CN101220527A - Long-acting antibacterial viscose fiber capable of emitting negative ions - Google Patents
Long-acting antibacterial viscose fiber capable of emitting negative ions Download PDFInfo
- Publication number
- CN101220527A CN101220527A CNA2007101907317A CN200710190731A CN101220527A CN 101220527 A CN101220527 A CN 101220527A CN A2007101907317 A CNA2007101907317 A CN A2007101907317A CN 200710190731 A CN200710190731 A CN 200710190731A CN 101220527 A CN101220527 A CN 101220527A
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- Prior art keywords
- viscose
- tourmaline particles
- agent
- antioxidant
- negative ions
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- 229920000297 Rayon Polymers 0.000 title claims abstract description 23
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 10
- 239000000835 fiber Substances 0.000 title abstract description 8
- 150000002500 ions Chemical class 0.000 title abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 18
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 11
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 11
- 229940070527 tourmaline Drugs 0.000 claims abstract description 10
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 10
- 239000011032 tourmaline Substances 0.000 claims abstract description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000003115 biocidal effect Effects 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 239000007822 coupling agent Substances 0.000 claims abstract description 6
- 239000002002 slurry Substances 0.000 claims abstract description 4
- 238000009987 spinning Methods 0.000 claims abstract description 4
- 239000001993 wax Substances 0.000 claims abstract 4
- 150000001450 anions Chemical class 0.000 claims description 16
- 239000003292 glue Substances 0.000 claims description 6
- 239000012190 activator Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 210000002966 serum Anatomy 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008267 milk Substances 0.000 claims description 2
- 210000004080 milk Anatomy 0.000 claims description 2
- 235000013336 milk Nutrition 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 230000003068 static effect Effects 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000004753 textile Substances 0.000 abstract description 7
- 239000004744 fabric Substances 0.000 abstract description 5
- 230000036541 health Effects 0.000 abstract description 3
- 230000003213 activating effect Effects 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000011550 stock solution Substances 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000008280 blood Substances 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 102000005606 Activins Human genes 0.000 description 1
- 108010059616 Activins Proteins 0.000 description 1
- 241000606153 Chlamydia trachomatis Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000588653 Neisseria Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000488 activin Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000001900 immune effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004089 microcirculation Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention discloses a viscose fiber with long-acting antibiosis and capable of emitting negative ions and a production method thereof. The invention adopts the method that the emulsion slurry which is evenly prepared by tourmaline particles modified by low-density polyethylene wax, antioxidant and coupling agent, activating agent, nano antibacterial agent (mainly nano silver), dispersing auxiliary agent and the like is added into the common viscose stock solution, and the viscose fiber which can generate negative ions and antibacterial effect is produced according to the common conventional spinning method. The fiber can be used for manufacturing antibacterial textiles or health textiles, and is an important direction for upgrading textiles for clothing and daily use. They can be used as health underwear and leisure wear, and can also be used as bedroom articles such as curtains, carpets, car interior decorative cloth, bed sheets, quilts and the like.
Description
Technical field
The present invention relates to a kind of viscose, belong to textile technology field with long acting antibiotic, energy transmitting anion.
Background technology
Anion is a kind of electronegative gas ion in the air.All gases composition in the atmosphere not exclusively exists with a minute submode, and wherein a part exists with the free state of ion.Wherein electronegative molecule or particulate (being commonly called as anion) can not only be facilitated the synthetic and vitamin storage of human body, the physiological activity of reinforcement and human activin, vital movement to human body and other biological has crucial influence, so its be otherwise known as " air vitamin ".In medical circle, it is the effective means that has killing pathogenic bacteria and purify air that anion is identified.After its mechanism mainly is anion and bacterium combines, make bacterium produce the change of structure or the transfer of energy, cause bacterium death, final decline is sunken to ground.Medical research shows that electronegative particulate makes oxygen content increase in the blood in the air, helps blood oxygen and carries, absorbs and utilize, and has the metabolism of the human body of promotion, and the raising human immunological competence strengthens human body flesh energy, regulates the effect of human body function balance.According to textual criticism, anion is to 7 systems of human body, and nearly more than 30 kinds of diseases have inhibition, alleviation and auxiliary curing effect, and is especially more obvious to the health-care function of human body.
It is the most extensive that present stage uses, and effect also is that best a kind of nano-antibacterial element is exactly a Nano Silver.Nano Silver (Nano Silver) is exactly that particle diameter is accomplished nano level argent simple substance.The Nano Silver particle diameter about 25 nanometers, all has strong inhibition and killing action to tens of kinds of pathogenic microorganisms such as Escherichia coli, gonococcus, chlamydia trachomatises, and can not produce drug resistance mostly.What deserves to be mentioned is that this product is met the water antibacterial effect and more strengthened, and is more conducive to treatment of diseases.It has following characteristics: 1. broad-spectrum antiseptic; 2. potent sterilization; 3. permeability is strong; 4. recyclability; 5. antibiotic lasting; 6. safety non-toxic; 7. have no drug resistance.
