CN106498531A - A kind of antibiosis anti-acarien fiber and preparation method thereof - Google Patents
A kind of antibiosis anti-acarien fiber and preparation method thereof Download PDFInfo
- Publication number
- CN106498531A CN106498531A CN201610918026.3A CN201610918026A CN106498531A CN 106498531 A CN106498531 A CN 106498531A CN 201610918026 A CN201610918026 A CN 201610918026A CN 106498531 A CN106498531 A CN 106498531A
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- CN
- China
- Prior art keywords
- acarien
- antibiosis anti
- compounding
- powder body
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 126
- 239000000835 fiber Substances 0.000 title claims abstract description 70
- 238000002360 preparation method Methods 0.000 title abstract description 18
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims abstract description 102
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 86
- 238000013329 compounding Methods 0.000 claims abstract description 62
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000005770 Eugenol Substances 0.000 claims abstract description 51
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229960002217 eugenol Drugs 0.000 claims abstract description 51
- 239000000843 powder Substances 0.000 claims abstract description 46
- 239000011787 zinc oxide Substances 0.000 claims abstract description 42
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 claims abstract description 35
- BJIOGJUNALELMI-ONEGZZNKSA-N Isoeugenol Natural products COC1=CC(\C=C\C)=CC=C1O BJIOGJUNALELMI-ONEGZZNKSA-N 0.000 claims abstract description 34
- BJIOGJUNALELMI-ARJAWSKDSA-N cis-isoeugenol Chemical compound COC1=CC(\C=C/C)=CC=C1O BJIOGJUNALELMI-ARJAWSKDSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 20
- 238000002074 melt spinning Methods 0.000 claims abstract description 20
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 230000003750 conditioning effect Effects 0.000 claims abstract description 9
- -1 polyethylene Polymers 0.000 claims description 28
- 239000012752 auxiliary agent Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 11
- 230000003078 antioxidant effect Effects 0.000 claims description 11
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims description 2
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 239000004626 polylactic acid Substances 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 230000002421 anti-septic effect Effects 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000007873 sieving Methods 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 description 18
- 229920001155 polypropylene Polymers 0.000 description 18
- 230000000844 anti-bacterial effect Effects 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 238000001035 drying Methods 0.000 description 9
- 238000009987 spinning Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 229920002292 Nylon 6 Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 230000002147 killing effect Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000628997 Flos Species 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 description 2
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 2
- 201000004624 Dermatitis Diseases 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- 230000000895 acaricidal effect Effects 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 229940095731 candida albicans Drugs 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 210000001035 gastrointestinal tract Anatomy 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229960002418 ivermectin Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 244000144977 poultry Species 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- 229930192734 Avilamycin Natural products 0.000 description 1
- 239000004190 Avilamycin Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241001478240 Coccus Species 0.000 description 1
- 206010014198 Eczema infantile Diseases 0.000 description 1
- 239000005657 Fenpyroximate Substances 0.000 description 1
