CN106519841A - Flowable carbon fiber and magnalium alloy type water-soluble colored nanometer UV coating and preparation method thereof - Google Patents
Flowable carbon fiber and magnalium alloy type water-soluble colored nanometer UV coating and preparation method thereof Download PDFInfo
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- CN106519841A CN106519841A CN201610976889.6A CN201610976889A CN106519841A CN 106519841 A CN106519841 A CN 106519841A CN 201610976889 A CN201610976889 A CN 201610976889A CN 106519841 A CN106519841 A CN 106519841A
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- water
- soluble
- coating
- water solublity
- solublity
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to a flowable carbon fiber and magnalium alloy type water-soluble colored nanometer UV coating. The flowable carbon fiber and magnalium alloy type water-soluble colored nanometer UV coating comprises the following components in percentage by weight: 40-47% of water-soluble acrylate synthetic resin, 23-26% of water-soluble polyurethane synthetic resin, 5-8% of water-soluble acrylic resin, 4-6% of water-soluble photoinitiator, 0.2-0.3% of water-soluble defoaming agent, 0.5-0.7% of water-soluble levelling agent, 2-3% of water-soluble anti-settling agent, 2-3.3% of water-soluble nanometer color paste, 4-6% of water-soluble aluminum paste, and 7-12% of pure water diluent. The preparation method comprises the following steps: feeding materials; starting a dispersing machine to disperse; then feeding materials and stirring; and observing the dispersing uniformity at every half an hour of stirring. The flowable carbon fiber and magnalium alloy type water-soluble colored nanometer UV coating can flow under normal temperature, is free of VOC (Volatile Organic Compound), and can be solified through ultraviolet light; the solid content reaches one hundred percent; the coating can be irradiated by ultraviolet light to form a film after solidifying cross-linking.
Description
Technical field
The present invention relates to a kind of UV coating and preparation method thereof, and in particular to a kind of water solublity UV coating and its preparation side
Method.
Background technology
Traditional coating factory provides oiliness UV ultraviolet coating for travelling trader, and which is not environmentally and film performance can not meet more
Wide requirement, using the oiliness dilution dilution agent of 20%-40%, they are volatile solvents, and solidification is evaporate in air, can be made
VOC content is exceeded in air, and environmental pollution is larger, human injury is more to a certain degree present, this kind of coating and contain admittedly
Amount is low.There is data to suggest that organic volatile not only atmosphere pollution brings on a disaster to weather, can also endanger the health of the mankind.With
Country puts into effect the policy execution of VOC content, and traditional solvent-based paints coating, is faced with adjustment formula or water solublity is regenerated.
The international trend of NO.VOC is and international joint.As the cosmetics film forming matter water solublity UV UV nanos of industrial component
Coating, also requires that solvent-free and high solids content index.The VOC content of national standard is provided up for downstream travelling trader production.It is existing
It is that the factory oneself that needs painting is dissolved with solvent that technology Zhong Yeyou coating producer provides 100% oiliness ultraviolet (UV) coating.Prior art
In particularly 3C electronic products, if VOC free, it is possible to avoid the infringement to health of people.
The content of the invention
Goal of the invention:The invention aims to overcome deficiency of the prior art, there is provided a kind of room temperature is flowable
VOC free, ultraviolet photo-curing, 100% solid content can be good, attached with ultraviolet light source shines solidification crosslinking film forming, paint film flexibility
Put forth effort, and the good carbon fibre materials of pure water intersolubility, the coloured nanometer UV coating of magnalium material water solublity and its preparation side
Method.
Technical scheme:In order to solve above-mentioned technical problem, a kind of flowable carbon fibre materials of the present invention, magnalium
The coloured nanometer UV coating of alloy material water solublity, by weight percentage, it includes following components,
(1)Water-soluble acrylic synthetic resin 40%-47%;
(2)Soluble polyurethane synthetic resin 23%-26%;
(3)Water soluble acrylic resin 5%-8%;
(4)Water-soluble light trigger 4%-6%;
(5)Water solublity defoamer 0.2%-0.3%;
(6)Water solublity levelling agent 0.5%-0.7%;
(7)Water solublity anti-settling agent 2%-3%;
(8)Water-soluble nano mill base 2%-3.3%;
(9)Water-soluble aluminum silver paste 4%-6%;
(10)Pure water diluent 7%-12%.
