CN106520238A - Fuel gas/fuel oil synergist for industrial kiln stove and boiler and preparation method and application of fuel gas/fuel oil synergist - Google Patents
Fuel gas/fuel oil synergist for industrial kiln stove and boiler and preparation method and application of fuel gas/fuel oil synergist Download PDFInfo
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- CN106520238A CN106520238A CN201611095796.9A CN201611095796A CN106520238A CN 106520238 A CN106520238 A CN 106520238A CN 201611095796 A CN201611095796 A CN 201611095796A CN 106520238 A CN106520238 A CN 106520238A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/12—Liquefied petroleum gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
- C10L1/1855—Cyclic ethers, e.g. epoxides, lactides, lactones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/04—Catalyst added to fuel stream to improve a reaction
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses fuel gas/fuel oil synergist for an industrial boiler and a kiln stove and a preparation method and application of the fuel gas/fuel oil synergist and belongs to the field of application of fuel gas/fuel oil to industrial kiln stoves and boilers. The synergist comprises a mixture containing transition metallocene and catocene, methyl tertiary butyl ether, cyclohexane peroxide, absolute ethyl alcohol, isopropanol, ethylene glycol monobutyl ether and petroleum ether. The synergist is good in anti-detonating performance; no corrosion is caused to metal pipes, containers, rubber, plastic and the like; the production process is safe and stable; under the combustion condition that pure oxygen does not need to be added or no enriched oxygen is involved, the fuel gas/fuel oil can be combusted fully in deficient oxygen/air, and the effects of energy conservation and consumption reduction are achieved; the initiation temperature is effectively lowered; the energy conservation rate can be remarkably increased; and the effect of reducing pollutant emission can be achieved. The synergist has the beneficial effects that safety is good, consumption is low, and the gas saving rate is high; the fuel gas can be saved by 22% at the maximum or above; and emission of harmful exhaust gas is reduced, and in particular, nitrogen emission can be remarkably reduced.
Description
Technical field
The invention belongs to combustion gas/fuel oil is in Industrial Stoves, boiler applications field, and in particular to a kind of Industrial Boiler and kiln
With combustion gas/synergist for fuel oil and preparation method and application.
Background technology
With developing rapidly for China's industrial economy, combustion gas (fuel oil) social required quantity is increasing and environmental protection
Requirement more and more higher to the discharge of carbon and NOx.All the more strict to the emission request of Industrial Stoves, combustion gas (fuel oil) is used as cleaning
Application of the fuel in Industrial Stoves will be greatly improved.At present, China it is quick eliminate and prohibit using traditional fire coal,
Fuel oil kiln and boiler.Combustion gas (fuel oil) is just being widely used in Industrial Stoves burning as clean fuel.But, fire at present
The price of gas (fuel oil) is higher than the price of the fuel such as coal and fuel oil and C3-C5 so that it is low that enterprise's production capacity increases benefit.
The fuel gas energy-saving product of a kind of energy efficiency of market demand, environmental emission reduction, reduces enterprise's production capacity and improves business economic effect
Benefit, reduces exhaust emission.
At present in numerous patents of the gas synergist (including rare earth addition) that China declares to approve, one is substantially
A little Metal Cuttings, the synergist that burns under the conditions of pure oxygen.Without in synergy section that is oxygen deprivation or burning in air ambient
Can additive.These additives burnt under the conditions of pure oxygen are not applied in Industrial Stoves, are burnt in the oxygen-lean atmosphere of boiler.This
And current all fuel gas additives DeGrain or unfruitful reason in combustion gas (fuel oil) Industrial Stoves, boiler combustion
It is located.
