CN106518150A - Composite ceramsite prepared from water purification sludge and diatomite - Google Patents
Composite ceramsite prepared from water purification sludge and diatomite Download PDFInfo
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- CN106518150A CN106518150A CN201610951061.5A CN201610951061A CN106518150A CN 106518150 A CN106518150 A CN 106518150A CN 201610951061 A CN201610951061 A CN 201610951061A CN 106518150 A CN106518150 A CN 106518150A
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- diatomite
- clean water
- sludge
- water sludge
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Dispersion Chemistry (AREA)
- Treatment Of Sludge (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention relates to composite ceramsite prepared from water purification sludge and diatomite and a preparation method of the composite ceramsite and belongs to the field of inorganic nonmetallic materials. The composite ceramsite is prepared from raw materials in parts by weight as follows: 60-90 parts of water purification sludge, 20-30 parts of diatomite and 10-20 parts of calcium oxide. The preparation method of the composite ceramsite comprises preparation steps of mixing, pelletizing, drying, preheating and roasting. The water purification sludge produced in the production process of a water supply plant and waste diatomite used for auxiliary filtration in a brewery are used as raw materials, the dispose problem of the two wastes can be effectively solved, and wastes are treated by wastes by recycling.
Description
Technical field
The invention belongs to field of inorganic nonmetallic material, and in particular to a kind of clean water sludge and diatomite prepare for dirt
The composite haydite of water process.
Background technology
Clean water sludge is the accessory substance that waterworks is produced during purification raw water, and it mostlys come from filter back washing
The spoil disposal water of draining, sedimentation basin or depositing reservoir.Due to coagulant being added in raw water precipitation process and softens medicament, in sludge
Corresponding oxide and hydroxide, such as Fe can be contained2O3、SiO2、CaO、Mg(OH)2Deng clean water sludge almost contains raw water
The all elements and compound of the surface layer for being flowed through, based on inorganic constituents, the organic principle such as humus is less.Current water purification
Sludge carries out landfill disposal primarily as discarded object, both increased the production cost of waterworks, while also occupying a large amount of
Land resource, if improper the conducting oneself well of clean water sludge is put, there will be to environment produce " secondary pollution " danger.Due to clean water sludge
Main component it is similar to conventional clay, therefore clay can be replaced using clean water sludge to carry out the preparation of haydite, this is to dirt
The minimizing of mud, innoxious, recycling have positive meaning.
Diatomite is a kind of biological siliceous rock of porous property, its main component SiO2, also containing a small amount of iron calcium
The metal oxides such as magnalium, usual SiO2The more high then diatomite performance of content is better.There are on diatomite housing a large amount of rows in order
The micropore of row, therefore diatomaceous pore volume and specific surface area very big, bulk density very little, with stronger absorption property and mistake
Filter ability, is industrially commonly used in the aspects such as sewage disposal adsorbent, brewery's drainage, catalyst carrier.
At present for haydite does not have a proper definition, haydite belongs to a kind of light-weight aggregate, with reference to artificial light
The definition gathered materials:Haydite is that a kind of bulk density is less than 1100kg/m3, particle diameter possesses certain compression strength, surface in 5 ~ 20mm
There is the light-weight aggregate of the shell of ceramic or enamel.In view of using function, haydite is broadly divided into building ceramsite and water process pottery
Grain.Based on leca and haydites of book structure, clay material has drawn from arable land the haydite of current China, and shale materials need to exploit
Massif, this can cause, and land resource aggravation is nervous and ecological environment is destroyed, therefore utilizes with reference to solid waste resource recovery
Just there is important practical significance to develop novel ceramsite material.
Have some to be utilized respectively sludge or diatomite to prepare the patent of invention of haydite:CN101148348A discloses one
The method for planting preparing haydite by sintering urban domestic sewage sludge, with more than 70% city sludge as primary raw material, flyash and clay are
Auxiliary material, through drying, is pulverized and mixed, then obtains ceramic product through techniques such as batch mixing, extrusion forming, preheating, roastings.
