CN106541711A - A kind of parallel synthesizer and synthetic method of air-sensitive film transferred based on microdroplet premix - Google Patents
A kind of parallel synthesizer and synthetic method of air-sensitive film transferred based on microdroplet premix Download PDFInfo
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- CN106541711A CN106541711A CN201610899309.8A CN201610899309A CN106541711A CN 106541711 A CN106541711 A CN 106541711A CN 201610899309 A CN201610899309 A CN 201610899309A CN 106541711 A CN106541711 A CN 106541711A
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- microdroplet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J3/00—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
- B41J3/407—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
- B05C9/02—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material to surfaces by single means not covered by groups B05C1/00 - B05C7/00, whether or not also using other means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J29/00—Details of, or accessories for, typewriters or selective printing mechanisms not otherwise provided for
- B41J29/38—Drives, motors, controls or automatic cut-off devices for the entire printing mechanism
- B41J29/393—Devices for controlling or analysing the entire machine ; Controlling or analysing mechanical parameters involving printing of test patterns
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Abstract
The invention belongs to air-sensitive film synthesis technical field, more specifically, it is related to the parallel synthesizer and synthetic method of a kind of air-sensitive film transferred based on microdroplet premix, the parallel synthesizer of the air-sensitive film includes spacing object stage, control module, three-dimensional slide unit, microdroplet pre-mix module and microdroplet transfer module, microdroplet pre-mix module combines to realize that air-sensitive raw material is premixed using array peristaltic pump and array microdroplet syringe needle, microdroplet transfer module adopts airtight automatic fine injector, the substrate of framing photographic head and prefabricated orientation film coordinates to realize the precise positioning setting of quantitative microdroplet and air-sensitive film in transfer process jointly.The invention also discloses the preparation method of air-sensitive film.The present invention can realize the quantitative and even mixing of different materials difference component gas sensitive, various air-sensitive films are rapidly prepared precisely, while the blockage problem during print procedure can be avoided, and it is not more than the quantitative microdroplet premix transfer of the nL levels of 1 μm of nanometer air-sensitive raw material suspension suitable for size.
Description
Technical field
The invention belongs to air-sensitive film synthesis technical field, more particularly, to a kind of gas transferred based on microdroplet premix
The parallel synthesizer of quick film and synthetic method, which precisely can rapidly prepare various air-sensitive films, while can avoid printing
During blockage problem.
Background technology
Air-sensitive film is screened based on " Combinatorial materials science " method in prior art, high-performance air-sensitive film can be greatly improved
The efficiency of optimization." Combinatorial materials science " includes two critical process：Parallel synthesis, iron-enriched yeast.Wherein, parallel synthesis refers to height
Speed, the material for synchronously synthesizing a large amount of different components；Iron-enriched yeast refers to while characterizing to the performance of lot of materials.
At present, the parallel synthesis technique of gas sensitive is based primarily upon inkjet technology to realize, in inkjet technology
The component of gas sensitive is controlled by controlling the amount that sprays of different component.But further investigations have shown that, inkjet printing skill
Art can cause the mixing of component uneven and layering occurs, cause the poor performance of air-sensitive film；And due to spraying in inkjet technology
Nozzle aperture footpath is generally less than 50 μm, and when spraying the suspension containing microparticle, solvent volatilization at shower nozzle can cause microparticle blocking spray
Head, which is only suitable for spraying neat liquid, thus its material synthesis method can only limit which using non-precipitating methods such as collosol and gels
Use of its nano material synthetic method in gas sensitive synthesizes parallel, significantly limit the parallel conjunction of high-performance air-sensitive film
Into.
As the parallel synthesis technique of existing gas sensitive has a drawbacks described above and deficiency, this area need badly make into
The improvement of one step and perfect, the preparation method of a kind of parallel synthesizer of new air-sensitive film of design and air-sensitive film so as to Neng Goushi
The quantitative and even mixing of existing different materials difference component gas sensitive, is precisely rapidly formed air-sensitive film, while can avoid beating
Blockage problem during print, and it is not more than the quantitative microdroplet of nL levels of 1 μm of nanometer air-sensitive raw material suspension suitable for size
Transfer.
