobile film and preparation method therefor | |
| CN106236598B (en) | A kind of preparation method of uvioresistant skincare material additive | |
| CN110101860A (en) | Nano metal sulfide flower of bismuth doping and preparation method thereof | |
| CN103130261A (en) | Preparation method of transparent rare earth composite oxide ultraviolet screener | |
| CN106511106B (en) | A kind of nano-titanium dioxide/nano zinc oxide composite powder material | |
| CN113476320B (en) | Sun-proof cosmetic composition and preparation method thereof | |
| CN111067811A (en) | Calcined kaolin loaded with nano TiO2Composite uvioresistant agent and its prepn process | |
| CN110773145A (en) | Ce-doped TiO based on modified diatomite 2Preparation method and application of floating type photocatalytic composite material | |
| CN107189600A (en) | A kind of outdoor heat insulation and heat control coating used for textiles and preparation method thereof | |
| CN102274129B (en) | Nano-sized core-shell composite material used for cosmetics and preparation method thereof | |
| CN109023922A (en) | The preparation method of graphene composite material | |
| CN104288019A (en) | Moisturizing aloe gel and preparation method thereof | |
| CN104017431A (en) | Preparation method of nano CeO2 aqueous printing ink used for ultraviolet resistance | |
| CN107083679A (en) | A kind of preparation method of photocatalysis smelly eliminating automatically cleaning window curtain fabric | |
| CN110240191A (en) | A kind of preparation method of nearly colour of skin carbonitride/nano zine oxide ultraviolet light screener | |
| CN106352379A (en) | Microwave leakage preventive microwave oven | |
| KR20130083422A (en) | Synthetic method of near infrared radiation shielding metal oxide mixture |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210114 Address after: 215400 No. 20, Jian Xiong Road, science and Education Town, Taicang, Suzhou, Jiangsu Patentee after: SUZHOU YUANLUE INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: Suzhou Yuxi New Material Technology Co., Ltd., building 1, No. 6, Beijing West Road, Taicang Economic Development Zone, Suzhou City, Jiangsu Province 215400 Patentee before: SUZHOU YUXI NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right |