The water-soluble acrylic synthetic resin is water-borne acrylic resin, hydroxypropyl acrylate, acrylic acid, metering system
Acid, the quarternary copolymerized synthetic of styrene.
Contain hydroxyl, ehter bond, unsaturated bond in the soluble polyurethane synthetic resin.
The water-soluble light trigger is diazol, diaryl group iodized salt, triaryl sulfonium salts, alkyl sulfosalt, ferrum virtue
One kind in hydrocarbon salt, sulfonyloxy ketone and triaryl silica ether.
The water solublity defoamer is dimethicone.
The water solublity levelling agent is polyether-modified dimethione.
The water solublity anti-settling agent is aerosil.
The water-soluble nano mill base is water-soluble nano black wash, the blue slurry of water-soluble nano, in the purple slurry of water-soluble nano
It is a kind of.
The pure water diluent is deionized water.
A kind of preparation method of the coloured nanometer UV coating of flowable carbon fibre materials, magnalium material water solublity, it
Comprise the following steps,
(1)Successively according to water-soluble acrylic synthetic resin, pure water diluent, soluble polyurethane synthetic resin, water solublity third
The order of olefin(e) acid resin is fed intake;
(2)Feed intake and finish rear seal-cover dispersion machine lid, open dispersion machine dispersion, rotating speed is controlled in 800-1200 r/min, makes water
Soluble acrylic synthetic resin, soluble polyurethane synthetic resin, water soluble acrylic resin and pure water diluent are sufficiently stirred for 1
More than hour
(3)Again by water-soluble light trigger, water solublity defoamer, water solublity levelling agent, water solublity anti-settling agent, water-soluble nano color
Slurry and water-soluble aluminum silver paste are added, and dispersion machine is stirred more than 2 hours;
(4)Often disperse half an hour, the lower dispersed homogeneous degree of observation, the temperature of dispersion cup is not above 50 DEG C ± 5 DEG C.
Aluminum in the water-soluble aluminum silver paste is, in lepidiod aluminium powder, to account for formula 3-10%.
The water-soluble nano mill base is dispersed in the semi-products in paint vehicle by pigment or pigment and inserts.
Beneficial effect:Compared with prior art, its remarkable advantage is the present invention:The present invention by accurate component proportion and
Rigorous procedure of processing, the product 100% of manufacture do not contain oil-based solvent, are the thick liquid that can be flowed under room temperature, facilitate latting drown
Using or directly use, can apply in electronic product, metallic article, plasthetics and other 3C electronic products, using neck
Domain extensively, does not result in the pollution of air V OC, room temperature good fluidity, it is not necessary to which travelling trader's player whose turn comes next oiliness diluent dissolves, using letter
Just, product intersolubility is good, can recoat, and paint film property is excellent, and preparation technology of the present invention is not used molten using dispersion reaction at a high speed
Agent is dehydrated, therefore no any solvent introduces product.
Specific embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment 1:
A kind of flowable carbon fibre materials of the present invention, the coloured nanometer UV coating of magnalium material water solublity, by weight
Amount percentages, it includes following components,
(1)Water-soluble acrylic synthetic resin 42%;
(2)Soluble polyurethane synthetic resin 24%;
(3)Water soluble acrylic resin 6%;
(4)Water-soluble light trigger 4.5%;
(5)Water solublity defoamer 0.22%;
(6)Water solublity levelling agent 0.55%;
(7)Water solublity anti-settling agent 2.1%;
(8)Water-soluble nano mill base 2.2%;
(9)Water-soluble aluminum silver paste 4.5%;
(10)Pure water diluent 8%.
The water-soluble acrylic synthetic resin is water-borne acrylic resin, hydroxypropyl acrylate, acrylic acid, metering system
Acid, the quarternary copolymerized synthetic of styrene.
