Agent and floatation process are selected in a kind of flotation of big scale Scaly graphite ore deposit soon
Technical field
The present invention relates to agent and floatation process are selected in a kind of flotation of big scale Scaly graphite ore deposit soon, belong to graphite flotation technology
Field.
Background technology
China's graphite resource enriches, and reserves and yield all occupy first place in the world.Graphite ore can be divided into crystalloid stone by crystal habit
Ink and aphanitic graphite, and Scaly graphite is divided into two kinds of compact crystal shape graphite and crystalline flake graphite.Compact crystal shape graphite ore
Stone content in nature is less, exploitation it is few, and its grade is high, typically just directly can utilize through picking.
And crystalline flake graphite is the more Scaly graphite of beneficiation research.Crystalline flake graphite is typically due to crystallization preferably, natural floatability, because
This takes traditional floatation process to can be obtained by higher grade and the rate of recovery.But the size due to crystalline flake graphite piece and its property
Can be in close relations, the bigger graphite quality of scale is better.Therefore in order to improve the economic benefit of crystalline flake graphite ore deposit, preferably develop
Using the graphite resource of China, just graphite flakes must be protected in graphite ore dressing process, and ensure grade and return
Yield.
Many experts and scholars had carried out some researchs in terms of graphite ore grinding attachment and multistage grinding etc. in the past, achieved
Some achievements.But low due to there is device efficiency, beneficiation cost is high, the problems such as index is unstable, it is difficult to popularization and application.Document
《The research of protection flaky graphite ore dressing》Disclose and can realize protecting the purpose of flaky graphite using barrel medium ore grinding.
Document《Graphite ore dressing and crystal protection test research》Disclose different Regrinding equipments, grinding media and medium different ratio pair again
The impact of protection graphite crystal, it is believed that desk-top vibromill is used as coarse concentrate regrinding equipment, then grinding media is that steel ball and post mixing are matched somebody with somebody
Than efficiency of regrinding can be improved, can be with effective protection graphite flakes.
The content of the invention
The present invention is for protecting the deficiency for existing to graphite flakes during graphite mineral processing, there is provided a kind of big scale is brilliant
Agent and floatation process are selected in the flotation of matter graphite ore soon.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:
Agent is selected in a kind of flotation of big scale Scaly graphite ore deposit soon, it is characterised in that including following component:The first of 50~65wt%
The acetone of base isobutyl carbinol, the petroleum ether of 20~30wt% and 10~25wt%.
The invention has the beneficial effects as follows:It is excellent that the graphite that the present invention is provided selects agent quickly sub-elect in neutral ore pulp soon
Matter flaky graphite ore deposit, and the big scale Scaly graphite concentrate of high-grade can be obtained by by the short dressing process do not regrinded, with
Traditional big scale Scaly graphite ore deposit floatation process is compared, can with effective protection graphite flakes, while can also reduce collecting agent and
The consumption of foaming agent, such that it is able to reduce production cost.
The present invention also provides a kind of big scale Scaly graphite ore deposit floatation process, comprises the steps:
1) raw material big scale Scaly graphite ore deposit is crushed, ball milling, adds to select in ore milling product soon and put into after agent floating
Flotation is carried out in selecting machine, rough concentrate and mine tailing is obtained, it is described to select agent to include following component soon:The methyl-isobutyl of 50~65wt%
The acetone of methyl alcohol, the petroleum ether of 20~30wt% and 10~25wt%;
2) by step 1) in gained rough concentrate input flotation device in carry out repeatedly selecting selected soon, be obtained graphite concentrate with
Ore deposit, the chats of repeatedly selected rear gained is merged;
3) by step 2) obtained by mine tailing adjust pH value, the kerosene and foaming agent terpenic oil for being added thereto to emulsifier stirs
Mix rear flotation and rough concentrate and mine tailing be obtained, rough concentrate is regrinded through ball milling, add in product of regrinding emulsifier kerosene and
Flotation is carried out after foaming agent terpenic oil primary cleaning concentrate and chats is obtained, primary cleaning concentrate is regrinded through sand milling, product of regrinding
Flotation is carried out after the kerosene and foaming agent terpenic oil that add emulsifier in product again and is obtained recleaning concentrate and chats, two
Secondary selected concentrate and step 2) in gained chats merges after Jing after multiple sand milling and flotation graphite concentrate and chats, will repeatedly
After selected, the chats of gained merges;
4) step 3) in gained mine tailing in add emulsifier after kerosene and foaming agent terpenic oil scanned, in obtaining
Ore deposit and mine tailing;
5) by step 3), 4) in gained chats merge, concentration, ball milling, be added thereto to emulsifier kerosene and
Scanned after foaming agent terpenic oil, regrind Jing many times, after flotation graphite concentrate and tailings.
