CN106497709A - A kind of perfumed soap cleaning agent with skin effect and its conjugate with continuous class and preparation method - Google Patents

A kind of perfumed soap cleaning agent with skin effect and its conjugate with continuous class and preparation method Download PDF

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Publication number
CN106497709A
CN106497709A CN201610903971.6A CN201610903971A CN106497709A CN 106497709 A CN106497709 A CN 106497709A CN 201610903971 A CN201610903971 A CN 201610903971A CN 106497709 A CN106497709 A CN 106497709A
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China
Prior art keywords
cleaning agent
perfumed soap
essential oil
soap cleaning
polyurethane
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Granted
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CN201610903971.6A
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CN106497709B (en
Inventor
龙永杰
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DONGGUAN TAIKANG FOAM SPONGE Co Ltd
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DONGGUAN TAIKANG FOAM SPONGE Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/005Synthetic soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/225Polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44Perfumes; Colouring materials; Brightening agents ; Bleaching agents
    • C11D9/442Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44Perfumes; Colouring materials; Brightening agents ; Bleaching agents
    • C11D9/444Dyes; Pigments

Abstract

The present invention relates to skin care technical field, and in particular to a kind of perfumed soap cleaning agent with skin effect and its conjugate with continuous class and preparation method, the perfumed soap cleaning agent include the raw material of following weight portion:Higher fatty acids sodium:80 120 parts, functional component:1 10 parts, into Studies of The Aromatic Substances A:0.2 2 parts and colour former A:0.2 2 parts.The perfumed soap cleaning agent and the conjugate of continuous class, perfumed soap cleaning agent and continuous class are according to weight than 6 10:1 ratio is obtained.The preparation method includes the preparation of polyurethane prepolymer A, the preparation of polyurethane prepolymer B, the preparation of bathing class polyurethane, the preparation of perfumed soap cleaning agent and the preparation of conjugate.The perfumed soap cleaning agent of the present invention and its conjugate environmental protection with continuous class, nontoxic to skin non-stimulated, with multiple skin-care effects, it is suitable for various skin and uses.The preparation method is simple to operate, the pollution of low cost, preparation process is few, is conducive to production and environmental protection.