- 208000005577 Gastroenteritis Diseases 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 206010035664 Pneumonia Diseases 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 206010039085 Rhinitis allergic Diseases 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 206010052568 Urticaria chronic Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- XIRGHRXBGGPPKY-OTPQUNEMSA-N [(2r,3s,4r,6s)-6-[(2'r,3's,3ar,4r,4'r,6s,7ar)-6-[(2s,3r,4r,5s,6r)-2-[(2r,3s,4s,5s,6s)-6-[(2r,3as,3'ar,6'r,7r,7's,7ar,7'ar)-7'-acetyl-7'-hydroxy-6'-methyl-7-(2-methylpropanoyloxy)spiro[4,6,7,7a-tetrahydro-3ah-[1,3]dioxolo[4,5-c]pyran-2,4'-6,7a-dihydro-3ah- Chemical compound O([C@H]1[C@H](O)C[C@@H](O[C@@H]1C)O[C@H]1[C@H](O)CC2(O[C@]3(C)C[C@@H](O[C@H](C)[C@H]3O2)O[C@H]2[C@@H](OC)[C@@H](C)O[C@H]([C@@H]2O)O[C@H]2[C@H](O)[C@H](OC)[C@H](OC3[C@@H]([C@@H]4O[C@]5(O[C@H]4CO3)[C@@H]3OCO[C@H]3[C@@](O)([C@@H](C)O5)C(C)=O)OC(=O)C(C)C)O[C@@H]2COC)O[C@@H]1C)C(=O)C1=C(C)C(Cl)=C(O)C(Cl)=C1OC XIRGHRXBGGPPKY-OTPQUNEMSA-N 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 201000010105 allergic rhinitis Diseases 0.000 description 1
- 231100000360 alopecia Toxicity 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 201000008937 atopic dermatitis Diseases 0.000 description 1
- 229960005185 avilamycin Drugs 0.000 description 1
- 235000019379 avilamycin Nutrition 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229960002233 benzalkonium bromide Drugs 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 208000024376 chronic urticaria Diseases 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 208000030603 inherited susceptibility to asthma Diseases 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229940028340 phenol / zinc oxide Drugs 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000002062 proliferating effect Effects 0.000 description 1
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000037384 skin absorption Effects 0.000 description 1
- 231100000274 skin absorption Toxicity 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229960005486 vaccine Drugs 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of antibiosis anti-acarien fiber and preparation method thereof, described antibiosis anti-acarien fiber is added by organic mite-proof agent eugenol and/or isoeugenol and antiseptic and mite-proof agent obtained in inorganic antiseptic zinc oxide compounding by polymer, is obtained through melt spinning.Organic mite-proof agent eugenol and/or isoeugenol are first mixed by the present invention with inorganic antiseptic zinc oxide, and through ball mill refinement, sieving obtains compounding antibiosis anti-acarien powder body, then carries out Surface coating with surface conditioning agent to the compounding antibiosis anti-acarien powder body.Then direct addition method is adopted, will mixes with polymer uniform through surface coated compounding antibiosis anti-acarien powder body, antibiosis anti-acarien fiber is obtained through melt spinning；Or masterbatch method is adopted, first antibiosis anti-acarien master batch being prepared through surface coated compounding antibiosis anti-acarien powder body with polymer melt blending, then antibiosis anti-acarien master batch being mixed with polymer uniform, the fiber with the anti-mite effect of long acting antibiotic will be obtained through melt spinning.
Description
Technical field
The invention belongs to fiber and fabric manufacturing technology field, more particularly to a kind of antibiosis anti-acarien fiber and its preparation.
Background technology
With growth in the living standard, people increasingly pay attention to health.The households such as medicated clothing, bedding, carpet, medicated cushion are weaved
Articles for use are the prolific ideal places of the pathogenic microorganism such as staphylococcus aureuses, escherichia coli, Candida albicans and acarid.
Wherein, staphylococcus aureuses, escherichia coli and Candida albicans can cause the diseases such as pneumonia, gastroenteritis and dermatitis；Acarid is not
Only itself can spread germs, virus, the polypide after its secretions, metabolite and death is also strong sensitization source, can
Cause allergic rhinitises, infantile eczema and chronic urticaria, or even cause the diseases such as bronchial asthma.Therefore, manufacture man is given
The anti-mite performance of fibre antibacterial of textile product is occupied, not only significant to intercepting pathophoresiss, and gradually learned
Art circle and the concern of industrial quarters.
The method for giving household textile product antibiosis anti-acarien performance at present mainly has two kinds.One kind is during spinning
Antiseptic and mite-proof agent is added, another kind is the surface that antiseptic and mite-proof agent is attached to fabric by the method for fabric post-treatment.It is based on
Both thinkings, people have had been developed for miscellaneous fiber with antibacterial or anti-mite performance.