Mostly use in these additives at present, dimethyl ether, hydrogen peroxide, the chemical raw material such as perchloric acid, hydrochloric acid, due to this
A little materials can produce heavy corrosion to container containing, equipment, Work tool, and Long-Time Service has very big potential safety hazard.Make in solvent
Enter for additive and corrosion is produced to rubber packing, rubber tube, metallic conduit, instrument etc. after pipe network, Long-Time Service is easily caused
Gas leakage accident.Separately there are some to use dope, jelly or solids.Such as nano aluminium oxide, nanoscale 5Ni/
5MgO-SiO2Deng.Component of these materials Jing after dissolving as additive, is difficult vaporization long-time using can stick to whole combustion
On the tube wall of gas passage, or separate out the whole passage of liquid blocking.Employing aromatic compound also, such as：Benzene, toluene and dimethylbenzene
Make solvent, not only toxicity is big for this kind of material, human body is damaged, welding, also to making using the sealing of equipment, Work tool
Help into serious prestige, such as：Decompression Valve seal, rubber hose etc., these additives substantially no energy-conservation under combustion case in atmosphere
The effect of reduction of discharging.
The content of the invention
In order to overcome the shortcoming of prior art and deficiency, the primary and foremost purpose of the present invention is to provide a kind of Industrial Boiler and kiln
Stove combustion gas/synergist for fuel oil.It is fuel that the synergist is applied to combustion gas (natural gas, liquefied petroleum gas, propane and C4-C5)
Industrial Boiler and saving energy in kiln and reduction NOx and CO2Discharge capacity.Extend application and can be used in fuel oil (gasoline, diesel oil, heavy oil, coal
Tar) in energy-conservation and reduce discharge.
Another object of the present invention is to provide the preparation side of above-mentioned Industrial Boiler and kiln combustion gas/synergist for fuel oil
Method.
It is still another object of the present invention to provide the application of above-mentioned Industrial Boiler and kiln combustion gas/synergist for fuel oil.
The purpose of the present invention is achieved through the following technical solutions：
A kind of Industrial Stoves and boiler combustion gas/synergist for fuel oil, including following components：Containing magnesium-yttrium-transition metal cyclopentadienyl compound with
The pungent mixture of Kato, methyl tertiary butyl ether(MTBE), peroxidating thiacyclohexane, absolute ethyl alcohol, isopropanol, ethylene glycol monobutyl ether (EGMBE), petroleum ether.
A kind of Industrial Stoves and boiler combustion gas/synergist for fuel oil, including following component by weight：Containing transition group
Metallocene compound and the pungent mixture 24～26% of Kato, methyl tertiary butyl ether(MTBE) 14～16%, peroxidating thiacyclohexane 14～16%,
Absolute ethyl alcohol 18～22%, isopropanol 4～6%, ethylene glycol monobutyl ether (EGMBE) 9～11%, petroleum ether 9～11%.
Preferably, including following component by weight：Containing magnesium-yttrium-transition metal cyclopentadienyl compound and the pungent mixture of Kato
25%th, methyl tertiary butyl ether(MTBE) 15%, peroxidating thiacyclohexane 15%, absolute ethyl alcohol 20%, isopropanol 5%, ethylene glycol monobutyl ether (EGMBE)
10%, petroleum ether 10%.
In the described cyclopentadienyl compound containing the magnesium-yttrium-transition metal mixture pungent with Kato, the cyclopentadienyl compound containing magnesium-yttrium-transition metal is pungent with Kato
Mass ratio be 3：2.
The described cyclopentadienyl compound containing magnesium-yttrium-transition metal is preferably dicyclopentadienyl nickel and two luxuriant ceriums.
Preferably, the pungent mass ratio of described dicyclopentadienyl nickel, two luxuriant ceriums and Kato is 3:3:4.
The luxuriant cerium of described two is synthesized with Organo-Electrochemical Method, and with the cyclopentadiene after purification as raw material, metallic cerium is
Anode and negative electrode, sodium bromide make conducting salt, and DMF (DMF) makees organic solvent, are protected using nitrogen, constant-current source
Electrolysis, has synthesized two luxuriant ceriums.
Described combustion gas is natural gas, liquefied petroleum gas, propane and C4-C5 etc., but not limited to this.
Described fuel oil is gasoline, diesel oil, heavy oil, coal tar etc., but not limited to this.
Described Industrial Stoves are glass furnace, furnace, cement kiln, metal melt kiln etc., but not limited to this.