CN102757255A discloses a kind of method that utilization clean water sludge prepares light ceramic with sewage sludge, with clean water sludge and dirt
Sewage sludge is primary raw material, is made using sintering technology.CN102491729A provide it is a kind of for micro-polluted water pretreatment
The preparation method of boiling water copper water-supply pipe haydite, the haydite is by a certain proportion of water supply plant dewatered sludge, modified zeolite powder and foaming
Agent in mass ratio 50 ~ 60%, 35% ~ 49%, 1% ~ 5% ratio uniform is blended in balling-up on comminutor, and roasting after drying raw meal is made pottery
Grain, is sieved after being cooled to room temperature and is obtained haydite finished product.CN102775120A discloses a kind of diatomite porous pottery
The preparation method of grain, the method is first by NaOH, waterglass and water according to 4:17:1:5 are mixed with maturing agent;According to matter
Amount 45% ~ 55% diatomite of percentage, 10% ~ 18% bentonite, 35% ~ 38% water uniformly mix, and are pressed into spheric granules;According to quality
Percentage is equipped with 20% ~ 30% flyash, 20% ~ 30% diatomite, 50% maturing agent and is uniformly mixed with shell powder;By above-mentioned system
The spheric granules got ready and shell powder are by 3:Roll in 1 mass ratio input stuffed dumplings machine and haydite is obtained.CN104785203A is public
A kind of production method of diatomite water purification haydite of cloth, the haydite is by diatomite and bentonite according to 10:1 mass ratio is passed through
The operations such as dispensing, mud processed, granulation, drying, roasting are made, and obtained haydite quality is penetrating, possesses adsorptivity and filterability, favorably
In the attachment and procreation of microorganism.
The content of the invention
It is an object of the invention to solve the problems, such as to producing secondary pollution to environment caused by water supply plant clean water sludge, while
Waste diatomite with reference to produced by brewery carries out solid waste resource recovery utilization, develops one kind using clean water sludge and silicon
Composite haydite prepared by diatomaceous earth.From the point of view of the composition of sludge, the organic matter and energy content of sludge is higher, can meet firing
When basic demand, but the SiO in sludge2And Al2O3Content is relatively low, individually with firing ceramsite by using sludge can not balling-up, because
This can be added with SiO2For the diatomite of main component, while a small amount of calcium oxide of blending is used as binding agent.
Technical scheme:The invention discloses composite haydite prepared by a kind of clean water sludge and diatomite, including following characteristics:
It is raw materials used for clean water sludge, diatomite, calcium oxide, mixing according to a certain percentage, balling-up, drying, 400 DEG C of preheating 25min,
900 ~ 1200 DEG C of roasting 30min are formed.
Composite haydite prepared by a kind of described clean water sludge and diatomite, it is characterised in that:It is raw materials used for water purification it is dirty
Mud, diatomite, calcium oxide, the ratio by mass:60 ~ 90 parts of clean water sludge;20 ~ 30 parts of diatomite;Calcium oxide 10 ~ 20
Part.
Further, the composite haydite that prepared by a kind of described clean water sludge and diatomite, it is characterised in that:The diatom
Soil is one or more of waste diatomite or ordinary silicon diatomaceous earth raw material that the brewery for reclaiming is used for drainage, and the raw material is adopted
During Retrieve beer factory drainage waste diatomite, need to carry out hydro-thermal method pretreatment to waste diatomite:Heating-up temperature is 160 DEG C, adds
The hot time is 6h, obtains the diatomite material for removing impurity.
The present invention has following beneficial effect:
1. the blending amount of sludge is up to more than 60%, and the fusing point of sludge is low, and the raising of sludge components can significantly reduce mixture
Fusing point, firing energy consumption reduces;Disposal clean water sludge can be processed on a large scale, realize the recycling of sludge, effectively solving
Secondary pollution problem existing for the traditional landfill stabilization of water supply plant clean water sludge.
2., with diatomite as auxiliary material, the waste diatomite produced for brewery's drainage provides a kind of the new of recycling
Approach, realizes the purpose of " treatment of wastes with processes of wastes against one another ".
3. preferably, pore structure is flourishing for composite haydite product strength obtained in, and water absorption rate is high, and absorption property is good, suitable to make
For material for water treatment.
