CN106497709B - A kind of perfumed soap detergent with skin effect and its conjugate and preparation method with continuous class - Google Patents
A kind of perfumed soap detergent with skin effect and its conjugate and preparation method with continuous class Download PDFInfo
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- CN106497709B CN106497709B CN201610903971.6A CN201610903971A CN106497709B CN 106497709 B CN106497709 B CN 106497709B CN 201610903971 A CN201610903971 A CN 201610903971A CN 106497709 B CN106497709 B CN 106497709B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/005—Synthetic soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/442—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/444—Dyes; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to skin care technical fields, more particularly to a kind of perfumed soap detergent with skin effect and its with the conjugate and preparation method of continuous class, which includes the raw material of following parts by weight: higher fatty acids sodium: 80-120 parts, functional component: 1-10 parts, at A:0.2-2 parts of Studies of The Aromatic Substances and A:0.2-2 parts of colour former.The conjugate of the perfumed soap detergent and continuous class, perfumed soap detergent and continuous class are made according to the ratio of weight ratio 6-10:1.The preparation method includes the preparation of polyurethane prepolymer A, the preparation of polyurethane prepolymer B, the preparation of bathing class polyurethane, the preparation of perfumed soap detergent and the preparation of conjugate.Perfumed soap detergent of the invention and its environmentally protective with the conjugate of continuous class, it is nontoxic to skin non-stimulated, there are a variety of skin-care effects, various skin is suitble to use.The preparation method is easy to operate, at low cost, preparation process pollution is few, is conducive to produce and protect environment.
Description
Technical field
The present invention relates to skin care technical fields, and in particular to a kind of perfumed soap detergent with skin effect and its with continuous class
Conjugate and preparation method.
Background technique
With the development of society, the appearance that people are higher and higher, coloured and dazzling to the pursuit of beauty, it will be rich and varied to people
Life bring confidence, but due to many shadows such as computer radiation, outdoor ultraviolet light irradiation, dietary factor and life stress
It rings, there is the face of part people acne, verruca plana, chloasma, freckle, wind face occur and itch, dry the symptoms such as peeling, thus
People more regard the skin health situation of oneself, and the requirement to skin care item is also higher and higher.
Currently, perfumed soap is used as a kind of most common and most widely used personal cleansing articles, and traditional perfumed soap can only be right
The skin epidermis of human body rise simple cleaning action, cannot generate other skin cares effect, it is difficult to meet people to skin care item,
The increasingly higher demands of cleaning product.
Summary of the invention
In order to overcome shortcoming and defect existing in the prior art, the purpose of the present invention is to provide one kind to have skin care effect
The perfumed soap detergent of fruit, the perfumed soap detergent is environmentally protective to swash, and there is oil of dispelling to dispel dirt, anti-acne, moist, maintenance, anti-oxidant, whitening
Equal skin-care effects, it is nontoxic to skin stingless.
The conjugate of the perfumed soap detergent and continuous class that another object of the present invention is to provide a kind of with skin effect, should
Conjugate is suitble to various skin to use, and improves the clean rate of skin epidermis, can reach cleaning and nurse the double effects of skin.
It is also an object of the present invention to provide a kind of perfumed soap detergent with skin effect and its knots with continuous class
Close object and preparation method, the preparation method is easy to operate, at low cost, preparation process pollution is few, is conducive to produce in batches and protect
Retaining ring border.
The purpose of the invention is achieved by the following technical solution: a kind of perfumed soap detergent with skin effect, the perfume (or spice)
Soap detergent includes the raw material of following parts by weight:
80-120 parts of higher fatty acids sodium
1-10 parts of functional component
At 0.2-2 parts of Studies of The Aromatic Substances A
0.2-2 parts of colour former A.
Preferably, the higher fatty acids sodium is in palmitoleic acid sodium, sodium laurate, odium stearate and linolenic acid sodium
It is at least one.Higher fatty acids sodium of the present invention increases the water solubility, foamability and dirt-removing power of skin-protection soap, right
The irritation of skin is low.More preferably, the higher fatty acids sodium be by palmitoleic acid sodium, sodium laurate and odium stearate with
The mixture of weight ratio 2.4-3.2:1.4-2.2:1 composition.