The content of the invention
For the disadvantages described above or Improvement requirement of prior art, transferred the invention provides a kind of based on microdroplet premix
Parallel synthesizer of air-sensitive film and preparation method thereof, according to the parallel synthesizer of air-sensitive film transferred based on microdroplet premix
Film forming mechanism and feature, make further research to the architectural feature and synthesis technique of parallel synthesizer and design, with battle array
Row peristaltic pump, array microdroplet syringe needle and airtight automatic fine injector combine, and the mode for carrying out quantitative microdroplet premix comes accurate
The constituent species and content of control gas sensitive, the mode of quantitative microdroplet premix are equal to realize quantitative different component gas sensitives
Even mixing, is realized the quantitative microdroplet transfer of different component gas sensitive premixed liquids, is utilized using airtight automatic fine injector
Framing photographic head and prefabricated orientation film realizing precise positioning and the setting of air-sensitive film, the device can rapid, high volume prepare not
With component air-sensitive film, and component mixing is uneven in solving the problems, such as the parallel synthetic method of existing inkjet printing, while can keep away
Exempt from the blockage problem in print procedure.
For achieving the above object, according to one aspect of the present invention, there is provided a kind of gas transferred based on microdroplet premix
The parallel synthesizer of quick film, it is characterised in that it include spacing object stage, the control module for being arranged on spacing object stage side,
The three-dimensional slide unit arranged against control module and the microdroplet pre-mix module being connected with three-dimensional slide unit and microdroplet transfer module；
The control module includes the communication interface and on and off switch for being oppositely arranged on control module both sides, and is arranged on
The status indicator lamp on control module top；
The microdroplet pre-mix module includes array raw material cavity, array peristaltic pump, wriggling pump hose and array microdroplet syringe needle；Institute
Stating microdroplet transfer module includes airtight automatic fine injector；
The three-dimensional slide unit includes the guide rail along 3 directions of rectangular coordinate system x, y, z, and the guide rail in wherein x and y directions sets
Put on spacing object stage and in I-shaped, the vertical beam in the middle of I-shaped is y directions, the intersection of the guide rail in x and y directions
The guide rail in two z directions is provided with, the side of above-mentioned y traversing guides is placed with array peristaltic pump, the array peristaltic pump correspondence sets
Array raw material cavity is equipped with, a wriggling flexible pipe on each peristaltic pump of the array peristaltic pump, is provided with, above-mentioned wriggling flexible pipe
Two ends are connected with corresponding raw material cavity and microdroplet syringe needle respectively, to transferring raw material；The three-dimensional slide unit also includes being respectively provided with
X, y, z direction three motors and be arranged on the guide rail slide block of y traversing guide opposite sides, it is solid on the guide rail slide block
Surely there are framing photographic head, array microdroplet syringe needle and airtight automatic fine injector, the spacing object stage of the guide rail homonymy
On be set side by side with the substrate of dismountable array premix chamber and prefabricated orientation film, above-mentioned array peristaltic pump and array microdroplet syringe needle
Combine and then can be extracted by the airtight automatic fine injector by raw material quantitative microdroplet in the specified location of array premix chamber
The suspension of specified arrays premix intracavity is transferred to the specified location of the substrate of prefabricated orientation film.
It is further preferred that the substrate of the prefabricated orientation film is referred to form a series of by being screen printed onto substrate surface
Different shape positions the substrate of mesh.Precise positioning is capable of achieving using the substrate of the type, is easy to accurate film forming.
Preferably, the drip hole pore diameter range of the array microdroplet syringe needle is 100-1000 μm.Using peristaltic pump and microdroplet pin
Head combines and comes quantitative micro- " drop ", so as to realize the quantitative microdroplet in gas sensitive pre-compounding process.Entered using airtight automatic fine
Sample device is realizing auto injection and microdroplet to air-sensitive membrane material suspension.And the drip hole pore size control of array microdroplet syringe needle exists
In 100-1000 μ ms, it is possible to resolve the blockage problem occurred in the parallel synthetic method of existing inkjet printing, realize that size is little
In the quantitative microdroplet of nL levels of the nanometer air-sensitive raw material suspension of 1 μm of granule.
