CN106520154A - Processing method of husk slag of Xanthoceras sorbifolia Bunge and products - Google Patents
Processing method of husk slag of Xanthoceras sorbifolia Bunge and products Download PDFInfo
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- CN106520154A CN106520154A CN201610873034.0A CN201610873034A CN106520154A CN 106520154 A CN106520154 A CN 106520154A CN 201610873034 A CN201610873034 A CN 201610873034A CN 106520154 A CN106520154 A CN 106520154A
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- shinyleaf yellowhorn
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- fruit shell
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C1/00—Working-up tar
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
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- Life Sciences & Earth Sciences (AREA)
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- Cosmetics (AREA)
Abstract
The invention relates to a processing method of husk slag of Xanthoceras sorbifolia Bunge and products, the husk slag of Xanthoceras sorbifolia Bunge is dried and crushed to obtain husk slag powder of Xanthoceras sorbifolia Bunge, and by destructive distillation, smoldering carbonization, standing, atmospheric distillation, alkali addition, filtering for impurity removal and other processes, waste of development and utilization of the Xanthoceras sorbifolia Bunge is treated for conversion into pyroligneous liquor, wood tar and bio-charcoal capable of being further used. The prepared pyroligneous liquor product is good in grade and controllable in quality, can be used as additives in cosmetics or agricultural and sideline products, and has a significant development value; at the same time, the processing method has the advantages of simple technological process and easy industrialization operation, has a positive significance to the industrial development of the Xanthoceras sorbifolia Bunge.
Description
Technical field
The invention belongs to chemical industry chemical field, more particularly to a kind of processing method of shinyleaf yellowhorn fruit shell slag and products thereof.
Background technology
Shiny-leaved yellowhorn (Xanthoceras sorbifolia Bunge) is that Sapindaceae (Sapindaceae) shiny-leaved yellowhorn category is planted
Thing, single category single, is the distinctive rare traditional oil tree of China, has the title of northern oil tea, is China's forestry and Department of Science and Technology's weight
The farm-forestry crop that power develops and helps.Shiny-leaved yellowhorn whole body all has higher Development volue, and such as shiny-leaved yellowhorn perianth is passed with improvement
Prostatitic effect；Leaf has sterilized, antitumor, function of reducing blood sugar bioactivity；The one kind of branch as traditional mongolian medicine, with dispelling
Wind dehumidifying, effect of swelling and pain relieving.And the most also most Development volue of hitherto reported is its seed and shell, research is aobvious
Show the seed benevolence oil-containing of shiny-leaved yellowhorn more than 60%, its oil is rich in unrighted acid, and can promote CO2 laser weld, again containing one kind
Raw special effects materials nervonic acid；Shiny-leaved yellowhorn seed extract shinyleaf yellowhorn fruit kernel cream, the work(with treatment infantile enuresis
Effect, is main component that our kind new medicine infantile enuresises stop；Triterpenes, flavonoids is isolated from shinyleaf yellowhorn fruit shell,
The Compound Compounds such as alkaloids, monoterpene and fatty acid, wherein isolated saponins compound shinyleaf yellowhorn shell
Glycosides, with anti-inflammatory, treats infantile enuresis, strengthens memory, antitumor to wait pharmacological action, Shenyang Inst. of Applied Ecology, Chinese Academy of Sciences
Researcher's research finds that the compound has the effect of significantly treatment senile dementia.