Preferably, the functional component is seaweed, bamboo charcoal, aloe, vitamin E, green-tea extract, ginseng extract, day
Zhu Kui extract, tea tree extract, licorice, Honegsukle flower P.E, Flos Rosae Rugosae extract, Herba Lysimachiae foenumgraeci extract, cucumber
Extract, lemon extract, Yoghourt extract, tea tree ethereal oil, Peppermint essential oil, narra essential oil, flores aurantii essential oil, cinnamon essential oil,
Pogostemon cablin essential, needle juniper essential oil, eucalyptus quintessence oil, Salvia japonica essential oil, myrrh essential oil, Cananga odorata quintessence oil, bigarabe leaf essential oil, fish pelargonium
At least one in essential oil, Bergamot, asarum flower essential oil, polyphenol powde essential oil, yulan essential oil, lily of the valley essential oil and Rosemary Oil
Kind.The present invention by above-mentioned functional component, make polyurethane skincare soap have oil of dispelling dispel dirt, anti-acne, Sage Extract, moist, maintenance,
The skin-care effects such as anti-oxidant, whitening, wrinkle resistant, increase elasticity, and above-mentioned plants essential oil functional component, play polyurethane skincare soap
To relieving mood, the effect relieved stress, the effect of each essential oil, is specific as follows:
1. tea tree ethereal oil: can bactericidal antiphlogistic, restrain pore, improve skin quality fragility, melanin deposition, whelk repeatedly, skin
The skin problem such as skin aging enables skin pure and fresh smooth；
2. Peppermint essential oil: can purifying skin, balance skin fat secretion, shrinkable capilary, releive itch, inflammation and burn
Wound excludes vivotoxin, removes blackhead, and facilitate the improvement of respiratory problems；
3. narra essential oil: can pre- anti-wrinkle, purification skin, promote cell reconstruction, eliminate black eye, can balance and soften
Skin improves dry, desalination texture, can separately control insomnia, mood placating；
4. flores aurantii essential oil: there is whitening, moisturizing, improve sensitive skin, improvement dry skin and promote cytothesis function,
It in addition can relieving mood, anti-melancholy, conditioning endocrine, increase resistance of human body；
5. cinnamon essential oil: pre- anti-wrinkle, treatment whelk mildly restrain skin, promote blood circulation, anti-aging can subtract
Fertilizer, the slack and undisciplined skin after consolidation weight-reducing, can suitably treat melancholia；
6. Pogostemon cablin essential: pore can be restrained, Firm, promote skin regeneration, have good bactericidal effect that can treat the youth
Acne, scytitis, scar and allergy.It can be used for anti-melancholy；
7. needle juniper essential oil: acne and dermatitis can be treated and convergence pore, Bergamot Mint Extract enable skin clean and white,
It can be used for losing weight；
8. eucalyptus quintessence oil: can sterilize, treat whelk, promote wound healing, improve obstruction skin, can also eliminate tired
Labor, calm mood；
9. Salvia japonica essential oil: the bloodstain that pore is coarse and skin dry and wet rash, after eliminating dark sore more can be improved, it can skin whitening
And promote cytothesis；
10. myrrh essential oil: to dry skin, aging, the coarse effect that has clear improvement；
11. Cananga odorata quintessence oil: adjustable acth secretion minds at rest, makes one to feel joy；
12. bigarabe leaf essential oil: adjustable skin function mitigates sebum secretion, has sterilizing function to acne, whelk, also
Anti-depression, calming nerves system allow body to keep pure and fresh vigor；
13. Geranium Essential: sebum secretion can be balanced, make turgor；Slack and undisciplined, pore obstruction and oiliness skin can be improved
Skin is suitble to various skins, can also relieve pain, antibacterial, can increase cytophylaxis function and promotes to recycle；
14. Bergamot: the smegma of oily skin can be balanced, can promote wound healing, pain can be mitigated, it is right
In indigestion and depressed also helpful；
15. asarum flower essential oil: menstruation can be improved and had some setbacks, and stress is adjusted, loosens mood, eliminates fatigue, refreshes oneself
The effect of restoring consciouness；
16. polyphenol powde essential oil: second-hand smoke, purification air can be decomposed, and the metabolism of body can be promoted, while may be used also
It eliminates physical fatigue and balances mood；
17. yulan essential oil: can moisturizing, it is anti-it is sensitive, balance sebum secretion, prevent and treat whelk, activate aging skin
Cell promotes skin blood circulation, can increase immune function of human body, can eliminate peculiar smell, inhibit bacterium, on the other hand can also delay
And stress；
18. lily of the valley essential oil: peculiar smell can be eliminated, inhibit bacterial growth, function of immune system can be increased；
19. Rosemary Oil: skin can be restrained, conditioning skin fat secretion promotes blood circulation, mitigation dermohemia,
Edema, swelling, can pre- anti-wrinkle, skin, removal dandruff, can also eliminate fatigue.
Preferably, it is described at Studies of The Aromatic Substances A be thyme essential oil, Lavender, sandalwood essential oil and clove oil in extremely
Few one kind；The colour former A be rose glycosides, carrotene, turmeric, balsamine glycosides, sunset yellow and blueberry extract in extremely
Few one kind.The present invention is not only made skin-protection soap have pure and fresh fragrance, but also the pressure that can releive, is adjusted by above-mentioned at Studies of The Aromatic Substances A
Mood, pleasure mood；The present invention also passes through above-mentioned colour former A, can beautify the appearance of skin-protection soap, produces jointly with colour former
The atmosphere of raw pleasant.More preferably, described at Studies of The Aromatic Substances A is by thyme essential oil, Lavender and clove oil
The mixture formed with weight ratio 1.5-2.5:1-2:1；More preferably, the colour former A is by rose glycosides, carrotene
The mixture formed with balsamine glycosides with weight ratio 1.4-2.2:2.4-3.2:1.
Another object of the present invention is achieved through the following technical solutions: a kind of perfumed soap detergent with skin effect and silk floss
The conjugate of class, the conjugate are clear according to the stable perfumed soap of ratio, the performance of weight ratio 6-10:1 by perfumed soap detergent and continuous class
Clean dose with the conjugate of continuous class.
