CN106513164A - Large-scale crystalline graphite ore flotation fast selecting agent and flotation technology - Google Patents

Large-scale crystalline graphite ore flotation fast selecting agent and flotation technology Download PDF

Info

Publication number
CN106513164A
CN106513164A CN201610985834.1A CN201610985834A CN106513164A CN 106513164 A CN106513164 A CN 106513164A CN 201610985834 A CN201610985834 A CN 201610985834A CN 106513164 A CN106513164 A CN 106513164A
Authority
CN
China
Prior art keywords
flotation
concentrate
chats
graphite
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610985834.1A
Other languages
Chinese (zh)
Other versions
CN106513164B (en
Inventor
李建伟
李启轩
李永进
邓淑萍
程才
张忠伟
张文彬
李姗姗
盖莉莉
曹英奇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JINJIAN ENGINEERING DESIGN Co Ltd
Original Assignee
JINJIAN ENGINEERING DESIGN Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JINJIAN ENGINEERING DESIGN Co Ltd filed Critical JINJIAN ENGINEERING DESIGN Co Ltd
Priority to CN201610985834.1A priority Critical patent/CN106513164B/en
Publication of CN106513164A publication Critical patent/CN106513164A/en
Application granted granted Critical
Publication of CN106513164B publication Critical patent/CN106513164B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B7/00Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/004Organic compounds
    • B03D1/008Organic compounds containing oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/004Organic compounds
    • B03D1/012Organic compounds containing sulfur

Landscapes

  • Lubricants (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The invention relates to a large-scale crystalline graphite ore flotation fast selecting agent and a flotation technology. The agent comprises following components including, by weight, 50% to 65% of methyl isobutyl carbinol, 20% to 30% of petroleum ether and 10% to 25% of acetone. The graphite ore flotation fast selecting agent can rapidly select high-quality large-scale graphite ore from neutral pulp, and high-grade large-scale crystalline graphite concentrate can be obtained through the short selection technology free of regrinding; compared with a traditional large-scale crystalline graphite ore flotation technology, graphite scales can be effectively protected, meanwhile, the consumption amount of the floatation agent can be reduced, and the production cost is reduced.

