CN106531394A - Electromagnetic coil, coil insulation skeleton and modified nylon material for preparing skeleton - Google Patents
Electromagnetic coil, coil insulation skeleton and modified nylon material for preparing skeleton Download PDFInfo
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- CN106531394A CN106531394A CN201611174858.5A CN201611174858A CN106531394A CN 106531394 A CN106531394 A CN 106531394A CN 201611174858 A CN201611174858 A CN 201611174858A CN 106531394 A CN106531394 A CN 106531394A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F5/00—Coils
- H01F5/02—Coils wound on non-magnetic supports, e.g. formers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- Engineering & Computer Science (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an electromagnetic coil, a coil insulation skeleton and a modified nylon material for preparing the skeleton. The coil insulation skeleton is ultrathin, the thickness of the wall is only 1mm and the coil insulation skeleton comprises an annular skeleton base plate; the inner annular surface and the outer annular surface of the skeleton base plate extend upwards along the axial directions respectively to form an inner annular surface barrier sheet and an outer annular surface barrier sheet; and an accommodating groove for placing the coil is formed among the outer annular surface barrier sheet, the skeleton base plate and the inner annular surface barrier sheet. Non-woven fabric is replaced with the coil insulation skeleton, so that assembly of the coil and the coil insulation skeleton is very simple and the assembly efficiency is effectively improved.
Description
Technical field
The present invention relates to a kind of solenoid, coil insulation framework and prepare the modified nylon materials of the skeleton.
Background technology
Existing solenoid, which is mainly made up of coil case and coil, and coil case one end is provided with concentric setting
Put and for placing the placing trough of coil, and in order to make to be insulated between coil and spacing shell, existing way is past
Toward the outside winding non-woven fabrics that can be selected in coil, its structure is as shown in Figure 9.Its assembling process is:First in the outer bread of coil 8
Non-woven fabrics 10 are wrapped, then the coil 8 for having coated is placed in placing trough 91, subsequently asphalt mixtures modified by epoxy resin is poured into toward in placing trough
Fat, you can realize the fixation between coil 8 and coil case 9.
Above-mentioned electromagnetic coil structure is simple, but its drawback for existing is, during assembling solenoid, needs
The winding non-woven fabrics 10 toward on coil 8 of one circle circle, so as to cause packaging efficiency low.
The content of the invention
The first object of the present invention be to provide it is a kind of quickly can realize assemble coil insulation framework, its can quickly with
Coil realizes assembling, improves packaging efficiency.
The present invention above-mentioned technical purpose technical scheme is that:A kind of coil insulation framework, bag
The base plate of support of annular is included, the base plate of support inner ring surface and outer ring surface extend axially upward to form inner ring surface stop respectively along which
Piece and outer ring surface barrier sheet, the outer ring surface barrier sheet, form for placing coil between base plate of support and inner ring surface barrier sheet
Storage tank.
By above-mentioned setting, this coil insulation framework is first put into coil in storage tank, now during use
Inner ring surface barrier sheet can play good position-limiting action with outer ring surface barrier sheet to coil, while also can play very to coil
Good clamping action.Additionally, after in the placing trough that coil insulation framework is placed on coil case, inner ring surface barrier sheet and
Outer ring surface barrier sheet can be good at coil with coil case to keeping apart, and be prevented effectively from coil case appearance powered existing
As.
Preferably, the inner ring surface barrier sheet and outer ring surface barrier sheet are the arc-like sheet being arranged concentrically with base plate of support.
By above-mentioned setting, after coil is placed in storage tank, the outer ring surface of inner ring surface barrier sheet can be with coil
Inner ring surface fit together well, the inner ring surface of outer ring surface barrier sheet can be good at the outer ring surface of coil and be fitted in one
Rise, effectively increase the contact area between inside and outside anchor ring barrier sheet and coil, and after increasing contact area, inner and outer rings
There is between face and coil larger frictional force, avoid coil to depart from storage tank to a certain extent.
Preferably, the inner ring surface barrier sheet has multiple and is distributed along base plate of support inner ring surface uniform circular.
By above-mentioned setting, multiple inner ring surface barrier sheets can be good at playing position-limiting action to coil, prevent coil edge
Its radial direction is moved;The presence of inner ring surface barrier sheet simultaneously also can play iris action between coil and coil case,
Prevent coil case powered;Additionally, inner ring surface barrier sheet is divided into multi-disc, which is relative to an annular barrier sheet, Neng Gouyou
The material-saving of effect, reduces production cost.