Preferably, the continuous class is bathing class polyurethane, and bathing class polyurethane is by polyurethane prepolymer A and polyurethane prepolymer
Object B is made according to the ratio of weight ratio 1.5-3.5:1；
The polyurethane prepolymer A includes the raw material of following parts by weight:
Stearic alcohol ether 0.5-1.5 parts
1-10 parts of epoxide
1-10 parts of antibacterial agent
At 0.2-2 parts of Studies of The Aromatic Substances B
0.2-2 parts of colour former B.
The present invention passes through the weight ratio of strict control polyurethane prepolymer A and polyurethane prepolymer B, helps to be made high-quality
The stable continuous class of amount, performance.
Preferably, the stearic alcohol ether be cetearyl alcohol alcohol ether, cetearyl alcohol alcohol ether -20, polyoxyethylene stearyl alcohol ether and
At least one of PPG-15 tristearin alcohol ether；The epoxide is ethylene oxide, propylene oxide, epoxy resin and epoxy chlorine
At least one of propane；The antibacterial agent is sodium benzoate, outstanding person horse BP antibacterial agent, Jia Landan and iodo propinyl ammonia formic acid fourth
At least one of ester.The present invention makes skin-protection soap have preferable wetting, decontamination and emulsifying power by above-mentioned stearic alcohol ether
Power；The present invention plays solidification also by above-mentioned epoxide, and skin-protection soap is made to have the function of resistance to mould；The present invention
Also by above-mentioned antibacterial agent, plays the role of antibacterial and sterilization to skin-protection soap, the growth of bacterium can be prevented.
More preferably, the stearic alcohol ether is stearic by cetearyl alcohol alcohol ether, polyoxyethylene stearyl alcohol ether and PPG-15
The mixture that alcohol ether is formed with weight ratio 1.4-2.2:0.8-1.2:1；More preferably, the epoxide is by epoxy second
The mixture that alkane, propylene oxide and epoxy resin are formed with weight ratio 1.5-2.5:1-2:1；More preferably, the antibacterial agent
It is made of outstanding horse BP antibacterial agent, Jia Landan and iodo propinyl ammonia butyl formate with weight ratio 0.8-1.2:1.4-2.2:1
Mixture.
Preferably, it is described at Studies of The Aromatic Substances B be Rosa Damascana, refined jasmine oil, lily essential oil, osmanthus essential oil and yulan essential oil in
At least one；The colour former B is in alkermes, tomato red, chlorophyll, carthamic acid, lemon yellow and blueberry extract
At least one.The present invention not only makes skin-protection soap have pure and fresh fragrance, but also the pressure that can releive by above-mentioned at Studies of The Aromatic Substances B,
Adjust mood, pleasure mood；The present invention also passes through above-mentioned colour former B, can beautify the appearance of skin-protection soap, total with colour former
With the atmosphere for generating pleasant.More preferably, described at Studies of The Aromatic Substances B is by Rosa Damascana, refined jasmine oil and osmanthus essential oil
The mixture formed with weight ratio 1.5-2.5:1-2:1；More preferably, the colour former B be by carthamic acid, lemon yellow and
The mixture that blueberry extract is formed with weight ratio 1.4-2.2:2.4-3.2:1.
Preferably, the polyurethane prepolymer B is diphenylmethylene diisocyanate polyol prepolymer, diphenylmethyl
Alkane diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate
At least one of polyol prepolymer.The present invention makes polyurethane have adhesiveness and solidification by above-mentioned polyurethane prepolymer B
Property, make skin-protection soap that there are the performances such as thermoplasticity and elasticity.More preferably, the polyurethane prepolymer B is diphenylmethylene
Diisocyanate polyol prepolymer, methyl diphenylene diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyalcohol
The mixing that prepolymer and poly methylene poly phenyl poly isocyanate polyol prepolymer are formed with weight ratio 1.5-2.5:1-2:1
Object.
A further object of the invention is achieved through the following technical solutions: a kind of above-mentioned perfumed soap with skin effect is clear
Clean dose with the preparation method of the conjugate of continuous class, include the following steps:
(1) preparation of polyurethane prepolymer A: weigh according to the weight ratio stearic alcohol ether, epoxide, antibacterial agent, at
Studies of The Aromatic Substances B and colour former B, is mixed evenly, and polyurethane prepolymer A is made；
(2) preparation of polyurethane prepolymer B: it is pre- that diphenylmethylene diisocyanate polyalcohol is weighed according to the weight ratio
Polymers, methyl diphenylene diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer or polymethylene are more
Polyphenyl polyisocyanate polyol prepolymer, stirs evenly, and polyurethane prepolymer B is made；
(3) preparation of bathing class polyurethane: by poly- ammonia made from polyurethane prepolymer A made from step (1) and step (2)
Ester prepolymer B is uniformly mixed according to the ratio of weight ratio 1.5-3.5:1, carries out foamable reaction, and bathing class polyurethane is made；
(4) preparation of perfumed soap detergent: weigh higher fatty acids sodium, functional component according to the weight ratio, at Studies of The Aromatic Substances A and
Colour former A, is mixed evenly, and perfumed soap detergent is made；
(5) preparation of the conjugate of perfumed soap detergent and bathing class polyurethane: perfumed soap detergent made from step (4) is pressed
It is dissolved into bathing class polyurethane made from step (3) according to the ratio of weight ratio 6-10:1, obtains mixture, feed the mixture into
It is cooled and shaped into mold, the conjugate of perfumed soap detergent and bathing class polyurethane with skin effect is made.
