CN106519322A - Non-slip rubber material - Google Patents
Non-slip rubber material Download PDFInfo
- Publication number
- CN106519322A CN106519322A CN201610988850.6A CN201610988850A CN106519322A CN 106519322 A CN106519322 A CN 106519322A CN 201610988850 A CN201610988850 A CN 201610988850A CN 106519322 A CN106519322 A CN 106519322A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a non-slip rubber material. The non-slip rubber material is composed of two parts of raw materials; the first part is composed of natural rubber, butadiene rubber, butadiene styrene rubber, zinc oxide, octadecanoic acid, age resisters, reinforcing agents, polyethylene glycol, coumarone resin, softening agents and glass fibers; and the second part is composed of vulcanizing agents and vulcanization accelerators, wherein the vulcanizing agents account for 0.9-1.1% of the total weight of the first part, and the vulcanization accelerators account for 0.59-1.01% of the total weight of the first part. According to the formula, the natural rubber is adopted as the main body material, the adverse factor that a rubber sole becomes hard in winter is overcome according to the particularity of a molecular structure of the natural rubber, the special composite, namely the glass fibers are added into the rubber material, the glass fibers are organically integrated with the rubber material through the resin and act like small nails after buried into the rubber sole, and therefore the rubber sole can feel like fine abrasive paper and the effect of preventing slip on ice surfaces can be realized.
Description
Technical field
The invention belongs to field of rubber technology, and in particular to a kind of on-slip sizing material.
Background technology
Generally winter temperature is relatively low, and current footwear glue bottom is easily hardened, particularly the particularity of winter ice face,
Footwear glue bottom is reduced with the coefficient of friction of ice face, and the non-skid property at footwear glue bottom is decreased obviously, and causes the easy Fall injuries of human body.
The content of the invention
The purpose of the present invention is that as solving the deficiencies in the prior art and provides a kind of on-slip sizing material suitable for ice face.
The purpose of the present invention is realized in the following manner：
A kind of on-slip sizing material, is made up of two parts raw material, and Part I is made up of the raw material of following weight portion：Natural rubber
30.72-31.79 parts, butadiene rubber 9.00-10.07 parts, butadiene-styrene rubber 9.54-10.60 parts, Zinc Oxide 2.17-2.65 part, ten
Eight alkanoic acid 1.59-2.64 parts, age resistor 1.17-1.44 parts, reinforcing agent 25.07-27.61 parts, Polyethylene Glycol 1.42-1.53 parts,
Coumarone indene resin 1.59-2.68 parts, softening agent 9.53-10.10 parts, glass fibre 1.06-1.59 parts；Part II raw material is by sulfur
Agent and vulcanization accelerator composition, 0.9-1.1% of the vulcanizing agent for Part I raw material gross weight, vulcanization accelerator is Part I
The 0.59-1.01% of raw material gross weight.
N- isopropyl-N '-diphenyl-para-phenylene diamine and 0.63-0.79 weight of the age resistor by 0.54-0.65 weight portions
2,2,4- trimethyl -1,2- dihyaroquinolines the composition of part.
The reinforcing agent is white carbon.
The softening agent is machine oil.
The vulcanizing agent is sulfur.
The vulcanization accelerator is made up of altax, accelerant CZ and diphenylguanidine；Altax is Part I raw material
The 0.09-0.11% of gross weight, accelerant CZ for Part I raw material gross weight 0.3-0.5%, diphenylguanidine are Part I raw material
The 0.2-0.4% of gross weight.
The preparation method of insulation acid and alkali-resistance sizing material as above, comprises the following steps：
（1）After natural rubber is plasticated, add butadiene rubber, butadiene-styrene rubber and refine；
（2）In step（1）In add in the sizing material plasticated and anticipate impregnated glass fiber, mix homogeneously；
（3）By step（2）In the plastic cement input banbury for obtaining, successively by Zinc Oxide, octadecanoid acid, age resistor, coumarone
Resin, reinforcing agent, Polyethylene Glycol, softening agent input banbury mix homogeneously；
（4）In the logical radiating of flat machine pull-up after dumping, vulcanizing agent and accelerator is added, mixing is uniform.
This formula using the particularity of its molecular structure, overcomes glue bottom in the winter time using natural rubber as material of main part
The unfavorable factor that glue bottom is hardened under environment, adds special composite material-glass fibre, in addition in sizing material using resin by glass
Fiber is organically blended in sizing material with sizing material, and glass fibre is embedded in rear such as nail small one by one in glue bottom, makes rubber glue
The effect in ice face on-slip is played just like the sensation as fine sandpaper in bottom.