4. this method practicality is advanced, simple to operate, with low cost, non-secondary pollution, can be by social benefit, ecological benefits
With economic benefit organic unity.
Description of the drawings
Fig. 1 prepares composite haydite sample for 1100 DEG C of sintering of clean water sludge and diatomite.
Specific embodiment
Embodiments of the present invention are illustrated below by way of specific instantiation, those skilled in the art can be by this specification
Disclosed content understands other advantages and effect of the present invention easily.The present invention can also pass through concrete realities different in addition
The mode of applying is carried out or applies, the every details in this specification can also based on different viewpoints with application, without departing from
Various modifications and changes are carried out under the spirit of the present invention.
Embodiment 1:
The present embodiment provides composite haydite prepared by a kind of clean water sludge and diatomite, and by weight calculating, its raw material includes:
80 parts of clean water sludge;
20 parts of diatomite;
10 parts of calcium oxide.
(1)Raw material prepares
Drying and processing is carried out at a temperature of 110 DEG C to clean water sludge.
If diatomite is the waste diatomite for brewery being recovered from for drainage, hydro-thermal method process is carried out to waste diatomite:Will
Diatomite is uniformly mixed with water, is placed in reactor, reactor is placed in constant temperature blast drying oven and heats 6 h, and heating-up temperature is
160 DEG C, diatomite is taken out after the completion of reaction, room temperature is naturally cooled to.Can be by hydro-thermal method by organic carbon therein, will
Organic matter condenses into small spherical particles, so that waste diatomite activity recovery.
According to above-mentioned weight ratio, pretreated clean water sludge, diatomite and calcium oxide are added water and is uniformly mixed, obtained
To mixture.
(2)Prepare balling-up
Mixture is processed into into spheroid, sphere diameter scope is 2cm ~ 5cm, spheroid is placed in electric heating constant temperature drying machine and is warming up to
105 DEG C of drying, obtain drying material.
(3)The pre-heat treatment
Drying material is placed in into cabinet-type electric furnace the pre-heat treatment:Heating rate is set as 10 DEG C/min, temperature is risen to from room temperature in electric furnace
400 DEG C, 25min is preheated at a temperature of 400 DEG C.By drying material preheating, mixing spheroid can be prevented effectively from and abruptly enter high temperature
Environment and cause rupture, while can also reduce the later stage roasting power consumption.
(4)Roasting spheroid
The spheroid that the pre-heat treatment is crossed roasting in cabinet-type electric furnace, heating rate are 10 DEG C/min, and sintering temperature is 1000 DEG C, roasting
The burning time is 30min, then naturally cools to room temperature, becomes finished product composite haydite.
Embodiment 2:
The present embodiment provides composite haydite prepared by a kind of clean water sludge and diatomite, and by weight calculating, its raw material includes:
80 parts of clean water sludge;
20 parts of diatomite;
10 parts of calcium oxide.
Preparation process:
(1)Raw material prepares
Drying and processing is carried out at a temperature of 110 DEG C to clean water sludge.
Diatomite is the waste diatomite for being recovered from brewery for drainage, carries out hydro-thermal method process to waste diatomite:By silicon
Diatomaceous earth is uniformly mixed with water, is placed in reactor, reactor is placed in constant temperature blast drying oven and heats 6 h, and heating-up temperature is 160
DEG C, diatomite is taken out after the completion of reaction, room temperature is naturally cooled to.
According to above-mentioned weight ratio, pretreated clean water sludge, diatomite and calcium oxide are added water and is uniformly mixed, obtained
To mixture.
(2)Prepare balling-up
By mixture hand rubbing into spheroid, sphere diameter scope is 2cm ~ 5cm, spheroid is placed in electric heating constant temperature drying machine and is warming up to
105 DEG C of drying, obtain drying material.
(3)The pre-heat treatment
Drying material is placed in into cabinet-type electric furnace the pre-heat treatment:Heating rate is set as 10 DEG C/min, temperature is risen to from room temperature in electric furnace
400 DEG C, 25min is preheated at a temperature of 400 DEG C.By drying material preheating, mixing spheroid can be prevented effectively from and abruptly enter high temperature
Environment and cause rupture, while can also reduce the later stage roasting power consumption.