Description

Agent and floatation process are selected in a kind of flotation of big scale Scaly graphite ore deposit soon
Technical field
The present invention relates to agent and floatation process are selected in a kind of flotation of big scale Scaly graphite ore deposit soon, belong to graphite flotation technology Field.
Background technology
China's graphite resource enriches, and reserves and yield all occupy first place in the world.Graphite ore can be divided into crystalloid stone by crystal habit Ink and aphanitic graphite, and Scaly graphite is divided into two kinds of compact crystal shape graphite and crystalline flake graphite.Compact crystal shape graphite ore Stone content in nature is less, exploitation it is few, and its grade is high, typically just directly can utilize through picking. And crystalline flake graphite is the more Scaly graphite of beneficiation research.Crystalline flake graphite is typically due to crystallization preferably, natural floatability, because This takes traditional floatation process to can be obtained by higher grade and the rate of recovery.But the size due to crystalline flake graphite piece and its property Can be in close relations, the bigger graphite quality of scale is better.Therefore in order to improve the economic benefit of crystalline flake graphite ore deposit, preferably develop Using the graphite resource of China, just graphite flakes must be protected in graphite ore dressing process, and ensure grade and return Yield.
Many experts and scholars had carried out some researchs in terms of graphite ore grinding attachment and multistage grinding etc. in the past, achieved Some achievements.But low due to there is device efficiency, beneficiation cost is high, the problems such as index is unstable, it is difficult to popularization and application.Document 《The research of protection flaky graphite ore dressing》Disclose and can realize protecting the purpose of flaky graphite using barrel medium ore grinding. Document《Graphite ore dressing and crystal protection test research》Disclose different Regrinding equipments, grinding media and medium different ratio pair again The impact of protection graphite crystal, it is believed that desk-top vibromill is used as coarse concentrate regrinding equipment, then grinding media is that steel ball and post mixing are matched somebody with somebody Than efficiency of regrinding can be improved, can be with effective protection graphite flakes.
The content of the invention
The present invention is for protecting the deficiency for existing to graphite flakes during graphite mineral processing, there is provided a kind of big scale is brilliant Agent and floatation process are selected in the flotation of matter graphite ore soon.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:
Agent is selected in a kind of flotation of big scale Scaly graphite ore deposit soon, it is characterised in that including following component:The first of 50~65wt% The acetone of base isobutyl carbinol, the petroleum ether of 20~30wt% and 10~25wt%.
The invention has the beneficial effects as follows:It is excellent that the graphite that the present invention is provided selects agent quickly sub-elect in neutral ore pulp soon Matter flaky graphite ore deposit, and the big scale Scaly graphite concentrate of high-grade can be obtained by by the short dressing process do not regrinded, with Traditional big scale Scaly graphite ore deposit floatation process is compared, can with effective protection graphite flakes, while can also reduce collecting agent and The consumption of foaming agent, such that it is able to reduce production cost.
The present invention also provides a kind of big scale Scaly graphite ore deposit floatation process, comprises the steps:
1) raw material big scale Scaly graphite ore deposit is crushed, ball milling, adds to select in ore milling product soon and put into after agent floating Flotation is carried out in selecting machine, rough concentrate and mine tailing is obtained, it is described to select agent to include following component soon:The methyl-isobutyl of 50~65wt% The acetone of methyl alcohol, the petroleum ether of 20~30wt% and 10~25wt%;
2) by step 1) in gained rough concentrate input flotation device in carry out repeatedly selecting selected soon, be obtained graphite concentrate with Ore deposit, the chats of repeatedly selected rear gained is merged;
3) by step 2) obtained by mine tailing adjust pH value, the kerosene and foaming agent terpenic oil for being added thereto to emulsifier stirs Mix rear flotation and rough concentrate and mine tailing be obtained, rough concentrate is regrinded through ball milling, add in product of regrinding emulsifier kerosene and Flotation is carried out after foaming agent terpenic oil primary cleaning concentrate and chats is obtained, primary cleaning concentrate is regrinded through sand milling, product of regrinding Flotation is carried out after the kerosene and foaming agent terpenic oil that add emulsifier in product again and is obtained recleaning concentrate and chats, two Secondary selected concentrate and step 2) in gained chats merges after Jing after multiple sand milling and flotation graphite concentrate and chats, will repeatedly After selected, the chats of gained merges;
4) step 3) in gained mine tailing in add emulsifier after kerosene and foaming agent terpenic oil scanned, in obtaining Ore deposit and mine tailing;
5) by step 3), 4) in gained chats merge, concentration, ball milling, be added thereto to emulsifier kerosene and Scanned after foaming agent terpenic oil, regrind Jing many times, after flotation graphite concentrate and tailings.
The beneficial effect of floatation process that the present invention is provided is:
The technique of the present invention realizes the purpose that graphite flakes are protected in ore dressing process, it is ensured that big scale crystalloid stone The grade and the rate of recovery of black ore deposit concentrate, while beneficiation reagent consumption can be reduced, stable technical process does not increase production cost, The level of profitability can also be effectively improved.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, step 3), 4) and 5) described in emulsifying agent include following component:60~75wt% dodecyl sulphates Sodium, 25~40wt% sulphation monoglycerides.
It is the dispersibility that improve kerosene in ore pulp using the beneficial effect of above-mentioned further technical scheme, so as to Grade and the rate of recovery that graphite selects step concentrate slowly can be effectively ensured, and the consumption of floating agent can be reduced.
Further, step 3) in time for regrinding of sand mill be no less than 20min.
It is to be conducive to improving selected operating efficiency using the beneficial effect of above-mentioned further technical scheme, shortens selected stream Journey, so as to simplify mineral processing circuit.
Description of the drawings
Process charts of the Fig. 1 for the embodiment of the present invention;
Specific embodiment
The principle and feature of the present invention are described below in conjunction with example, example is served only for explaining the present invention, and It is non-for limiting the scope of the present invention.
Embodiment 1:
Agent, including following component are selected in a kind of flotation of big scale Scaly graphite ore deposit soon:The methyl isobutyl carbinol of 50wt%, The acetone of the petroleum ether and 20wt% of 30wt%.
A kind of big scale Scaly graphite ore deposit floatation process, comprises the steps:
Raw ore is big scale Scaly graphite ore deposit, and fixed carbon content is 15.28%, and graphite flakes are with diameter greater than 0.5mm, this reality Apply the emulsification that the kerosene used in example is made up of the lauryl sodium sulfate through 60wt%, 40wt% sulphation monoglycerides Agent emulsification.
