CN104513590A - High-corrosion resistance two-component waterborne epoxy coating capable of quickly drying at room temperature - Google Patents

High-corrosion resistance two-component waterborne epoxy coating capable of quickly drying at room temperature Download PDF

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Publication number
CN104513590A
CN104513590A CN201410806772.4A CN201410806772A CN104513590A CN 104513590 A CN104513590 A CN 104513590A CN 201410806772 A CN201410806772 A CN 201410806772A CN 104513590 A CN104513590 A CN 104513590A
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China
Prior art keywords
component
room temperature
aqueous epoxy
epoxy coating
temperature quick
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Granted
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CN201410806772.4A
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Chinese (zh)
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CN104513590B (en
Inventor
李明
丁武斌
杜传芹
王自龙
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Shanghai Hilong Shine New Material Co., Ltd.
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HILONG PETROLEUM INDUSTRY GROUP Co Ltd
SHANGHAI HILONG SHINE NEW MATERIAL CO Ltd
SHANGHAI HILONG OIL CHEMICAL RESEARCH INSTITUTE
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a high-corrosion resistance two-component waterborne epoxy coating capable of quickly drying at the room temperature. The high-corrosion resistance two-component waterborne epoxy coating capable of quickly drying at the room temperature comprises a component A and a component B, wherein the component A comprises the following raw materials in percentage by weight: 50-60% of a waterborne epoxy emulsion, 0.5-1.5% of a defoamer, 1-2% of a dispersing agent, 6.5-15% of titanium dioxide, 17-24% of talcum powder and 7-15.5% of anti-rust pigment; the component B comprises the following raw materials in percentage by weight: 45-55% of a waterborne epoxy curing agent, 42-50% of deionized water and 3-5% of a cosolvent; before coating, the component A and the component B are mixed in a weight ratio of A: B of (5.0-6.5): 1 for use. The high-corrosion resistance two-component waterborne epoxy coating capable of quickly drying at the room temperature overcomes the defect of a solvent-type coating, is low in VOC (volatile organic compound) content, can quickly cure at the room temperature, is excellent in corrosion resistance: a 40-60-micron dry film has the salt fog resistance of up to 750 hours, and has a popularization and application value.