But, while the fiber with antibiosis anti-acarien function is up to the present actually rare.Chinese patent application CN
103882543A discloses a kind of polyester fiber with antibiosis anti-acarien performance, and antiseptic and mite-proof agent therein is 300 nanometers of powder
Body, but do not announce its active ingredient.Chinese patent application CN 103882543A is disclosed and is closed by sol-gel process
Into sodium borosilicate ceramic powder as anti-mite and antimicrobial component, in the fiber of thermal plasticity high polymer matrix, main
Antibiosis anti-acarien mechanism is to have loaded silver in the powder body, can play a part of sterilization；Three oxidations two contained in sodium borosilicate
Boron, boric acid and sodium salt can cause acarid to be dehydrated, and then play a part of mite killing.But for a long time by gastrointestinal tract or skin absorption a small amount of
Boric acid, can occur slight symptom of digestive tract, dermatitis, alopecia and hepatorenal damage, so the fiber containing this kind of antiseptic and mite-proof agent
It is not suitable for directly contacting with skin.
Antibiosis anti-acarien fiber can be obtained by solvent spinning or Final finishing after organic antibacterial agent and mite-proof agent compounding.Example
Such as, the organic drugs such as quaternary ammonium salt benzalkonium bromide, benzalkonium chloride and pyrethrin are configured to by Chinese patent application CN 1995498A
Solution according to 0.1%-2% ratio mix with viscose glue after spinning.Chinese patent application CN 101067242A is by quaternary ammonium salt or season
The antibacterial miticide such as salt antibacterial polymer, propargite, fenpyroximate is dissolved in cellulose spin dope fiber of respinning out.No
Cross, organic antibacterial agent and mite-proof agent is less is added in synthetic fibers by melt spinning, main cause is their thermostability
Poor, begin at a lower temperature volatilize and decompose, it is impossible to meet the temperature requirement of polymer melt processing.In addition, big portion
The antibacterial and mite-proof agent for dividing belongs to pesticide category, and their safety also causes the worry of people.
Eugenol or isoeugenol are a kind of natural products extracted from plant, with very strong bactericidal effect, also have
There iss very strong mite killing and drive demodicid mite.Chinese patent CN1718005A discloses extraction eugenol from plant, and passes through
Experiment proves that the compound of Flos Caryophylli phenols can reach acaricidal activity as the severe toxicity chemical classes such as same avilamycin, ivermectin,
Low toxic and environment-friendly, to person poultry harmless.Eugenol is used as the antibacterial in a kind of Wound filling in Chinese patent CN 101590287B
Agent, experiment show that the hydrogel containing 0.5% eugenol is read to escherichia coli, staphylococcus aureuses, bacillus pyocyaneus and white
Coccus and their mixed vaccine have strong killing action.But as other organic antibacterial agents and mite-proof agent, eugenol or
The thermostability of isoeugenol is poor, starts a large amount of volatilizations at 100 DEG C, it is impossible to prepare by the method for melt spinning and contain eugenol
Or the antibiosis anti-acarien fiber of isoeugenol.
Content of the invention
In view of the shortcomings of the prior art, purpose of the invention is to provide a kind of antibiosis anti-acarien fiber and its preparation side
Method.
To achieve these goals, the present invention is employed the following technical solutions：
A kind of antibiosis anti-acarien fiber, including following raw material by weight：
Preferably, described polymer is the thermoplastic polymer suitable for melt spinning.
It is further preferred that described polymer is selected from, but it is not limited to, polyethylene, polypropylene, polyformaldehyde, polyamide, poly-
One or more in ester, polylactic acid etc..
Preferably, described surface conditioning agent is selected from, but is not limited to, silane coupler, aluminate coupling agent, titanate esters idol
Connection agent, aluminum titanium coupling agent, stearic acid, stearate, Titanium Dioxide, one or more in silicon dioxide etc..
Preferably, the antibiosis anti-acarien fiber also includes auxiliary agent.
It is further preferred that the auxiliary agent includes dispersant, antioxidant etc..
