CN106520420A - Method for preparing glass cleaning agent through chicken fat - Google Patents
Method for preparing glass cleaning agent through chicken fat Download PDFInfo
- Publication number
- CN106520420A CN106520420A CN201610919078.2A CN201610919078A CN106520420A CN 106520420 A CN106520420 A CN 106520420A CN 201610919078 A CN201610919078 A CN 201610919078A CN 106520420 A CN106520420 A CN 106520420A
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- chicken fat
- glass
- mulberry leaf
- cleaning agent
- stirring
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a method for preparing a glass cleaning agent through chicken fat and belongs to the technical field of glass cleaning agents. Firstly, ampholytic surfactants are prepared, compounding and steaming are conducted through the chicken fat and folium mori, the folium mori is used for absorbing the chicken fat, the folium mori is then squeezed to obtain the chicken fat containing the active ingredients of the folium mori, the chicken fat and alkali are subjected to saponification, a saponated substance and sodium dodecyl benzene sulfonate are compounded, and finally the glass cleaning agent is obtained through grinding and mixing with other raw materials. The glass cleaning agent prepared by the invention does not contain phosphorus compounds and acid substances, the freezing point of liquid can be remarkably reduced as the ethanediol is added, the use effect of the cleaning agent is effectively improved at the low temperature, the glass structure is not corroded any more after the glass cleaning agent is used, a layer of lubricating film is generated on the surface of the glass after the glass is cleaned, the glass is protected, and the glass cleaning agent has broad application prospects.
Description
Technical field
The present invention relates to a kind of method that utilization chicken fat prepares glass cleaner, belongs to glass cleaner technical field.
Background technology
Glass is widely used in building and vapour because of its glossy clear with good light transmittance and decorative effect
On the door and windows such as car, but glass is easily dirty, after contamination dust or oil stain, not only affects sight line and attractive in appearance, it is also possible to
Serious accident is caused, therefore will be cleaned in time.Building and door/window glass of automobile are once mainly with 3 kinds of cleaning ways：Clear water,
Organic solvent or alkali lye and glass scavenger specially, the detergency of clear water are limited, and the use of solvent and alkali lye has security and asks
Cleaning topic, and because glass is solid solution that various colloids are organized the formation of, being easily corroded, such as many times of Jing, glass surface
Can become coarse, affect glass transparent degree, not only cleansing power is good and easy to use for glass scavenger specially, is on market
One of scavenger specially quite favored.As the development of society, cleaning agent industry development are enlivened increasingly, people are to glass cleaning
The requirement of agent also more and more higher, while basic cleansing power is required, in addition it is also necessary to cleaning agent effect is complete, environmental sound,
Save scavenging period, simplify cleaning etc., this development trend is caused by many factors, such as people are used for indoor clear
The time washed is fewer and feweri, and kinsfolk has respective occupation, and this kind of family seldom carries out loaded down with trivial details indoor cleaning work etc.,
These require the more complete glass cleaner of exploitation effect, can be in the basic cleaning energy for keeping and improving glass cleaner
On the basis of power, add functional component, give the anti-pollution again of glass surface, quick-drying, antifog, hydrophilic and not trace after washing
The performances such as mark.But, current glass cleaner species commercially is relatively more, some use phosphorus-containing compounds, some uses
Other structures are produced corrosion by weak acid, resist pollution capacity again not strong, at low temperature the decontamination energy of cleaning glass window after some cleanings
Power is relatively low, and effect is excessively poor, thus prepare it is a kind of not only pollution-free but will not etching glass surface novel environment friendly glass cleaner,
With wide Prospect of R ＆ D.