The beneficial effects of the present invention are perfumed soap detergent of the invention, have oil of dispelling dispel dirt, anti-acne, moist, maintenance,
The skin-care effects such as anti-oxidant, whitening, it is nontoxic to skin non-stimulated.
The conjugate of perfumed soap detergent and continuous class of the invention, continuous class are bathing class polyurethane, bathing class polyurethane and perfume
Soap detergent combines, and is convenient for people to use, and can improve the clean rate of skin epidermis, is suitble to various skin to use, can reach clear
Clean and nursing skin double effects.
Preparation method of the invention is easy to operate, at low cost, preparation process pollution is few, is conducive to batch production and protection ring
Border.
Specific embodiment
For the ease of the understanding of those skilled in the art, below with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying refers to not is limitation of the invention.
Embodiment 1
A kind of perfumed soap detergent with skin effect, the raw material including following parts by weight:
80 parts of higher fatty acids sodium
2 parts of functional component
At 0.2 part of Studies of The Aromatic Substances A
0.2 part of colour former A.
The higher fatty acids sodium is odium stearate.
The functional component is ginseng extract, Flos Pelargonii Hortori, licorice, Honegsukle flower P.E, narra
Essential oil or flores aurantii essential oil.
It is described at Studies of The Aromatic Substances A be thyme essential oil；The colour former A is rose glycosides, carrotene.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, by perfumed soap detergent and continuous class according to weight
Ratio than 6:1 is made.
It is described silk floss class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to
The ratio of weight ratio 1.5:1 is made.
The polyurethane prepolymer A includes the raw material of following parts by weight:
0.5 part of stearic alcohol ether
1 part of epoxide
1 part of antibacterial agent
At 0.2 part of Studies of The Aromatic Substances B
0.2 part of colour former B.
The tristearin alcohol ether is cetearyl alcohol alcohol ether；The epoxide is ethylene oxide；The antibacterial agent is benzene first
Sour sodium.
It is described at Studies of The Aromatic Substances B be lily essential oil；The colour former B is alkermes, tomato red.
The polyurethane prepolymer B is diphenylmethylene diisocyanate polyol prepolymer.
The preparation method of a kind of perfumed soap detergent with skin effect and the conjugate of continuous class, includes the following steps:
(1) preparation of polyurethane prepolymer A: weigh according to the weight ratio stearic alcohol ether, epoxide, antibacterial agent, at
Studies of The Aromatic Substances B and colour former B, is mixed evenly, and polyurethane prepolymer A is made；
(2) preparation of polyurethane prepolymer B: it is pre- that diphenylmethylene diisocyanate polyalcohol is weighed according to the weight ratio
Polymers stirs evenly, and polyurethane prepolymer B is made；
(3) preparation of bathing class polyurethane: by poly- ammonia made from polyurethane prepolymer A made from step (1) and step (2)
Ester prepolymer B is uniformly mixed according to the ratio of weight ratio 1.5:1, carries out foamable reaction, and bathing class polyurethane is made；
(4) preparation of perfumed soap detergent: weigh higher fatty acids sodium, functional component according to the weight ratio, at Studies of The Aromatic Substances A and
Colour former A, is mixed evenly, and perfumed soap detergent is made；
(5) preparation of perfumed soap detergent and the conjugate of continuous class: by perfumed soap detergent made from step (4) according to weight ratio
The ratio of 6:1 is dissolved into bathing class polyurethane made from step (3), and mixture is obtained, and is added mixture to cold in mold
But it forms, the conjugate of perfumed soap detergent and continuous class with skin effect is made.
Embodiment 2
The difference of the present embodiment and above-described embodiment 1 is:
A kind of perfumed soap detergent with skin effect, the raw material including following parts by weight:
90 parts of higher fatty acids sodium
4 parts of functional component
At 0.5 part of Studies of The Aromatic Substances A
0.5 part of colour former A.
The higher fatty acids sodium is linolenic acid sodium.
The functional component is tea tree extract, Herba Lysimachiae foenumgraeci extract, Fructus Cucumidis sativi extract, lemon extract, Yoghourt extraction
Object, Peppermint essential oil or cinnamon essential oil.
It is described at Studies of The Aromatic Substances A be thyme essential oil；The colour former A is turmeric.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, by perfumed soap detergent and continuous class according to weight
Ratio than 7:1 is made.
It is described silk floss class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to
The ratio of weight ratio 2:1 is made.
The polyurethane prepolymer A includes the raw material of following parts by weight:
0.8 part of stearic alcohol ether
3 parts of epoxide
3 parts of antibacterial agent
At 0.5 part of Studies of The Aromatic Substances B
0.5 part of colour former B.
The tristearin alcohol ether is cetearyl alcohol alcohol ether -20.；The epoxide is propylene oxide；The antibacterial agent is
Sodium benzoate.