Description

A kind of perfumed soap cleaning agent with skin effect and its conjugate with continuous class and preparation Method
Technical field
The present invention relates to skin care technical field, and in particular to a kind of perfumed soap cleaning agent with skin effect and its with continuous class Conjugate and preparation method.
Background technology
With the development of society, people will be given people rich and varied to beautiful pursuit more and more higher, coloured and dazzling appearance Life bring confidence, but due to many shadows such as computer radiation, outdoor ultraviolet irradiation, dietary factor and life stress Ring, the face for there are part people occurs in that acne, flat wart, chloasma, freckle, wind face itch, dry the symptoms such as peeling, thus People more regard the skin health situation of oneself, the also more and more higher of the requirement to skin care item.
At present, perfumed soap is used as the most common and most widely used personal cleansing articles for use of one kind, and traditional perfumed soap can only be right The skin epidermis of human body plays simple cleaning action, it is impossible to produce other skin nursings effect, it is difficult to meet people to skin care item, The higher and higher requirement of cleaning product.
Content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of imitate with skin care The perfumed soap cleaning agent of fruit, the perfumed soap cleaning agent environmental protection swash, with oil of dispelling dispel dirt, anti-acne, moisten, maintenance, anti-oxidant, whitening Deng skin-care effect, nontoxic to skin stingless.
Another object of the present invention is to the conjugate of a kind of perfumed soap cleaning agent with skin effect and continuous class is provided, should Conjugate is suitable for various skin and uses, and improves the clean rate of skin epidermis, can reach the double effectses of cleaning and nursing skin.
It is also an object of the present invention to provide a kind of perfumed soap cleaning agent with skin effect and its knot with continuous class Compound and preparation method, the preparation method is simple to operate, the pollution of low cost, preparation process is few, is conducive to producing in batches and protects Retaining ring border.
The purpose of the present invention is achieved through the following technical solutions:A kind of perfumed soap cleaning agent with skin effect, the perfume (or spice) Soap cleaning agent includes the raw material of following weight portion:
Higher fatty acids sodium 80-120 parts
Functional component 1-10 parts
Into Studies of The Aromatic Substances A 0.2-2 parts
Colour former A 0.2-2 parts.
Preferably, the higher fatty acids sodium is in palmitoleic acid sodium, sodium laurate, odium stearate and linolenic acid sodium At least one.Higher fatty acids sodium of the present invention, increased water solubility, foamability and the dirt-removing power of skin-protection soap, right The excitant of skin is low.Be more highly preferred to, the higher fatty acids sodium be by palmitoleic acid sodium, sodium laurate and odium stearate with Weight compares 2.4-3.2:1.4-2.2:The mixture of 1 composition.
Preferably, the functional component is marine alga, bamboo charcoal, aloe, vitamin E, green-tea extract, ginseng extract, day Zhu Kui extracts, tea tree extract, licorice, Honegsukle flower P.E, Flos Rosae Rugosae extract, Herba Lysimachiae foenumgraeci extract, cucumber Extract, lemon extract, Yoghourt extract, tea tree ethereal oil, Peppermint essential oil, narra essential oil, flores aurantii essential oil, cinnamon essential oil, Pogostemon cablin essential, needle juniper essential oil, eucalyptus quintessence oil, Salvia japonica essential oil, myrrh essential oil, Cananga odorata quintessence oil, bigarabe leaf essential oil, fish pelargonium In essential oil, Bergamot, asarum flower essential oil, polyphenol powde essential oil, yulan essential oil, lily of the valley essential oil and Rosemary Oil at least one Kind.The present invention by above-mentioned functional component, make polyurethane skincare soap have oil of dispelling dispel dirt, anti-acne, Sage Extract, moisten, maintenance, The skin-care effects such as anti-oxidant, whitening, wrinkle resistant, increase elasticity, and above-mentioned plants essential oil functional component, rise polyurethane skincare soap Arrive relieving mood, alleviate the effect of pressure, effect of each essential oil is specific as follows:
1. tea tree ethereal oil:Can bactericidal antiphlogistic, restrain pore, improve skin quality fragility, melanin deposition, whelk repeatedly, skin old The skin problems such as change, make skin pure and fresh smooth;
2. Peppermint essential oil:Can purifying skin, balance skin fat secretion, collapsible capilary, releive and itch, inflammation and burn, Vivotoxin is excluded, blackhead is removed, and is contributed to the improvement of respiratory problems;
3. narra essential oil:Can pre- anti-wrinkle, purify skin, promote cell reproduce, eliminate livid ring around eye, can balance and soften flesh Skin, improvement are dried, desalination texture, can separately control insomnia, mood placating;
4. flores aurantii essential oil:There is whitening, moisturizing, improve skin sensitivity, improve scaly dry skin and promote cytothesis function, in addition Can relieving mood, anti-melancholy, conditioning endocrine, increase resistance of human body;
5. cinnamon essential oil:Pre- anti-wrinkle, treatment whelk, gently restrain skin, stimulate circulation, and anti-aging can be lost weight, tightly Slack and undisciplined skin after real fat-reducing, can suitably treat melancholia;
6. Pogostemon cablin essential:Pore, Firm can be restrained, promote skin regeneration, have good bactericidal action treat whelk, skin Skin inflammation, scar and allergy.Can be used for anti-melancholy;
7. needle juniper essential oil:Acne and dermatitis and convergence pore can be treated, Bergamot Mint Extract makes skin clean and white, can use In fat-reducing;
8. eucalyptus quintessence oil:Can be sterilized, whelk is treated, promotes wound healing, improve obstruction skin, also can dispelling fatigue, town Pledge love thread;
9. Salvia japonica essential oil:The bloodstain that pore is thick and skin dry and wet rash, after eliminating dark sore more can be improved, skin whitening can be promoted Enter cytothesis;
10. myrrh essential oil:To scaly dry skin, aging, the coarse effect that has clear improvement;
11. Cananga odorata quintessence oils:Adjustable acth secretion, minds at rest, and makes one to feel vigorously pleased;
12. bigarabe leaf essential oils:Adjustable skin function, mitigates sebum secretion, has sterilizing function to acne, whelk, also resists and prevents Funeral, calming nerves system, allow body to keep pure and fresh vigor;
