CN106521954A - Collagen and cashmere composite fabric with anti-bacterial and radiation-proof functions and preparation method of fabric - Google Patents
Collagen and cashmere composite fabric with anti-bacterial and radiation-proof functions and preparation method of fabric Download PDFInfo
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- CN106521954A CN106521954A CN201611144291.7A CN201611144291A CN106521954A CN 106521954 A CN106521954 A CN 106521954A CN 201611144291 A CN201611144291 A CN 201611144291A CN 106521954 A CN106521954 A CN 106521954A
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- 210000000085 cashmere Anatomy 0.000 title claims abstract description 47
- 102000008186 Collagen Human genes 0.000 title claims abstract description 36
- 108010035532 Collagen Proteins 0.000 title claims abstract description 36
- 229920001436 collagen Polymers 0.000 title claims abstract description 30
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 239000004744 fabric Substances 0.000 title claims abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 title abstract 4
- 230000003471 anti-radiation Effects 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title description 5
- 239000000835 fiber Substances 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000000919 ceramic Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 7
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 7
- 229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 7
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 7
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 102000014171 Milk Proteins Human genes 0.000 claims abstract description 5
- 108010011756 Milk Proteins Proteins 0.000 claims abstract description 5
- 235000021239 milk protein Nutrition 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- GGRHYQCXXYLUTL-UHFFFAOYSA-N chloromethyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OCCl GGRHYQCXXYLUTL-UHFFFAOYSA-N 0.000 claims abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 230000003115 biocidal effect Effects 0.000 claims description 10
- 230000005855 radiation Effects 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 3
- NEHMKBQYUWJMIP-UHFFFAOYSA-N anhydrous methyl chloride Natural products ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000003837 high-temperature calcination Methods 0.000 claims description 3
- 235000013336 milk Nutrition 0.000 claims description 3
- 239000008267 milk Substances 0.000 claims description 3
- 210000004080 milk Anatomy 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- -1 pivalic acid chloromethane Ester Chemical class 0.000 claims description 3
- 238000009987 spinning Methods 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 2
- XUBKPYAWPSXPDZ-UHFFFAOYSA-N [Ba].OS(O)(=O)=O Chemical compound [Ba].OS(O)(=O)=O XUBKPYAWPSXPDZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 abstract description 4
- 238000004043 dyeing Methods 0.000 abstract description 4
- QVRCRKLLQYOIKY-UHFFFAOYSA-M 1-methyl-3-prop-2-enylimidazol-1-ium;chloride Chemical compound [Cl-].C[N+]=1C=CN(CC=C)C=1 QVRCRKLLQYOIKY-UHFFFAOYSA-M 0.000 abstract 1
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 241001122767 Theaceae Species 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 208000012886 Vertigo Diseases 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003519 biomedical and dental material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- ZYDSTVMBNBPPLQ-UHFFFAOYSA-N chloromethyl pentanoate Chemical group CCCCC(=O)OCCl ZYDSTVMBNBPPLQ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses collagen and cashmere composite fabric with anti-bacterial and radiation-proof functions. The collagen and cashmere composite fabric with anti-bacterial and radiation-proof functions is prepared from raw materials in parts by weight as follows: 43-46 parts of cashmere fibers, 18-20 parts of far infrared ceramic fibers, 14-17 parts of milk protein fibers, 8.6-9.3 parts of pure collagen powder, 2.6-3.3 parts of ethylene glycol diglycidyl ether, 1-2 parts of white oil, 5-7 parts of tea leaf residues, 0.2-0.4 parts of anhydrous sodium pyrophosphate, 2.4-2.7 parts of nano barium sulfate, 1.4-1.7 parts of chloromethyl pivalate, 1.2-1.5 parts of a silane coupling agent KH560, 192-197 parts of 1-allyl-3-methylimidazolium chloride and a proper amount of water. Oxygen low-temperature plasma is adopted for pretreatment, modified collagen is grafted on surfaces of cashmere composite fibers with ethylene glycol diglycidyl ether as a crosslinking agent, and the prepared cashmere composite fabric has better anti-bacterial and radiation-proof functions and dyeing performance.