Jing third party's test chamber is tested, and made by this sizing material, there is being foaming agent at glue bottom（SLS）It is above the ceramic tile of solution, front
The anti-skidding coefficient of friction 0.45 of the palm, the anti-skidding coefficient of friction 0.37 of heel reach EU criteria requirement.
Specific embodiment
Embodiment 1：
A kind of on-slip sizing material, is made up of two parts raw material, and Part I is made up of the raw material of following weight portion：Natural rubber
30.72-31.79 parts, butadiene rubber 9.00-10.07 parts, butadiene-styrene rubber 9.54-10.60 parts, Zinc Oxide 2.17-2.65 part, ten
Eight alkanoic acid 1.59-2.64 parts, age resistor 1.17-1.44 parts, reinforcing agent 25.07-27.61 parts, Polyethylene Glycol 1.42-1.53 parts,
Coumarone indene resin 1.59-2.68 parts, softening agent 9.53-10.10 parts, glass fibre 1.06-1.59 parts；Part II raw material is by sulfur
Agent and vulcanization accelerator composition, 0.9-1.1% of the vulcanizing agent for Part I raw material gross weight, vulcanization accelerator is Part I
The 0.59-1.01% of raw material gross weight.
Preferably, N- isopropyl-N '-diphenyl-para-phenylene diamine and 0.63- of the age resistor by 0.54-0.65 weight portions
2,2,4- trimethyl -1,2- dihyaroquinolines the composition of 0.79 weight portion；The reinforcing agent is white carbon；The softening agent is machine
Oil；The vulcanizing agent is sulfur；The vulcanization accelerator is made up of altax, accelerant CZ and diphenylguanidine；Altax is
The 0.09-0.11% of Part I raw material gross weight, accelerant CZ for Part I raw material gross weight 0.3-0.5%, diphenylguanidine is
The 0.2-0.4% of Part I raw material gross weight.
The preparation method of insulation acid and alkali-resistance sizing material as above, comprises the following steps：
（1）After natural rubber is plasticated, add butadiene rubber, butadiene-styrene rubber and refine；
（2）In step（1）In add in the sizing material plasticated and anticipate impregnated glass fiber, make preimpregnation adhesive
Glass fibre can be combined together with rubber well, close uniform；
（3）By step（2）In the plastic cement input banbury for obtaining, successively by Zinc Oxide, octadecanoid acid, age resistor, coumarone
Resin, reinforcing agent, Polyethylene Glycol, softening agent input banbury mix homogeneously；Avoid the conglomerations such as softening agent；
（4）In the logical radiating of flat machine pull-up after dumping, vulcanizing agent and accelerator is added, beat triangle bag and perpendicular bag is each 3 times, and knead equal
It is even.
Embodiment 2
A kind of on-slip sizing material, is made up of two parts raw material, and Part I is made up of following raw material：Natural rubber 31.1Kg, suitable fourth
9.5 Kg of rubber, 10.3 Kg of butadiene-styrene rubber, 2.2 Kg of Zinc Oxide, 1.59 Kg of octadecanoid acid, 0.6 Kg of antioxidant 4010NA and
0.68 Kg of anti-aging agent RD, 26.6 Kg of reinforcing agent white carbon, 1.5 Kg of Polyethylene Glycol, 2.4 Kg of coumarone indene resin, softening agent
10.05 Kg of machine oil, 1.4 Kg of glass fibre, Part II raw material are made up of vulcanizing agent and vulcanization accelerator, and vulcanizing agent is sulfur
Sulphur, accounts for the 0.9% of Part I raw material gross weight, i.e. 0.88Kg；Vulcanization accelerator is by altax, accelerant CZ and diphenylguanidine group
Into；Altax for Part I raw material gross weight 0.09%, i.e. 0.09Kg, accelerant CZ are Part I raw material gross weight
0.3%, i.e. 0.29Kg, accelerator for Part I raw material gross weight 0.4%, i.e. 0.39Kg；Preparation method is with embodiment 1.
The on-slip sizing compound formula that embodiment of the present invention 3-20 is provided is shown in Table 1-3, and other are with embodiment 1.
Above-described is only the preferred embodiment of the present invention, it is noted that for a person skilled in the art, not
Under the premise of departing from general idea of the present invention, some changes and improvements can also be made, these should also be considered as the protection of the present invention
Scope.
Claims (7)
1. a kind of on-slip sizing material, it is characterised in that be made up of two parts raw material, Part I is made up of the raw material of following weight portion：
Natural rubber 30.72-31.79 parts, butadiene rubber 9.00-10.07 parts, butadiene-styrene rubber 9.54-10.60 parts, Zinc Oxide 2.17-
2.65 parts, octadecanoid acid 1.59-2.64 parts, age resistor 1.17-1.44 parts, reinforcing agent 25.07-27.61 parts, Polyethylene Glycol
1.42-1.53 parts, coumarone indene resin 1.59-2.68 parts, softening agent 9.53-10.10 parts, glass fibre 1.06-1.59 parts；Second
Part material is made up of vulcanizing agent and vulcanization accelerator, and 0.9-1.1% of the vulcanizing agent for Part I raw material gross weight, sulfuration promote
0.59-1.01% of the agent for Part I raw material gross weight.