The beneficial effect of floatation process that the present invention is provided is:
The technique of the present invention realizes the purpose that graphite flakes are protected in ore dressing process, it is ensured that big scale crystalloid stone
The grade and the rate of recovery of black ore deposit concentrate, while beneficiation reagent consumption can be reduced, stable technical process does not increase production cost,
The level of profitability can also be effectively improved.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, step 3), 4) and 5) described in emulsifying agent include following component:60~75wt% dodecyl sulphates
Sodium, 25~40wt% sulphation monoglycerides.
It is the dispersibility that improve kerosene in ore pulp using the beneficial effect of above-mentioned further technical scheme, so as to
Grade and the rate of recovery that graphite selects step concentrate slowly can be effectively ensured, and the consumption of floating agent can be reduced.
Further, step 3) in time for regrinding of sand mill be no less than 20min.
It is to be conducive to improving selected operating efficiency using the beneficial effect of above-mentioned further technical scheme, shortens selected stream
Journey, so as to simplify mineral processing circuit.
Description of the drawings
Process charts of the Fig. 1 for the embodiment of the present invention;
Specific embodiment
The principle and feature of the present invention are described below in conjunction with example, example is served only for explaining the present invention, and
It is non-for limiting the scope of the present invention.
Embodiment 1:
Agent, including following component are selected in a kind of flotation of big scale Scaly graphite ore deposit soon:The methyl isobutyl carbinol of 50wt%,
The acetone of the petroleum ether and 20wt% of 30wt%.
A kind of big scale Scaly graphite ore deposit floatation process, comprises the steps:
Raw ore is big scale Scaly graphite ore deposit, and fixed carbon content is 15.28%, and graphite flakes are with diameter greater than 0.5mm, this reality
Apply the emulsification that the kerosene used in example is made up of the lauryl sodium sulfate through 60wt%, 40wt% sulphation monoglycerides
Agent emulsification.
A, by above-mentioned crushing raw ore to -4mm, reusing ball mill carries out ore grinding, ore milling concentration 60%, and the ore grinding time is
6min, it is 55% that mog is -0.15mm contents;Ore milling product puts into flotation device after the above-mentioned graphite of addition selects agent soon
Carry out fast choosing to roughly select, floatation concentration is 20%, and flotation time is 2min, and rough concentrate and mine tailing a is obtained;
B, primary cleaning is selected soon to rough concentrate input flotation device obtained in step A, select the primary cleaning concentration to be soon
12.16%, select the primary cleaning time to be 2min soon, be obtained and select primary cleaning concentrate and chats a soon;Will be the fast choosing for obtaining once smart
Concentrate selection is selected recleaning soon, selects recleaning concentration to be 8.58% soon, is selected the recleaning time to be 2min soon, is obtained most
Whole graphite concentrate and chats b;
C, in mine tailing a obtained in step A add regulator calcium oxide, adjustment slurry pH be 9, add through emulsifying agent
Kerosene stirring after emulsification, is roughly selected, and floatation concentration is 19.86%, and flotation time is 4min, and rough concentrate and mine tailing b is obtained;
Reagent combination is roughly selected for calcium oxide 2000g, emulsified kerosene 120g and terpenic oil are added in big scale Scaly graphite green ore per ton
60g;
D, rough concentrate obtained in step C is once regrinded using ball mill, concentration of once regrinding is 35.24%, then
Consume time as 6min, it is 71.24% that mog is -0.15mm contents, product of once regrinding input flotation device adds emulsification
Kerosene and terpenic oil stirring, carry out primary cleaning, and primary cleaning concentration is 17.65%, and the primary cleaning time is 4min, is obtained one
Secondary selected concentrate and chats c, primary cleaning reagent combination be big scale Scaly graphite ore deposit emulsified kerosene consumption 40g relatively per ton and
Terpenic oil consumption 20g;By obtained primary cleaning concentrate using sand mill carry out it is secondary regrind, secondary concentration of regrinding is
16.28%, secondary to be consumed time as 20min again, it is 82.81% that mog is -0.15mm contents, by secondary product of regrinding with
Ore deposit a, chats b put into flotation device and add emulsified kerosene and terpenic oil stirring after merging, carry out recleaning, and recleaning concentration is
12.32%, the recleaning time is 4min, and recleaning concentrate and chats d is obtained, and recleaning reagent combination is relatively per ton
Big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g;Obtained recleaning concentrate is adopted into sand mill