The present usual functionality viscose of producing on the market though also may have certain transmitting anion function and antibacterial effect, because its production process complexity, technological process are long, so causes its price higher.In the world as the sky silk produced of Austrian Lenzin company, its price was once per ton up to 60,000 yuans.Simultaneously, since the difference of production method, the present most functional viscose fibers that occur, and its antibacterial effect all can not keep for a long time, and the concentration of transmitting anion is very low, does not almost have real health-care function.
Summary of the invention
The object of the present invention is to provide a kind of viscose and production method with long acting antibiotic and energy transmitting anion.
Technical solution of the present invention is:
1, the tourmaline particles of particle diameter 400～600nm is put into super mixer, add low density polyethylene (LDPE) wax, a spot of antioxidant and coupling agent and carry out modification;
2, surface treatment is good tourmaline particles and activator, nano antibacterial agent (mainly being Nano Silver) and dispersing aid etc. evenly are mixed with the serum material, add by specific process by a certain percentage, through static and dynamically mixing, this powder is dispersed in the artificial fibre viscose glue;
3,,,, produce the viscose that can produce anion and antibacterial effect of the present invention by the adjusting process parameter by general conventional spinning process according to actual conditions.
The viscose of processing and fabricating of the present invention not only can effectively stop the breeding growth of microorganism on fiber or fabric, has the self-cleaning function of health, also has odor-resistant result.The antiseptic that wherein contains, after strong effect such as washing, surface abrasion, the antibacterial action of fiber can descend hardly, is nonvolatil.Because it has the function of transmitting anion and far infrared, therefore can also promote the blood microcirculation of human body simultaneously; Because anion discharges electric charge, the absorption dust is so can purify air; It also has antibiotic and sterilizing function, can destroy bacterial activity and cause its death.
This fiber can be used for making antibacterial fabric or healthy textiles, is the important directions of taking and living and upgrading with textiles.They can also make dormitory articles such as curtain, carpet, upholstery cloth and sheet, quilt except can doing health-care underclothes, leisure wear.
The specific embodiment
The invention will be further described below in conjunction with specific embodiment:
Select the tourmaline particles of particle diameter 450nm for use, addition is controlled at 15%, and (to the percentage by weight of viscose glue stoste, together, the antioxidant of a kind of dibutyl hydroxy toluene by name (BHT), content are controlled at 0.02%, coupling agent 0.01% down; Low density polyethylene (LDPE) wax 0.05%.These several materials fill with the speed of 10000rpm and to close mixing in the rapid-result blender of height.
(mixture of particle diameter≤20nm) 6%, dispersing aid 0.03% evenly mixes, and adds industrial pure water simultaneously, in the hope of making a kind of milk slurry with containing activator 2%, nano antibacterial agent with the above tourmaline particles that makes.
The slurry that makes in the xanthating machine that viscose glue is produced, in the mode implanter with dynamic mixing, is opened the agitator of xanthating machine, make it at the uniform velocity to stir with the rotating speed of 200rpm, thus the particular adhesive stoste that obtains mixing.Carry out spinning by general viscose filament yarn production procedure, obtain having the functional artificial fiber of anion emission function and antibacterial effect.
Detect through Shanghai textiles inspection center, the fabric that the viscose filament yarn that makes with present embodiment is made, its anion emission concentration is 6580/square centimeter, every square centimeter of surface bacteria sum＜5, after washing 20 times, its correlated performance maintains about 98% of previous level.
Claims (4)
1. one kind has the long acting antibiotic also viscose and the production method of energy transmitting anion, it is characterized in that: the serum material that the tourmaline particles of being carried out modification by low density polyethylene (LDPE) wax, antioxidant, coupling agent and activator, nano antibacterial agent (mainly being Nano Silver) and dispersing aid etc. evenly are mixed with joins in the common viscose glue stoste, produces by general conventional spinning process.
2. viscose according to claim 1 is characterized in that: the tourmaline particles of particle diameter 400～600nm is put into super mixer, add low density polyethylene (LDPE) wax, a spot of antioxidant and coupling agent and carry out modification.
3. viscose according to claim 1, it is characterized in that: tourmaline particles that surface treatment is good and activator, nano antibacterial agent (mainly being Nano Silver) and dispersing aid etc. evenly are mixed with the serum material, add by specific process by a certain percentage, through static and dynamically mixing, this powder is dispersed in the viscose glue raw coal liquid.