Preferably, the airtight automatic fine injector includes lashing step-by-step controller, airtight microsyringe.
Preferably, signal condition control circuit, wriggling pump controller, motor are additionally provided with inside the control module
Controller and transfer controller, the signal condition control circuit input are connected with PC by communication interface, and the signal is adjusted
Reason control circuit output end is connected with wriggling pump controller, controllor for step-by-step motor and transfer controller；The array peristaltic pump,
Motor and airtight automatic fine injector are connected with control module；Described image positioning shooting head is also connected with PC, by
This realizes the signal transmission of whole device and optimal control.
Specifically, the prefabricated orientation film on substrate realizes air-sensitive film positioning and setting, with three-dimensional slide unit precise control microdroplet
Transfer block motion realizes positioning microdroplet transfer；The precise control of air-sensitive film thickness is realized by the transfer of quantitative microdroplet.The gas
The substrate of close microsyringe, framing photographic head and prefabricated orientation film is coordinated to realize that the precise positioning of air-sensitive film is fixed jointly
Shape.
The running of the parallel synthesizer of air-sensitive film transferred based on microdroplet premix is mainly：PC ends control software fortune
Row sends signal, and signal condition control circuit receives the signal and drive control device makes controller complete command adapted thereto, three-dimensional sliding
Motor, array peristaltic pump and airtight automatic fine injector on platform presses command adapted thereto operation.Microdroplet premix transfer operation
Process is：Synthesize the component requirements of film on demand, variety classes air-sensitive raw material is first by array peristaltic pump in array raw material cavity
Inflow wriggling pump hose is precisely controlled, and then injection array premix chamber is flowed out from array microdroplet syringe needle and is specified in cavity, then will
Array premix chamber low frequency ultrasound makes gas sensitive mix homogeneously, then again by airtight automatic fine injector from array premix chamber
Specified cavity in extract gas sensitive suspension, finally under the auxiliary of framing photographic head, microdroplet is transferred to prefabricated positioning
The specified location of the substrate of film.
It is another aspect of this invention to provide that there is provided a kind of air-sensitive film side of synthesis parallel transferred based on microdroplet premix
Method, it is characterised in that the method is comprised the following steps：
The parallel synthesizer of (a) using the above-mentioned air-sensitive film transferred based on microdroplet premix, by the parallel synthesizer
Communication interface be connected with PC；
B the substrate of prefabricated orientation film and array premix chamber are first separately fixed at correspondence position on object stage by ()；
The material component of (c) according to setting, by the air-sensitive raw material injection array raw material cavity of variety classes different content
In specified feedstock bottle；
D () sets up rectangular coordinate system by xyz directions of the guide rail of three-dimensional slide unit, obtain array using framing photographic head
Premix chamber origin is identified, and carries out origin correction, then according to different air-sensitive raw material microdroplets is injected into by the component of setting
In the cavity of corresponding array premix chamber；
E () treats pre-compounding process after the completion of, supersound process 5min after the cavity taking-up of the array premix chamber that will be equipped with mixed liquor,
Thus difference component air-sensitive membrane material suspension is obtained；
F () obtains the origin mark of prefabricated positioning film substrate using framing photographic head, and be corrected, described airtight
Automatic fine injector takes out the air-sensitive membrane material suspension for specifying metering from the specified cavity of array premix chamber, then transfers
To the specified location of the substrate of prefabricated orientation film, microdroplet transfer process is completed；
G () treats microdroplet transfer process after the completion of, the substrate of prefabricated orientation film is stood into 30min, is then removed, is put into Muffle
In stove with 3 DEG C it is per minute be warmed up to 300 DEG C～700 DEG C after be incubated 2h, rear furnace cooling obtains air-sensitive film.