Carrying out three times to regrind, concentration being regrinded for three times for 14.11%, consume time again for three times as 20min, mog is -0.15mm contents
For 87.26%, three products input flotation devices of regrinding are added into emulsified kerosenes and terpenic oil stirring, carry out triple cleaning, three times
Selected concentration is 9.32%, and the triple cleaning time is 4min, and triple cleaning concentrate and chats e, triple cleaning reagent combination is obtained
It is big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g relatively per ton;By obtained triple cleaning concentrate
Four times are carried out using sand mill to regrind, concentration is regrinded for four times for 11.32%, are consumed time again for four times as 20min, mog for-
0.15mm contents are 90.11%, and four product input flotation devices of regrinding are added emulsified kerosene and terpenic oil stirring, four times are carried out
Selected, four times selected concentration is 7.12%, and four selected times are 4min, and four selected concentrate and chats f is obtained, and four times selected
Reagent combination is big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g relatively per ton;By obtained four times
Selected concentrate carries out five times using sand mill and regrinds, and regrinds concentration for five times for 9.86%, is consumed time as 20min, ore grinding again for five times
It is 91.35% that fineness is -0.15mm contents, and five product input flotation devices of regrinding are added emulsified kerosene and terpenic oil stirring,
Carry out five times it is selected, five selected concentration are 6.11%, and five selected times are 3min, and final graphite concentrate and chats g is obtained,
Five selected reagent combinations are big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g relatively per ton, chats
Can again return to regrind selected again;
E, mine tailing b obtained in step C is added emulsified kerosene and foaming agent terpenic oil scanned, scanning concentration is
15.29%, the time of scanning is 2.5min, obtains chats j and mine tailing c;It is big scale crystalloid stone relatively per ton to scan reagent combination
Black ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g;
F, obtained chats c, chats d, chats e and chats j are merged, mass concentration is concentrated into for 28.56%, so
Regrinded using ball mill afterwards, ore milling concentration is 29.28%, the middling ore regrinding time is 8min, then grinding rate contains for -0.15mm
Measure as 86.82%, in product of regrinding, add emulsified kerosene and foaming agent terpenic oil to carry out flotation, chats floatation concentration is
12.32%, chats flotation time is 3.5min, and chats h and mine tailing c is obtained;Chats floating agent formula is big squama relatively per ton
Piece crystalloid graphite ore emulsified kerosene consumption 40g and terpenic oil consumption 20g;By obtained chats h return to step C, and carry out successively
Five times in step C are regrinded five refining process, and final graphite concentrate product is obtained.
G, obtained chats f and chats g are merged, concentration is concentrated into for 12.39%, then by the merging after concentration
Three times of ore deposit return to step C are regrinded in step, and carry out three times of step C triple cleaning processes of regrinding successively, and final stone is obtained
Black concentrate.
The grade of final gained graphite concentrate is 99.91%, and the rate of recovery is 86.52%, graphite concentrate scale granularity for+
0.282mm contents account for 82.64%.
Embodiment 2:
Agent, including following component are selected in a kind of flotation of big scale Scaly graphite ore deposit soon:The methyl isobutyl carbinol of 65wt%,
The acetone of the petroleum ether and 15wt% of 20wt%.
The present embodiment with the difference of embodiment 1 is:1) flotation for using selects agent different soon;2) kerosene for using be through
The emulsifier being made up of the lauryl sodium sulfate of 70wt%, 30wt% sulphation monoglycerides.
The grade of the final gained graphite concentrate of the present embodiment is 99.83%, and the rate of recovery is 88.36%, graphite concentrate scale
Granularity accounts for 85.28% for+0.282mm contents.
Embodiment 3:
Agent, including following component are selected in a kind of flotation of big scale Scaly graphite ore deposit soon:The methyl isobutyl carbinol of 50wt%,
The acetone of the petroleum ether and 25wt% of 25wt%.
The present embodiment with the difference of embodiment 1 is:1) flotation for using selects agent different soon;2) kerosene for using be through
The emulsifier being made up of the lauryl sodium sulfate of 75wt%, 25wt% sulphation monoglycerides.
The grade of the final gained graphite concentrate of the present embodiment is 99.93%, and the rate of recovery is 85.37%, graphite concentrate scale
Granularity accounts for 80.36% for+0.282mm contents.
The foregoing is only presently preferred embodiments of the present invention, not to limit the present invention, all spirit in the present invention and
Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.