4. viscose according to claim 1 is characterized in that: select the tourmaline particles of particle diameter 450nm for use, addition is controlled at 15% (to the percentage by weight of viscose glue stoste, down together); The antioxidant of a kind of dibutyl hydroxy toluene by name (BHT), content is controlled at 0.02%; Coupling agent 0.01%; Low density polyethylene (LDPE) wax 0.05%.These several materials fill with the speed of 10000rpm and to close mixing in the rapid-result blender of height.(mixture of particle diameter≤20nm) 6%, dispersing aid 0.03% evenly mixes, and adds industrial pure water simultaneously, in the hope of making a kind of milk slurry with containing activator 2%, nano antibacterial agent with the above tourmaline particles that makes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101907317A CN101220527A (en) | 2007-11-28 | 2007-11-28 | Long-acting antibacterial viscose fiber capable of emitting negative ions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101907317A CN101220527A (en) | 2007-11-28 | 2007-11-28 | Long-acting antibacterial viscose fiber capable of emitting negative ions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101220527A true CN101220527A (en) | 2008-07-16 |
Family
ID=39630588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101907317A Pending CN101220527A (en) | 2007-11-28 | 2007-11-28 | Long-acting antibacterial viscose fiber capable of emitting negative ions |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101220527A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102121139A (en) * | 2011-01-11 | 2011-07-13 | 上海珍奥生物科技有限公司 | Preparation method of tourmaline viscose fibers |
| CN102772079A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Sterile quilt with nutrients |
| CN102877153A (en) * | 2011-07-14 | 2013-01-16 | 广东柏堡龙股份有限公司 | Negative ion cool lining and method for preparing same |
| CN105080220A (en) * | 2015-09-09 | 2015-11-25 | 江苏创云环保科技有限公司 | Air filter material as well as preparation method and application of air filter material |
| CN105926100A (en) * | 2016-07-01 | 2016-09-07 | 马威（中国）有限公司 | Cool-sense skin care blended yarn with negative ion releasing function and yarn spinning technology thereof |
| CN107299410A (en) * | 2017-08-18 | 2017-10-27 | 太仓佩利斯高分子材料有限公司 | A kind of processing technology of long acting antibiotic chinlon filament |
| CN107385553A (en) * | 2017-08-18 | 2017-11-24 | 太仓佩利斯高分子材料有限公司 | A kind of processing technology of long acting antibiotic polyester filament |
| CN107460596A (en) * | 2017-08-04 | 2017-12-12 | 宁波黄古林工艺品有限公司 | A kind of bamboo fibre summer sleeping mat and preparation method thereof |
| CN107513776A (en) * | 2017-08-18 | 2017-12-26 | 太仓佩利斯高分子材料有限公司 | A kind of processing technology of long acting antibiotic spandex filament |
-
2007
- 2007-11-28 CN CNA2007101907317A patent/CN101220527A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102121139A (en) * | 2011-01-11 | 2011-07-13 | 上海珍奥生物科技有限公司 | Preparation method of tourmaline viscose fibers |
| CN102121139B (en) * | 2011-01-11 | 2013-03-13 | 上海珍奥生物科技有限公司 | Preparation method of tourmaline viscose fibers |
| CN102772079A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Sterile quilt with nutrients |
| CN102772079B (en) * | 2011-05-09 | 2016-05-11 | 紫罗兰家纺科技股份有限公司 | Aseptic nutrient adding quilt |
| CN102877153A (en) * | 2011-07-14 | 2013-01-16 | 广东柏堡龙股份有限公司 | Negative ion cool lining and method for preparing same |
| CN105080220A (en) * | 2015-09-09 | 2015-11-25 | 江苏创云环保科技有限公司 | Air filter material as well as preparation method and application of air filter material |
| CN105926100A (en) * | 2016-07-01 | 2016-09-07 | 马威（中国）有限公司 | Cool-sense skin care blended yarn with negative ion releasing function and yarn spinning technology thereof |
| CN107460596A (en) * | 2017-08-04 | 2017-12-12 | 宁波黄古林工艺品有限公司 | A kind of bamboo fibre summer sleeping mat and preparation method thereof |
| CN107299410A (en) * | 2017-08-18 | 2017-10-27 | 太仓佩利斯高分子材料有限公司 | A kind of processing technology of long acting antibiotic chinlon filament |
| CN107385553A (en) * | 2017-08-18 | 2017-11-24 | 太仓佩利斯高分子材料有限公司 | A kind of processing technology of long acting antibiotic polyester filament |
| CN107513776A (en) * | 2017-08-18 | 2017-12-26 | 太仓佩利斯高分子材料有限公司 | A kind of processing technology of long acting antibiotic spandex filament |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Open date: 20080716 |