A, by above-mentioned crushing raw ore to -4mm, reusing ball mill carries out ore grinding, ore milling concentration 60%, and the ore grinding time is 6min, it is 55% that mog is -0.15mm contents;Ore milling product puts into flotation device after the above-mentioned graphite of addition selects agent soon Carry out fast choosing to roughly select, floatation concentration is 20%, and flotation time is 2min, and rough concentrate and mine tailing a is obtained;
B, primary cleaning is selected soon to rough concentrate input flotation device obtained in step A, select the primary cleaning concentration to be soon 12.16%, select the primary cleaning time to be 2min soon, be obtained and select primary cleaning concentrate and chats a soon;Will be the fast choosing for obtaining once smart Concentrate selection is selected recleaning soon, selects recleaning concentration to be 8.58% soon, is selected the recleaning time to be 2min soon, is obtained most Whole graphite concentrate and chats b;
C, in mine tailing a obtained in step A add regulator calcium oxide, adjustment slurry pH be 9, add through emulsifying agent Kerosene stirring after emulsification, is roughly selected, and floatation concentration is 19.86%, and flotation time is 4min, and rough concentrate and mine tailing b is obtained; Reagent combination is roughly selected for calcium oxide 2000g, emulsified kerosene 120g and terpenic oil are added in big scale Scaly graphite green ore per ton 60g;
D, rough concentrate obtained in step C is once regrinded using ball mill, concentration of once regrinding is 35.24%, then Consume time as 6min, it is 71.24% that mog is -0.15mm contents, product of once regrinding input flotation device adds emulsification Kerosene and terpenic oil stirring, carry out primary cleaning, and primary cleaning concentration is 17.65%, and the primary cleaning time is 4min, is obtained one Secondary selected concentrate and chats c, primary cleaning reagent combination be big scale Scaly graphite ore deposit emulsified kerosene consumption 40g relatively per ton and Terpenic oil consumption 20g;By obtained primary cleaning concentrate using sand mill carry out it is secondary regrind, secondary concentration of regrinding is 16.28%, secondary to be consumed time as 20min again, it is 82.81% that mog is -0.15mm contents, by secondary product of regrinding with Ore deposit a, chats b put into flotation device and add emulsified kerosene and terpenic oil stirring after merging, carry out recleaning, and recleaning concentration is 12.32%, the recleaning time is 4min, and recleaning concentrate and chats d is obtained, and recleaning reagent combination is relatively per ton Big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g;Obtained recleaning concentrate is adopted into sand mill Carrying out three times to regrind, concentration being regrinded for three times for 14.11%, consume time again for three times as 20min, mog is -0.15mm contents For 87.26%, three products input flotation devices of regrinding are added into emulsified kerosenes and terpenic oil stirring, carry out triple cleaning, three times Selected concentration is 9.32%, and the triple cleaning time is 4min, and triple cleaning concentrate and chats e, triple cleaning reagent combination is obtained It is big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g relatively per ton;By obtained triple cleaning concentrate Four times are carried out using sand mill to regrind, concentration is regrinded for four times for 11.32%, are consumed time again for four times as 20min, mog for- 0.15mm contents are 90.11%, and four product input flotation devices of regrinding are added emulsified kerosene and terpenic oil stirring, four times are carried out Selected, four times selected concentration is 7.12%, and four selected times are 4min, and four selected concentrate and chats f is obtained, and four times selected Reagent combination is big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g relatively per ton;By obtained four times Selected concentrate carries out five times using sand mill and regrinds, and regrinds concentration for five times for 9.86%, is consumed time as 20min, ore grinding again for five times It is 91.35% that fineness is -0.15mm contents, and five product input flotation devices of regrinding are added emulsified kerosene and terpenic oil stirring, Carry out five times it is selected, five selected concentration are 6.11%, and five selected times are 3min, and final graphite concentrate and chats g is obtained, Five selected reagent combinations are big scale Scaly graphite ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g relatively per ton, chats Can again return to regrind selected again;
E, mine tailing b obtained in step C is added emulsified kerosene and foaming agent terpenic oil scanned, scanning concentration is 15.29%, the time of scanning is 2.5min, obtains chats j and mine tailing c;It is big scale crystalloid stone relatively per ton to scan reagent combination Black ore deposit emulsified kerosene consumption 40g and terpenic oil consumption 20g;
F, obtained chats c, chats d, chats e and chats j are merged, mass concentration is concentrated into for 28.56%, so Regrinded using ball mill afterwards, ore milling concentration is 29.28%, the middling ore regrinding time is 8min, then grinding rate contains for -0.15mm Measure as 86.82%, in product of regrinding, add emulsified kerosene and foaming agent terpenic oil to carry out flotation, chats floatation concentration is 12.32%, chats flotation time is 3.5min, and chats h and mine tailing c is obtained;Chats floating agent formula is big squama relatively per ton Piece crystalloid graphite ore emulsified kerosene consumption 40g and terpenic oil consumption 20g;By obtained chats h return to step C, and carry out successively Five times in step C are regrinded five refining process, and final graphite concentrate product is obtained.
G, obtained chats f and chats g are merged, concentration is concentrated into for 12.39%, then by the merging after concentration Three times of ore deposit return to step C are regrinded in step, and carry out three times of step C triple cleaning processes of regrinding successively, and final stone is obtained Black concentrate.
The grade of final gained graphite concentrate is 99.91%, and the rate of recovery is 86.52%, graphite concentrate scale granularity for+ 0.282mm contents account for 82.64%.
Embodiment 2:
Agent, including following component are selected in a kind of flotation of big scale Scaly graphite ore deposit soon:The methyl isobutyl carbinol of 65wt%, The acetone of the petroleum ether and 15wt% of 20wt%.
The present embodiment with the difference of embodiment 1 is:1) flotation for using selects agent different soon;2) kerosene for using be through The emulsifier being made up of the lauryl sodium sulfate of 70wt%, 30wt% sulphation monoglycerides.
The grade of the final gained graphite concentrate of the present embodiment is 99.83%, and the rate of recovery is 88.36%, graphite concentrate scale Granularity accounts for 85.28% for+0.282mm contents.
Embodiment 3:
Agent, including following component are selected in a kind of flotation of big scale Scaly graphite ore deposit soon:The methyl isobutyl carbinol of 50wt%, The acetone of the petroleum ether and 25wt% of 25wt%.
The present embodiment with the difference of embodiment 1 is:1) flotation for using selects agent different soon;2) kerosene for using be through The emulsifier being made up of the lauryl sodium sulfate of 75wt%, 25wt% sulphation monoglycerides.
The grade of the final gained graphite concentrate of the present embodiment is 99.93%, and the rate of recovery is 85.37%, graphite concentrate scale Granularity accounts for 80.36% for+0.282mm contents.
The foregoing is only presently preferred embodiments of the present invention, not to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.