Description

The high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying
Technical field
The present invention relates to technical field of coatings, be specifically related to the high anticorrosion double-component aqueous epoxy coating of a kind of room temperature quick-drying.
Background technology
At present, the coating mainly solvent based coating that anticorrosive coating system is used.Solvent based coating can discharge a large amount of VOC(volatile organic compoundss---and this refers to that class volatile organic matter that can produce harm), inflammable and explosive, easy contaminate environment, is unfavorable for the health of human body.In addition, existing solvent based coating, as reached good preservative effect, generally needs thicker coating, if under the low rete state of 40 ~ 60 microns, the time of phthalic resin coating salt spray resistance is generally no more than 150 hours, and epoxypaint is also difficult to reach 500 hours.Along with more and more stricter to environmental requirement of coating industry, develop low VOC, environmental friendliness, the water-borne coatings with excellent antiseptic property becomes the trend of industry development.
Summary of the invention
The object of the invention is to the deficiency solving above-mentioned solvent based coating, there is provided a kind of room temperature quick-drying high anticorrosion double-component aqueous epoxy coating, its VOC content is low, can fast setting under room temperature, there is excellent antiseptic property simultaneously: salt spray resistance was more than 750 hours under the photopolymer layer state of 40 ~ 60 microns, had significant Social benefit and economic benefit.
For achieving the above object, this invention takes following technical scheme.
The high anticorrosion double-component aqueous epoxy coating of a kind of room temperature quick-drying, comprise component A and B component, it is characterized in that, in described component A, the weight percent of each raw material is:
Aqueous epoxy emulsion 50 ~ 60%;
Defoamer 0.5 ~ 1.5%;
Dispersion agent 1 ~ 2%;
Titanium dioxide 6.5 ~ 15%;
Talcum powder 17 ~ 24%;
Rust-stabilising pigment 7 ~ 15.5%;
In described B component, the weight percent of each raw material is:
Aqueous epoxy curing agent 45 ~ 55%;
Deionized water 42 ~ 50%;
Solubility promoter 3 ~ 5%;
By described component A, A:B=5.0 ~ 6.5:1 is used in combination by weight with described B component before application.
Optionally, described aqueous epoxy emulsion is Ancarez AR555.
Optionally, described aqueous epoxy curing agent is Anquamine 419.
Optionally, described defoamer is the one of Surfynol DF58 or Airase 5300.
Optionally, described dispersion agent is the one of Disperbyk 190 or ZetaSperse 3600.
Optionally, described talcum powder particle diameter is 800 ~ 2000 orders.
Optionally, described solubility promoter is propylene glycol monomethyl ether.
Optionally, described rust-stabilising pigment is phosphoric acid salt or silicophosphate class pigment.
The positively effect of the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying of the present invention is:
VOC content is low, can fast setting under room temperature, has excellent antiseptic property: salt spray resistance reaches 750 hours under the photopolymer layer state of 40 ~ 60 microns, has significant Social benefit and economic benefit.
Embodiment
Below provide the embodiment of the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying of the present invention, 3 embodiments are provided.But it should be pointed out that enforcement of the present invention is not limited to following embodiment.
embodiment 1
(1)the high anticorrosion double-component aqueous epoxy coating of a kind of room temperature quick-drying, comprise component A and B component, in described component A, the weight percent of each raw material is:
Aqueous epoxy emulsion 50%, adopt that air Chemicals company limited produces, product are called Ancarez AR555, solid content is the product of 55%.
Defoamer 0.5%, adopts air Chemicals company limited to produce ,product are called the product of Surfynol DF58.
Dispersion agent 2.0%, adopts that air Chemicals company limited produces, that product are called ZetaSperse3600 product.
Titanium dioxide 15%, adopts that E.I.Du Pont Company produces, that product are called R-902 product.
Talcum powder 17%, adopt Yong'an City prestige to pause 1250 order talcum powder that ultra-fine mineral products company limited produces.
Rust-stabilising pigment 15.5%, adopts the APW-II type aluminium triphosphate that Guangxi Xinjing Sci. & Tech. Co., Ltd. produces.
In described B component, the weight percent of each raw material is:
Aqueous epoxy curing agent 55%, adopts that air Chemicals company limited produces, that product are called Anquamine419 product.
Deionized water 42%, adopt specific conductivity≤0.50us/cm, water temperature is the deionized water of 25 DEG C.
Solvent 3%, adopts propylene glycol monomethyl ether commercially available.
(2) preparation method of the high anticorrosion double-component aqueous epoxy coating of the room temperature quick-drying of embodiment 1, comprises the following steps:
(1) raw material of component A and B component is prepared by described weight percent
The weight percent (introduction see above) of each raw material in component A;
The weight percent (introduction see above) of each raw material in B component.
(2) mixing of component A raw material and packaging
1. the defoamer after the aqueous epoxy emulsion of formula half amount and weighing, dispersion agent are added high speed dispersor mixing successively.
2. the titanium dioxide after slowly adding weighing successively under 2m/s rotating speed, talcum powder, rust-stabilising pigment, add the aqueous epoxy emulsion of residue half amount to control the viscosity of dispersion simultaneously again; With the fineness of 10m/s high speed dispersion to 20 ~ 30 micron.
3. by component A independent packaging.
(3) mixing of B component raw material and packaging
1. taking aqueous epoxy curing agent by formula ratio is contained in another clean container, and the deionized water slowly add weighing successively under 4m/s rotating speed after and solvent, be uniformly dispersed.
2. by B component independent packaging.
(3)the use of the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying prepared by embodiment 1
Before application, component A packaging is packed with B component and takes apart, after mixing with B component weight ratio A:B=6.5:1 by component A, carry out application.
embodiment 2
(1) the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying, comprise component A and B component, in described component A, the weight percent of each raw material is:
Aqueous epoxy emulsion 60%, (raw material of employing is with embodiment 1).
Defoamer 1.5%, adopts that air Chemicals company limited produces, that product are called Airase 5300 product.
Dispersion agent 1.0%, adopts that Bi Ke chemical assistant company produces, that product are called Disperbyk 190 product.
Titanium dioxide 6.5%, (raw material of employing is with embodiment 1).
Talcum powder 24%, (raw material of employing is with embodiment 1).
Rust-stabilising pigment 7%, adopts that Halox company of the U.S. produces, that product are called HALOX SZP-391 product.
In described B component, the weight percent of each raw material is:
Aqueous epoxy curing agent 45%, (raw material of employing is with embodiment 1).
Deionized water 50%, (raw material of employing is with embodiment 1).
Solvent 5%, (raw material of employing is with embodiment 1).
(2) preparation method's (with embodiment 1) of the high anticorrosion double-component aqueous epoxy coating of the room temperature quick-drying of embodiment 2.
(3) use of the high anticorrosion double-component aqueous epoxy coating of the room temperature quick-drying of embodiment 2 preparation
Basic with embodiment 1, its difference is the weight ratio of component A and B component is 5.0:1.
Embodiment 3
(1) the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying, comprise component A and B component, in described component A, the weight percent of each raw material is:
Aqueous epoxy emulsion 55%, (raw material of employing is with embodiment 1).
Defoamer 0.8%, adopts that air Chemicals company limited produces, that product are called Surfynol DF58 product.
Dispersion agent 1.5%, adopts that Bi Ke chemical assistant company produces, that product are called Disperbyk 190 product.
Titanium dioxide 10.5%, (raw material of employing is with embodiment 1).
Talcum powder 19.5%, (raw material of employing is with embodiment 1).
Rust-stabilising pigment 12.7%, adopts the APW-II type aluminium triphosphate that Guangxi Xinjing Sci. & Tech. Co., Ltd. produces.
In B component, the weight percent of each raw material is:
Aqueous epoxy curing agent 52.4%, (raw material of employing is with embodiment 1).
Deionized water 44%, (raw material of employing is with embodiment 1).
Solvent 3.6%, (raw material of employing is with embodiment 1).
(2) preparation method's (with embodiment 1) of the high anticorrosion double-component aqueous epoxy coating of the room temperature quick-drying of embodiment 3.
(3) use of the high anticorrosion double-component aqueous epoxy coating of the room temperature quick-drying of embodiment 3 preparation
Basic with embodiment 1, its difference is the weight ratio of component A and B component is 5.62:1.
To the detection of the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying prepared by embodiment 1-3
By GB/T 6753.1; GB/T 1728; GB/T 9286; GB/T 1732 standard and ASTM D 522; The high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying prepared by ASTM B 117 couples of embodiment 1-3 detects, and detected result is in table 1.
table 1.the performance table of the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying prepared by embodiment 1-3
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the two weight percentages of the present invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (8)

1. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying, comprise component A and B component, it is characterized in that, in described component A, the weight percent of each raw material is:
aqueous epoxy emulsion 50~ 60%;
Defoamer 0.5 ~ 1.5%;
Dispersion agent 1 ~ 2%;
Titanium dioxide 6.5 ~ 15%;
Talcum powder 17 ~ 24%;
Rust-stabilising pigment 7 ~ 15.5%;
In described B component, the weight percent of each raw material is:
Aqueous epoxy curing agent 45 ~ 55%;
Deionized water 42 ~ 50%;
Solubility promoter 3 ~ 5%;
By described component A, A:B=5.0 ~ 6.5:1 is used in combination by weight with described B component before application.
2. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying according to claim 1, it is characterized in that, described aqueous epoxy emulsion is Ancarez AR555.
3. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying according to claim 1, it is characterized in that, described aqueous epoxy curing agent is Anquamine 419.
4. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying according to claim 1, it is characterized in that, described defoamer is the one of Surfynol DF58 or Airase 5300.
5. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying according to claim 1, it is characterized in that, described dispersion agent is the one of Disperbyk 190 or ZetaSperse 3600.
6. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying according to claim 1, it is characterized in that, described talcum powder particle diameter is 800 ~ 2000 orders.
7. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying according to claim 1, it is characterized in that, described solubility promoter is propylene glycol monomethyl ether.
8. the high anticorrosion double-component aqueous epoxy coating of room temperature quick-drying according to claim 1, it is characterized in that, described rust-stabilising pigment is phosphoric acid salt or silicophosphate class pigment.
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047048A (en) * 2016-05-24 2016-10-26 杭州萧山临江化工制品有限公司 Salt spray resistant coating for marine steel structures
CN106047087A (en) * 2016-08-22 2016-10-26 湖南太子化工涂料有限公司 Room temperature self-drying two-component epoxy heavy anti-corrosion prime coat and preparation method thereof
CN106634446A (en) * 2016-12-30 2017-05-10 重庆美固环保科技有限公司 Double-component aqueous functional paint for internal wall
CN107236385A (en) * 2017-06-30 2017-10-10 苏州日新水性涂料有限公司 A kind of epoxy is from dry ash sealing wax
CN107236427A (en) * 2017-07-07 2017-10-10 珠海富邦新材料科技有限公司 Aqueous rolling spray pull head paint and preparation method and application
CN107474693A (en) * 2017-08-29 2017-12-15 河北晨阳工贸集团有限公司 Low-surface-energy metal water-base epoxy paint base composition and preparation method thereof
CN107474684A (en) * 2017-07-18 2017-12-15 河北晨阳工贸集团有限公司 A kind of epoxy interior wall sealing wax and preparation method thereof
CN107892858A (en) * 2017-11-22 2018-04-10 纳梁(上海)新材料科技有限公司 A kind of new aqueous double-component epoxy hammer paint
CN108864891A (en) * 2018-06-05 2018-11-23 河北晨阳工贸集团有限公司 A kind of two-component quick-drying abrasion-resistance water epoxy coating and preparation method thereof
CN109401474A (en) * 2018-11-01 2019-03-01 中山科邦化工材料技术有限公司 A kind of aqueous quick drying paint and preparation method thereof
CN111019483A (en) * 2019-12-25 2020-04-17 清远雅克化工有限公司 High-performance water-based epoxy coating and preparation method thereof
CN112708328A (en) * 2020-12-29 2021-04-27 上海海隆赛能新材料有限公司 Heat-preservation and heat-insulation protective coating and preparation method thereof