It is described at Studies of The Aromatic Substances B be refined jasmine oil；The colour former B is chlorophyll.
The polyurethane prepolymer B is diphenylmethylene diisocyanate polyol prepolymer.
The preparation method of a kind of perfumed soap detergent with skin effect and the conjugate of continuous class in the step (2), is pressed
Diphenylmethylene diisocyanate polyol prepolymer is weighed according to weight proportion, is stirred evenly, polyurethane prepolymer B is made；
In the step (3), by polyurethane prepolymer made from polyurethane prepolymer A made from step (1) and step (2)
B is uniformly mixed according to the ratio of weight ratio 2:1, carries out foamable reaction, and bathing class polyurethane is made；
In the step (5), perfumed soap detergent made from step (4) is dissolved into step according to the ratio of weight ratio 7:1
(3) in bathing class polyurethane made from, mixture is obtained, adds mixture in mold and is cooled and shaped, being made has skin care
The conjugate of the perfumed soap detergent of effect and continuous class.
Embodiment 3
The difference of the present embodiment and above-described embodiment 1 is:
A kind of perfumed soap detergent with skin effect, the raw material including following parts by weight:
100 parts of higher fatty acids sodium
6 parts of functional component
At 1.0 parts of Studies of The Aromatic Substances A
1.0 parts of colour former A.
The higher fatty acids sodium is palmitoleic acid sodium.
The functional component is that seaweed, bamboo charcoal, aloe, vitamin E, green-tea extract, tea tree ethereal oil or rose are extracted
Object.
It is described at Studies of The Aromatic Substances A be Lavender；The colour former A is balsamine glycosides.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, by perfumed soap detergent and continuous class according to weight
Ratio than 8:1 is made.
It is described silk floss class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to
The ratio of weight ratio 2.5:1 is made.
The polyurethane prepolymer A includes the raw material of following parts by weight:
1.0 parts of stearic alcohol ether
5 parts of epoxide
1.0 parts of antibacterial agent
1.0 parts of colour former B.
The tristearin alcohol ether is polyoxyethylene stearyl alcohol ether；The epoxide is epoxy resin；The antibacterial agent is
Jia Landan.
It is described at Studies of The Aromatic Substances B be Rosa Damascana；The colour former B is carthamic acid.
The polyurethane prepolymer B is methyl diphenylene diisocyanate polyol prepolymer.
The preparation method of a kind of perfumed soap detergent with skin effect and the conjugate of continuous class in the step (2), is pressed
Methyl diphenylene diisocyanate polyol prepolymer is weighed according to weight proportion, is stirred evenly, polyurethane prepolymer B is made；
In the step (3), by polyurethane prepolymer made from polyurethane prepolymer A made from step (1) and step (2)
B is uniformly mixed according to the ratio of weight ratio 2.5:1, carries out foamable reaction, and bathing class polyurethane is made；
In the step (5), perfumed soap detergent made from step (4) is dissolved into step according to the ratio of weight ratio 8:1
(3) in bathing class polyurethane made from, mixture is obtained, adds mixture in mold and is cooled and shaped, being made has skin care
The conjugate of the perfumed soap detergent of effect and continuous class.
Embodiment 4
The difference of the present embodiment and above-described embodiment 1 is:
A kind of perfumed soap detergent with skin effect, the raw material including following parts by weight:
110 parts of higher fatty acids sodium
8 parts of functional component
At 1.5 parts of Studies of The Aromatic Substances A
1.5 parts of colour former A.
The higher fatty acids sodium is sodium laurate.
The functional component is Geranium Essential, Bergamot, asarum flower essential oil, polyphenol powde essential oil, yulan essential oil, bell
Lenzin oil or Rosemary Oil.
It is described at Studies of The Aromatic Substances A be sandalwood essential oil；The colour former A is sunset yellow.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, by perfumed soap detergent and continuous class according to weight
Ratio than 9:1 is made.
It is described silk floss class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to
The ratio of weight ratio 3:1 is made.
The polyurethane prepolymer A includes the raw material of following parts by weight:
1.2 parts of stearic alcohol ether
7 parts of epoxide
7 parts of antibacterial agent
At 1.5 parts of Studies of The Aromatic Substances B
1.5 parts of colour former B.
The tristearin alcohol ether is PPG-15 tristearin alcohol ether；The epoxide is epoxychloropropane；The antibacterial agent is
Outstanding horse BP antibacterial agent.
It is described at Studies of The Aromatic Substances B be osmanthus essential oil；The colour former B is lemon yellow.
The polyurethane prepolymer B is toluene di-isocyanate(TDI) polyol prepolymer.
The preparation method of a kind of perfumed soap detergent with skin effect and the conjugate of continuous class in the step (2), is pressed
Toluene di-isocyanate(TDI) polyol prepolymer is weighed according to weight proportion, is stirred evenly, polyurethane prepolymer B is made；
In the step (3), by polyurethane prepolymer made from polyurethane prepolymer A made from step (1) and step (2)
B is uniformly mixed according to the ratio of weight ratio 3:1, carries out foamable reaction, and bathing class polyurethane is made；
In the step (5), perfumed soap detergent made from step (4) is dissolved into step according to the ratio of weight ratio 9:1
(3) in bathing class polyurethane made from, mixture is obtained, adds mixture in mold and is cooled and shaped, being made has skin care
The conjugate of the perfumed soap detergent of effect and continuous class.