The preparation method of described Industrial Stoves and boiler combustion gas/synergist for fuel oil, comprises the steps：
(1) at room temperature will be methyl tertiary butyl ether(MTBE) and the cyclopentadienyl compound containing magnesium-yttrium-transition metal pungent with Kato mixture stirring equal
It is even, obtain mixture；
(2) and then again peroxidating thiacyclohexane, absolute ethyl alcohol, isopropanol, ethylene glycol monobutyl ether (EGMBE) are sequentially added to step (1)
In the mixture for obtaining, stir to obtain yellow solution, stands, and filters off precipitation, adds petroleum ether and stirring uniformly, has both obtained work
Industry kiln and boiler combustion gas/synergist for fuel oil.
The time of described standing is preferably 2～3 hours.
Answering in the combustion gas/fuel oil of described Industrial Stoves and boiler combustion gas/synergist for fuel oil in air/oxygen deprivation
With.
The addition of described Industrial Stoves and boiler combustion gas/synergist for fuel oil is percentage by volume 0.2～0.5%.
The present invention mechanism be：The synergist that the present invention adds in combustion gas/fuel oil, plays magnesium-yttrium-transition metal cyclopentadienyl compound
Osmotically active catalyzing activation combustion gas/combustion mechanism of the fuel oil under lean oxygen condition, reduces the initiation temperature of combustion gas/fuel oil, makes combustion
The thermal energy that gas/fuel combustion process is produced rapidly diffuses into the burner hearth physical boundary of kiln and boiler, improves the heat in burner hearth
Temperature inside energy conducting power and balance burner hearth, improving combustion gas/fuel utilization ratio is fully achieved the release of combustion heat energy
Burn completely.Combustion gas/fuel oil is effectively saved, combustion gas/fuel cost is greatly reduced, while effectively reducing the CO in tail gas2With
The discharge of NOx, realizing low-carbon emission reduces Pm2.5 pollutions.The Industrial Stoves and boiler combustion gas/synergist for fuel oil of the present invention
It is a kind of with combustion gas/fuel oil burning is made in oxygen deprivation completely, anti-knock properties are good, to nothings such as metallic conduit, container, rubber, plastics
Corrosion, the synergist of safety and stability in production process.
The synergist of the present invention be to improve combustion gas as target, realized by the initiation temperature of combustion gas is greatly reduced class without
Flame burns, and makes flame flame envelope border, thermaltransmission mode not only improve heat transference efficiency by being changed into outside flame in flame, temperature
Degree field is uniform, it is possible to effectively reduce aflame temperature peak, so as to reduce the generation of nitrogen oxides.
Concertedness containing magnesium-yttrium-transition metal cyclopentadienyl compound and the pungent mixture of Kato is mainly reflected in two luxuriant ceriums and dicyclopentadienyl nickel
Application of composite can effectively reduce combustion gas/fuel oil initiation temperature, and the two cyclopentadienyl ceriums ability for improving burn rate pungent to Kato also increases.
The present invention is had the following advantages and effect relative to prior art：
(1) synergist of the invention has makes the abundant burning in oxygen deprivation/air of combustion gas/fuel oil reach energy-saving work
With；Initiation temperature is effectively reduced, fractional energy savings can be improved by a relatively large margin, the effect of disposal of pollutants is reduced.
(2) the different conventional fuel gas additives (synergist) of synergist of the invention must be in the case of comburant oxygen
Effectively, situation about but burning in air/oxygen deprivation.The synergist of the present invention is that one kind is unprecedented can effectively reduce combustion
The gas synergist with catalysis of gas/fuel oil initiation temperature.Used in the gas industry kiln with combustion gas/fuel oil as combustion gas
A kind of combustion of energy-saving and emission-reduction by a relatively large margin is can reach under the burning condition that pure oxygen or oxygen-enriched participation need not be added in stove, boiler just
Gas/synergist for fuel oil.
(3) synergist of the invention has security good, and consumption is few, the characteristics of solar term rate is high, can save combustion gas highest
Can reach more than 22%；Harmful smoke discharge is reduced, the advantages of particularly can be greatly decreased nitrogen discharged.Which is found not yet at present
His fractional energy savings in practical application in the case of kiln combustion with meagre oxygen can reach gas synergist so far.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention not limited to this.