Preferably, the outer ring surface barrier sheet has multiple, and the radian of the outer ring surface barrier sheet is more than inner ring surface barrier sheet
Radian.
By above-mentioned setting, multiple outer ring surface barrier sheets can be good at playing position-limiting action to coil, prevent coil edge
Its radial direction is moved;The presence of inner ring surface barrier sheet simultaneously also can play iris action between coil and coil case,
Prevent coil case powered;Additionally, outer ring surface barrier sheet is divided into multi-disc, which is relative to an annular barrier sheet, Neng Gouyou
The material-saving of effect, reduces production cost;And the diameter of outer ring surface is the diameter for being greater than inner ring surface, therefore also just it is not required to
The radian of outer ring surface barrier sheet is arranged to into identical with the radian of inner ring surface barrier sheet, can further material-saving, reduce
Production cost.
Preferably, the inner ring surface barrier sheet and the interlaced setting of outer ring surface barrier sheet.
By above-mentioned setting, the projection of inner ring surface barrier sheet and outer ring surface barrier sheet on coil, almost can cover
Whole circular arc, therefore no matter coil is moved along which direction of horizontal direction, inside and outside barrier sheet can produce one to coil
Fixed barrier effect, realizes to the good position-limiting action of coil.
Preferably, the base plate of support is provided with through wires hole, through wires hole side wall be provided with by through wires hole be separated into into
The dividing plate of line through wires hole and outlet through wires hole, the base plate of support outer ring surface just to form banking stop to upwardly extending at dividing plate, institute
The width for stating banking stop is more than the width of dividing plate but is less than the width of through wires hole, and the outer ring surface barrier sheet, banking stop are uniform
Circle distribution is on the lateral wall of base plate of support.
By above-mentioned setting, inlet wire through wires hole and there is through wires hole and separated by dividing plate, can effectively by inlet wire
Through wires hole and the wire occurred between through wires hole separate, and prevent the phenomenon of short circuit;And when by banking stop along itself and fixation
The connecting line of base plate connection is turned over when turning 90 degrees, and a banking stop part is covered on inlet wire through wires hole, some covering
On outlet through wires hole, and two wires on coil from outer ring surface out, having respectively entered carries out through wires hole and outlet is worn
String holes, due to spreading out of for this both threads, therefore can form a sulculus on the outer ring surface of coil, and this just can be for limit
Bit slice puts in, and then enables banking stop to go to good position-limiting action to spacing, prevents which from occurring rotating in storage tank
Phenomenon.And the mode of circle distribution, ensure that no matter coil is towards which direction motion, outer ring surface barrier sheet and banking stop
What the resistance of given coil was just as, prevent each uneven and caused part outer ring surface barrier sheet of place force and limit
There is breakage phenomenon in bit slice.
Preferably, first through hole, the base plate of support lower end is distributed with around its center of circle uniform circular on the base plate of support
Face is provided with the salient point that several are offseted with accommodating trench bottom on coil case.
By above-mentioned setting, after fixed base plate is put in the placing trough of coil case, the salient point on skeleton floor
Can offset with the bottom surface of placing trough, so that there is certain gap between base plate of support and placement groove bottom, and work as epoxy
After resin is poured in placing trough, epoxy resin can pass through through hole stream to base plate of support and place between groove bottom, can be very
The fixation of the fixed base plate of good realization,
Preferably, the salient point is corresponded with first through hole and salient point is distributed near the first through hole corresponding to which.
By above-mentioned resin, during processing, in order to material-saving as far as possible, often by coil insulation
Skeleton is made thin thin, and at this time, and after which carry coil and put in placing trough, coil can form crowded to base plate of support
Pressure, the phenomenon for making base plate of support deformation occur;And pass through through hole is arranged on beside first through hole such that it is able to effectively put
Put fixed base plate and deformation occur near first through hole, can effectively ensure that through hole one end and place and have one between trench bottom
Fixed gap, it is ensured that the fine fixation of coil insulation framework.
The second object of the present invention is to provide a kind of modified nylon materials for making above-mentioned coil insulation framework, is not affecting
While nylon material processing characteristics and mechanical property, reduce the usage amount of nano material, prevent the material melts time too early and
The problems such as blanking is difficult, blanking is uneven when the feed opening for causing is blocked, fed.