Embodiment 5
The difference of the present embodiment and above-described embodiment 1 is:
A kind of perfumed soap detergent with skin effect, the raw material including following parts by weight:
120 parts of higher fatty acids sodium
10 parts of functional component
At 2 parts of Studies of The Aromatic Substances A
2 parts of colour former A.
The higher fatty acids sodium is linolenic acid sodium.
The functional component is Pogostemon cablin essential, needle juniper essential oil, eucalyptus quintessence oil, Salvia japonica essential oil, myrrh essential oil, Yilan
Essential oil or bigarabe leaf essential oil.
It is described at Studies of The Aromatic Substances A be clove oil；The colour former A is blueberry extract.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, by perfumed soap detergent and continuous class according to weight
Ratio than 10:1 is made.
It is described silk floss class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to
The ratio of weight ratio 3.5:1 is made.
The polyurethane prepolymer A includes the raw material of following parts by weight:
1.5 parts of stearic alcohol ether
10 parts of epoxide
10 parts of antibacterial agent
At 2 parts of Studies of The Aromatic Substances B
2 parts of colour former B.
The tristearin alcohol ether is PPG-15 tristearin alcohol ether；The epoxide is epoxychloropropane；The antibacterial agent is
Iodo propinyl ammonia butyl formate.
It is described at Studies of The Aromatic Substances B be yulan essential oil；The colour former B is blueberry extract.
The polyurethane prepolymer B is poly methylene poly phenyl poly isocyanate polyol prepolymer.
The preparation method of a kind of perfumed soap detergent with skin effect and the conjugate of continuous class in the step (2), is pressed
Poly methylene poly phenyl poly isocyanate polyol prepolymer is weighed according to weight proportion, is stirred evenly, polyurethane prepolymer is made
B；
In the step (3), by polyurethane prepolymer made from polyurethane prepolymer A made from step (1) and step (2)
B is uniformly mixed according to the ratio of weight ratio 3.5:1, carries out foamable reaction, and bathing class polyurethane is made；
In the step (5), perfumed soap detergent made from step (4) is dissolved into step according to the ratio of weight ratio 10:1
(3) in bathing class polyurethane made from, mixture is obtained, adds mixture in mold and is cooled and shaped, being made has skin care
The conjugate of the perfumed soap detergent of effect and continuous class.
Embodiment 6
The difference of the present embodiment and above-described embodiment 1 is:
A kind of perfumed soap detergent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate
The mixture formed with odium stearate with weight ratio 2.4:2.2:1.
It is described to be made of thyme essential oil, Lavender and cloves essence with weight ratio 1.5:2.0:1 at Studies of The Aromatic Substances A
Mixture；The mixing that the colour former A is made of rose glycosides, carrotene and balsamine glycosides with weight ratio 1.4:3.2:1
Object.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, the tristearin alcohol ether is by cetostearyl alcohol
The mixture that ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether are formed with weight ratio 1.4:1.2:1；The epoxy compound
The mixture that object is made of ethylene oxide, propylene oxide and epoxy resin with weight ratio 1.5:2.0:1；The antibacterial agent be by
The mixture that outstanding horse BP antibacterial agent, Jia Landan and iodo propinyl ammonia butyl formate are formed with weight ratio 0.8:2.2:1.
It is described to be mixed at Studies of The Aromatic Substances B by Rosa Damascana, refined jasmine oil and osmanthus essential oil with what weight ratio 1.5:2.0:1 was formed
Close object；The mixture that the colour former B is made of carthamic acid, lemon yellow and blueberry extract with weight ratio 1.4:3.2:1.
The polyurethane prepolymer B is that diphenylmethylene diisocyanate polyol prepolymer, diphenyl methane two are different
Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol
The mixture that prepolymer is formed with weight ratio 1.5:2.0:1.
Embodiment 7
The difference of the present embodiment and above-described embodiment 2 is:
A kind of perfumed soap detergent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate
The mixture formed with odium stearate with weight ratio 2.6:2.0:1.
It is described to be made of thyme essential oil, Lavender and cloves essence with weight ratio 1.7:1.7:1 at Studies of The Aromatic Substances A
Mixture；The mixing that the colour former A is made of rose glycosides, carrotene and balsamine glycosides with weight ratio 1.6:3.0:1
Object.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, the tristearin alcohol ether is by cetostearyl alcohol
The mixture that ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether are formed with weight ratio 1.6:1.1:1；The epoxy compound
The mixture that object is made of ethylene oxide, propylene oxide and epoxy resin with weight ratio 1.7:1.8:1；The antibacterial agent be by
The mixture that outstanding horse BP antibacterial agent, Jia Landan and iodo propinyl ammonia butyl formate are formed with weight ratio 0.9:2.0:1.
It is described to be mixed at Studies of The Aromatic Substances B by Rosa Damascana, refined jasmine oil and osmanthus essential oil with what weight ratio 1.7:1.8:1 was formed
Close object；The mixture that the colour former B is made of carthamic acid, lemon yellow and blueberry extract with weight ratio 1.6:3.0:1.