Embodiment 1
The Industrial Stoves and boiler combustion gas/synergist for fuel oil of the present invention include following material, by weight：Containing transition
(wherein, the pungent mass ratio of dicyclopentadienyl nickel, two luxuriant ceriums and Kato is 3 to race's metallocene compound with the pungent mixture of Kato:3:4) 25%,
Methyl tertiary butyl ether(MTBE) 15%, peroxidating thiacyclohexane 15%, absolute ethyl alcohol 20%, isopropanol 5%, ethylene glycol monobutyl ether (EGMBE) 10%, stone
Oily ether 10%.
The preparation method of described Industrial Stoves and boiler combustion gas/synergist for fuel oil, comprises the steps：
Above-mentioned material is pressed into methyl tertiary butyl ether(MTBE) at room temperature containing magnesium-yttrium-transition metal cyclopentadienyl compound and card according to the above ratio
The pungent mixture of support, stirs, obtains mixture；Then again by peroxidating thiacyclohexane absolute ethyl alcohol isopropyl
Alcohol ethylene glycol monobutyl ether (EGMBE) is sequentially added into said mixture, and stir to obtain yellow solution, is stood 2 hours and is filtered off and sinks
Shallow lake adds petroleum ether and stirring uniformly, has both obtained Industrial Stoves and boiler combustion gas/synergist for fuel oil.
The Industrial Stoves and boiler combustion gas/synergist for fuel oil that the present embodiment is obtained are added with percentage by volume 0.45%
Dosage is added, as a result as shown in table 1.
The effect of the synergist that 1 embodiment of table 1 is obtained
Catalyst in Chinese patent " 201620336364.1, gas energy-conserving device " is used as control synergist, and is not added with
The process of synergist is used as blank.
The ignition temperature of combustion gas/fuel oil can be reduced using the Industrial Stoves and boiler combustion gas/synergist for fuel oil of the present invention
Degree and raising burn rate：The application in natural gas can make the initiation temperature of natural gas be reduced to 380～420 DEG C, and burn rate reaches 4.5m/
S, compared with synergist is not added with, effect is significant；Initiation temperature can only somewhat be reduced using control synergist and burn rate is improved：Ignition
At 580～600 DEG C, burn rate is 3.5m/s to temperature, and compared with synergist is not added with, effect is not notable；It is not added with the process of synergist：
630～650 DEG C of initiation temperature, burn rate is 3.2m/s.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention not by above-described embodiment
Limit, other any Spirit Essences without departing from the present invention and the change, modification, replacement made under principle, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of Industrial Stoves and boiler combustion gas/synergist for fuel oil, it is characterised in that including following components：Containing magnesium-yttrium-transition metal
Luxuriant compound and the pungent mixture of Kato, methyl tertiary butyl ether(MTBE), peroxidating thiacyclohexane, absolute ethyl alcohol, isopropanol, one fourth of ethylene glycol
Ether, petroleum ether.
2. Industrial Stoves according to claim 1 and boiler combustion gas/synergist for fuel oil, it is characterised in that press including following
The component of weight ratio meter：Containing magnesium-yttrium-transition metal cyclopentadienyl compound and the pungent mixture 24～26% of Kato, methyl tertiary butyl ether(MTBE) 14～
16%th, peroxidating thiacyclohexane 14～16%, absolute ethyl alcohol 18～22%, isopropanol 4～6%, ethylene glycol monobutyl ether (EGMBE) 9～11%,
Petroleum ether 9～11%.
3. Industrial Stoves according to claim 1 and 2 and boiler combustion gas/synergist for fuel oil, it is characterised in that include with
Under component by weight：Containing magnesium-yttrium-transition metal cyclopentadienyl compound and the pungent mixture 25% of Kato, methyl tertiary butyl ether(MTBE) 15%, mistake
Oxidation thiacyclohexane 15%, absolute ethyl alcohol 20%, isopropanol 5%, ethylene glycol monobutyl ether (EGMBE) 10%, petroleum ether 10%.