The content of the invention
The technical problem to be solved：It is more for glass cleaner species currently used in the market, mostly
It is phosphorus-containing compound, seriously corroded is produced to glass structure, and anti-secondary pollution is indifferent, cleaning glass window goes at low temperature
The relatively low defect of dirty ability, the method comprises the steps of firstly, preparing zwitterionic surfactant, then steamed with chicken fat and mulberry leaf compounding, allow mulberry leaf to inhale
Attached chicken fat, Jing squeezings obtain the chicken fat containing mulberry leaf active component, then will the chicken fat containing active component and alkali reaction, by reactant and
Neopelex is compounded, and is finally aided with other raw mill mixing and be can be prepared by glass cleaner, and the present invention is obtained
Glass cleaner does not contain phosphorus species and acidic materials, and the addition of ethylene glycol can significantly reduce the freezing point of liquid, effectively improve
The effect that cleaning agent is used at low temperature, will not produce any corrosion to glass structure after use, after cleaning can be in glass table
Face produces one layer of lubricating film, glass is played a protective role, is had broad application prospects.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is：
（1）7～9g monoxones are added in the there-necked flask with agitator, dropping funel and thermometer, flask is placed on into 4
Be stirred in～6 DEG C of water-bath, 40～50mL mass concentrations are added under stirring for the NaOH of 0.07g/mL
Solution, is added dropwise 15～20g dimethyl dodecylamines after continuing 10～15min of stirring, raises bath temperature and stirs to 70～80 DEG C
Mix 2～3h of reaction and obtain zwitterionic surfactant, it is standby；
（2）The cucumber strip for being cut into after fresh cucumber is peeled that length is 5～8cm is taken, and food steamer is placed on by what cucumber strip interlocked anyhow
In, then warp layer cloth is covered on cucumber strip, the one layer of mulberry leaf that tile on gauze are rebasing, and wherein mulberry leaf laying depth is 2～3cm,
Last to spread chicken fat on mulberry leaf again, laying amount is 3～5 times of mulberry leaf gross mass, after the boiling water in steamer is put food steamer
2～3h is steamed in entering steamer；
（3）Mulberry leaf are taken out after steaming end, the chicken fat of mulberry leaf of squeezing out in being put into refined filtration oil press absorption, by 100～120g chicken fat
Add reactor in, after being heated to 100～110 DEG C again in kettle add 18～30g NaOH, start agitator with
200～300r/min rotating speed 2～4h of stirring reaction；
（4）Room temperature is naturally cooled to after above-mentioned stirring reaction terminates, then adds 15～30g sodium chloride, normal temperature in reactor
It is separated by filtration after 15～20min of stirring and obtains filter residue, is 1 in mass ratio:Neopelex and filter residue are well mixed by 1
Obtain mixing cleaning additive；
（5）Count by weight, weigh 10～15 parts of standby zwitterionic surfactants, 30～35 parts of above-mentioned mixing cleaning additions
Agent, 10～15 parts of ethylene glycol, 1～3 part of lignosulfonate and 100～120 parts of deionized waters be sequentially loaded in colloid mill 50～
To discharge after 500～600r/min rotating speed 1～2h of ground and mixed at 60 DEG C, glass cleaner after tinning, is obtained final product.
The present invention application process be：By the glass cleaner and water that are prepared using chicken fat obtained by the present invention it is by volume
1：1～1：Obtain dilution after 3 mixing, then with spray gun by dilution even application in glass surface, after its natural air drying, use
Clean cotton is wiped.After testing, compared with using traditional glass cleaner, which is antifog, frost prevention duration extend 30～
50%, and glass surface is without vestige, corrosion-free, and under low-temperature condition, soil removal efficiency stills remain in more than 98%.
The invention has the beneficial effects as follows：
（1）The effects such as zwitterionic surfactant contained in the glass cleaner of the present invention has infiltration, permeates, and clean
One layer of bright film is formed in glass surface simultaneously, many excellent performances of glass surface is imparted, is prevented glass dirty again
Contaminate, make glass surface hydrophilicity more preferably, its application is more extensive compared with prior art；
（2）The method that the present invention prepares glass cleaner using chicken fat, its raw material is easy to get, with low cost, and various composition is nontoxic,
It is corrosion-free, and will not be affected by season and region, it is convenient using process safety, with good using effect.