Contain hydroxyl, ehter bond, unsaturated bond in the soluble polyurethane synthetic resin.
The water-soluble light trigger is diazol, diaryl group iodized salt, triaryl sulfonium salts, alkyl sulfosalt, ferrum virtue
One kind in hydrocarbon salt, sulfonyloxy ketone and triaryl silica ether.
The water solublity defoamer is dimethicone.
The water solublity levelling agent is polyether-modified dimethione.
The water solublity anti-settling agent is aerosil.
The water-soluble nano mill base is water-soluble nano black wash, the blue slurry of water-soluble nano, in the purple slurry of water-soluble nano
It is a kind of.
The pure water diluent is deionized water.
A kind of preparation method of the coloured nanometer UV coating of flowable carbon fibre materials, magnalium material water solublity, it
Comprise the following steps,
(1)Successively according to water-soluble acrylic synthetic resin, pure water diluent, soluble polyurethane synthetic resin, water solublity third
The order of olefin(e) acid resin is fed intake;
(2)Feed intake and finish rear seal-cover dispersion machine lid, open dispersion machine dispersion, rotating speed is controlled in 900 r/min, makes water solublity third
Olefin(e) acid synthetic resin, soluble polyurethane synthetic resin, water soluble acrylic resin and pure water diluent be sufficiently stirred for 1 hour with
On
(3)Again by water-soluble light trigger, water solublity defoamer, water solublity levelling agent, water solublity anti-settling agent, water-soluble nano color
Slurry and water-soluble aluminum silver paste are added, and dispersion machine is stirred more than 2 hours;
(4)Often disperse half an hour, the lower dispersed homogeneous degree of observation, the temperature of dispersion cup is not above 50 DEG C ± 5 DEG C.
Embodiment 2
A kind of flowable carbon fibre materials of the present invention, the coloured nanometer UV coating of magnalium material water solublity, by weight
Amount percentages, it includes following components,
(1)Water-soluble acrylic synthetic resin 44%;
(2)Soluble polyurethane synthetic resin 24.5%;
(3)Water soluble acrylic resin 6.5%;
(4)Water-soluble light trigger 5%;
(5)Water solublity defoamer 0.25%;
(6)Water solublity levelling agent 0.6%;
(7)Water solublity anti-settling agent 2.4%;
(8)Water-soluble nano mill base 2.8%;
(9)Water-soluble aluminum silver paste 5%;
(10)Pure water diluent 9%.
The water-soluble acrylic synthetic resin is water-borne acrylic resin, hydroxypropyl acrylate, acrylic acid, metering system
Acid, the quarternary copolymerized synthetic of styrene.
Contain hydroxyl, ehter bond, unsaturated bond in the soluble polyurethane synthetic resin.
The water-soluble light trigger is diazol, diaryl group iodized salt, triaryl sulfonium salts, alkyl sulfosalt, ferrum virtue
One kind in hydrocarbon salt, sulfonyloxy ketone and triaryl silica ether.
The water solublity defoamer is dimethicone.
The water solublity levelling agent is polyether-modified dimethione.
The water solublity anti-settling agent is aerosil.
The water-soluble nano mill base is water-soluble nano black wash, the blue slurry of water-soluble nano, in the purple slurry of water-soluble nano
It is a kind of.
The pure water diluent is deionized water.
A kind of preparation method of the coloured nanometer UV coating of flowable carbon fibre materials, magnalium material water solublity, it
Comprise the following steps,
(1)Successively according to water-soluble acrylic synthetic resin, pure water diluent, soluble polyurethane synthetic resin, water solublity third
The order of olefin(e) acid resin is fed intake;
(2)Feed intake and finish rear seal-cover dispersion machine lid, open dispersion machine dispersion, rotating speed is controlled in 1000 r/min, makes water solublity
Acrylic acid synthetic resin, soluble polyurethane synthetic resin, water soluble acrylic resin and pure water diluent are sufficiently stirred for 1 hour
More than
(3)Again by water-soluble light trigger, water solublity defoamer, water solublity levelling agent, water solublity anti-settling agent, water-soluble nano color
Slurry and water-soluble aluminum silver paste are added, and dispersion machine is stirred more than 2 hours;
(4)Often disperse half an hour, the lower dispersed homogeneous degree of observation, the temperature of dispersion cup is not above 50 DEG C ± 5 DEG C.