In general, possess following excellent compared with prior art, mainly by the contemplated above technical scheme of the present invention
Point and beneficial effect：
(1) the parallel synthesizer of the application and method adopt " drop " replacement " spray ", i.e., using peristaltic pump and microdroplet syringe needle
It is and airtight microsyringe combines and comes quantitative micro- " drop ", quantitative micro- in gas sensitive premix transfer process so as to realize
Drop.Micro- " drop " drip hole aperture is in 100-1000 μ ms, it is possible to resolve the blocking occurred in the parallel synthetic method of existing inkjet printing
Problem, it is possible to achieve size is not more than the quantitative microdroplet of nL levels of the nanometer air-sensitive raw material suspension of 1 μm of granule.
(2) the parallel synthesizer and method of the application adopts peristaltic pump, microdroplet syringe needle and airtight automatic fine injector
The mode of quantitative microdroplet of combining comes the constituent species and content of precise control air-sensitive raw material, and the mode premixed with microdroplet carrys out reality
Now quantitative different component air-sensitive raw material uniformly mixes, it is possible to resolve in the parallel synthetic method of existing inkjet printing, component mixes not
Uniform problem.Using airtight automatic fine injector microdroplet transfer, airtight automatic fine injector, framing photographic head and
Prefabricated orientation film combines and can realize precise positioning and the setting of air-sensitive film.
(3) quantitative and even of different component gas sensitive is mixed by the parallel synthesizer and method of the application；To containing chi
The quantitative microdroplet transfer of nL levels of the very little nanometer air-sensitive raw material suspension for being not more than 1 μm, its tool being capable of precise positioning and setting gas
Quick film；Rapid, high volume prepares different component air-sensitive film, and the parallel synthesizer simple structure, and high precision, air-sensitive film are closed parallel
Into efficiency high, have a wide range of applications in materialogy is combined into.
Description of the drawings
Fig. 1 is the structural representation of the parallel synthesizer of the air-sensitive film transferred based on microdroplet premix.
Fig. 2 is the block diagram of the parallel synthesizer operation principle of the air-sensitive film transferred based on microdroplet premix.
In all of the figs, identical reference be used for represent identical element or structure, wherein：
1 guide rail, 2 motors, 3 framing photographic head, 4 wriggling pump hoses, 5 array microdroplet syringe needles, 6 arrays premix
Chamber, 7 spacing object stages, the substrate of 8 prefabricated orientation film, 9 airtight automatic fine injectors, 10 guide rail slide blocks, 11 array peristaltic pumps,
12 communication interfaces, 13 control modules, 14 status indicator lamps, 15 on and off switch, 16 three-dimensional slide units, 17 array raw material cavities.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, it is below in conjunction with drawings and Examples, right
The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only to explain the present invention, and
It is not used in the restriction present invention.As long as additionally, technical characteristic involved in invention described below each embodiment
Do not constitute conflict each other can just be mutually combined.