Claims (4)

1. agent is selected in a kind of big scale Scaly graphite ore deposit flotation soon, it is characterised in that including following component:The methyl of 50~65wt% The acetone of isobutyl carbinol, the petroleum ether of 20~30wt% and 10~25wt%.
2. a kind of big scale Scaly graphite ore deposit floatation process, it is characterised in that comprise the steps:
1) raw material big scale Scaly graphite ore deposit is crushed, ball milling, added to select soon that flotation device after agent, is put into in ore milling product In carry out flotation, rough concentrate and mine tailing is obtained, it is described to select agent to include following component soon:The methyl-isobutyl first of 50~65wt% The acetone of alcohol, the petroleum ether of 20~30wt% and 10~25wt%;
2) by step 1) in gained rough concentrate input flotation device in carry out repeatedly selecting selected soon, prepared graphite concentrate and chats, The chats of repeatedly selected rear gained is merged;
3) by step 2) obtained by mine tailing adjust pH value, be added thereto to emulsifier kerosene and foaming agent terpenic oil stirring after Flotation is obtained rough concentrate and mine tailing, and rough concentrate is regrinded through ball milling, and kerosene and the foaming of emulsifier are added in product of regrinding Flotation is carried out after agent terpenic oil primary cleaning concentrate and chats is obtained, primary cleaning concentrate is regrinded through sand milling, regrinded in product Flotation is carried out after the kerosene and foaming agent terpenic oil that add emulsifier again recleaning concentrate and chats, secondary fine is obtained Concentrate selection and step 2) in gained chats merges after Jing after multiple sand milling and flotation graphite concentrate and chats, will be multiple selected The chats of gained merges afterwards;
4) step 3) in gained mine tailing in add emulsifier after kerosene and foaming agent terpenic oil scanned, obtain chats and Mine tailing;
5) by step 3), 4) in the chats of gained merge, concentration, ball milling is added thereto to kerosene and the foaming of emulsifier Scanned after agent terpenic oil, regrind Jing many times, after flotation graphite concentrate and tailings.
3. big scale Scaly graphite ore deposit floatation process according to claim 2, it is characterised in that step 3), 4) and 5) in Described emulsifying agent includes following component:60~75wt% lauryl sodium sulfate, 25~40wt% sulphation monoglycerides.
4. big scale Scaly graphite ore deposit floatation process according to claim 2, it is characterised in that step 3) in sand mill again The time of mill is no less than 20min.
CN201610985834.1A 2016-11-09 2016-11-09 A kind of big scale Scaly graphite mine floatation process Active CN106513164B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610985834.1A CN106513164B (en) 2016-11-09 2016-11-09 A kind of big scale Scaly graphite mine floatation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610985834.1A CN106513164B (en) 2016-11-09 2016-11-09 A kind of big scale Scaly graphite mine floatation process