Embodiment 3:
A kind of flowable carbon fibre materials of the present invention, the coloured nanometer UV coating of magnalium material water solublity, by weight
Amount percentages, it includes following components,
(1)Water-soluble acrylic synthetic resin 46%;
(2)Soluble polyurethane synthetic resin 25%;
(3)Water soluble acrylic resin 7%;
(4)Water-soluble light trigger 5.5%;
(5)Water solublity defoamer 0.28%;
(6)Water solublity levelling agent 0.65%;
(7)Water solublity anti-settling agent 2.7%;
(8)Water-soluble nano mill base 3.1%;
(9)Water-soluble aluminum silver paste 5.5%;
(10)Pure water diluent 11%.
The water-soluble acrylic synthetic resin is water-borne acrylic resin, hydroxypropyl acrylate, acrylic acid, metering system
Acid, the quarternary copolymerized synthetic of styrene.
Contain hydroxyl, ehter bond, unsaturated bond in the soluble polyurethane synthetic resin.
The water-soluble light trigger is diazol, diaryl group iodized salt, triaryl sulfonium salts, alkyl sulfosalt, ferrum virtue
One kind in hydrocarbon salt, sulfonyloxy ketone and triaryl silica ether.
The water solublity defoamer is dimethicone.
The water solublity levelling agent is polyether-modified dimethione.
The water solublity anti-settling agent is aerosil.
The water-soluble nano mill base is water-soluble nano black wash, the blue slurry of water-soluble nano, in the purple slurry of water-soluble nano
It is a kind of.
The pure water diluent is deionized water.
A kind of preparation method of the coloured nanometer UV coating of flowable carbon fibre materials, magnalium material water solublity, it
Comprise the following steps,
(1)Successively according to water-soluble acrylic synthetic resin, pure water diluent, soluble polyurethane synthetic resin, water solublity third
The order of olefin(e) acid resin is fed intake;
(2)Feed intake and finish rear seal-cover dispersion machine lid, open dispersion machine dispersion, rotating speed is controlled in 1100 r/min, makes water solublity
Acrylic acid synthetic resin, soluble polyurethane synthetic resin, water soluble acrylic resin and pure water diluent are sufficiently stirred for 1 hour
More than
(3)Again by water-soluble light trigger, water solublity defoamer, water solublity levelling agent, water solublity anti-settling agent, water-soluble nano color
Slurry and water-soluble aluminum silver paste are added, and dispersion machine is stirred more than 2 hours;
(4)Often disperse half an hour, the lower dispersed homogeneous degree of observation, the temperature of dispersion cup is not above 50 DEG C ± 5 DEG C.
The present invention does not contain oil-based solvent by accurate component proportion and rigorous procedure of processing, the product 100% of manufacture,
For the thick liquid that can be flowed under room temperature, facilitate latting drown to use or directly use, can apply in electronic product, metal system
Product, plasthetics and other 3C electronic products, application extensively, do not result in air V OC and pollute, room temperature good fluidity,
The dissolving of travelling trader's player whose turn comes next oiliness diluent is not needed, easy to use, product intersolubility is good, can recoat, and paint film property is excellent, this
Bright preparation technology does not use solvent dehydration, therefore no any solvent introduces product using dispersion reaction at a high speed.
The invention provides a kind of thinking and method, implement the method and approach of the technical scheme a lot, above institute
States only be the preferred embodiment of the present invention, it is noted that for those skilled in the art, without departing from
On the premise of the principle of the invention, some improvements and modifications can also be made, these improvements and modifications also should be regarded as the guarantor of the present invention
Shield scope, in the present embodiment, clearly each ingredient not can use prior art to be realized.