Fig. 1 is the structural representation of the parallel synthesizer of the air-sensitive film transferred based on microdroplet premix.As shown in figure 1,
Which includes spacing object stage 7, the control module 13 for being arranged on 7 side of spacing object stage, the three-dimensional arranged against control module 13
Slide unit 16 and the microdroplet pre-mix module being connected with three-dimensional slide unit and microdroplet transfer module；
The control module 13 includes the communication interface 12 and on and off switch 15 for being oppositely arranged on 13 both sides of control module, with
And it is arranged on the status indicator lamp 14 on 13 top of control module；
Microdroplet pre-mix module includes array raw material cavity 17, array peristaltic pump 11, wriggling pump hose 4 and array microdroplet syringe needle 5；
The microdroplet transfer module is airtight automatic fine injector 9；
The three-dimensional slide unit includes the guide rail 1 along 3 directions of rectangular coordinate system x, y, z, the wherein guide rail 1 in x and y directions
It is arranged on spacing object stage 7 and in I-shaped, the vertical beam of I-shaped is y directions, the intersection of the guide rail 1 in x and y directions
The guide rail 1 in two z directions is provided with, the side of above-mentioned y traversing guides is placed with array peristaltic pump 11, the array peristaltic pump 11 pairs
Array raw material cavity 17 should be provided with, a wriggling flexible pipe 4 on each peristaltic pump of array peristaltic pump 11, is provided with, above-mentioned wriggling is soft
The two ends of pipe 4 are connected with corresponding raw material cavity and microdroplet syringe needle respectively, to transferring raw material；Three-dimensional slide unit 16 also includes setting respectively
Put x, y, z direction three motors and be arranged on the guide rail slide block 10 of y traversing guide opposite sides, on guide rail slide block 10
It is fixed with framing photographic head 3, array microdroplet syringe needle 5 and airtight automatic fine injector 9, the spacing object stage of guide rail homonymy
The substrate 8 of dismountable array premix chamber 6 and prefabricated orientation film is set side by side with 7, above-mentioned array peristaltic pump 11 is micro- with array
Drop syringe needle 5 combine can by raw material quantitative microdroplet array premix chamber 6 specified location, then by airtight automatic fine injector
Suspension in 9 extraction specified arrays premix chambers 6 is transferred to the specified location of the substrate 8 of prefabricated orientation film.
In one particular embodiment of the present invention, the substrate 8 of prefabricated orientation film is by being screen printed onto substrate surface
Form a series of substrate of positioning mesh of different shapes.
In another specific embodiment of the present invention, the drip hole pore diameter range of array microdroplet syringe needle 5 is 100-1000 μm.
In another specific embodiment of the present invention, airtight automatic fine injector 9 include lashing step-by-step controller,
Airtight microsyringe.
The present invention another specific embodiment in, be additionally provided with inside control module 13 signal condition control circuit,
Wriggling pump controller, controllor for step-by-step motor and transfer controller, signal condition control circuit input pass through communication interface 12
Connect with PC, signal condition control circuit output end is connected with wriggling pump controller, controllor for step-by-step motor and transfer controller；
Array peristaltic pump 11, motor 2 and airtight automatic fine injector 9 are connected with the control module 13；Framing is imaged
3 are also connected with PC.
Fig. 2 is the parallel synthesizer fundamental diagram of air-sensitive film transferred based on microdroplet premix.As shown in Fig. 2 air-sensitive
The control process of the parallel synthesizer of film is mainly：The control software operation of PC ends sends signal, and signal condition control circuit is received
Simultaneously drive control device makes controller complete command adapted thereto to the signal, and three-dimensional slide unit motor and peristaltic pump press command adapted thereto fortune
OK.Microdroplet premix transfers running：Synthesize the component requirements of film on demand, variety classes air-sensitive is former in array raw material cavity 17
Material is precisely controlled inflow wriggling pump hose 4 by array peristaltic pump 11 first, then flows out injection array from array microdroplet syringe needle 5
Premix chamber 6 is specified in cavity, and 6 low frequency ultrasound of array premix chamber is made gas sensitive mix homogeneously then, pipeline is then cleaned,
Control to flow into peristaltic pump flexible pipe 4 by array peristaltic pump 11 again, finally under the auxiliary of framing photographic head 3 microdroplet be transferred to it is pre-
The specified location of the substrate 8 of orientation film processed.