Publications (2)

Publication Number Publication Date
CN106513164A true CN106513164A (en) 2017-03-22
CN106513164B CN106513164B (en) 2018-07-27

Family

ID=58350460

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610985834.1A Active CN106513164B (en) 2016-11-09 2016-11-09 A kind of big scale Scaly graphite mine floatation process

Country Status (1)

Country Link
CN (1) CN106513164B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109046756A (en) * 2018-09-12 2018-12-21 山东泰东环保科技股份有限公司 Graphite choosing method is enriched in steel desulfurization slag
CN109647630A (en) * 2018-12-28 2019-04-19 中建材蚌埠玻璃工业设计研究院有限公司 A kind of short route method of purification of graphite
CN111135956A (en) * 2019-12-24 2020-05-12 湖北冶金地质研究所(中南冶金地质研究所) Method for protecting scale in graphite processing
CN111715397A (en) * 2020-05-27 2020-09-29 中国地质科学院郑州矿产综合利用研究所 Mixed roughing method for extra-large scale graphite ores
CN111841830A (en) * 2020-06-28 2020-10-30 中国地质科学院郑州矿产综合利用研究所 Low-grade middling sorting method for graphite ore
CN113477345A (en) * 2021-07-28 2021-10-08 烟台金鹏冶金设计研究工程有限公司 Flotation method capable of protecting integrity of graphite flakes
CN114918045A (en) * 2022-05-12 2022-08-19 矿冶科技集团有限公司 Graphite ore flotation reagent and preparation method thereof
WO2023130790A1 (en) * 2022-01-06 2023-07-13 中国地质大学(北京) Method for full resource utilization of graphite ores

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109909062B (en) * 2019-03-27 2021-03-09 青海省地质矿产测试应用中心 Mineral separation method of protective scale for fine-grained crystalline graphite ore
CN110813519A (en) * 2019-11-25 2020-02-21 郑州大学 Method for protecting crystalline graphite flakes by improving mineral separation process of graphite ore

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105289835A (en) * 2015-10-28 2016-02-03 武汉理工大学 Purification technique for mineral separation of low-grade fine crystalline flake graphite
CN105457743A (en) * 2015-11-16 2016-04-06 湖南有色金属研究院 Beneficiation method of micro-fine particle graphite ores for producing high-carbon graphite
CN105583086A (en) * 2015-12-21 2016-05-18 北京矿冶研究总院 Flotation column flotation method for flake graphite
CN105903582A (en) * 2016-06-30 2016-08-31 宜昌新成石墨有限责任公司 Airflow ore-dressing device and method for protecting flaky graphite

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105289835A (en) * 2015-10-28 2016-02-03 武汉理工大学 Purification technique for mineral separation of low-grade fine crystalline flake graphite
CN105457743A (en) * 2015-11-16 2016-04-06 湖南有色金属研究院 Beneficiation method of micro-fine particle graphite ores for producing high-carbon graphite
CN105583086A (en) * 2015-12-21 2016-05-18 北京矿冶研究总院 Flotation column flotation method for flake graphite
CN105903582A (en) * 2016-06-30 2016-08-31 宜昌新成石墨有限责任公司 Airflow ore-dressing device and method for protecting flaky graphite