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047048A (en) * 2016-05-24 2016-10-26 杭州萧山临江化工制品有限公司 Salt spray resistant coating for marine steel structures
CN106047087A (en) * 2016-08-22 2016-10-26 湖南太子化工涂料有限公司 Room temperature self-drying two-component epoxy heavy anti-corrosion prime coat and preparation method thereof
CN106634446A (en) * 2016-12-30 2017-05-10 重庆美固环保科技有限公司 Double-component aqueous functional paint for internal wall
CN107236385A (en) * 2017-06-30 2017-10-10 苏州日新水性涂料有限公司 A kind of epoxy is from dry ash sealing wax
CN107236427A (en) * 2017-07-07 2017-10-10 珠海富邦新材料科技有限公司 Aqueous rolling spray pull head paint and preparation method and application
CN107474684A (en) * 2017-07-18 2017-12-15 河北晨阳工贸集团有限公司 A kind of epoxy interior wall sealing wax and preparation method thereof
CN107474693A (en) * 2017-08-29 2017-12-15 河北晨阳工贸集团有限公司 Low-surface-energy metal water-base epoxy paint base composition and preparation method thereof
CN107892858A (en) * 2017-11-22 2018-04-10 纳梁(上海)新材料科技有限公司 A kind of new aqueous double-component epoxy hammer paint
CN108864891A (en) * 2018-06-05 2018-11-23 河北晨阳工贸集团有限公司 A kind of two-component quick-drying abrasion-resistance water epoxy coating and preparation method thereof
CN109401474A (en) * 2018-11-01 2019-03-01 中山科邦化工材料技术有限公司 A kind of aqueous quick drying paint and preparation method thereof
CN111019483A (en) * 2019-12-25 2020-04-17 清远雅克化工有限公司 High-performance water-based epoxy coating and preparation method thereof
CN112708328A (en) * 2020-12-29 2021-04-27 上海海隆赛能新材料有限公司 Heat-preservation and heat-insulation protective coating and preparation method thereof

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