A kind of method for preparing above-mentioned antibiosis anti-acarien fiber, comprises the following steps：
(1) eugenol and/or isoeugenol are mixed with zinc oxide, through ball mill refinement, is sieved, obtained compounding antibacterial and prevent
Demodicid mite powder body；
(2) surface conditioning agent is added to compounding antibiosis anti-acarien powder body, Surface coating is carried out to which；
(3) by a small amount of polymer with mix homogeneously through surface coated compounding antibiosis anti-acarien powder body, the auxiliary agent of step (2),
Melting extrusion pelletize, obtains compounding antibiosis anti-acarien master batch；
(4) polymer of surplus is mixed homogeneously with compounding antibiosis anti-acarien master batch, auxiliary agent, through melt spinning, antibacterial is obtained
Mite-assistant fiber.
Wherein prepare auxiliary agent used in compounding antibiosis anti-acarien master batch to spin with the master batch melting of compounding antibiosis anti-acarien with polymer
During silk, auxiliary agent used is identical.
Preferably, the mean diameter of the compounding antibiosis anti-acarien powder body for obtaining in step (1) is less than 1.2 μm；In step (2)
The mean diameter through surface coated compounding antibiosis anti-acarien powder body for arriving is less than 3 μm.
Preferably, the polymer content in the compounding antibiosis anti-acarien master batch for obtaining in step (3) is 40%～90%.
The method that another kind prepares above-mentioned antibiosis anti-acarien fiber, comprises the following steps：
(1) eugenol and/or isoeugenol are mixed with zinc oxide, through ball mill refinement, is sieved, obtained compounding antibacterial and prevent
Demodicid mite powder body；
(2) surface conditioning agent is added to compounding antibiosis anti-acarien powder body, Surface coating is carried out to which；
(3) by polymer with mix homogeneously through surface coated compounding antibiosis anti-acarien powder body, the auxiliary agent of step (2), melting is spun
Silk, is obtained antibiosis anti-acarien fiber.
Preferably, the mean diameter of the compounding antibiosis anti-acarien powder body for obtaining in step (1) is less than 1.2 μm；In step (2)
The mean diameter through surface coated compounding antibiosis anti-acarien powder body for arriving is less than 3 μm.
The kind of the auxiliary agent of the technique, equipment and interpolation of compounding antibiosis anti-acarien master batch is prepared in the present invention using extrusion by melting
Class and content, and prepare the species of the auxiliary agent of technique, equipment and the interpolation of antibiosis anti-acarien fiber using melt spinning method and contain
Amount is identical with equipment with the existing process of selected polymer.
Eugenol and isoeugenol are a kind of liquid organic compounds, with excellent sterilization and acaricidal ability, due to which
Boiling point relatively low and be difficult in polymeric matrix dispersed, therefore, using directly adding eugenol and/or different in the polymer
Eugenol, the antibiosis anti-acarien poor-performing that antibiosis anti-acarien fiber is prepared by the method for melt spinning.Zinc oxide is that one kind has
The inorganic compound of certain sterilizing ability, is widely used in polymeric material, but directly adds zinc oxide warp in the polymer
Antibiosis anti-acarien fiber prepared by the method for melt spinning does not possess antibacterial effect substantially.
In the present invention, by eugenol and/or the compounding of isoeugenol and zinc oxide, using eugenol and/or isobutyl
Chemical interaction between fragrant phenol and zinc oxide, significantly improves the heat stability of eugenol and/or isoeugenol；Using eugenol
And/or the synergism between isoeugenol and zinc oxide, significantly improve its antibiosis anti-acarien effect；Using surface conditioning agent to Flos Caryophylli
Phenol and/or isoeugenol carry out Surface coating with the compounding antibiosis anti-acarien powder body of zinc oxide, on the one hand improve compounding antibiosis anti-acarien
Powder body dispersibility in the polymer, on the other hand gives its slow release characteristic, significantly improves the antibiosis anti-acarien effect of prepared fiber
The enduring quality of fruit.Test indicate that, even if using antibiosis anti-acarien fiber obtained in this preparation method after washing 50 times, still
Excellent antibiosis anti-acarien performance can be kept.