The polyurethane prepolymer B is that diphenylmethylene diisocyanate polyol prepolymer, diphenyl methane two are different
Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol
The mixture that prepolymer is formed with weight ratio 1.8:1.7:1.
Embodiment 8
The difference of the present embodiment and above-described embodiment 3 is:
A kind of perfumed soap detergent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate
The mixture formed with odium stearate with weight ratio 2.8:1.8:1.
It is described to be made of thyme essential oil, Lavender and cloves essence with weight ratio 2.0:1.5:1 at Studies of The Aromatic Substances A
Mixture；The mixing that the colour former A is made of rose glycosides, carrotene and balsamine glycosides with weight ratio 1.8:2.8:1
Object.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, the tristearin alcohol ether is by cetostearyl alcohol
The mixture that ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether are formed with weight ratio 1.8:1.0:1；The epoxy compound
The mixture that object is made of ethylene oxide, propylene oxide and epoxy resin with weight ratio 2.0:1.5:1；The antibacterial agent be by
The mixture that outstanding horse BP antibacterial agent, Jia Landan and iodo propinyl ammonia butyl formate are formed with weight ratio 1.0:1.8:1.
It is described to be mixed at Studies of The Aromatic Substances B by Rosa Damascana, refined jasmine oil and osmanthus essential oil with what weight ratio 2.0:1.5:1 was formed
Close object；The mixture that the colour former B is made of carthamic acid, lemon yellow and blueberry extract with weight ratio 1.8:2.8:1.
The polyurethane prepolymer B is that diphenylmethylene diisocyanate polyol prepolymer, diphenyl methane two are different
Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol
The mixture that prepolymer is formed with weight ratio 2.0:1.5:1.
Embodiment 9
The difference of the present embodiment and above-described embodiment 4 is:
A kind of perfumed soap detergent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate
The mixture formed with odium stearate with weight ratio 3.0:1.6:1.
It is described to be made of thyme essential oil, Lavender and cloves essence with weight ratio 2.3:1.3:1 at Studies of The Aromatic Substances A
Mixture；The mixing that the colour former A is made of rose glycosides, carrotene and balsamine glycosides with weight ratio 2.0:2.6:1
Object.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, the tristearin alcohol ether is by cetostearyl alcohol
The mixture that ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether are formed with weight ratio 2.0:0.9:1；The epoxy compound
The mixture that object is made of ethylene oxide, propylene oxide and epoxy resin with weight ratio 2.3:1.2:1；The antibacterial agent be by
The mixture that outstanding horse BP antibacterial agent, Jia Landan and iodo propinyl ammonia butyl formate are formed with weight ratio 1.1:1.6:1.
It is described to be mixed at Studies of The Aromatic Substances B by Rosa Damascana, refined jasmine oil and osmanthus essential oil with what weight ratio 2.3:1.2:1 was formed
Close object；The mixture that the colour former B is made of carthamic acid, lemon yellow and blueberry extract with weight ratio 2.0:2.6:1.
The polyurethane prepolymer B is that diphenylmethylene diisocyanate polyol prepolymer, diphenyl methane two are different
Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol
The mixture that prepolymer is formed with weight ratio 2.2:1.3:1.
Embodiment 10
The difference of the present embodiment and above-described embodiment 5 is:
A kind of perfumed soap detergent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate
The mixture formed with odium stearate with weight ratio 3.2:1.4:1.
It is described to be made of thyme essential oil, Lavender and cloves essence with weight ratio 2.5:1.0:1 at Studies of The Aromatic Substances A
Mixture；The mixing that the colour former A is made of rose glycosides, carrotene and balsamine glycosides with weight ratio 2.2:2.4:1
Object.
The conjugate of a kind of perfumed soap detergent with skin effect and continuous class, the tristearin alcohol ether is by cetostearyl alcohol
The mixture that ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether are formed with weight ratio 2.2:0.8:1；The epoxy compound
The mixture that object is made of ethylene oxide, propylene oxide and epoxy resin with weight ratio 2.5:1.0:1；The antibacterial agent be by
The mixture that outstanding horse BP antibacterial agent, Jia Landan and iodo propinyl ammonia butyl formate are formed with weight ratio 1.2:1.4:1.
It is described to be mixed at Studies of The Aromatic Substances B by Rosa Damascana, refined jasmine oil and osmanthus essential oil with what weight ratio 2.5:1.0:1 was formed
Close object；The mixture that the colour former B is made of carthamic acid, lemon yellow and blueberry extract with weight ratio 2.2:2.4:1.
The polyurethane prepolymer B is that diphenylmethylene diisocyanate polyol prepolymer, diphenyl methane two are different
Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol
The mixture that prepolymer is formed with weight ratio 2.5:1.0:1.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other way,
Do not depart under the premise of present inventive concept it is any obviously replace it is within the scope of the present invention.