A kind of parallel synthetic method of air-sensitive film transferred based on microdroplet premix that the present invention is provided, it is characterised in that should
Method is comprised the following steps：
A the parallel synthesizer of () using the air-sensitive film transferred based on microdroplet premix described in claim 1, should
The communication interface 12 of parallel synthesizer is connected with PC；
B the substrate 8 and array premix chamber 6 of prefabricated orientation film are first separately fixed at correspondence position on object stage by ()；
The material component of (c) according to setting, by the air-sensitive raw material injection array raw material cavity 17 of variety classes different content
Specified feedstock bottle in；
D () sets up rectangular coordinate system by xyz directions of the guide rail of three-dimensional slide unit 16, obtained using framing photographic head 3
Array premix chamber origin is identified, and carries out origin correction, then according to different air-sensitive raw material microdroplets is noted by the component of setting
Enter in the cavity of corresponding array premix chamber 6；
E () treats pre-compounding process after the completion of, supersound process after the cavity taking-up of the array premix chamber 6 that will be equipped with mixed liquor
5min, is thus obtained difference component air-sensitive membrane material suspension；
F () obtains the origin mark of prefabricated positioning film substrate 8 using framing photographic head 3, and be corrected, the gas
Close automatic fine injector 9 takes out the air-sensitive membrane material suspension for specifying metering from the specified cavity of array premix chamber 6, then
The specified location of the substrate 8 of prefabricated orientation film is transferred to, microdroplet transfer process is completed；
G () treats microdroplet transfer process after the completion of, the substrate 8 of prefabricated orientation film is stood into 30min, is then removed, is put into horse
Not in stove with 3 DEG C it is per minute be warmed up to 300 DEG C～700 DEG C after be incubated 2h, rear furnace cooling obtains air-sensitive film.
Embodiment：
A kind of CuO and WO of the parallel synthesizer synthesis Pt modifications of air-sensitive film transferred based on microdroplet premix3Two vigour
The preparation method of quick membrane material, its idiographic flow are as follows：
A () turns on the power switch 15, in USB communication interfaces 12 insert USB data line, will be controlled by USB data line
Module is connected with PC, realizes PC ends with control module communication.
B organic positioning film substrate and array premix chamber are separately fixed at correspondence position on object stage by ().
C () molar concentration is respectively the H of 0.2mol/L, 0.5mol/L, 0.5mol/L2PtCl6·6H2O solution, CuO hang
Turbid liquid and WO3Suspension respectively takes 5mL and is injected separately in 1,2, No. 3 bottles of raw material cavity.
D () makes origin with premix chamber anchor point to overlap by software correction in PC ends running control software.Then by 0.2,
0.5th, 0.5 and 0.5%, 60%, 39.5% control software original slurry material concentration hurdle and air-sensitive film molar fraction hurdle are separately input to.So
" premix " button is clicked on afterwards, is started automatic microdroplet and is premixed program, will H2PtCl6·6H2O solution, CuO suspensions, WO3It is suspended
Microdroplet takes in 10.4 μ L, 0.5mL, 0.35mL injection premix chamber A2 bottles liquid respectively.
(e) in automatic microdroplet pre-compounding process, facilities for observation kinestate, it is ensured that the process is normally carried out.Treat pre- sneaking out
After the completion of journey, the premix chamber that will be equipped with mixed liquor takes out ultrasound 5min, and so far air-sensitive membrane material suspension premix is completed.
F () makes origin overlap with organic positioning film substrate anchor point again by software correction.Then click on " transfer " to press
Button, starts automatic microdroplet transfer printing procedure, i.e., 2 μ L gas sensitive mixed liquors is taken from premix chamber A2 bottles and is transferred to organic orientation film
Substrate specified location.
(g) in automatic microdroplet transfer process, facilities for observation kinestate, it is ensured that the process is normally carried out.Treat that microdroplet turns
After the completion of print process, static 30min, then substrate remove, in Muffle furnace with 3 DEG C it is per minute be warmed up to suitable temperatures insulation
2h, rear furnace cooling obtain the material membrane of different component, and so far whole preparation process is completed.
As it will be easily appreciated by one skilled in the art that the foregoing is only presently preferred embodiments of the present invention, not to
The present invention, all any modification, equivalent and improvement made within the spirit and principles in the present invention etc. are limited, all should be included
Within protection scope of the present invention.