Claims (10)
1. the coloured nanometer UV coating of a kind of flowable carbon fibre materials, magnalium material water solublity, it is characterised in that:By weight
Amount percentages, it includes following components,
(1)Water-soluble acrylic synthetic resin 40%-47%;
(2)Soluble polyurethane synthetic resin 23%-26%;
(3)Water soluble acrylic resin 5%-8%;
(4)Water-soluble light trigger 4%-6%;
(5)Water solublity defoamer 0.2%-0.3%;
(6)Water solublity levelling agent 0.5%-0.7%;
(7)Water solublity anti-settling agent 2%-3%;
(8)Water-soluble nano mill base 2%-3.3%;
(9)Water-soluble aluminum silver paste 4%-6%;
(10)Pure water diluent 7%-12%.
2. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:The water-soluble acrylic synthetic resin is water-borne acrylic resin, hydroxypropyl acrylate, acrylic acid, methyl
The quarternary copolymerized synthetic of acrylic acid, styrene.
3. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:Contain hydroxyl, ehter bond, unsaturated bond in the soluble polyurethane synthetic resin.
4. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:The water-soluble light trigger is diazol, diaryl group iodized salt, triaryl sulfonium salts, alkyl sulfosalt, ferrum
One kind in arene salt, sulfonyloxy ketone and triaryl silica ether.
5. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:The water solublity defoamer is dimethicone.
6. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:The water solublity levelling agent is polyether-modified dimethione.
7. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:The water solublity anti-settling agent is aerosil.
8. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:The water-soluble nano mill base is water-soluble nano black wash, the blue slurry of water-soluble nano, in the purple slurry of water-soluble nano
One kind.
9. the coloured nanometer UV coating of flowable carbon fibre materials according to claim 1, magnalium material water solublity,
It is characterized in that:The pure water diluent is deionized water.
10. a kind of flowable carbon fibre materials according to claim 1, coloured nanometer UV of magnalium material water solublity
The preparation method of coating, it is characterised in that:It comprises the following steps,
(1)Successively according to water-soluble acrylic synthetic resin, pure water diluent, soluble polyurethane synthetic resin, water solublity third
The order of olefin(e) acid resin is fed intake;
(2)Feed intake and finish rear seal-cover dispersion machine lid, open dispersion machine dispersion, rotating speed is controlled in 800-1200 r/min, makes water
Soluble acrylic synthetic resin, soluble polyurethane synthetic resin, water soluble acrylic resin and pure water diluent are sufficiently stirred for 1
More than hour
(3)Again by water-soluble light trigger, water solublity defoamer, water solublity levelling agent, water solublity anti-settling agent, water-soluble nano color
Slurry and water-soluble aluminum silver paste are added, and dispersion machine is stirred more than 2 hours;
(4)Often disperse half an hour, the lower dispersed homogeneous degree of observation, the temperature of dispersion cup is not above 50 DEG C ± 5 DEG C.
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CN201610976889.6A CN106519841A (en) | 2016-11-08 | 2016-11-08 | Flowable carbon fiber and magnalium alloy type water-soluble colored nanometer UV coating and preparation method thereof |
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Cited By (2)
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CN107129731A (en) * | 2017-04-28 | 2017-09-05 | 江苏巨珩新材料科技有限公司 | Carbon fiber and plastic surface apply UV coating and preparation method thereof with coloured nanometer list |
CN110016273A (en) * | 2019-04-28 | 2019-07-16 | 刘子瑄 | A kind of water paint and preparation method thereof in plastic metal class material |
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CN102977753A (en) * | 2011-09-02 | 2013-03-20 | 深圳市宝光工业有限公司 | Aqueous UV paint and preparation method thereof |
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CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107129731A (en) * | 2017-04-28 | 2017-09-05 | 江苏巨珩新材料科技有限公司 | Carbon fiber and plastic surface apply UV coating and preparation method thereof with coloured nanometer list |
CN110016273A (en) * | 2019-04-28 | 2019-07-16 | 刘子瑄 | A kind of water paint and preparation method thereof in plastic metal class material |
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