Beneficial effects of the present invention
The present invention has advantages below compared with prior art：
(1) from the low toxic and environment-friendly extracted from plant, to person poultry harmless, and there is very strong sterilization, mite killing and drive demodicid mite and make
Eugenol or isoeugenol natural product overcome existing organic mite-proof agent such as Ah as organic mite-proof agent of the present invention
The highly toxic problems such as dimension rhzomorph, ivermectin；
(2) by eugenol and/or the compounding of isoeugenol and zinc oxide, using eugenol and/or isoeugenol and oxygen
Change the chemical interaction between zinc, significantly improve the heat stability of eugenol and/or isoeugenol, overcome eugenol or isobutyl
The thermostability of fragrant phenol is poor, starts a large amount of volatilizations at 100 DEG C, it is impossible to prepare by the method for melt spinning and contain eugenol or different
The notable deficiency of the antibiosis anti-acarien fiber of eugenol；
(3) using the synergism between eugenol and/or isoeugenol and zinc oxide, its antibiosis anti-acarien effect is significantly improved
Really；
(4) eugenol and/or isoeugenol are carried out with the compounding antibiosis anti-acarien powder body of zinc oxide using surface conditioning agent
Surface coating, on the one hand improves its dispersibility in the polymer, on the other hand gives its slow release characteristic, significantly improves prepared
The enduring quality of the antibiosis anti-acarien effect of fiber.
Description of the drawings
Fig. 1 is the infrared spectrum that zinc oxide, eugenol and eugenol-zinc oxide compounds antiseptic and mite-proof agent；
Fig. 2 is the thermogravimetric curve figure that zinc oxide, eugenol and eugenol-zinc oxide compounds antiseptic and mite-proof agent.
Specific embodiment
The present invention is further detailed below by specific embodiment, but the invention is not limited in following institute
The specific embodiment that enumerates.
A kind of preparation of 1 antibiosis anti-acarien polypropylene fibre of embodiment
(1) formula for preparing antibiosis anti-acarien polypropylene fibre is following (weight portion)：
(2) preparation of antibiosis anti-acarien polypropylene fibre is comprised the following steps：
Step 1：Weigh organic mite-proof agent isoeugenol 0.05 part (weight) and 1.00 parts of inorganic antiseptic zinc oxide (weight
Amount), high-speed mixer high-speed stirred is added to, after mix homogeneously, through planetary ball mill grinding refinement, is sieved, is obtained average
Particle diameter is 1.18 μm of isoeugenol/zinc oxide compounding antibiosis anti-acarien powder body；
Step 2：Isoeugenol after by refinement/zinc oxide compounding antibiosis anti-acarien powder body is placed in high-speed mixer, is being stirred
Mixing 0.09 part of (weight) Silane coupling reagent KH-570 of addition in mixed process carries out surface coating modification process to which, is obtained average
Particle diameter is 2.75 μm of surface coated isoeugenols/zinc oxide compounding antibiosis anti-acarien powder body；
Step 3：Weigh 100 parts of (weight) polypropylene anti-with the Surface coating isoeugenol of step 2 gained/zinc oxide compounding
The anti-mite powder body of bacterium, with auxiliary agent such as dispersant, antioxidant etc. is mixed homogeneously after drying 1 hour at 100 DEG C, is then added to melting and is spun
Spinning in silk machine, is obtained antibiosis anti-acarien polypropylene fibre, and its antibiosis anti-acarien performance is shown in Table 1.