Description
Technical field
The present invention relates to textile material technical field, more particularly to a kind of collagen sheep with antibiotic radiation proof function
Suede composite material and preparation method thereof.
Background technology
Cashmere fiber is a kind of natural precious textile material, and in recent years, cashmere apparel product is competing in fierce garment market
In striving with its comfortable feel, color and luster is unique, quality is frivolous, heat-insulation breathable is good the features such as be increasingly subject to consumers.But
As ecological environment opposite applies flexibly the friendly requirement of light green color, health, comfortable, environmental protection, the safe consumption master for having become people
Topic.Therefore, using environmental pollution is little or free of contamination process technology, exploitation with skin-friendly and the features such as emollient, can
The high-grade cashmere fabric for lifting its added value of product is the direction for being worth research.
Collagen has low antigenicity, superior biocompatibility and biological degradability, in biomedical material, medicine
Many fields such as delivery vehicles, organizational project, cosmetics, food have critically important status.Especially in recent years, with collagen egg
White bioaffinity is at the aspect such as textile material is modified, compound gradually into focus.Collagen can be given necessary to skin layer
Nutrient, makes the collagen activity reinforcement in skin, keeps the integrality of cuticula moisture and fibre structure, improve skin thin
The physiology circulation of born of the same parents' living environment and enhancing skin histology.Once collagen is securable to cashmere fiber, then may produce
The various health care functions such as skin care, anti-aging and whitening,《Using plasma-crosslinking agent complex technique in cashmere fiber
Collagen is fixed on surface》One literary grace pre-processes cashmere fiber with oxygen low temperature plasma, using ethylene glycol diglycidyl
Collagen is grafted onto cashmere surface as crosslinking agent by ether, as a result shows absorb-discharge humid and the dyeing of collagen modification cashmere fiber
Property is superior to untreatment fiber.In addition, the fixation of collagen has certain changing to the ultimate strength and extension at break of fiber
Kind effect.
The absorb-discharge humid and dyeability of cashmere are only improved in text, but cashmere yield is few expensive, pure cashmere is such as
Fruit stores the improper even raw mite that goes mouldy that can make moist because of the humidity of environment, due to the intensity of cashmere itself it is poor, it is washed how easy
Crushing, conglomeration, balling-up, the especially cold north are dried, and cashmere product is also also easy to produce electrostatic etc..So that develop having
Multifunctional novel collagen Cashmere composite shell fabric.
The content of the invention
The object of the invention is exactly for the defect for making up prior art, there is provided a kind of collagen with antibiotic radiation proof function
Albumen Cashmere composite shell fabric and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of collagen Cashmere composite shell fabric with antibiotic radiation proof function, is prepared by the raw materials in：Cashmere
Fiber 43-46, far IR ceramic fiber 18-20, milk protein fiber 14-17, pure collagen protein powder 8.6-9.3, ethylene glycol two
Glycidol ether 2.6-3.3, white oil 1-2, tealeaf residue 5-7, anhydrous sodium pyrophosphate 0.2-0.4, nano barium sulfate 2.4-2.7, spy
It is valeric acid chloromethyl ester 1.4-1.7, silane coupler KH5601.2-1.5,1- pi-allyl -3- methylimidazole villaumites 192-197, appropriate
Water.
A kind of preparation method of described collagen Cashmere composite shell fabric with antibiotic radiation proof function, including it is following
Step：
（1）By nano barium sulfate in 460-480 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds silane idol
Connection agent KH560 stirring 10-15 minutes, it is vacuum dried to obtain modified nano-barium sulfate；
（2）Tealeaf residue is dried into ground 100 mesh sieve, the anhydrous sodium pyrophosphate solution stirring that mass concentration is 4-8% is sprayed mixed
Even, the magnetic agitation 2-3 hour in 60-80 DEG C of water bath with thermostatic control is washed to neutral vacuum drying, adds white oil, pivalic acid chloromethane
Ester ultrasonic grinding 1-3 hours, dry the tealeaf residue superfines that must be modified；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, far IR ceramic fiber, milk
Azelon grinds 20-40 minutes, is heated to 100-120 DEG C, adds step（2）Material stirring reacts 50-70 minutes, spinning,
Drying is put into reaction chamber, using oxygen low temperature plasma, processes 1 minute in electric discharge pressure 150Pa, power 120W, obtain etc. from
Daughter pre-processes cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control to be stirred continuously to whole dissolvings toward pure collagen protein powder, add
Step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two
10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air
It is dry, discharging.