Claims (6)
1. it is a kind of based on microdroplet premix transfer the parallel synthesizer of air-sensitive film, it is characterised in which includes spacing object stage
(7) control module (13) of spacing object stage (7) side, the three-dimensional slide unit (16) arranged against control module (13), are arranged on
And the microdroplet pre-mix module that is connected with three-dimensional slide unit and microdroplet transfer module；
The control module (13) includes the communication interface (12) and on and off switch for being oppositely arranged on the control module (13) both sides
(15), and it is arranged on the status indicator lamp (14) on the control module (13) top；
The microdroplet pre-mix module includes array raw material cavity (17), array peristaltic pump (11), wriggling pump hose (4) and array microdroplet
Syringe needle (5)；The microdroplet transfer module includes airtight automatic fine injector (9)；
The three-dimensional slide unit includes the guide rail (1) along 3 directions of rectangular coordinate system x, y, z, the wherein guide rail (1) in x and y directions
It is arranged on spacing object stage (7) and in I-shaped, the vertical beam in the middle of I-shaped is y directions, the guide rail (1) in x and y directions
Intersection be provided with the guide rail (1) in two z directions, the side of the y traversing guides is placed with array peristaltic pump (11), the battle array
Row peristaltic pump (11) is correspondingly arranged on array raw material cavity (17), is provided with one on each peristaltic pump of the array peristaltic pump (11)
Root wriggling flexible pipe (4), the two ends of above-mentioned wriggling flexible pipe (4) are connected with corresponding raw material cavity and microdroplet syringe needle respectively, to convey
Raw material；The three-dimensional slide unit (16) also includes being separately positioned on three motors in x, y, z direction and being arranged on y directions leading
The guide rail slide block (10) of rail opposite side, is fixed with framing photographic head (3), array microdroplet syringe needle on the guide rail slide block (10)
(5) and airtight automatic fine injector (9), dismountable battle array is set side by side with the spacing object stage (7) of the guide rail side
The substrate (8) of row premix chamber (6) and prefabricated orientation film, above-mentioned array peristaltic pump (11) is combined with array microdroplet syringe needle (5) can
By raw material quantitative microdroplet in the specified location of array premix chamber (6), then extracted by the airtight automatic fine injector (9) and referred to
Determine the specified location that the suspension in array premix chamber (6) is transferred to the substrate (8) of prefabricated orientation film.
2. the parallel synthesizer of air-sensitive film for being transferred based on microdroplet premix as claimed in claim 1, it is characterised in that described
The substrate (8) of prefabricated orientation film is a series of base that positioning mesh of different shapes are formed by being screen printed onto substrate surface
Piece.
3. the parallel synthesizer of air-sensitive film for being transferred based on microdroplet premix as claimed in claim 1 or 2, it is characterised in that
The drip hole pore diameter range of the array microdroplet syringe needle (5) is 100-1000 μm.
4. the parallel synthesizer of air-sensitive film for being transferred based on microdroplet premix as claimed in claim 3, it is characterised in that described
Airtight automatic fine injector (9) includes lashing step-by-step controller, airtight microsyringe.
5. the parallel synthesizer of air-sensitive film for being transferred based on microdroplet premix as claimed in claim 4, it is characterised in that described
Signal condition control circuit, wriggling pump controller, controllor for step-by-step motor and transfer control are additionally provided with inside control module (13)
Device processed, the signal condition control circuit input are connected with PC by communication interface (12), the signal condition control circuit
Outfan is connected with wriggling pump controller, controllor for step-by-step motor and transfer controller；The array peristaltic pump (11), stepping electricity
Machine (2) and airtight automatic fine injector (9) are connected with the control module (13)；Described image positioning shooting head (3) also with
PC is connected.