A kind of preparation of 2 antibiosis anti-acarien nylon 6 fiber of embodiment
(1) formula for preparing antibiosis anti-acarien nylon 6 fiber is following (weight portion)：
(2) preparation of antibiosis anti-acarien nylon 6 fiber is comprised the following steps：
Step 1：Weigh organic mite-proof agent eugenol 0.25 part (weight) and isoeugenol 0.25 part (weight) and inorganic anti-
2.50 parts of microbial inoculum zinc oxide (weight), is added to high-speed mixer high-speed stirred, after mix homogeneously, grinds through planetary ball mill
Refinement, sieves, and prepared mean diameter is 1.12 μm of (eugenol+isoeugenol)/zinc oxide compounding antibiosis anti-acarien powder body；
Step 2：(eugenol+isoeugenol)/zinc oxide compounding antibiosis anti-acarien powder body after by refinement is placed in mixed at high speed
In machine, in stirring mixed process, add 0.10 part of (weight) silane resin acceptor kh-550 and 0.05 part of (weight) Titanium Dioxide pair
Which carries out surface coating modification process, and prepared 3.15 parts of (weight) mean diameters are 2.25 μm of Surface coating (eugenol+isobutyl
Fragrant phenol)/zinc oxide compounding antibiosis anti-acarien powder body；
Step 3：Weigh 7.35 parts of (weight) nylon 6 and 3.15 parts of (weight) step 2 gained Surface coating (eugenol+
Isoeugenol)/zinc oxide compounding antibiosis anti-acarien powder body, with auxiliary agent such as dispersant, antioxidant etc. after drying 1 hour at 100 DEG C
Mix homogeneously, melting extrusion pelletize are obtained 10.5 parts (weight) (eugenol+isoeugenol)/zinc oxide compounding antibiosis anti-acarien female
Grain, 6 content 70% of nylon in the master batch；
Step 4：Weigh the Surface coating (eugenol of 92.65 parts of (weight) nylon 6 and 10.50 parts of (weight) step 3 gained
+ isoeugenol)/zinc oxide compounding antibiosis anti-acarien master batch, with auxiliary agent such as dispersant, antioxidant etc. after drying 2 hours at 120 DEG C
Mix homogeneously, is then added to spinning in melt spinning machine, and antibiosis anti-acarien nylon 6 fiber is obtained, and its antibiosis anti-acarien performance is shown in Table 1.
A kind of preparation of 3 antibiosis anti-acarien polyethylene fibre of embodiment
(1) formula for preparing antibiosis anti-acarien polyethylene fibre is following (weight portion)：
(2) preparation of antibiosis anti-acarien polyethylene fibre is comprised the following steps：
Step 1：Organic mite-proof agent eugenol 0.25 part (weight) and 4.00 parts of inorganic antiseptic zinc oxide (weight) is weighed,
High-speed mixer high-speed stirred is added to, after mix homogeneously, through planetary ball mill grinding refinement, is sieved, mean diameter is obtained
Compounding antibiosis anti-acarien powder body for 1.05 μm of eugenol/zinc oxide；
Step 2：The compounding antibiosis anti-acarien powder body of the eugenol/zinc oxide after by refinement is placed in high-speed mixer, is being stirred
Mixing 0.30 part of (weight) titanate coupling agent of addition in mixed process carries out surface coating modification process to which, is obtained 4.55 parts
(weight) mean diameter is 1.75 μm of surface coated eugenol/zinc oxide compounding antibiosis anti-acarien powder body；
Step 3：Weigh the surface coated Flos Caryophylli of 3.03 parts of (weight) polyethylene and 4.55 parts of (weight) step 2 gained
Phenol/zinc oxide compounding antibiosis anti-acarien powder body, with auxiliary agent such as dispersant, antioxidant etc. is mixed after drying 1 hour at 100 DEG C
Even, melting extrusion pelletize is obtained 7.58 parts of (weight) eugenol/zinc oxide compounding antibiosis anti-acarien master batch, polyethylene in the master batch
Content 40%；
Step 4：Weigh the Surface coating eugenol of 96.97 parts of (weight) polyethylene and 7.58 parts of (weight) step 3 gained/
Zinc oxide compounds antibiosis anti-acarien master batch, mixs homogeneously with auxiliary agent such as dispersant, antioxidant etc., so at 100 DEG C after drying 1 hour
After be added to spinning in melt spinning machine, antibiosis anti-acarien polyethylene fibre is obtained, its antibiosis anti-acarien performance is shown in Table 1.