There is excellent wearability, self lubricity by adopting above-mentioned technical proposal, nylon66 fiber, mechanical strength is higher, resistance to
Oil, acid and alkali resistance and alkyl halide, hydro carbons, esters and ketones solvent, noiselessness, energy self-extinguishment, it is adaptable to make various machineries, vapour
Impeller, fan blade in the part of car, chemical industry and electrical installation, such as various gears, roller, bearing axle, the pump housing, high pressure sealing
The high intensity parts such as circle, valve seat, pad, bushing, various handles, housing, bracing frame, as the base material of modified nylon materials,
The characteristics of with high intensity, low coefficient of thermal expansion, low-shrinkage, low low water absorbable, and dimensionally stable;Nylon 6T full name are for poly- to benzene
Two formyl hexamethylene diamines, with excellent soldering resistance, excellent high temperature rigid, excellent dimensional stability, good melting stream
Dynamic property, excellent thin-wall moldability, high-moduluss, chemical-resistant are good, and water absorption rate is low, and thermal coefficient of expansion is stable, to temperature change
Dimensional stability it is good, by adding nylon 6T, can improve the material heat-resisting quantity, dimensional stability, meanwhile,
During ejection formation, it is difficult unedged;Glass fibre is a kind of Inorganic Non-metallic Materials of excellent performance, is had compared with organic fiber
There is heatproof high, do not fire, anti-corruption, heat-insulated, sound-proofing are good, tensile strength is high, the characteristics of electrical insulating property is good, can serve as in the material
Reinforcing material, electrically insulating material and heat-insulating material;The use environment that automotive plastic parts face most of the time is more severe
Carve, therefore, the anti-flammability of nylon material becomes a vital factor, adds fire retardant in modified nylon materials, can
To improve the anti-flammability of the material, so as to improve the performance of the material;TPU is between rubber and plastics as elastomer
A kind of material, TPU all have flexibility within the scope of very wide temperature, and which has good opposing energy to oils and many solvents
Power, also good resistance to weather, extremely excellent resistance to high-energy ray performance, wearability, tear resistance bend that to disturb intensity all very excellent
Good, tensile strength is high, and percentage elongation is big, in the component of modification of nylon adds TPU, can be lifted the material impact strength and
Oil resistivity;ZnOw is four needle-likes, and four acicular textures make it have superhigh intensity, and addition can make material exist in the material
The aspects such as mechanical property, dimensional homogeneity, thermal contraction, thermal deformation and other performances increase;The addition of compatilizer
The interface compatibility of nylon and TPU can be made, so as to greatly improve the toughness of blend;The addition of lubricant can make reduction group
The internal friction for dividing, reduces coefficient of friction, to improve the greasy property of material, so as to improve the pliability of material;Black agglomerate
Use can make the nylon material in dyeing course, make pigment that there is more preferable dispersibility, be conducive to keep pigment change
Stability is learned, the colour stable of material is made;The addition of antioxidant can delay the material to occur oxidizing process in blending and modifying,
So as to preventing the aging of polymer and extending its service life;By the blending and modifying of these components, obtained modification of nylon material
, with excellent mobility, temperature tolerance, oil resistivity, wearability, also with preferable mechanical property and processing characteristics, size is steady for material
It is qualitative good, the characteristics of with high intensity, high rigidity.
The third object of the present invention is to provide a kind of solenoid that can quickly realize and assembling.
The present invention above-mentioned technical purpose technical scheme is that:A kind of solenoid, including line
Circle shell, the placing trough being arranged on coil case and coil, also including above-mentioned coil insulation framework, the coil insulation framework
Intercept coil and coil case.
By above-mentioned setting, the coil is first put into coil in placing trough during assembling, and stop is changed in outside
Piece, inner ring surface barrier sheet and base plate of support can be realized to the good fixation of coil and insulating effect, subsequently will be loaded with coil
Coil insulation framework is placed in placing trough, then waters epoxy resin.Its installation process is simple and convenient, it is not necessary to a circle circle
Winding non-woven fabrics, effectively improve packaging efficiency.
In sum, the invention has the advantages that:
1. the installation rate of coil is effectively improved, working (machining) efficiency is improved;
2. can be good at realizing the fixation to coil;
3. the thickness of coil rack can be made thin thin, and such as 1mm is thick, save material well, reduce processing cost.