(4)Roasting spheroid
The spheroid that the pre-heat treatment is crossed roasting in cabinet-type electric furnace, heating rate are 10 DEG C/min, and sintering temperature is 1100 DEG C, roasting
The burning time is 30min, then naturally cools to room temperature, becomes finished product composite haydite.Haydite sample photo is presented glaze referring to Fig. 1
Matter lustrous surface.
Embodiment 3:
The present embodiment provides composite haydite prepared by a kind of clean water sludge and diatomite, and by weight calculating, its raw material includes:
90 parts of clean water sludge;
20 parts of diatomite;
15 parts of calcium oxide.
Preparation process:
(1)Raw material prepares
Drying and processing is carried out at a temperature of 110 DEG C to clean water sludge.
Diatomite is the waste diatomite for being recovered from brewery for drainage, carries out hydro-thermal method process to waste diatomite:By silicon
Diatomaceous earth is uniformly mixed with water, is placed in reactor, reactor is placed in constant temperature blast drying oven and heats 6 h, and heating-up temperature is 160
DEG C, diatomite is taken out after the completion of reaction, room temperature is naturally cooled to.
According to above-mentioned weight ratio, pretreated clean water sludge, diatomite and calcium oxide are added water and is uniformly mixed, obtained
To mixture.
(2)Prepare balling-up
By mixture hand rubbing into spheroid, sphere diameter scope is 2cm ~ 5cm, spheroid is placed in electric heating constant temperature drying machine and is warming up to
105 DEG C of drying, obtain drying material.
(3)The pre-heat treatment
Drying material is placed in into cabinet-type electric furnace the pre-heat treatment:Heating rate is set as 10 DEG C/min, temperature is risen to from room temperature in electric furnace
400 DEG C, 25min is preheated at a temperature of 400 DEG C.By drying material preheating, mixing spheroid can be prevented effectively from and abruptly enter high temperature
Environment and cause rupture, while can also reduce the later stage roasting power consumption.
(4)Roasting spheroid
The spheroid that the pre-heat treatment is crossed roasting in cabinet-type electric furnace, heating rate are 10 DEG C/min, and sintering temperature is 1100 DEG C, roasting
The burning time is 30min, then naturally cools to room temperature, becomes finished product composite haydite.
Embodiment 4:
The present embodiment provides composite haydite prepared by a kind of clean water sludge and diatomite, and by weight calculating, its raw material includes:
80 parts of clean water sludge;
20 parts of diatomite;
15 parts of calcium oxide.
Preparation process:
(1)Raw material prepares
Drying and processing is carried out at a temperature of 110 DEG C to clean water sludge.
Diatomite is the waste diatomite for being recovered from brewery for drainage, carries out hydro-thermal method process to waste diatomite:By silicon
Diatomaceous earth is uniformly mixed with water, is placed in reactor, reactor is placed in constant temperature blast drying oven and heats 6 h, and heating-up temperature is 160
DEG C, diatomite is taken out after the completion of reaction, room temperature is naturally cooled to.
According to above-mentioned weight ratio, pretreated clean water sludge, diatomite and calcium oxide are added water and is uniformly mixed, obtained
To mixture.
(2)Prepare balling-up
By mixture hand rubbing into spheroid, sphere diameter scope is 2cm ~ 5cm, spheroid is placed in electric heating constant temperature drying machine and is warming up to
105 DEG C of drying, obtain drying material.
(3)The pre-heat treatment
Drying material is placed in into cabinet-type electric furnace the pre-heat treatment:Heating rate is set as 10 DEG C/min, temperature is risen to from room temperature in electric furnace
400 DEG C, 25min is preheated at a temperature of 400 DEG C.By drying material preheating, mixing spheroid can be prevented effectively from and abruptly enter high temperature
Environment and cause rupture, while can also reduce the later stage roasting power consumption.