A kind of preparation of 4 antibiosis anti-acarien polyester fiber of embodiment
(1) formula for preparing antibiosis anti-acarien polyester fiber is following (weight portion)：
(2) preparation of antibiosis anti-acarien polyester fiber is comprised the following steps：
Step 1：Organic mite-proof agent eugenol 0.10 part (weight) and 0.50 part of inorganic antiseptic zinc oxide (weight) is weighed,
High-speed mixer high-speed stirred is added to, after mix homogeneously, through planetary ball mill grinding refinement, is sieved, mean diameter is obtained
Eugenol for 1.1 μm/zinc oxide compounding antibiosis anti-acarien powder body；
Step 2：Eugenol after by refinement/zinc oxide compounding antibiosis anti-acarien powder body is placed in high-speed mixer, in stirring
Add 0.01 part of (weight) silicon dioxide surface coating modification process to be carried out to which in mixed process, 0.61 part (weight) is obtained and puts down
Particle diameter is 1.55 μm of surface coated eugenol/zinc oxide compounding antibiosis anti-acarien powder body；
Step 3：Weigh the Surface coating eugenol/oxygen of 5.49 parts of (weight) polyester and 0.61 part of (weight) step 2 gained
Change zinc compounding antibiosis anti-acarien powder body, mix homogeneously with auxiliary agent such as dispersant, antioxidant etc. after drying 2 hours at 120 DEG C, melt
Extruding pelletization, is obtained 6.10 parts of (weight) eugenol/zinc oxide compounding antibiosis anti-acarien master batch, amount of polyester 90% in the master batch；
Step 4：Weigh the Surface coating eugenol/oxygen of 94.51 parts of (weight) polyester and 6.10 parts of (weight) step 3 gained
Change zinc compounding antibiosis anti-acarien master batch, mix homogeneously with auxiliary agent such as dispersant, antioxidant etc. after drying 2 hours at 120 DEG C, then
Spinning in melt spinning machine is added to, antibiosis anti-acarien polyester fiber is obtained, its antibiosis anti-acarien performance is shown in Table 1.
A kind of preparation of 1 polypropylene fibre of comparative example
(1) formula for preparing polypropylene fibre is following (weight portion)：
Polypropylene 100
Isoeugenol 0.05
(2) preparation of polypropylene fibre is comprised the following steps：
Weigh the isoeugenol of 100 parts of (weight) polypropylene and 0.05 part, after drying 1 hour at 100 DEG C with dispersant,
The mix homogeneously such as antioxidant, are then added to spinning in melt spinning machine, and polypropylene fibre is obtained, and its antibiosis anti-acarien performance is shown in Table 1.
A kind of preparation of 2 polypropylene fibre of comparative example
(1) formula for preparing polypropylene fibre is following (weight portion)：
Polypropylene 100
Zinc oxide 1.00
Silane coupling reagent KH-570 0.09
(2) preparation of polypropylene fibre is comprised the following steps：
Step 1：1.00 parts of inorganic antiseptic zinc oxide (weight) is weighed, through planetary ball mill grinding refinement, is sieved, is made
Obtain the Zinc oxide powder that mean diameter is 1.18 μm；
Step 2：Zinc oxide after by refinement is placed in high-speed mixer, adds 0.09 part of (weight in stirring mixed process
Amount) Silane coupling reagent KH-570 carries out surface coating modification process to which, and it is 2.75 μm of surface coated oxygen that mean diameter is obtained
Change zinc powder body；
Step 3：The coated with zinc oxide powder body of 100 parts of (weight) polypropylene and step 2 gained is weighed, at 100 DEG C
Mix homogeneously with auxiliary agent such as dispersant, antioxidant etc. after drying 1 hour, be then added to spinning in melt spinning machine, be obtained poly- third
Alkene fiber, its antibiosis anti-acarien performance are shown in Table 1.
The measure of the antibiosis anti-acarien performance of fiber
Antibiosis anti-acarien fiber prepared by embodiment 1 to embodiment 4 is spun into fabric and the fiber prepared by comparative example 1-2
Be spun into fabric anti-microbial property and anti-mite performance respectively according to GB/T24253-2009《The evaluation of the anti-mite performance of textile》And FZ/
T73023-2006《Antibiosis knitting product》It is measured, acquired results are as shown in table 1：
1 embodiment 1-4 of table and the antibiosis anti-acarien the performance test results of fiber prepared by comparative example 1-2
The result explanation of embodiment 1-4 imparts the outstanding antibiosis anti-acarien performance of fiber after adding compounding antiseptic and mite-proof agent.