At present, shiny-leaved yellowhorn has had large-scale cultivation, annual fruit yield in the area such as Shaanxi, Gansu, Liaoning, Shanxi
It is huge, and in fruit, the quality of shinyleaf yellowhorn fruit shell accounts for more than the 50% of gross mass, which is developed be only limitted to minority at present
Scientific research institution extracts active ingredient therein, and is in laboratory stage, and the active constituent content of extraction seldom, extracts residue and accounts for
More than the 95% of gross mass.And in fact, the Planting household of most plantation shiny-leaved yellowhorns does not develop profit to the part
With all using the part as the discarded object discarding during exploitation shiny-leaved yellowhorn benevolence.Develop the correlation of application at present to which
Patent have shinyleaf yellowhorn shell saponin(e isoreactivity composition extraction (CN201010575230.2, CN200410059140.2,
CN201110082904.X、CN201310419295.1)；The preparation (CN201410209803.8) of shinyleaf yellowhorn shell health-care pillow,
Sheep feed containing the shiny-leaved yellowhorn dregs of fat and shinyleaf yellowhorn shell and preparation method thereof (CN201410498068.7) etc..As it was previously stated, literary
The active component contained in hat shell has various pharmacologically actives, but content is extremely low；Develop as health-care pillow, due to its work(
The factor of the aspects such as effect, market value has to be tested；And be good selection as feed development, but economic worth is again not
It is high.Cheng Xian etc. discloses a kind of method (CN201010254318.4) of comprehensive utilization shinyleaf yellowhorn fruit shell, and the method will pass through
Shinyleaf yellowhorn shell is switched to bio-natural gas, life by a series of processes such as gas explosion, microorganism conversion, acidifying, methanation, enzymolysis, fermentation
Derivative macromolecular material of thing ethanol, lignin etc., realize in shinyleaf yellowhorn fruit shell hemicellulose, lignin and cellulose these three
Reasonable, the effectively utilizes of main natural polymer component.But the method complex technical process, condition be harsh, for equipment
It is all very high Deng requirement, and waste liquid the like waste in production process, can be still produced, secondary pollution is produced to environment, thus it is real
The difficulty of existing industrialized production is than larger, the worth discussion of feasibility.In view of currently for many present in shinyleaf yellowhorn shell utilization
The shinyleaf yellowhorn fruit shell slag of problem, especially process constituents extraction, it is intended to find and develop a kind of technical process it is simple,
It is easy to the high shinyleaf yellowhorn fruit shell Slag treatment method of industrialization and added value.
The content of the invention
In order to solve problem above, it is an object of the present invention to provide a kind of technical process is simple, be easy to industrialization and added value
High shinyleaf yellowhorn fruit shell Slag treatment method and products thereof.
The purpose of the present invention is achieved through the following technical solutions：
A kind of processing method of shinyleaf yellowhorn fruit shell slag, comprises the following steps：
(1) it is dried, crushes
Shinyleaf yellowhorn fruit shell slag is dried, is crushed, obtain shinyleaf yellowhorn fruit shell ground-slag；
(2) destructive distillation
By step, (1) gained shell ground-slag is poured in retort, sealing and reinforcing retort after filling closely, then gradient increased temperature
Destructive distillation, condenses recovered flue gas, obtains pyrolytic behavior A；
(3) smoulder carbonization
Treat that (2) middle shinyleaf yellowhorn fruit shell slag is not producing flue gas to step, stops destructive distillation and condensation is collected, continue to keep sealed shape
State, makes material continue to smoulder the charcoal that is carbonized to obtain using itself waste heat；
(4) stand
Pyrolytic behavior A stratification is obtained in taking step (2), is obtained as upper liquid C and subnatant D；
(5) air-distillation
Step (4) gained upper liquid C air-distillation is taken, refined liquid E is obtained；
Plus alkali, filtering and impurity removing (6)
Step (4) gained subnatant D is taken, is added alkaline solution to stir to no longer precipitation is produced, is filtered to remove insoluble
Material, obtains final product refined liquid F.
Preferably, step (2) middle gradient increased temperature speed be 10 DEG C/min.
Preferably, (2) middle pyrolysis temperature gradient rises to 300 DEG C to step.
Preferably, (4) time of repose is 48h to step.
Preferably, (5) air-distillation temperature is 98-130 DEG C to step.
Step (6) in added alkaline solution be NaOH, the mixing of one or two kinds of in potassium hydroxide solution it is molten
Liquid.
Further object is that refined liquid E, institute obtained in the processing method of the above-mentioned shinyleaf yellowhorn fruit shell slag of offer
Refined liquid E stated is pyrolkigneous liquid, and color is light red, and, between 3-4, clarification is bright, has light smoke aroma for pH value.
Application of above-mentioned obtained refined liquid E in cosmetics, agricultural byproducts are prepared as additive.