(4)Roasting spheroid
The spheroid that the pre-heat treatment is crossed roasting in cabinet-type electric furnace, heating rate are 10 DEG C/min, and sintering temperature is 1000 DEG C, roasting
The burning time is 30min, then naturally cools to room temperature, becomes finished product composite haydite.
The present invention preferably case study on implementation is the foregoing is only, and is not used to limit the present invention, it is every in core of the present invention
With any modification, replacement, improvement made outside principle etc., should be included within the scope of the present invention.
Claims (3)
1. the composite haydite that prepared by a kind of clean water sludge and diatomite, it is characterised in that:It is raw materials used for clean water sludge, diatom
Soil, calcium oxide, mixing according to a certain percentage, balling-up, drying, 400 DEG C of preheating 25min, 900 ~ 1200 DEG C of roasting 30min are formed.
2. composite haydite prepared by a kind of clean water sludge and diatomite according to right 1, it is characterised in that:It is raw materials used to be
Clean water sludge, diatomite, calcium oxide, the ratio by mass:60 ~ 90 parts of clean water sludge;20 ~ 30 parts of diatomite;Calcium oxide
10 ~ 20 parts.
3. the composite haydite for preparing according to a kind of clean water sludge described in right 1 and diatomite, it is characterised in that:The diatomite
Brewery to reclaim is used for one or more of the waste diatomite or ordinary silicon diatomaceous earth raw material of drainage, and the raw material is adopted back
When receiving brewery's drainage waste diatomite, need to carry out hydro-thermal method pretreatment to waste diatomite:Heating-up temperature is 160 DEG C, heating
Time is 6h, obtains the diatomite material for removing impurity.
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CN201610951061.5A CN106518150B (en) | 2016-11-30 | 2016-11-30 | A kind of composite haydite of clean water sludge and diatomite preparation |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109020604A (en) * | 2018-09-02 | 2018-12-18 | 长沙埃比林环保科技有限公司 | A method of haydite is prepared using solid waste |
WO2021047282A1 (en) * | 2019-09-10 | 2021-03-18 | 东北农业大学 | Preparation method for artificially simulated soil rich in humus |
CN112844304A (en) * | 2021-02-05 | 2021-05-28 | 苏州科技大学 | Sodium pyrophosphate modified water purification sludge/zeolite composite adsorbent and preparation method and application thereof |
CN113481013A (en) * | 2021-07-14 | 2021-10-08 | 昆明理工大学 | Method for preparing soil conditioner by utilizing ceramsite in-situ hydrothermal combination with biochar |
TWI754236B (en) * | 2020-03-02 | 2022-02-01 | 明春窯業股份有限公司 | The method of water treatment sludge recycling |
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CN1868968A (en) * | 2005-05-25 | 2006-11-29 | 郑恒春 | Calcining method of ceramic particle |
KR20160070040A (en) * | 2016-03-31 | 2016-06-17 | 주식회사 다산컨설턴트 | Ceramic filter for treating contaminated water and the manufacturing method thereof |
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2016
- 2016-11-30 CN CN201610951061.5A patent/CN106518150B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1868968A (en) * | 2005-05-25 | 2006-11-29 | 郑恒春 | Calcining method of ceramic particle |
KR20160070040A (en) * | 2016-03-31 | 2016-06-17 | 주식회사 다산컨설턴트 | Ceramic filter for treating contaminated water and the manufacturing method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109020604A (en) * | 2018-09-02 | 2018-12-18 | 长沙埃比林环保科技有限公司 | A method of haydite is prepared using solid waste |
WO2021047282A1 (en) * | 2019-09-10 | 2021-03-18 | 东北农业大学 | Preparation method for artificially simulated soil rich in humus |
TWI754236B (en) * | 2020-03-02 | 2022-02-01 | 明春窯業股份有限公司 | The method of water treatment sludge recycling |
CN112844304A (en) * | 2021-02-05 | 2021-05-28 | 苏州科技大学 | Sodium pyrophosphate modified water purification sludge/zeolite composite adsorbent and preparation method and application thereof |
CN113481013A (en) * | 2021-07-14 | 2021-10-08 | 昆明理工大学 | Method for preparing soil conditioner by utilizing ceramsite in-situ hydrothermal combination with biochar |
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