After washing 50 times, fabric is maintained to preferable antibiosis anti-acarien performance.The result of comparative example 1 is due in polypropylene
Melt spinning during, caused by isoeugenol volatilized.Comparative example 2 without eugenol or isoeugenol, only aoxidizing
In the case of zinc is as antiseptic and mite-proof agent, antibiosis anti-acarien effect is significant is relatively low.
Below the present invention is described in detail, the above, only the preferred embodiments of the invention, not as
Limit the scope of the present invention, i.e., all according to the made impartial change of the application scope and modification, all should still belong to covering scope of the present invention
Interior.
Claims (10)
1. a kind of antibiosis anti-acarien fiber, it is characterised in that including following raw material by weight：
2. antibiosis anti-acarien fiber according to claim 1, it is characterised in that described polymer is suitable for melt spinning
Thermoplastic polymer.
3. antibiosis anti-acarien fiber according to claim 1 and 2, it is characterised in that described polymer is selected from polyethylene, poly-
One or more in propylene, polyformaldehyde, polyamide, polyester, polylactic acid.
4. antibiosis anti-acarien fiber according to claim 1, it is characterised in that described surface conditioning agent is selected from silane coupled
Agent, aluminate coupling agent, titanate coupling agent, aluminum titanium coupling agent, stearic acid, stearate, Titanium Dioxide, in silicon dioxide
One or more.
5. antibiosis anti-acarien fiber according to claim 1, it is characterised in that the antibiosis anti-acarien fiber includes auxiliary agent, institute
Stating auxiliary agent includes dispersant, antioxidant.
6. a kind of method of the antibiosis anti-acarien fiber prepared any one of claim 1-5, it is characterised in that including following
Step：
(1) eugenol and/or isoeugenol are mixed with zinc oxide, through ball mill refinement, is sieved, obtain compounding antibiosis anti-acarien powder
Body；
(2) surface conditioning agent is added to compounding antibiosis anti-acarien powder body, Surface coating is carried out to which；
(3) by a small amount of polymer with mix homogeneously through surface coated compounding antibiosis anti-acarien powder body, the auxiliary agent of step (2), melt
Extruding pelletization, obtains compounding antibiosis anti-acarien master batch；
(4) polymer of surplus is mixed homogeneously with compounding antibiosis anti-acarien master batch, auxiliary agent, through melt spinning, antibiosis anti-acarien is obtained
Fiber.
7. method according to claim 6, it is characterised in that the compounding antibiosis anti-acarien powder body obtained in step (1) flat
Particle diameter is less than 1.2 μm；The mean diameter through surface coated compounding antibiosis anti-acarien powder body obtained in step (2) is less than 3 μm.
8. method according to claim 6, it is characterised in that in the compounding antibiosis anti-acarien master batch obtained in step (3)
Polymer content is 40wt%～90wt%.
9. a kind of method of the antibiosis anti-acarien fiber prepared any one of claim 1-5, it is characterised in that including following
Step：
(1) eugenol and/or isoeugenol are mixed with zinc oxide, through ball mill refinement, is sieved, obtain compounding antibiosis anti-acarien powder
Body；
(2) surface conditioning agent is added to compounding antibiosis anti-acarien powder body, Surface coating is carried out to which；
(3) by polymer with mix homogeneously through surface coated compounding antibiosis anti-acarien powder body, the auxiliary agent of step (2), melt spinning, system
Obtain antibiosis anti-acarien fiber.
10. method according to claim 9, it is characterised in that the compounding antibiosis anti-acarien powder body obtained in step (1) flat
Particle diameter is less than 1.2 μm；The mean diameter through surface coated compounding antibiosis anti-acarien powder body obtained in step (2) is less than 3 μm.
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