CN106520347A - Lubricant composition for spinning processing process for total-synthesis monel 400 alloy - Google Patents
Lubricant composition for spinning processing process for total-synthesis monel 400 alloy Download PDFInfo
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- CN106520347A CN106520347A CN201610966179.5A CN201610966179A CN106520347A CN 106520347 A CN106520347 A CN 106520347A CN 201610966179 A CN201610966179 A CN 201610966179A CN 106520347 A CN106520347 A CN 106520347A
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
- C10M2203/065—Well-defined aromatic compounds used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/08—Halogenated waxes
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
Abstract
The invention discloses a lubricant composition for a spinning processing process for a total-synthesis monel 400 alloy. According to the lubricant composition disclosed by the invention, alkyl naphthalene with a mass ratio being 50% and metallocene polyalpha-olefin a mass ratio being 50% are compounded as base oil which matched with various composite additives comprising an antioxidant, a metal deactivator, an oiliness agent, a friction improver, an extreme pressure agent, an anti-wear agent, an antirust agent, an anti-foaming agent, an oxygen and corrosion resisting agent, and the like. The composition disclosed by the invention has very good high-temperature lubrication, extreme-pressure wear-resistant carrying capacity, permeability, diffusivity, cleaning property and anti-rust property.
Description
Technical field
A kind of 400 alloy rotary pressing processing technology lubricant compositionss of complete synthesis Monel of the present invention belong to metal working lubricant
Agent field.
Background technology
Also known as nickel alloy, a kind of other elements such as copper, ferrum, manganese that added based on metallic nickel are formed monel metal
Alloy.Monel metal good corrosion resistance, is silvery white in color, and is suitable as side wire material.
The single phase solid solution for being organized as high intensity of 400 alloy of Monel, single phase austenite tissue, it be a kind of consumption most
Greatly, the purposes most splendid corrosion resistant alloy of wide, combination property.This alloy has excellent anti-corrosion in Fluohydric acid. and fluorine gas medium
Property, also there is excellent corrosion resistance to hot concentrated alkali liquid.The corruption of also resistance to neutral solution, water, sea water, air, organic compound etc. simultaneously
Erosion.One key character of the alloy is typically not produce stress corrosion cracking (SCC), and cutting ability is good.
Rotary pressure technology originates from ancient times pottery, is that one kind combines forging, extruding, draw piece, bending, looping mill rolling, transverse rolling
With few advanced technologies without machining of the process characteristic such as edging.Generally by metal letter base, plate blank or prefabricated blank tail
Hold out against on spinning machine mould, plug and blank rotation are driven by main shaft;Material is squeezed in by spinning wheel from blank side simultaneously
On the core of rotation, material is made to produce the continuous plastic deformation of pointwise, so as to obtain the hollow rotary body zero of various shape of generatrix
Part.According to the blank thickness situation of change during rotary pressing processing, spinning process is divided into two kinds of conventional spinning and shear spinning.
The referred to as general rotation of conventional spinning.During general rotation, the thickness of blank is held essentially constant, and shaping relies primarily on blank edge
The contraction of circumference and along radial direction it is indeformable realizing with length.Which is mainly characterized by forming process, substantially can be seen
Go out the change of blank external diameter.The basic mode of conventional spinning has:Draw spinning (drawing rotation), necking in spindown (contracting rotation) and expanding bulging
Three kinds of (expanding rotation) etc..The lubricant of 400 alloy conventional spinning of complete synthesis Monel requires to solve:Spinning part surface quality requirements
Height, spinning curved surface material thickness is uniform, curved surface links up, the skill with wear-resistant, anti scuffing, cut performance and reduction distortional stress
Art is difficult.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good high temperature lubricating, extreme-pressure anti-wear carrying energy
Power, permeability, diffusibility, cleaning, the 400 alloy rotary pressing processing technology lubricant compositionss of complete synthesis Monel of rust-preventing characteristic.
The present invention solves above-mentioned technical problem by following technical solution:
400 alloy rotary pressing processing technology lubricant compositionss of a kind of complete synthesis Monel, using the alkyl of mass ratio 50%
Naphthalene and 50% metallocene poly alpha olefin it is compound based on oil, coordinate various compound additives, its respective mass percent
Into being grouped into:
The mass percent summation of above each component is 100%.
Antioxidant is that the 4,4- di-2-ethylhexylphosphine oxides T511 of the cupric antioxidant T543 and 50% of mass ratio 50% is combined;
Metal deactivator is that the thiadiazole of the thiadiazoles derivative T561 and 50% of mass ratio 50% is combined.
Oiliness improver is sulfuration cottonseed oil T405;Friction improver is ethyl palmitate.
Extreme pressure agent is D2EHDTPA amine salt T307;Antiwear additive is chlorinated paraffin T302.
Antirust agent be the lanoline of mass ratio 50% and 50% petroleum sodium sulfonate T702 be combined;
Anti-foaming agent is acrylate and ether copolymer T912.Oxidation and corrosion inhibitor is dialkyldithiocarbamacompositions tungsten.