Specific embodiment
7～9g monoxones are added in the there-necked flask with agitator, dropping funel and thermometer, flask is placed on
Be stirred in 4～6 DEG C of water-bath, 40～50mL mass concentrations are added under stirring for the NaOH of 0.07g/mL
Solution, is added dropwise 15～20g dimethyl dodecylamines after continuing 10～15min of stirring, raises bath temperature and stirs to 70～80 DEG C
Mix 2～3h of reaction and obtain zwitterionic surfactant, take the cucumber strip for being cut into after fresh cucumber is peeled that length is 5～8cm, by cucumber
What bar interlocked anyhow is placed in food steamer, then covers warp layer cloth on cucumber strip, and the one layer of mulberry leaf that tile on gauze are rebasing, wherein
Mulberry leaf laying depth is 2～3cm, finally spreads chicken fat on mulberry leaf again, and laying amount is 3～5 times of mulberry leaf gross mass, treats steamer
In boiling water after food steamer be put in steamer steam 2～3h；Mulberry leaf are taken out after steaming end, is squeezed out in being put into refined filtration oil press
The chicken fat of mulberry leaf absorption, 100～120g chicken fat is added in reactor, is added after being heated to 100～110 DEG C again in kettle
18～30g NaOH, starts agitator with 200～300r/min rotating speed 2～4h of stirring reaction；Treat that above-mentioned stirring reaction terminates
After naturally cool to room temperature, then add 15～30g sodium chloride in reactor, be separated by filtration after 15～20min of stirring at normal temperature
To filter residue, it is 1 in mass ratio:1 neopelex and filter residue are well mixed obtain mix cleaning additive；By weight
Number meter, weighs 10～15 parts of standby zwitterionic surfactants, 30～35 parts of above-mentioned mixing cleaning additives, 10～15 parts of second
Glycol, 1～3 part of lignosulfonate and 100～120 parts of deionized waters are sequentially loaded in colloid mill at 50～60 DEG C with 500～
Discharge after 600r/min rotating speed 1～2h of ground and mixed, after tinning, obtain final product glass cleaner.
Example 1
7g monoxones are added in the there-necked flask with agitator, dropping funel and thermometer, flask is placed on into 4 DEG C of water
Be stirred in bath, 40mL mass concentrations are added under stirring for the sodium hydroxide solution of 0.07g/mL, continuation stirring
15g dimethyl dodecylamines are added dropwise after 10min, are raised bath temperature and are obtained both sexes interfacial activity to 70 DEG C of stirring reactions 2h
Agent, takes the cucumber strip for being cut into after fresh cucumber is peeled that length is 5～8cm, is placed on what cucumber strip interlocked anyhow in food steamer, then
Warp layer cloth is covered on cucumber strip, and the one layer of mulberry leaf that tile on gauze are rebasing, and wherein mulberry leaf laying depth is 2cm, is finally existed again
Chicken fat is spread on mulberry leaf, and laying amount is 3 times of mulberry leaf gross mass, food steamer is put in steamer after the boiling water in steamer and is steamed
2h；Mulberry leaf are taken out after steaming end, 100g chicken fat is added reactor by the chicken fat of mulberry leaf of squeezing out in being put into refined filtration oil press absorption
In, 18g NaOH is added in kettle again after being heated to 100 DEG C, start agitator with 200r/min rotating speed stirring reactions
2h；Room temperature is naturally cooled to after above-mentioned stirring reaction terminates, then adds 15g sodium chloride, stirring at normal temperature 15min in reactor
After be separated by filtration and obtain filter residue, be 1 in mass ratio:1 neopelex and filter residue are well mixed obtain mixing cleaning
Additive；Count by weight, weigh 10 parts of standby zwitterionic surfactants, 30 parts of above-mentioned mixing cleaning additives, 10 parts
Ethylene glycol, 1 part of lignosulfonate and 100 parts of deionized waters are ground with 500r/min rotating speeds in being sequentially loaded into colloid mill at 50 DEG C
Discharge after 1～2h of mixing, after tinning, obtain final product glass cleaner.
It is 1 by volume by the glass cleaner prepared using chicken fat obtained by the present invention and water：Diluted after 1 mixing
Liquid, then with spray gun by dilution even application in glass surface, after its natural air drying, with clean cotton wipe.After testing,
Compared with using traditional glass cleaner, which is antifog, frost prevention duration extends 30%, and glass surface is without vestige, corrosion-free,
And dirt-removing power stills remain in 98.5% under low-temperature condition.