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
孙传尧: "《选矿工程师手册 第4册》", 31 March 2015 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109046756A (en) * 2018-09-12 2018-12-21 山东泰东环保科技股份有限公司 Graphite choosing method is enriched in steel desulfurization slag
CN109046756B (en) * 2018-09-12 2020-09-18 山东泰东环保科技股份有限公司 Method for selecting enriched graphite in steelmaking desulfurization slag
CN109647630A (en) * 2018-12-28 2019-04-19 中建材蚌埠玻璃工业设计研究院有限公司 A kind of short route method of purification of graphite
CN109647630B (en) * 2018-12-28 2021-03-23 中建材蚌埠玻璃工业设计研究院有限公司 Short-process purification method of graphite
CN111135956A (en) * 2019-12-24 2020-05-12 湖北冶金地质研究所(中南冶金地质研究所) Method for protecting scale in graphite processing
CN111715397A (en) * 2020-05-27 2020-09-29 中国地质科学院郑州矿产综合利用研究所 Mixed roughing method for extra-large scale graphite ores
CN111841830A (en) * 2020-06-28 2020-10-30 中国地质科学院郑州矿产综合利用研究所 Low-grade middling sorting method for graphite ore
CN113477345A (en) * 2021-07-28 2021-10-08 烟台金鹏冶金设计研究工程有限公司 Flotation method capable of protecting integrity of graphite flakes
CN113477345B (en) * 2021-07-28 2023-10-03 烟台金鹏矿业机械有限公司 Flotation method capable of protecting integrity of graphite flake
WO2023130790A1 (en) * 2022-01-06 2023-07-13 中国地质大学(北京) Method for full resource utilization of graphite ores
CN114918045A (en) * 2022-05-12 2022-08-19 矿冶科技集团有限公司 Graphite ore flotation reagent and preparation method thereof
CN114918045B (en) * 2022-05-12 2024-04-12 矿冶科技集团有限公司 Graphite ore flotation reagent and preparation method thereof

Also Published As

Publication number Publication date
CN106513164B (en) 2018-07-27

Similar Documents

Publication Publication Date Title
CN106513164B (en) A kind of big scale Scaly graphite mine floatation process
CN102773152B (en) Fine flaky-cryptocrystalline mixed graphite separation technique
CN105413854B (en) Beneficiation method for high-oxidation-rate copper-molybdenum paragenic ore
CN101224441B (en) Molybdenum-tungsten oxide ore dressing process
CN105289835B (en) A kind of low-grade Fine particle processing purification by mineral technique
CN101507949B (en) Stone-like coal navajoite physical mineral dressing method
CN105435970B (en) A kind of ore-dressing technique of copper smelting-furnace slag flotation recycling copper
CN102441498B (en) Phosphorite double-reverse flotation process
CN105268559B (en) The beneficiation method of low-grade copper sulfide ores
CN101829634B (en) Flotation process of phosphorite with high iron and aluminum and low grade
CN103736569B (en) A kind of beneficiation method of sulphide ore
CN107377200B (en) A kind of purification by mineral method of high clay Fine particle processing
CN104722393B (en) A kind of beneficiation method for improving the microfine speculum iron rate of recovery
CN106492979B (en) A kind of method that ultrafine fraction cassiterite is recycled
CN106902975B (en) A kind of substep desiliconization method for upgrading of high alumina high-silicon type bauxite
CN1883815A (en) Flotation desilication method for bauxite
CN105013616B (en) A kind of method that molybdenum concntrate and lead iron concentrate are separated in the lead sulfide mixed concentrate from molybdenum
CN107537696B (en) A kind of Fine particle processing direct-reverse flotation purifying technique
CN109607527A (en) A kind of purification by mineral method of low-grade micro crystal graphite
CN105268539A (en) Mineral separation technology for recycling graphite and mica in graphite tailings
CN109453891A (en) A kind of high sesquialter collophane spiral chute floats process integration again
CN107537679A (en) A kind of purification by mineral method of low-grade flaky graphite
CN105381868A (en) Physical beneficiation phosphorus reduction method for skarn type high-phosphorus molybdenum ore
CN106669960A (en) Dissociation and recleaning technology for coking fine grain middling coal
CN114247559A (en) Tailing-free ore dressing method for lithium ore recovery

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A flotation process for large scale crystalline graphite ore

Effective date of registration: 20211220

Granted publication date: 20180727

Pledgee: Yantai financing guarantee Group Co.,Ltd.

Pledgor: JINJIAN ENGINEERING DESIGN Co.,Ltd.

Registration number: Y2021980015473

PE01 Entry into force of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20220629

Granted publication date: 20180727

Pledgee: Yantai financing guarantee Group Co.,Ltd.

Pledgor: JINJIAN ENGINEERING DESIGN Co.,Ltd.

Registration number: Y2021980015473

PC01 Cancellation of the registration of the contract for pledge of patent right