2. on-slip sizing material as claimed in claim 1, it is characterised in that N- isopropyl of the age resistor by 0.54-0.65 weight portions
2,2,4- trimethyl -1,2- dihyaroquinolines the composition of base-N '-diphenyl-para-phenylene diamine and 0.63-0.79 weight portions.
3. on-slip sizing material as claimed in claim 1, it is characterised in that the reinforcing agent is white carbon.
4. on-slip sizing material as claimed in claim 1, it is characterised in that the softening agent is machine oil.
5. on-slip sizing material as claimed in claim 1, it is characterised in that the vulcanizing agent is sulfur.
6. on-slip sizing material as claimed in claim 1, it is characterised in that the vulcanization accelerator by altax, accelerant CZ and
Diphenylguanidine is constituted；0.09-0.11% of the altax for Part I raw material gross weight, accelerant CZ are Part I raw material gross weight
0.3-0.5%, diphenylguanidine for Part I raw material gross weight 0.2-0.4%.
7. as described in any one of claim 1-6 insulation acid and alkali-resistance sizing material preparation method, it is characterised in that including following step
Suddenly：
（1）After natural rubber is plasticated, add butadiene rubber, butadiene-styrene rubber and refine；
（2）In step（1）In add in the sizing material plasticated and anticipate impregnated glass fiber, mix homogeneously；
（3）By step（2）In the plastic cement input banbury for obtaining, successively by Zinc Oxide, octadecanoid acid, age resistor, coumarone
Resin, reinforcing agent, Polyethylene Glycol, softening agent input banbury mix homogeneously；
（4）In the logical radiating of flat machine pull-up after dumping, vulcanizing agent and accelerator is added, mixing is uniform.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610988850.6A CN106519322A (en) | 2016-11-10 | 2016-11-10 | Non-slip rubber material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610988850.6A CN106519322A (en) | 2016-11-10 | 2016-11-10 | Non-slip rubber material |
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| Publication Number | Publication Date |
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| CN106519322A true CN106519322A (en) | 2017-03-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610988850.6A Pending CN106519322A (en) | 2016-11-10 | 2016-11-10 | Non-slip rubber material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107417998A (en) * | 2017-04-28 | 2017-12-01 | 黎明职业大学 | A kind of modification bamboo charcoal fiber rubber composite sole material and preparation method, application |
| CN110372928A (en) * | 2019-07-09 | 2019-10-25 | 佛山市南海创意鞋材有限公司 | A kind of sole slip limiting plate and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110258886A1 (en) * | 2010-04-26 | 2011-10-27 | Ku Do Moon | Slip-Resistant Rubber Composition, Outsole Using the Rubber Composition and Method of Manufacturing the Outsole |
| CN103965524A (en) * | 2014-05-20 | 2014-08-06 | 南京东亚橡塑制品有限公司 | Low-temperature-resistant sole material and preparation method thereof |
| CN104004237A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
| CN105602015A (en) * | 2015-11-14 | 2016-05-25 | 胡运冲 | Lightweight wear-resistant antiskiding rubber shoe sole material and preparation method thereof |
-
2016
- 2016-11-10 CN CN201610988850.6A patent/CN106519322A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110258886A1 (en) * | 2010-04-26 | 2011-10-27 | Ku Do Moon | Slip-Resistant Rubber Composition, Outsole Using the Rubber Composition and Method of Manufacturing the Outsole |
| CN103965524A (en) * | 2014-05-20 | 2014-08-06 | 南京东亚橡塑制品有限公司 | Low-temperature-resistant sole material and preparation method thereof |
| CN104004237A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
| CN105602015A (en) * | 2015-11-14 | 2016-05-25 | 胡运冲 | Lightweight wear-resistant antiskiding rubber shoe sole material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107417998A (en) * | 2017-04-28 | 2017-12-01 | 黎明职业大学 | A kind of modification bamboo charcoal fiber rubber composite sole material and preparation method, application |
| CN110372928A (en) * | 2019-07-09 | 2019-10-25 | 佛山市南海创意鞋材有限公司 | A kind of sole slip limiting plate and preparation method thereof |
| CN110372928B (en) * | 2019-07-09 | 2021-10-12 | 佛山市创意新材料科技有限公司 | Anti-slip sheet for shoe sole and preparation method thereof |
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Application publication date: 20170322 |
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