Example 2
9g monoxones are added in the there-necked flask with agitator, dropping funel and thermometer, flask is placed on into 6 DEG C of water
Be stirred in bath, 50mL mass concentrations are added under stirring for the sodium hydroxide solution of 0.07g/mL, continuation stirring
20g dimethyl dodecylamines are added dropwise after 15min, are raised bath temperature and are obtained both sexes interfacial activity to 80 DEG C of stirring reactions 3h
Agent, takes the cucumber strip for being cut into after fresh cucumber is peeled that length is 8cm, is placed on what cucumber strip interlocked anyhow in food steamer, then
Warp layer cloth is covered on cucumber strip, and the one layer of mulberry leaf that tile on gauze are rebasing, and wherein mulberry leaf laying depth is 3cm, finally again in mulberry
Chicken fat is spread on leaf, and laying amount is 5 times of mulberry leaf gross mass, food steamer is put in steamer after the boiling water in steamer and is steamed
3h；Mulberry leaf are taken out after steaming end, 120g chicken fat is added reactor by the chicken fat of mulberry leaf of squeezing out in being put into refined filtration oil press absorption
In, 30g NaOH is added in kettle again after being heated to 110 DEG C, start agitator with 300r/min rotating speed stirring reactions
4h；Room temperature is naturally cooled to after above-mentioned stirring reaction terminates, then adds 30g sodium chloride, stirring at normal temperature 20min in reactor
After be separated by filtration and obtain filter residue, be 1 in mass ratio:1 neopelex and filter residue are well mixed obtain mixing cleaning
Additive；Count by weight, weigh 15 parts of standby zwitterionic surfactants, 35 parts of above-mentioned mixing cleaning additives, 15 parts
Ethylene glycol, 3 parts of lignosulfonates and 120 parts of deionized waters are ground with 600r/min rotating speeds in being sequentially loaded into colloid mill at 60 DEG C
Discharge after mixing 2h, after tinning, obtain final product glass cleaner.
It is 1 by volume by the glass cleaner prepared using chicken fat obtained by the present invention and water：Diluted after 2 mixing
Liquid, then with spray gun by dilution even application in glass surface, after its natural air drying, with clean cotton wipe.After testing,
Compared with using traditional glass cleaner, which is antifog, frost prevention duration extends 40%, and glass surface is without vestige, corrosion-free,
And dirt-removing power stills remain in 99.0% under low-temperature condition.
Example 3
8g monoxones are added in the there-necked flask with agitator, dropping funel and thermometer, flask is placed on into 5 DEG C of water
Be stirred in bath, 45mL mass concentrations are added under stirring for the sodium hydroxide solution of 0.07g/mL, continuation stirring
18g dimethyl dodecylamines are added dropwise after 13min, are raised bath temperature and are obtained both sexes interfacial activity to 75 DEG C of stirring reactions 3h
Agent, takes the cucumber strip for being cut into after fresh cucumber is peeled that length is 6cm, is placed on what cucumber strip interlocked anyhow in food steamer, then
Warp layer cloth is covered on cucumber strip, and the one layer of mulberry leaf that tile on gauze are rebasing, and wherein mulberry leaf laying depth is 3cm, finally again in mulberry
Chicken fat is spread on leaf, and laying amount is 4 times of mulberry leaf gross mass, food steamer is put in steamer after the boiling water in steamer and is steamed
3h；Mulberry leaf are taken out after steaming end, 110g chicken fat is added reactor by the chicken fat of mulberry leaf of squeezing out in being put into refined filtration oil press absorption
In, 25g NaOH is added in kettle again after being heated to 105 DEG C, start agitator with 250r/min rotating speed stirring reactions
3h；Room temperature is naturally cooled to after above-mentioned stirring reaction terminates, then adds 23g sodium chloride, stirring at normal temperature 18min in reactor
After be separated by filtration and obtain filter residue, be 1 in mass ratio:1 neopelex and filter residue are well mixed obtain mixing cleaning
Additive；Count by weight, weigh 13 parts of standby zwitterionic surfactants, 32 parts of above-mentioned mixing cleaning additives, 13 parts
Ethylene glycol, 2 parts of lignosulfonates and 110 parts of deionized waters are ground with 550r/min rotating speeds in being sequentially loaded into colloid mill at 55 DEG C
Discharge after mixing 2h, after tinning, obtain final product glass cleaner.
It is 1 by volume by the glass cleaner prepared using chicken fat obtained by the present invention and water：Diluted after 3 mixing
Liquid, then with spray gun by dilution even application in glass surface, after its natural air drying, with clean cotton wipe.After testing,
Compared with using traditional glass cleaner, which is antifog, frost prevention duration extends 50%, and glass surface is without vestige, corrosion-free,
And dirt-removing power stills remain in 99.0% under low-temperature condition.