The remarkable advantage of the present invention:The present invention compositionss have good high temperature lubricating, extreme-pressure anti-wear bearing capacity,
Permeability, diffusibility, cleaning, rust-preventing characteristic.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The alkylnaphthalene of mass ratio 50% and 50% metallocene poly alpha olefin be combined | Surplus |
The cupric antioxidant (T543) of mass ratio 50% and 50% 4,4- di-2-ethylhexylphosphine oxides (T511) are compound | 0.25% |
The thiadiazoles derivative (T561) of mass ratio 50% and 50% thiadiazole are compound | 0.15% |
Sulfuration cottonseed oil (T405) | 4.5% |
Ethyl palmitate | 2.5% |
D2EHDTPA amine salt (T307) | 2.5% |
Chlorinated paraffin (T502) | 5.5% |
The lanoline of mass ratio 50% and 50% petroleum sodium sulfonate (T702) be combined | 0.1% |
Acrylate and ether copolymer (T912) | 40ppm |
Dialkyldithiocarbamacompositions tungsten | 0.9% |
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The alkylnaphthalene of mass ratio 50% and 50% metallocene poly alpha olefin be combined | Surplus |
The cupric antioxidant (T543) of mass ratio 50% and 50% 4,4- di-2-ethylhexylphosphine oxides (T511) are compound | 0.1% |
The thiadiazoles derivative (T561) of mass ratio 50% and 50% thiadiazole are compound | 0.1% |
Sulfuration cottonseed oil (T405) | 5.5% |
Ethyl palmitate | 2.3% |
D2EHDTPA amine salt (T307) | 3.5% |
Chlorinated paraffin (T302) | 6.5% |
The lanoline of mass ratio 50% and 50% petroleum sodium sulfonate (T702) be combined | 0.3% |
Acrylate and ether copolymer (T912) | 40ppm |
Dialkyldithiocarbamacompositions tungsten | 0.7% |
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The alkylnaphthalene of mass ratio 50% and 50% metallocene poly alpha olefin be combined | Surplus |
The cupric antioxidant (T543) of mass ratio 50% and 50% 4,4- di-2-ethylhexylphosphine oxides (T511) are compound | 0.15% |
The thiadiazoles derivative (T561) of mass ratio 50% and 50% thiadiazole are compound | 0.1% |
Sulfuration cottonseed oil (T405) | 4.95% |
Ethyl palmitate | 2.8% |
D2EHDTPA amine salt (T307) | 2.1% |
Chlorinated paraffin (T302) | 7.5% |
The lanoline of mass ratio 50% and 50% petroleum sodium sulfonate (T702) be combined | 0.3% |
Acrylate and ether copolymer (T912) | 40ppm |
Dialkyldithiocarbamacompositions tungsten | 1.1% |
Above each component mass percentage content summation is 100%.
The key technical indexes of 1 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 3 product of embodiment:
Claims (6)
1. 400 alloy rotary pressing processing technology lubricant compositionss of a kind of complete synthesis Monel, it is characterised in that:Using mass ratio
50% alkylnaphthalene and 50% metallocene poly alpha olefin it is compound based on oil, coordinate various compound additives, its respective matter
Amount percent into being grouped into:
The mass percent summation of above each component is 100%.
2. 400 alloy rotary pressing processing technology lubricant compositionss of a kind of complete synthesis Monel as claimed in claim 1, its feature
Be antioxidant be mass ratio 50% cupric antioxidant T543 and 50% 4,4- di-2-ethylhexylphosphine oxides T511 be combined;Metal deactivator
Be mass ratio 50% thiadiazoles derivative T561 and 50% thiadiazole be combined.
3. 400 alloy rotary pressing processing technology lubricant compositionss of a kind of complete synthesis Monel as claimed in claim 1, its feature
Be oiliness improver be sulfuration cottonseed oil T405;Friction improver is ethyl palmitate.
4. 400 alloy rotary pressing processing technology lubricant compositionss of a kind of complete synthesis Monel as claimed in claim 1, its feature
Be extreme pressure agent be D2EHDTPA amine salt T307;Antiwear additive is chlorinated paraffin T302.
5. 400 alloy rotary pressing processing technology lubricant compositionss of a kind of complete synthesis Monel as claimed in claim 1, its feature
Be antirust agent be mass ratio 50% lanoline and 50% petroleum sodium sulfonate T702 be combined;Anti-foaming agent is acrylate and ether
Copolymer T912.
6. 400 alloy rotary pressing processing technology lubricant compositionss of a kind of complete synthesis Monel as claimed in claim 1, its feature
Be oxidation and corrosion inhibitor be dialkyldithiocarbamacompositions tungsten.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101351533A (en) * | 2005-12-28 | 2009-01-21 | 出光兴产株式会社 | Lubricant for metal working |
CN104893797A (en) * | 2015-06-05 | 2015-09-09 | 广西大学 | Double-state logic transmission lubricant composition |
CN104962349A (en) * | 2015-06-05 | 2015-10-07 | 广西大学 | Totally-synthetic emulsible oil composition for seamless knitting machine |
CN105132090A (en) * | 2015-07-20 | 2015-12-09 | 广西大学 | Lubricant composition for open rotor engine gear transmission system |
-
2016
- 2016-11-04 CN CN201610966179.5A patent/CN106520347A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101351533A (en) * | 2005-12-28 | 2009-01-21 | 出光兴产株式会社 | Lubricant for metal working |
CN104893797A (en) * | 2015-06-05 | 2015-09-09 | 广西大学 | Double-state logic transmission lubricant composition |
CN104962349A (en) * | 2015-06-05 | 2015-10-07 | 广西大学 | Totally-synthetic emulsible oil composition for seamless knitting machine |
CN105132090A (en) * | 2015-07-20 | 2015-12-09 | 广西大学 | Lubricant composition for open rotor engine gear transmission system |
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