It is an advantage of the invention that：Optimization of C/C composites of the present invention improves production technology, will be far IR ceramic fiber, milk protein fine
Peacekeeping cashmere fiber is combined, and cashmere composite fibre is obtained as binding agent Jing wet spinnings with modified tealeaf residue superfines, not only
Alleviate due to the problem that the cashmere fiber that environmental degradation brings is reduced year by year that to also overcome pure cashmere product balling-up, low intensity easily mould
Become the defects such as raw mite, finally obtained cashmere composite fibre is pre-processed using oxygen low temperature plasma, in fiber
The less environmentally safe of damage in portion, plasma can etch the scale on cashmere surface, make scale layer thinning, weaken surface
" barrier " effect of scale, so as to strengthen its humidity absorption and release, improves hydrophily of the cashmere during follow-up dyeing and finishing etc., then
Modified collagen is grafted onto into cashmere surface using ethylene glycol diglycidylether as crosslinking agent, because of collagen also
Belong to the good protein of performance of keeping humidity, after crosslinking, improve the skin-friendly and beauty and health care performance of fabric, obtained cashmere is multiple
Close fabric and there is more preferable antibiotic radiation proof performance and dyeability.
Specific embodiment
A kind of collagen Cashmere composite shell fabric with antibiotic radiation proof function, is prepared by the raw materials in：
Cashmere fiber 43, far IR ceramic fiber 18, milk protein fiber 14, pure collagen protein powder 8.6, ethylene glycol diglycidylether
2.6th, white oil 1, tealeaf residue 5, anhydrous sodium pyrophosphate 0.2, nano barium sulfate 2.4, chloromethyl pivalate 1.4, silane coupler
KH560 1.2,1- pi-allyl -3- methylimidazole villaumites 192, suitable quantity of water.
A kind of preparation method of described collagen Cashmere composite shell fabric with antibiotic radiation proof function, including it is following
Step：
（1）By nano barium sulfate in 460-480 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds silane idol
Connection agent KH560 stirring 10-15 minutes, it is vacuum dried to obtain modified nano-barium sulfate；
（2）Tealeaf residue is dried into ground 100 mesh sieve, the anhydrous sodium pyrophosphate solution stirring that mass concentration is 4-8% is sprayed mixed
Even, the magnetic agitation 2-3 hour in 60-80 DEG C of water bath with thermostatic control is washed to neutral vacuum drying, adds white oil, pivalic acid chloromethane
Ester ultrasonic grinding 1-3 hours, dry the tealeaf residue superfines that must be modified；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, far IR ceramic fiber, milk
Azelon grinds 20-40 minutes, is heated to 100-120 DEG C, adds step（2）Material stirring reacts 50-70 minutes, spinning,
Drying is put into reaction chamber, using oxygen low temperature plasma, processes 1 minute in electric discharge pressure 150Pa, power 120W, obtain etc. from
Daughter pre-processes cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control to be stirred continuously to whole dissolvings toward pure collagen protein powder, add
Step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two
10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air
It is dry, discharging.
The bacteriostasis rate of staphylococcus aureus can reach using collagen Cashmere composite shell fabric obtained in the present invention
96.759%；Average ultimate strength is 8.89cN；Dyeing dye uptake can reach 98%.
Claims (2)
1. a kind of collagen Cashmere composite shell fabric with antibiotic radiation proof function, it is characterised in that by following weight portion
Raw material is made：Cashmere fiber 43-46, far IR ceramic fiber 18-20, milk protein fiber 14-17, pure collagen protein powder 8.6-
9.3rd, ethylene glycol diglycidylether 2.6-3.3, white oil 1-2, tealeaf residue 5-7, anhydrous sodium pyrophosphate 0.2-0.4, nanometer sulfuric acid
Barium 2.4-2.7, chloromethyl pivalate 1.4-1.7, silane coupler KH560 1.2-1.5,1- pi-allyl -3- methylimidazole villaumites
192-197, suitable quantity of water.