Description of the drawings
Fig. 1 is the structure chart of one coil insulation framework of embodiment;
Fig. 2 is the dorsal view of one coil insulation framework of embodiment;
Fig. 3 is the enlarged drawing of part A in Fig. 2, for embodying salient point;
Fig. 4 is the explosive view of embodiment one;
The local structural graph of Fig. 5 embodiments two, for embodying the second projection;
Fig. 6 is the structure chart of embodiment two, for embodying the first projection;
Fig. 7 is the structure chart of embodiment three, for embodying locating convex block;
Fig. 8 is the structure chart of example IV, for embodying cellular groove;
Fig. 9 is prior art construction figure.
In figure:1st, base plate of support;11st, first through hole;12nd, through wires hole;121st, inlet wire through wires hole;122nd, outlet through wires hole;
13rd, the second through hole;2nd, outer ring surface barrier sheet;3rd, inner ring surface barrier sheet;4th, banking stop;5th, dividing plate;6th, coil insulation framework;7th, it is convex
Point;8th, coil;9th, coil case;91st, placing trough;92nd, cellular groove;10th, non-woven fabrics;101st, the second projection;102nd, first
Projection;103rd, locating convex block.
Specific embodiment
The present invention is described in further detail below in conjunction with accompanying drawing.
Embodiment one:
A kind of solenoid, reference Fig. 4, including coil case 9, coil 8 and coil insulation framework 6, the upper surface of coil case 9
The placing trough 91 being engaged with coil insulation framework 6 is provided with, coil 8 is placed in placing trough 91 by coil insulation framework 6,
The wall thickness of coil insulation framework 6 is 1mm.
With reference to Fig. 1, coil insulation framework 6 includes the base plate of support 1 of ring-type, extends 4 on the inner ring surface of base plate of support 1
The inner ring surface barrier sheet 3 of individual arc, inner ring surface barrier sheet 3 is arranged concentrically with base plate of support 1 and these inner ring surface barrier sheets 3 are uniform
On base plate of support 1, the upper surface of inner ring surface barrier sheet 3 protrudes from the upper surface of base plate of support 1 to circle distribution.
Reference picture 1- Fig. 3, is provided through 3 first through hole 11 in the upper surface of base plate of support 1, this 3 first through hole
The 11 uniform circular distributions on base plate of support 1, are provided with through wires hole 12 wherein between two first through hole 11, and remaining first
Second through hole 13 is provided between through hole 11;It is provided with dividing plate 5 on the side wall of through wires hole 12, dividing plate 5 is by through wires hole 12
It is divided into separate inlet wire through wires hole 121 and outlet through wires hole 122.Shape is provided with the lower surface of base plate of support 1
For hemispheric salient point 7, the salient point 7 has 4 and is located near first through hole 11 respectively, it is ensured that one end end wall of first through hole 11
There is certain gap between 91 bottom of placing trough.
With reference to Fig. 1, upwardly extend to form 3 outer ring surface barrier sheets 2 and a banking stop on the outer ring surface of base plate of support 1
4, formed between outer ring surface barrier sheet 2, base plate of support 1 and inner ring surface barrier sheet 3 for placing the storage tank of coil 8, outer ring surface
Barrier sheet 2,4 uniform circular of banking stop is distributed on base plate of support 1 and outer ring surface barrier sheet 2, banking stop 4 and inner ring surface barrier sheet
3 interlaced distributions.The shape of outer ring surface barrier sheet 2 is also the arc and outer ring surface barrier sheet 2 being arranged concentrically with base plate of support 1
Radian be greater than the radian of inner ring surface barrier sheet 3;And banking stop 4 is, at dividing plate 5, banking stop 4 to be folded to skeleton
When 1 upper surface of base plate, dividing plate 5 can be covered by banking stop 4, meanwhile, which can also cover inlet wire through wires hole 121 and go out
A part for line through wires hole 122.
With reference to Fig. 1, and in order to enable outer ring surface barrier sheet 2 and inner ring surface barrier sheet 3 to play certain to coil 8
Clamping action, the present embodiment select for the angle between outer ring surface barrier sheet 2 and base plate of support 1 to be set to 87 degree, by inner ring surface
Angle between barrier sheet 3 and base plate of support 1 is also configured as 87 degree.