The present invention also aims to provide refined liquid F obtained in the processing method of above-mentioned shinyleaf yellowhorn fruit shell slag, its feature
It is that described refined liquid F is wood tar, color is black, pH value has penetrating odor between 7-8, is insoluble in water, easily
It is dissolved in alcohol.
Preparation technology parameter of the present invention it is preferred：
The selection of pyrolysis temperature：Take 500g shinyleaf yellowhorn shell slag distinguish gradient increased temperature to 200 DEG C, 300 DEG C, 400 DEG C, 500
DEG C, 600 DEG C, maintain at this temperature to there is no longer condensed product produce.Experimental result shows：Shinyleaf yellowhorn shell slag is in temperature
Condensed product generation is begun with when 170 DEG C, and as the rising condensed product of temperature is continuously increased, 170-200 DEG C of interval condensation is produced
Thing is 64g, and 200-300 DEG C of condensed product is 217g,>After 300 DEG C condensed product gradually decrease for<10g；Charcoal yield with
The rising of temperature and reduce, the charcoal quality that maximum temperature is obtained at 200 DEG C, 300 DEG C, 400 DEG C, 500 DEG C, 600 DEG C
Respectively 173g, 159g, 157g, 154g, 153g and 150g.Experimental result illustrates that shinyleaf yellowhorn shell slag starts at 170 DEG C point
Solution, temperature are decomposed when reaching 300 DEG C substantially and are finished, therefore pyrolysis temperature is warming up to 300 DEG C.
Standing separation pyrolkigneous liquid was determined with the time of wood tar：Dry distillation liquid 100g is taken respectively, is placed in separatory funnel and is stood 1
It was released lower floor's wood tar and weighs quality to 30 days.As a result show：Dry distillation liquid wood tar quality after standing 1 day is 2.5g,
After standing 48h, wood tar quality is 5.4g, and hereafter as the prolongation wood tar quality of time of repose has no increase, description of test is quiet
After putting 48h, wood tar is precipitated completely and is separated with pyrolkigneous liquid, therefore selects time of repose 48h to carry out wood in separation pyrolyzing product
Vinegar liquid and wood tar.
Beneficial effects of the present invention：
(1) shinyleaf yellowhorn fruit shell Slag treatment method technical process provided by the present invention is simple, easily realize that industrialization is operated,
While rich raw material sources.As the active constituent content that shinyleaf yellowhorn shell is extracted is little, extract residue and account for gross mass
More than 95%, the Planting households of most plantation shiny-leaved yellowhorns are not developed and utilized to the part, all using the part as
Exploitation shiny-leaved yellowhorn benevolence during discarded object abandon, if therefore for the present invention is carried out, shiny-leaved yellowhorn resource will be followed
Ring is using significant.
(2) product qualities are good, quality controllable：Document report research shows that the dry distillation liquid that ordinary material destructive distillation is obtained stands three
Thoroughly it is divided within more than individual month three layers, it is wood tar that upper strata is light oil, lower floor, and intermediate layer is pyrolkigneous liquid, and pyrolkigneous liquid is typically constituted from always
The 70-80% of dry distillation liquid.And the present invention, with shinyleaf yellowhorn shell slag as raw material, the carbonization under conditions of 300 DEG C of ＜ obtains destructive distillation
Liquid stands 48h and is divided into two-layer, and upper strata is pyrolkigneous liquid, and lower floor is wood tar, and the content of wood tar is extremely low, only accounts for dry distillation liquid total
5% of quality or so, and the pyrolkigneous liquid color for obtaining is bright, red with grape wine, quality is splendid.
(3) pyrolysis temperature is low, energy saving：Document report ordinary material pyrolysis temperature just decomposes more than 400 DEG C condensation
Liquid is produced, destructive distillation at such temperature, and one side energy consumption is big, the phenols that the dry distillation liquid that destructive distillation is obtained under another aspect high temperature is produced
Increase considerably etc. harmful substance, many problems are brought to follow-up process and product development.In the present invention, shinyleaf yellowhorn shell slag exists
Decompose at 170 DEG C, and 300 DEG C of temperature thoroughly can be decomposed, therefore one aspect of the present invention energy saving, on the other hand obtain
Destructive distillation product harmful substance reduce, post processing is simple, and product is safer.