Claims (1)
1. a kind of method that utilization chicken fat prepares glass cleaner, it is characterised in that specifically preparation process is：
（1）7～9g monoxones are added in the there-necked flask with agitator, dropping funel and thermometer, flask is placed on into 4
Be stirred in～6 DEG C of water-bath, 40～50mL mass concentrations are added under stirring for the NaOH of 0.07g/mL
Solution, is added dropwise 15～20g dimethyl dodecylamines after continuing 10～15min of stirring, raises bath temperature and stirs to 70～80 DEG C
Mix 2～3h of reaction and obtain zwitterionic surfactant, it is standby；
（2）The cucumber strip for being cut into after fresh cucumber is peeled that length is 5～8cm is taken, and food steamer is placed on by what cucumber strip interlocked anyhow
In, then warp layer cloth is covered on cucumber strip, the one layer of mulberry leaf that tile on gauze are rebasing, and wherein mulberry leaf laying depth is 2～3cm,
Last to spread chicken fat on mulberry leaf again, laying amount is 3～5 times of mulberry leaf gross mass, after the boiling water in steamer is put food steamer
2～3h is steamed in entering steamer；
（3）Mulberry leaf are taken out after steaming end, the chicken fat of mulberry leaf of squeezing out in being put into refined filtration oil press absorption, by 100～120g chicken fat
Add reactor in, after being heated to 100～110 DEG C again in kettle add 18～30g NaOH, start agitator with
200～300r/min rotating speed 2～4h of stirring reaction；
（4）Room temperature is naturally cooled to after above-mentioned stirring reaction terminates, then adds 15～30g sodium chloride, normal temperature in reactor
It is separated by filtration after 15～20min of stirring and obtains filter residue, is 1 in mass ratio:Neopelex and filter residue are well mixed by 1
Obtain mixing cleaning additive；
（5）Count by weight, weigh 10～15 parts of standby zwitterionic surfactants, 30～35 parts of above-mentioned mixing cleaning additions
Agent, 10～15 parts of ethylene glycol, 1～3 part of lignosulfonate and 100～120 parts of deionized waters be sequentially loaded in colloid mill 50～
To discharge after 500～600r/min rotating speed 1～2h of ground and mixed at 60 DEG C, glass cleaner after tinning, is obtained final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610919078.2A CN106520420A (en) | 2016-10-21 | 2016-10-21 | Method for preparing glass cleaning agent through chicken fat |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610919078.2A CN106520420A (en) | 2016-10-21 | 2016-10-21 | Method for preparing glass cleaning agent through chicken fat |
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| Publication Number | Publication Date |
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| CN106520420A true CN106520420A (en) | 2017-03-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610919078.2A Pending CN106520420A (en) | 2016-10-21 | 2016-10-21 | Method for preparing glass cleaning agent through chicken fat |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865681A (en) * | 2012-12-17 | 2014-06-18 | 青岛海芬海洋生物科技有限公司 | Automobile glass cleaning agent |
| CN104263566A (en) * | 2014-09-12 | 2015-01-07 | 皖南医学院 | Multifunctional cleaning cream for stain removal and sterilization and preparation method thereof |
| CN104845778A (en) * | 2015-05-23 | 2015-08-19 | 青岛康泰鑫环保科技有限公司 | Lubricant automotive windscreen washer fluid |
| CN104877818A (en) * | 2015-04-30 | 2015-09-02 | 青岛海蓝海洋复合功能材料科技有限公司 | Improved glassware detergent |
-
2016
- 2016-10-21 CN CN201610919078.2A patent/CN106520420A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865681A (en) * | 2012-12-17 | 2014-06-18 | 青岛海芬海洋生物科技有限公司 | Automobile glass cleaning agent |
| CN104263566A (en) * | 2014-09-12 | 2015-01-07 | 皖南医学院 | Multifunctional cleaning cream for stain removal and sterilization and preparation method thereof |
| CN104877818A (en) * | 2015-04-30 | 2015-09-02 | 青岛海蓝海洋复合功能材料科技有限公司 | Improved glassware detergent |
| CN104845778A (en) * | 2015-05-23 | 2015-08-19 | 青岛康泰鑫环保科技有限公司 | Lubricant automotive windscreen washer fluid |
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Application publication date: 20170322 |
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