6. it is a kind of based on microdroplet premix transfer the parallel synthetic method of air-sensitive film, it is characterised in that the method includes following step
Suddenly：
The parallel synthesis dress of (a) using the air-sensitive film transferred based on microdroplet premix any one of claim 1 to 5
Put, the communication interface (12) of the parallel synthesizer is connected with PC；
B the substrate (8) and array premix chamber (6) of prefabricated orientation film are first separately fixed at correspondence position on object stage by ()；
The material component of (c) according to setting, by air-sensitive raw material injection array raw material cavity (17) of variety classes different content
In specified feedstock bottle；
D () sets up rectangular coordinate system as xyz directions with the guide rail of three-dimensional slide unit (16), obtained using framing photographic head (3)
Array premix chamber origin is identified, and carries out origin correction, then according to different air-sensitive raw material microdroplets is noted by the component of setting
Enter in the cavity of corresponding array premix chamber (6)；
E () treats pre-compounding process after the completion of, supersound process 5min after the cavity taking-up of the array premix chamber (6) that will be equipped with mixed liquor,
Thus difference component air-sensitive membrane material suspension is obtained；
F () obtains the origin mark of prefabricated positioning film substrate (8) using framing photographic head (3), and be corrected, the gas
Close automatic fine injector (9) takes out the air-sensitive membrane material suspension for specifying metering from the specified cavity of array premix chamber (6),
The specified location of the substrate (8) of prefabricated orientation film is then transferred to, microdroplet transfer process is completed；
G () treats microdroplet transfer process after the completion of, the substrate (8) of prefabricated orientation film is stood into 30min, is then removed, is put into Muffle
In stove with 3 DEG C it is per minute be warmed up to 300 DEG C～700 DEG C after be incubated 2h, rear furnace cooling obtains air-sensitive film.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106914379A (en) * | 2017-03-31 | 2017-07-04 | 三门县职业中等专业学校 | A kind of full-automatic polyurethane guide wheel drip irrigation implement |
| CN111957276A (en) * | 2020-07-14 | 2020-11-20 | 华中科技大学 | Gas sensitive material parallel automatic synthesis device based on solvothermal method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053296A (en) * | 1990-01-09 | 1991-07-24 | 中国科学院沈阳应用生态研究所 | Integrated micro-pipe flow injection instrument and manufacturing process thereof |
| CN1673730A (en) * | 2005-03-31 | 2005-09-28 | 浙江大学 | Polypyrrol gas sensitive sensor |
| CN101158661A (en) * | 2007-11-16 | 2008-04-09 | 华中科技大学 | Semi-conductor oxidate gas sensor preparation method |
| CN101183086A (en) * | 2007-12-12 | 2008-05-21 | 天津工业大学 | Preparation method of nanometer tin oxide fibre air-sensitive film |
| CN101644695A (en) * | 2009-04-23 | 2010-02-10 | 中国科学院声学研究所 | Bulk acoustic wave sensor with high stability |
| CN101775703A (en) * | 2010-01-22 | 2010-07-14 | 天津工业大学 | Aluminum oxide/tin oxide nano-fiber composite membrane and preparation method thereof |
-
2016
- 2016-10-12 CN CN201610899309.8A patent/CN106541711B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053296A (en) * | 1990-01-09 | 1991-07-24 | 中国科学院沈阳应用生态研究所 | Integrated micro-pipe flow injection instrument and manufacturing process thereof |
| CN1673730A (en) * | 2005-03-31 | 2005-09-28 | 浙江大学 | Polypyrrol gas sensitive sensor |
| CN101158661A (en) * | 2007-11-16 | 2008-04-09 | 华中科技大学 | Semi-conductor oxidate gas sensor preparation method |
| CN101183086A (en) * | 2007-12-12 | 2008-05-21 | 天津工业大学 | Preparation method of nanometer tin oxide fibre air-sensitive film |
| CN101644695A (en) * | 2009-04-23 | 2010-02-10 | 中国科学院声学研究所 | Bulk acoustic wave sensor with high stability |
| CN101775703A (en) * | 2010-01-22 | 2010-07-14 | 天津工业大学 | Aluminum oxide/tin oxide nano-fiber composite membrane and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106914379A (en) * | 2017-03-31 | 2017-07-04 | 三门县职业中等专业学校 | A kind of full-automatic polyurethane guide wheel drip irrigation implement |
| CN111957276A (en) * | 2020-07-14 | 2020-11-20 | 华中科技大学 | Gas sensitive material parallel automatic synthesis device based on solvothermal method |
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