2. the making side of a kind of collagen Cashmere composite shell fabric with antibiotic radiation proof function according to claim 1
Method, it is characterised in that comprise the following steps：
（1）By nano barium sulfate in 460-480 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds silane idol
Connection agent KH560 stirring 10-15 minutes, it is vacuum dried to obtain modified nano-barium sulfate；
（2）Tealeaf residue is dried into ground 100 mesh sieve, the anhydrous sodium pyrophosphate solution stirring that mass concentration is 4-8% is sprayed mixed
Even, the magnetic agitation 2-3 hour in 60-80 DEG C of water bath with thermostatic control is washed to neutral vacuum drying, adds white oil, pivalic acid chloromethane
Ester ultrasonic grinding 1-3 hours, dry the tealeaf residue superfines that must be modified；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, far IR ceramic fiber, milk
Azelon grinds 20-40 minutes, is heated to 100-120 DEG C, adds step（2）Material stirring reacts 50-70 minutes, spinning,
Drying is put into reaction chamber, using oxygen low temperature plasma, processes 1 minute in electric discharge pressure 150Pa, power 120W, obtain etc. from
Daughter pre-processes cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control to be stirred continuously to whole dissolvings toward pure collagen protein powder, add
Step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two
10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air
It is dry, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611144291.7A CN106521954A (en) | 2016-12-13 | 2016-12-13 | Collagen and cashmere composite fabric with anti-bacterial and radiation-proof functions and preparation method of fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611144291.7A CN106521954A (en) | 2016-12-13 | 2016-12-13 | Collagen and cashmere composite fabric with anti-bacterial and radiation-proof functions and preparation method of fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106521954A true CN106521954A (en) | 2017-03-22 |
Family
ID=58341979
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611144291.7A Pending CN106521954A (en) | 2016-12-13 | 2016-12-13 | Collagen and cashmere composite fabric with anti-bacterial and radiation-proof functions and preparation method of fabric |
Country Status (1)
| Country | Link |
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| CN (1) | CN106521954A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104726995A (en) * | 2014-12-26 | 2015-06-24 | 安徽省中日农业环保科技有限公司 | Woven fabric capable of shielding UV light and imitating knitted effect and manufacturing method thereof |
| CN104911737A (en) * | 2015-05-20 | 2015-09-16 | 铜陵宏正网络科技有限公司 | Nanometer antibacterial mothproof cashmere composite fiber and manufacturing method thereof |
| CN104911736A (en) * | 2015-05-20 | 2015-09-16 | 铜陵宏正网络科技有限公司 | Polylactic acid fiber-containing ultraviolet resistant cashmere composite fiber and manufacturing method thereof |
| CN105220287A (en) * | 2015-08-31 | 2016-01-06 | 安徽天威羊绒制品有限公司 | A kind ofly add strong cashmere fiber of milk protein fiber blending pro-skin durability and preparation method thereof |
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2016
- 2016-12-13 CN CN201611144291.7A patent/CN106521954A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104726995A (en) * | 2014-12-26 | 2015-06-24 | 安徽省中日农业环保科技有限公司 | Woven fabric capable of shielding UV light and imitating knitted effect and manufacturing method thereof |
| CN104911737A (en) * | 2015-05-20 | 2015-09-16 | 铜陵宏正网络科技有限公司 | Nanometer antibacterial mothproof cashmere composite fiber and manufacturing method thereof |
| CN104911736A (en) * | 2015-05-20 | 2015-09-16 | 铜陵宏正网络科技有限公司 | Polylactic acid fiber-containing ultraviolet resistant cashmere composite fiber and manufacturing method thereof |
| CN105220287A (en) * | 2015-08-31 | 2016-01-06 | 安徽天威羊绒制品有限公司 | A kind ofly add strong cashmere fiber of milk protein fiber blending pro-skin durability and preparation method thereof |
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Application publication date: 20170322 |