Description of the drawings
Fig. 1 is the processing technological flow of shinyleaf yellowhorn fruit shell slag of the present invention
Specific embodiment
The present invention is described in further details below by example, these examples are only used for illustrating the present invention, do not limit
The scope of the present invention processed.
1 shinyleaf yellowhorn fruit shell Slag treatment method of embodiment
(1) it is dried, crushes
Shinyleaf yellowhorn fruit shell slag is dried, is crushed, obtain shinyleaf yellowhorn fruit shell ground-slag；
(2) destructive distillation
By step (1) gained shell ground-slag 500g, pour in retort, sealing and reinforcing retort, retort after filling closely
300 DEG C are warming up to the velocity gradient of 10 DEG C/min, destructive distillation at this temperature is then kept, recovered flue gas are condensed, is obtained pyrolytic behavior A；
(3) smoulder carbonization
Treat that (2) middle shinyleaf yellowhorn fruit shell slag is not producing flue gas to step, stops destructive distillation and condensation is collected, but continue to keep closed
State, makes material continue to smoulder using itself waste heat the charcoal about 152g that is carbonized to obtain；
(4) stand
Pyrolytic behavior A being obtained in taking step (2) and standing 48h, layering is obtained as upper liquid C about 250g and subnatant D about 17g；
(5) air-distillation
Step (4) gained upper liquid C air-distillation is taken, 98-130 degree Celsius of cut is collected, is obtained refined liquid E about 215g；
Plus alkali, filtering and impurity removing (6)
Step (4) gained subnatant D is taken, the stirring of saturation sodium hydroxide solution is added, is stirred well to and be there is no longer precipitation generation
Till, filter, remove insoluble substance, obtain final product refined liquid F about 14g.
2 shinyleaf yellowhorn fruit shell Slag treatment method of embodiment
(1) it is dried, crushes
Shinyleaf yellowhorn fruit shell slag is dried, is crushed, obtain shinyleaf yellowhorn fruit shell ground-slag；
(2) destructive distillation
By step (1) gained shell ground-slag 1000g, pour in retort, sealing and reinforcing retort, destructive distillation after filling closely
Kettle is warming up to 300 DEG C with the velocity gradient of 10 DEG C/min, then keeps destructive distillation at this temperature, condenses recovered flue gas, obtains pyrolytic behavior A
About 525g；
(3) smoulder carbonization
Treat that (2) middle shinyleaf yellowhorn fruit shell slag is not producing flue gas to step, stops destructive distillation and condensation is collected, but continue to keep closed
State, makes material continue to smoulder using itself waste heat the charcoal about 298g that is carbonized to obtain；
(4) stand
Pyrolytic behavior A being obtained in taking step (2) and standing 48h, layering is obtained as upper liquid C about 480g and subnatant D about 31g；
(5) air-distillation
Step (4) gained upper liquid C air-distillation is taken, 98-130 degree Celsius of cut is collected, is obtained refined liquid E about 408g；
Plus alkali, filtering and impurity removing (6)
Step (4) gained subnatant D is taken, the stirring of saturation sodium hydroxide solution is added, is stirred well to and be there is no longer precipitation generation
Till, filter, remove insoluble substance, obtain final product refined liquid F about 28g.