During assembling to solenoid, first coil 8 is placed in storage tank, now outer ring surface barrier sheet
2 inner ring surface, the outer ring surface of inner ring surface barrier sheet 3 are fitted in the outer ring surface and inner ring surface just with coil 8 such that it is able to line
Circle 8 plays a part of spacing well and clamping.Then the two ends of coil 8 are each passed through into inlet wire through wires hole 121 and outlet is worn
String holes 122, due to due to winding, the two ends of wire are all on the outer ring surface of coil 8, therefore by the wire at two ends
Through after two through wires holes, the parts of two wires can be formed on the outer ring surface of coil 8 two it is raised, two it is raised between formed
One sulculus, and banking stop 4 can be just snapped onto in this sulculus such that it is able to the circumference of coil 8 is risen by banking stop 4
To good restriction effect, prevent coil 8 from the phenomenon for rotating occur.
Subsequently, the coil insulation framework 6 for being loaded with coil 8 is put in placing trough 91, the presence of salient point 7 can make coil
There is certain gap between 6 bottom surface of insulation framework and the bottom surface of placing trough 91;Then epoxy resin is toppled over toward in placing trough 91,
Epoxy resin can play good filling effect to the space between 91 side wall of coil insulation framework 6 and placing trough, and due to having
The presence of first through hole 11 and the second through hole 13, epoxy resin also can pass through first through hole 11 and the second through hole 13 is flowed into fixation
In space between 91 bottom of base plate and placing trough, realize to 6 good fixation of coil insulation framework.
Embodiment two:
A kind of solenoid, with reference to Fig. 5 and Fig. 6, the present embodiment with the difference of embodiment one is, in outer ring surface barrier sheet 2
Several the first projections 102 offseted with 91 inwall of placing trough are provided with outer ring surface, on the inner ring surface of inner ring surface barrier sheet 3
Several the second projections 101 offseted with 91 inwall of placing trough are provided with, by the effect of the first projection 102 and the second projection 101,
So that there is gap between 91 side wall of inner ring surface barrier sheet 3 and outer ring surface barrier sheet 2 and placing trough, when epoxy resin is poured into
After in placing trough 91, epoxy resin can be flowed in above-mentioned gap such that it is able to play solid well to coil insulation framework 6
Determine effect.
Embodiment three:
A kind of solenoid, with reference to Fig. 7, the present embodiment is to be provided with the inwall of storage tank with the difference of embodiment two
Two locating convex blocks 103, the beeline between two locating convex blocks 103 are identical with the width of the first projection 102, coil is exhausted
After edge skeleton 6 is put in storage tank, the first projection 102 is located between two locating convex blocks 103, the first projection 102 and convex
The shape of block 103 is cylindric.So as to the positioning action of locating convex block 103, the position of insulated coil skeleton can be played
Positioning action, prevents its installation site from offseting well, and the structure of cylinder, it is also possible to play guiding to a certain extent
Effect.
Example IV:
A kind of solenoid, with reference to Fig. 8, the present embodiment is on the inwall of storage tank to be provided with honeybee with the difference of embodiment one
Nest shape groove 92, the upper surface of the 92 thorough coil shell 9 of cellular groove.When epoxy resin is added toward in placing trough 91
Wait, epoxy resin can be as the stream of cellular groove 92 be between coil insulation framework 6 and accommodating groove sidewall such that it is able to coil
Insulation framework 6 plays good fixation.
Additionally, with regard to the formula and technique of above-mentioned coil insulation framework 6:
A1:Raw material is chosen, the raw material is modified nylon materials, and its recipe ingredient is by weight:150~200 parts of nylon66 fiber,
10~15 parts of nylon 6T, 20~50 parts of glass fibre, 50~70 parts of fire retardant, 7~10 parts of TPU, 1~3 part of ZnOw,
2~8 parts of compatilizer, 2~8 parts of lubricant, 1~2 part of black agglomerate, 0.1~0.5 part of antioxidant.
A2:Modified nylon materials are blown by hot hair dryer, so that modified nylon materials are dried;
A3:Preheated to injection machine so as to which the temperature at screw feeding is 265 DEG C;
A4:Then modified nylon materials are imported in injection machine, modified nylon materials are melted into liquid at screw feeding
State;
A5:The modified nylon materials of melting are injected in injection mold carries out molding;
A6:Pressurize process is carried out to the coil insulation framework 6 of injection mo(u)lding, pressurize temperature is 110 DEG C;
A7:In its natural state the coil insulation framework 6 of injection mo(u)lding is radiated.
Nylon66 fiber is purchased from Yuyao City Jin Shuye high molecule plastics company limited, measures relative viscosity according to standard ISO307 and is
2.6;Nylon 6T is purchased from plastic cement firm of Yuyao City pros.