Claims (1)
1. the conjugate of a kind of perfumed soap detergent with skin effect and continuous class, it is characterised in that: the conjugate is clear by perfumed soap
Clean dose is made with continuous class according to the ratio of weight ratio 6-10:1；
The perfumed soap detergent includes the raw material of following parts by weight:
The higher fatty acids sodium is palmitoleic acid sodium, sodium laurate and odium stearate with weight ratio (2.4-3.2): (1.4-
2.2): the mixture of 1 composition；The functional component is seaweed, bamboo charcoal, aloe, vitamin E, green-tea extract, ginseng extraction
Object, Flos Pelargonii Hortori, tea tree extract, licorice, Honegsukle flower P.E, Flos Rosae Rugosae extract, Herba Lysimachiae foenumgraeci extract,
Fructus Cucumidis sativi extract, lemon extract, Yoghourt extract, tea tree ethereal oil, Peppermint essential oil, narra essential oil, flores aurantii essential oil, cinnamon spirit
Oil, Pogostemon cablin essential, needle juniper essential oil, eucalyptus quintessence oil, Salvia japonica essential oil, myrrh essential oil, Cananga odorata quintessence oil, bigarabe leaf essential oil, day
In Zhu Kui essential oil, Bergamot, asarum flower essential oil, polyphenol powde essential oil, yulan essential oil, lily of the valley essential oil and Rosemary Oil extremely
Few one kind；Described at Studies of The Aromatic Substances A is at least one of thyme essential oil, Lavender, sandalwood essential oil and clove oil；Institute
Colour former A is stated by the mixing that forms for rose glycosides, carrotene and balsamine glycosides with weight ratio 1.4-2:2.4-3.2:1
Object；
The silk floss class is bathing class polyurethane, and bathing class polyurethane is by polyurethane prepolymer A and polyurethane prepolymer B according to weight
Ratio than 1.5-3.5:1 is made；The polyurethane prepolymer B is by diphenylmethylene diisocyanate polyalcohol pre-polymerization
Object, methyl diphenylene diisocyanate polyol prepolymer and toluene di-isocyanate(TDI) polyol prepolymer are according to weight ratio
1.5-2.5:1-2:1 the mixture of composition；
The polyurethane prepolymer A includes the raw material of following parts by weight:
The tristearin alcohol ether is cetearyl alcohol alcohol ether, cetearyl alcohol alcohol ether -20, polyoxyethylene stearyl alcohol ether and PPG-15 stearyl alcohol
At least one of ether；The epoxide is at least one of propylene oxide, epoxy resin and epoxychloropropane；It is described
Antibacterial agent is at least one of sodium benzoate and iodo propinyl ammonia butyl formate；It is described at Studies of The Aromatic Substances B be Rosa Damascana, jasmine
At least one of jasmine essential oil, lily essential oil, osmanthus essential oil and yulan essential oil；The colour former B is alkermes, tomato
At least one of red, chlorophyll, carthamic acid, lemon yellow and blueberry extract；
The conjugate of the perfumed soap detergent and continuous class, is made by following steps:
(1) stearic alcohol ether, epoxide, antibacterial agent, Cheng Xiang the preparation of polyurethane prepolymer A: are weighed according to weight
Substance B and colour former B, are mixed evenly, and polyurethane prepolymer A is made；
(2) preparation of polyurethane prepolymer B: diphenylmethylene diisocyanate polyalcohol pre-polymerization is weighed according to the weight ratio
Object, methyl diphenylene diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer, stir evenly, and are made
Polyurethane prepolymer B；
(3) preparation of bathing class polyurethane: polyurethane made from polyurethane prepolymer A made from step (1) and step (2) is pre-
Polymers B is uniformly mixed according to the ratio of weight ratio 1.5-3.5:1, carries out foamable reaction, and bathing class polyurethane is made；
(4) preparation of perfumed soap detergent: higher fatty acids sodium, functional component are weighed according to the weight ratio, at Studies of The Aromatic Substances A and quality
Substance A is mixed evenly, and perfumed soap detergent is made；
(5) preparation of the conjugate of perfumed soap detergent and bathing class polyurethane: by perfumed soap detergent made from step (4) according to weight
It measures the ratio than 6-10:1 to be dissolved into bathing class polyurethane made from step (3), obtains mixture, add mixture to mould
It is cooled and shaped in tool, the conjugate of perfumed soap detergent and bathing class polyurethane with skin effect is made.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453224A (en) * | 2011-07-15 | 2012-05-16 | 上海高裕海绵制品有限公司 | Technology for producing sponge from plant oil polyether |
| CN202786200U (en) * | 2012-08-17 | 2013-03-13 | 郑裕集 | Sponge soap |
| CN104762145A (en) * | 2015-04-17 | 2015-07-08 | 谢松芬 | Antipruritic toilet soap containing shrubby sophora extract |
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2016
- 2016-10-17 CN CN201610903971.6A patent/CN106497709B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453224A (en) * | 2011-07-15 | 2012-05-16 | 上海高裕海绵制品有限公司 | Technology for producing sponge from plant oil polyether |
| CN202786200U (en) * | 2012-08-17 | 2013-03-13 | 郑裕集 | Sponge soap |
| CN104762145A (en) * | 2015-04-17 | 2015-07-08 | 谢松芬 | Antipruritic toilet soap containing shrubby sophora extract |
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