4. Industrial Stoves according to claim 1 and 2 and boiler combustion gas/synergist for fuel oil, it is characterised in that：
It is described containing in magnesium-yttrium-transition metal cyclopentadienyl compound and the pungent mixture of Kato containing magnesium-yttrium-transition metal cyclopentadienyl compound and the pungent matter of Kato
Amount is than being 3：2.
5. Industrial Stoves according to claim 1 and 2 and boiler combustion gas/synergist for fuel oil, it is characterised in that：
The described cyclopentadienyl compound containing magnesium-yttrium-transition metal is dicyclopentadienyl nickel and two luxuriant ceriums.
6. Industrial Stoves according to claim 5 and boiler combustion gas/synergist for fuel oil, it is characterised in that：
The pungent mass ratio of described dicyclopentadienyl nickel, two luxuriant ceriums and Kato is 3:3:4.
7. Industrial Stoves according to claim 1 and 2 and boiler combustion gas/synergist for fuel oil, it is characterised in that：Described
Combustion gas is natural gas, liquefied petroleum gas, propane and C4-C5；
Described fuel oil be gasoline, diesel oil, heavy oil, coal tar；
Described Industrial Stoves are glass furnace, furnace, cement kiln, metal melting kiln.
8. the preparation method of the Industrial Stoves and boiler combustion gas/synergist for fuel oil described in any one of claim 1～7, which is special
Levy is to comprise the steps：
(1) at room temperature methyl tertiary butyl ether(MTBE) and the cyclopentadienyl compound containing magnesium-yttrium-transition metal pungent with Kato mixture is stirred, is obtained
To mixture；
(2) and then again peroxidating thiacyclohexane, absolute ethyl alcohol, isopropanol, ethylene glycol monobutyl ether (EGMBE) are sequentially added to step (1) and is obtained
Mixture in, stir to obtain yellow solution, stands, and filters off precipitation, and it is uniform to add petroleum ether and stirring, both industry kiln
Stove and boiler combustion gas/synergist for fuel oil.
9. the Industrial Stoves and boiler combustion gas/synergist for fuel oil described in any one of claim 1～7 is in air/oxygen deprivation
Application in combustion gas/fuel oil.
10. application according to claim 9, it is characterised in that：
The addition of described Industrial Stoves and boiler combustion gas/synergist for fuel oil is percentage by volume 0.2～0.5%.
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| CN201611095796.9A CN106520238B (en) | 2016-12-02 | 2016-12-02 | A kind of Industrial Stoves and boiler combustion gas/synergist for fuel oil and preparation method and application |
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| CN201611095796.9A CN106520238B (en) | 2016-12-02 | 2016-12-02 | A kind of Industrial Stoves and boiler combustion gas/synergist for fuel oil and preparation method and application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110194972A (en) * | 2018-12-29 | 2019-09-03 | 中润油新能源股份有限公司 | A kind of novel synthesizing environment-friendly energy-saving methanol gasoline and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003040269A1 (en) * | 2001-11-09 | 2003-05-15 | Carroll Robert W | Method and composition for improving fuel combustion |
| CN1597879A (en) * | 2003-09-15 | 2005-03-23 | 李跃红 | Synergistic mixed light hydrocarbon industrial gas |
| CN102634393A (en) * | 2012-04-11 | 2012-08-15 | 刘越 | Efficiency energy-saving additive for liquefied petroleum cutting gas |
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2016
- 2016-12-02 CN CN201611095796.9A patent/CN106520238B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003040269A1 (en) * | 2001-11-09 | 2003-05-15 | Carroll Robert W | Method and composition for improving fuel combustion |
| CN1597879A (en) * | 2003-09-15 | 2005-03-23 | 李跃红 | Synergistic mixed light hydrocarbon industrial gas |
| CN102634393A (en) * | 2012-04-11 | 2012-08-15 | 刘越 | Efficiency energy-saving additive for liquefied petroleum cutting gas |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110194972A (en) * | 2018-12-29 | 2019-09-03 | 中润油新能源股份有限公司 | A kind of novel synthesizing environment-friendly energy-saving methanol gasoline and preparation method thereof |
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| CN106520238B (en) | 2017-09-15 |
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