By melamine polyphosphate, solid acid, amido pyrrolotriazine derivatives it is melamine polyphosphate in mass ratio: Gu
Body acid: amido pyrrolotriazine derivatives=35: be made into fire retardant A at 8: 10, wherein solid acid are toluene sulfonic acide, p-methyl benzenesulfonic acid, right
Hydroxy benzenesulfonic acid is benzenesulfonic acid: p-methyl benzenesulfonic acid: p-hydroxybenzenyl sulfonate=1 in mass ratio: 1: 1 compounding is obtained;
It is melamine polyphosphate: solid acid in mass ratio by melamine polyphosphate, solid acid, amido pyrrolotriazine derivatives
: amido pyrrolotriazine derivatives=50: be made into fire retardant B at 9: 10, wherein solid acid are that dinitrobenzoic acid, periodic acid are in mass ratio
Dinitrobenzoic acid: periodic acid=1: 1 compounding is obtained;
It is melamine polyphosphate: solid acid in mass ratio by melamine polyphosphate, solid acid, amido pyrrolotriazine derivatives
: amido pyrrolotriazine derivatives=40: be made into fire retardant C at 10: 10, and wherein solid acid is trichloroacetic acid, ethylenediaminetetraacetic acid by quality
Than for trichloroacetic acid: ethylenediaminetetraacetic acid=1: 1 compounding is obtained.
By antioxidant 1010:Irgasfos 168 is antioxidant 1010: irgasfos 168=1 in mass ratio: 1 mixing, is answered
With antioxidant.
Using maleic anhydride stem grafting polyolefin as compatilizer A, maleic anhydride is grafted EVA as compatilizer B, and maleic anhydride connects
Used as Compatibilizer C, maleic anhydride is grafted POE as compatilizer D to branch HDPE.
By zinc stearate and stearate in mass ratio 1: 1 mixing be made into lubricant A, by politef, molybdenum bisuphide,
The mixing of silane resin acceptor kh-550 in mass ratio 1: 1: 1 is made into lubricant B, using ethylene bis stearamide as lubricant C, will be super
Branched unsaturated-resin is used as lubricant D.
Embodiment five
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:150 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) 10 parts of dried nylon 6T, 50 parts of fire retardant A, 7 parts of TPU, 1 part of ZnOw, 2 parts of compatilizer A, lubricant A
2 parts, 1 part of black agglomerate, 1,098 0.1 parts of antioxidant, mix homogeneously at room temperature;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 20 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
Embodiment six
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:170 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) 15 parts of dried nylon 6T, 55 parts of fire retardant C, 8 parts of TPU, 2 parts of ZnOw, 4 parts of compatilizer B, lubricant A
4 parts, 2 parts of black agglomerate, 0.2 part of compound antioxidant, mix homogeneously at room temperature;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 35 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
Embodiment seven
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:200 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) 15 parts of dried nylon 6T, fire retardant B70 parts, 10 parts of TPU, 3 parts of ZnOw, compatilizer D8 parts, lubricant C8
Part, 2 parts of black agglomerate, 1,098 0.5 parts of antioxidant, at room temperature mix homogeneously;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 50 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
Embodiment eight
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:180 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) dried nylon 6T14 parts, fire retardant B50 parts, 10 parts of TPU, 2 parts of ZnOw, 6 parts of Compatibilizer C, lubricant B
7 parts, 2 parts of black agglomerate, 0.3 part of antioxidant, mix homogeneously at room temperature;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 40 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
Embodiment nine
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:160 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) 11 parts of dried nylon 6T, 50 parts of fire retardant C, 6 parts of TPU, 3 parts of ZnOw, 2 parts of compatilizer A, compatilizer B
4 parts, 2 parts of lubricant A, 2 parts of lubricant C, 1.5 parts of black agglomerate, 0.2 part of antioxidant, mix homogeneously at room temperature;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 35 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
Embodiment ten
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:190 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) 13 parts of dried nylon 6T, 60 parts of fire retardant B, 8.5 parts of TPU, 1.5 parts of ZnOw, 3 parts of Compatibilizer C, phase
Hold 3 parts of agent D, 2 parts of lubricant A, 2 parts of lubricant C, 1.7 parts of black agglomerate, 0.4 part of antioxidant, at room temperature mix homogeneously;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 45 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
Embodiment 11
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:175 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) 12 parts of dried nylon 6T, 55 parts of fire retardant A, 8 parts of TPU, 2 parts of ZnOw, 1 part of compatilizer A, compatilizer B
2 parts, 2 parts of Compatibilizer C, 8 parts of lubricant B, 2 parts of black agglomerate, 0.25 part of antioxidant, mix homogeneously at room temperature;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 45 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
Embodiment 12
(1) nylon66 fiber and nylon 6T are dried under vacuum to into moisture content less than 0.10%;
(2) following raw material is added according to the mass fraction to high mixer:165 parts of the dried nylon66 fiber of Jing steps (1), Jing steps
(1) 15 parts of dried nylon 6T, 55 parts of fire retardant B, 9 parts of TPU, 1 part of ZnOw, 5 parts of compatilizer D, lubricant C
3 parts, 1 part of black agglomerate, 0.2 part of antioxidant, mix homogeneously at room temperature;
(3) raw material obtained in step (2) is passed through in double screw extruder from main feed mouth, by 40 parts of glass fibre from this pair of spiral shell
The side charging aperture of bar extruder is passed through in extruder, extruding pelletization.