3 shinyleaf yellowhorn fruit shell Slag treatment method of embodiment
(1) it is dried, crushes
Shinyleaf yellowhorn fruit shell slag through extracting is dried, crushes, and obtains shinyleaf yellowhorn fruit shell ground-slag；
(2) destructive distillation
By step (1) gained shell ground-slag 1500g, pour in retort, sealing and reinforcing retort, destructive distillation after filling closely
Kettle is warming up to 300 DEG C with the velocity gradient of 10 DEG C/min, then keeps destructive distillation at this temperature, condenses recovered flue gas, obtains pyrolytic behavior A
About 800g；
(3) smoulder carbonization
Treat that (2) middle shinyleaf yellowhorn fruit shell slag is not producing flue gas to step, stops destructive distillation and condensation is collected, but continue to keep closed
State, makes material continue to smoulder using itself waste heat the charcoal about 430g that is carbonized to obtain；
(4) stand
Pyrolytic behavior A being obtained in taking step (2) and standing 48h, layering is obtained as upper liquid C about 730g and subnatant D about 49g；
(5) air-distillation
Step (4) gained upper liquid C air-distillation is taken, 98-130 degree Celsius of cut is collected, is obtained refined liquid E about 702g；
Plus alkali, filtering and impurity removing (6)
Step (4) gained subnatant D is taken, the stirring of saturation sodium hydroxide solution is added, is stirred well to and be there is no longer precipitation generation
Till, filter, remove insoluble substance, obtain final product refined liquid F about 46g.
4 shinyleaf yellowhorn fruit shell Slag treatment method of embodiment
(1) it is dried, crushes
Shinyleaf yellowhorn fruit shell slag is dried, is crushed, obtain shinyleaf yellowhorn fruit shell ground-slag；
(2) destructive distillation
By step (1) gained shell ground-slag 2000g, pour in retort, sealing and reinforcing retort, destructive distillation after filling closely
Kettle is warming up to 300 DEG C with the velocity gradient of 10 DEG C/min, then keeps destructive distillation at this temperature, condenses recovered flue gas, obtains pyrolytic behavior A
About 980g；
(3) smoulder carbonization
Treat that (2) middle shinyleaf yellowhorn fruit shell slag is not producing flue gas to step, stops destructive distillation and condensation is collected, but continue to keep closed
State, makes material continue to smoulder using itself waste heat the charcoal about 584g that is carbonized to obtain；
(4) stand
Pyrolytic behavior A being obtained in taking step (2) and standing 48h, layering is obtained as upper liquid C about 900g and subnatant D about 62g；
(5) air-distillation
Step (4) gained upper liquid C air-distillation is taken, 98-130 degree Celsius of cut is collected, is obtained refined liquid E about 800g；
Plus alkali, filtering and impurity removing (6)
Step (4) gained subnatant D is taken, the stirring of saturation sodium hydroxide solution is added, is stirred well to and be there is no longer precipitation generation
Till, filter, remove insoluble substance, obtain final product refined liquid F about 53g.
The above, is only presently preferred embodiments of the present invention, not makees any pro forma restriction to the present invention, though
So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people
Member, in without departing from the technology of the present invention side's scope, when using the technology contents of the disclosure above make it is a little change or be modified to
The Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, according to the technical spirit pair of the present invention
Any simple modification, equivalent variations and modification that above example is made, still fall within the range of technical solution of the present invention.
Claims (9)
1. a kind of processing method of shinyleaf yellowhorn fruit shell slag, it is characterised in that comprise the following steps：
(1) it is dried, crushes
Shinyleaf yellowhorn fruit shell slag is dried, is crushed, obtain shinyleaf yellowhorn fruit shell ground-slag；
(2) destructive distillation
By step, (1) gained shell ground-slag is poured in retort, sealing and reinforcing retort after filling closely, then gradient increased temperature destructive distillation,
Condensation recovered flue gas, obtain pyrolytic behavior A；
(3) smoulder carbonization
Treat that (2) middle shinyleaf yellowhorn fruit shell slag is not producing flue gas to step, stops destructive distillation and condensation is collected, continue to keep air-tight state, make
Material is continued to smoulder the charcoal that is carbonized to obtain using itself waste heat；
(4) stand
Pyrolytic behavior A stratification is obtained in taking step (2), is obtained as upper liquid C and subnatant D；
(5) air-distillation
Step (4) gained upper liquid C air-distillation is taken, refined liquid E is obtained；
Plus alkali, filtering and impurity removing (6)
Step (4) gained subnatant D is taken, alkaline solution stirring is added, is stirred well to till there is no longer precipitation generation, is crossed and filter
Insoluble substance is removed, refined liquid F is obtained final product.