8 groups of modified nylon materials are obtained by above-described embodiment, following performance test is carried out;
Extrusion success rate (%):Above-mentioned 8 group of formula carries out 20 extrusion tests per group of formula, finished surface occur as joint line,
The bad phenomenon such as flow liner, finished surface be coarse, as fails, by (the 20- frequency of failures)/20=success rates, formula counted
Calculate;
Density (g/cm3):Tested according to GB/T2577-2005 standards;
Water absorption rate (%):At 23 DEG C, under 50%RH, tested according to iso62 standards;
Tensile strength (Mpa):At 23 DEG C, tested according to GB/T1040.2-2006 standards;
Bending strength (Mpa):At 23 DEG C, tested according to GB/T9341-2008 standards;
Bending moduluses (Mpa):At 23 DEG C, tested according to GBT9341-2008 standards;
Elongation at break (%):At 23 DEG C, tested according to GB/T100.2-2008 standards;
Heat distortion temperature (DEG C):Tested according to GB/T1634.2-2008 standards;
Izod notched impact strength (KJ/m2):At -30 DEG C, 23 DEG C, at 50 DEG C, surveyed according to GB/T1843-2008 standards
Examination;
UL flame retardant ratings:Tested according to UL94 standards.
Test result is as follows:
According to upper table data, select embodiment five as optimum embodiment, be compared with following comparative example.
Comparative example one
Comparative example one is embodiment nine without modified nylon materials obtained in ZnOw.
Comparative example two
Comparative example one is embodiment nine without modified nylon materials obtained in glass fibre.
Comparative example three
Comparative example three is embodiment nine without modified nylon materials obtained in melamine polyphosphate.
Comparative example four
Comparative example four is embodiment nine without modified nylon materials obtained in amido pyrrolotriazine derivatives.
Comparative example five
Comparative example five is embodiment nine without modified nylon materials obtained in lubricant.
Comparative example six
Comparative example six is embodiment nine without modified nylon materials obtained in compatilizer.
Comparative example seven
Comparative example seven is embodiment nine without modified nylon materials obtained in TPU.
Above-mentioned comparative example is obtained into 7 groups of modified nylon materials, above-mentioned performance test is carried out;
Test result is as follows:
From above-mentioned comparative example and embodiment, the mobility of modified nylon materials obtained in technique is prepared with the formula
Good, injection success rate is high, is less prone to injection bad phenomenon, and obtained modified nylon materials have high intensity, high tenacity, compared with
Good durothermic feature, and its good flame retardation effect.
This specific embodiment is only explanation of the invention, and which is not limitation of the present invention, people in the art
Member can make the modification for not having creative contribution after this specification is read as needed to the present embodiment, but as long as at this
All protected by Patent Law in the right of invention.
Claims (10)
1. a kind of coil insulation framework, is characterized in that:Including annular base plate of support (1), base plate of support (1) inner ring surface and
Outer ring surface extends axially upward to form inner ring surface barrier sheet (3) and outer ring surface barrier sheet (2) respectively along which, and the outer ring surface stops
Formed for placing coil between piece (2), base plate of support (1) and inner ring surface barrier sheet (3)(8)Storage tank.