2. a kind of processing method of shinyleaf yellowhorn fruit shell slag according to claim 1, it is characterised in that step (2) middle gradient increased temperature
Speed be 10 DEG C/min.
3. a kind of processing method of shinyleaf yellowhorn fruit shell slag according to claim 1, it is characterised in that step (2) middle pyrolysis temperature
Gradient rises to 300 DEG C.
4. a kind of processing method of shinyleaf yellowhorn fruit shell slag according to claim 1, it is characterised in that (4) time of repose is step
48h。
5. a kind of processing method of shinyleaf yellowhorn fruit shell slag according to claim 1, it is characterised in that step (5) air-distillation temperature
Spend for 98-130 DEG C.
6. a kind of processing method of shinyleaf yellowhorn fruit shell slag according to claim 1, it is characterised in that step (6) in added alkalescence
Solution is NaOH, the mixed solution of one or two kinds of in potassium hydroxide solution.
7. the processing method of the arbitrary shinyleaf yellowhorn fruit shell slag of claim 1-6, it is characterised in that described refined liquid E is wood
Vinegar liquid, color are light red, and, between 3-4, clarification is bright, has light smoke aroma for pH value.
8. the processing method of shinyleaf yellowhorn fruit shell slag according to claim 7, it is characterised in that described refined liquid E is in system
For the application in cosmetics, agricultural byproducts as additive.
9. the processing method of the arbitrary shinyleaf yellowhorn fruit shell slag of claim 1-6, it is characterised in that described refined liquid F is wood
Tar, color are black, and between 7-8, tool penetrating odor is insoluble in water, is soluble in alcohol pH value.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107541227A (en) * | 2017-04-19 | 2018-01-05 | 北京三聚绿能科技有限公司 | A kind of technique for preparing charcoal base manure high-quality biological matter charcoal co-production pyrolkigneous liquid |
| CN107624860A (en) * | 2017-10-13 | 2018-01-26 | 江苏省中国科学院植物研究所 | It is a kind of to prepare the application of the method and smoke solution of smoke solution in bacon is prepared using walnut shell |
| CN108975326A (en) * | 2018-09-11 | 2018-12-11 | 陕西中医药大学 | Spermoderm of Xanthoceras sorbifolia Bunge prepares the method and nanoporous carbon of nanoporous carbon |
| CN111302339A (en) * | 2020-02-24 | 2020-06-19 | 山东大学 | Porous carbon material prepared from xanthoceras sorbifolia bunge shell residue waste as well as preparation method and application of porous carbon material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899475A (en) * | 2010-08-17 | 2010-12-01 | 福州大学 | Method for comprehensively utilizing xanthoceras sorbifolia shells |
| CN105131984A (en) * | 2015-07-07 | 2015-12-09 | 大连民族大学 | Continuous reproduction technology using biomass wastes and waste liquid |
-
2016
- 2016-09-30 CN CN201610873034.0A patent/CN106520154A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899475A (en) * | 2010-08-17 | 2010-12-01 | 福州大学 | Method for comprehensively utilizing xanthoceras sorbifolia shells |
| CN105131984A (en) * | 2015-07-07 | 2015-12-09 | 大连民族大学 | Continuous reproduction technology using biomass wastes and waste liquid |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107541227A (en) * | 2017-04-19 | 2018-01-05 | 北京三聚绿能科技有限公司 | A kind of technique for preparing charcoal base manure high-quality biological matter charcoal co-production pyrolkigneous liquid |
| CN107624860A (en) * | 2017-10-13 | 2018-01-26 | 江苏省中国科学院植物研究所 | It is a kind of to prepare the application of the method and smoke solution of smoke solution in bacon is prepared using walnut shell |
| CN108975326A (en) * | 2018-09-11 | 2018-12-11 | 陕西中医药大学 | Spermoderm of Xanthoceras sorbifolia Bunge prepares the method and nanoporous carbon of nanoporous carbon |
| CN111302339A (en) * | 2020-02-24 | 2020-06-19 | 山东大学 | Porous carbon material prepared from xanthoceras sorbifolia bunge shell residue waste as well as preparation method and application of porous carbon material |
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