2. coil insulation framework according to claim 1, is characterized in that:The inner ring surface barrier sheet (3) and outer ring surface resistance
Catch (2) is the arc-like sheet being arranged concentrically with base plate of support (1).
3. coil insulation framework according to claim 2, is characterized in that:The inner ring surface barrier sheet (3) has multiple and edge
The distribution of base plate of support (1) inner ring surface uniform circular.
4. coil insulation framework according to claim 3, is characterized in that:The outer ring surface barrier sheet (2) has multiple, described
Radian of the radian of outer ring surface barrier sheet (2) more than inner ring surface barrier sheet (3).
5. coil insulation framework according to claim 4, is characterized in that:The inner ring surface barrier sheet (3) is hindered with outer ring surface
The interlaced setting of catch (2).
6. coil insulation framework according to claim 5, is characterized in that:The base plate of support (1) is provided with through wires hole
(12), through wires hole (12) side wall is provided with and for through wires hole (12) to be separated into inlet wire through wires hole (121) and outlet through wires hole
(122) dividing plate (5), base plate of support (1) outer ring surface just upwardly extend to form banking stop (4), the limit to dividing plate (5) place
The width of bit slice (4) is more than the width of dividing plate (5) but is less than the width of through wires hole (12), the outer ring surface barrier sheet (2), limit
Bit slice (4) uniform circular is distributed on the lateral wall of base plate of support (1).
7. coil insulation framework according to claim 1, is characterized in that:It is uniform around its center of circle on the base plate of support (1)
Circle distribution has first through hole (11), and base plate of support (1) lower surface is provided with several with storage tank bottom on coil case (9)
The salient point (7) that portion offsets.
8. coil insulation framework according to claim 7, is characterized in that:The salient point (7) is with first through hole (11) one by one
Corresponding and salient point (7) is near first through hole (11) distribution corresponding to which.
9. a kind of modified nylon materials for making coil insulation framework as claimed in claim 1, it is characterised in that the modified Buddhist nun
The recipe ingredient of imperial material is by weight:150 ~ 200 parts of nylon66 fiber, 10 ~ 15 parts of nylon 6T, 20 ~ 50 parts of glass fibre, resistance
Combustion 50 ~ 70 parts of agent, 7 ~ 10 parts of TPU, 1 ~ 3 part of ZnOw, 2 ~ 8 parts of compatilizer, 2 ~ 8 parts of lubricant, 1 ~ 2 part of black agglomerate,
0.1 ~ 0.5 part of antioxidant.
10. a kind of solenoid, including coil case (9), the placing trough (91) being arranged on coil case (9) and coil(8),
It is characterized in that:Also include the coil insulation framework (6) as described in claim 1-8 is arbitrary, coil insulation framework (6) resistance
Every coil and coil case (9).
Priority Applications (1)
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CN201611174858.5A CN106531394B (en) | 2016-12-17 | 2016-12-17 | Electromagnetic coil, coil insulation framework and the modified nylon materials for preparing the skeleton |
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CN201611174858.5A CN106531394B (en) | 2016-12-17 | 2016-12-17 | Electromagnetic coil, coil insulation framework and the modified nylon materials for preparing the skeleton |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110783053A (en) * | 2019-11-15 | 2020-02-11 | 广州供电局有限公司 | Section joint type nylon framework spiral coil fixing structure |
CN115394513A (en) * | 2022-07-21 | 2022-11-25 | 哈尔滨工业大学 | Coaxial symmetrical strong pulse four-coil-set supporting device and coaxial symmetrical strong pulse four-coil set |
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JPH0337425A (en) * | 1989-06-30 | 1991-02-18 | Ogura Clutch Co Ltd | Exciting device of electromagnetic connecting device |
JPH0341224A (en) * | 1989-07-06 | 1991-02-21 | Ogura Clutch Co Ltd | Electromagnetic coupling device |
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CN110783053A (en) * | 2019-11-15 | 2020-02-11 | 广州供电局有限公司 | Section joint type nylon framework spiral coil fixing structure |
CN115394513A (en) * | 2022-07-21 | 2022-11-25 | 哈尔滨工业大学 | Coaxial symmetrical strong pulse four-coil-set supporting device and coaxial symmetrical strong pulse four-coil set |
CN115394513B (en) * | 2022-07-21 | 2023-04-18 | 哈尔滨工业大学 | Coaxial symmetrical strong pulse four-coil-set supporting device and coaxial symmetrical strong pulse four-coil set |
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