13. Geranium Essentials:Sebum secretion can be balanced, make turgor;Slack and undisciplined, pore obstruction and Oily can be improved, fitted Close various skins, also can pain relieving, antibacterial, cytophylaxis function can be increased and promote to circulate;
14. Bergamots:The smegma of oily skin can be balanced, wound healing can be promoted, pain can be mitigated, for disappearing Change bad and depressed also helpful;
15. asarum flower essential oils:Menstruation can be improved to have some setbacks, and be can adjust stress, loosened mood, dispelling fatigue, refresh the mind Effect;
16. polyphenol powde essential oils:The second-hand smoke of energy decomposition, purify air, and the metabolism of body can be promoted, while can also eliminate Physical fatigue simultaneously balances mood;
17. yulan essential oils:Can moisturizing, anti-sensitive, balance sebum secretion, prevention and treatment whelk, activate aged skin cells, Promote skin blood circulation, by increasing capacitance it is possible to increase immune function of human body, peculiar smell can be eliminated, suppress bacterium, on the other hand can also relax essence Refreshing pressure;
18. lily of the valley essential oils:Peculiar smell, bacteria growing inhibiting can be eliminated, function of immune system can be increased;
19. Rosemary Oils:Skin can be restrained, conditioning skin fat secretion stimulates circulation, mitigate dermohemia, edema, Swelling, can pre- anti-wrinkle, skin, remove dandruff, also can dispelling fatigue.
Preferably, described into Studies of The Aromatic Substances A be thyme essential oil, Lavender, sandalwood essential oil and clove oil in extremely Few one kind;The colour former A be rose glycosides, carrotene, turmeric, balsamine glycosides, sunset yellow and blueberry extract at least A kind of.The present invention is not only made skin-protection soap that there is pure and fresh fragrance, and pressure of releiving, is adjusted feelings by above-mentioned into Studies of The Aromatic Substances A Thread, pleasure mood;The present invention can beautify the outward appearance of skin-protection soap, be produced with colour former jointly also by above-mentioned colour former A The atmosphere of pleasant.Be more highly preferred to, described into Studies of The Aromatic Substances A be by thyme essential oil, Lavender and clove oil with Weight compares 1.5-2.5:1-2:The mixture of 1 composition;Be more highly preferred to, the colour former A be by rose glycosides, carrotene and Balsamine glycosides compares 1.4-2.2 with weight:2.4-3.2:The mixture of 1 composition.
Another object of the present invention is achieved through the following technical solutions:A kind of perfumed soap cleaning agent with skin effect and silk floss The conjugate of class, the conjugate compare 6-10 by perfumed soap cleaning agent and continuous class according to weight:1 ratio, the perfumed soap of stable performance are clear Clean dose with the conjugate of continuous class.
Preferably, the continuous class is bathing class polyurethane, and bathing class polyurethane is by polyurethane prepolymer A and polyurethane prepolymer Thing B compares 1.5-3.5 according to weight:1 ratio is obtained;
The polyurethane prepolymer A includes the raw material of following weight portion:
Stearic alcohol ether 0.5-1.5 parts
Epoxide 1-10 parts
Antiseptic 1-10 parts
Into Studies of The Aromatic Substances B 0.2-2 parts
Colour former B 0.2-2 parts.
Weight ratio of the present invention by strictly control polyurethane prepolymer A and polyurethane prepolymer B, contributes to prepared high-quality Amount, the continuous class of stable performance.
Preferably, the stearic alcohol ether be cetearyl alcohol alcohol ether, cetearyl alcohol alcohol ether -20, polyoxyethylene stearyl alcohol ether and At least one in PPG-15 tristearin alcohol ethers;The epoxide is oxirane, expoxy propane, epoxy resin and epoxy chlorine At least one in propane;The antiseptic is Sodium Benzoate, outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia formic acid fourth At least one in ester.The present invention makes skin-protection soap that there is preferably wetting, decontamination and emulsifying power by above-mentioned stearic alcohol ether Power;The present invention plays solidification, makes skin-protection soap that there is the function of resistance to mould also by above-mentioned epoxide;The present invention Also by above-mentioned antiseptic, antibacterial and sterilized effect is played to skin-protection soap, can prevent growing for bacterium.
It is more highly preferred to, the stearic alcohol ether is stearic by cetearyl alcohol alcohol ether, polyoxyethylene stearyl alcohol ether and PPG-15 Alcohol ether compares 1.4-2.2 with weight:0.8-1.2:The mixture of 1 composition;It is more highly preferred to, the epoxide is by epoxy second Alkane, expoxy propane and epoxy resin compare 1.5-2.5 with weight:1-2:The mixture of 1 composition;It is more highly preferred to, the antiseptic It is, by outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia butyl formate, 0.8-1.2 is compared with weight:1.4-2.2:1 composition Mixture.
Preferably, described into Studies of The Aromatic Substances B be Rosa Damascana, refined jasmine oil, lily essential oil, osmanthus essential oil and yulan essential oil in At least one;The colour former B is in alkermes, tomato red, chlorophyll, carthamic acid, lemon yellow and blueberry extract At least one.The present invention not only makes skin-protection soap that there is pure and fresh fragrance, and pressure of releiving by above-mentioned into Studies of The Aromatic Substances B, Adjust mood, pleasure mood;The present invention can beautify the outward appearance of skin-protection soap also by above-mentioned colour former B, with colour former altogether With the atmosphere for producing pleasant.Be more highly preferred to, described into Studies of The Aromatic Substances B be by Rosa Damascana, refined jasmine oil and osmanthus essential oil 1.5-2.5 is compared with weight:1-2:The mixture of 1 composition;Be more highly preferred to, the colour former B be by carthamic acid, lemon yellow and Blueberry extract compares 1.4-2.2 with weight:2.4-3.2:The mixture of 1 composition.
Preferably, the polyurethane prepolymer B is MDI polyol prepolymer, diphenylmethyl Alkane diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate At least one in polyol prepolymer.The present invention makes polyurethane that there is cohesive and solidification by above-mentioned polyurethane prepolymer B Property, make skin-protection soap that there is the performances such as thermoplasticity and elasticity.It is more highly preferred to, the polyurethane prepolymer B is diphenylmethylene Diisocyanate polyol prepolymer, methyl diphenylene diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyalcohol Prepolymer and poly methylene poly phenyl poly isocyanate polyol prepolymer compare 1.5-2.5 with weight:1-2:The mixing of 1 composition Thing.
A further object of the invention is achieved through the following technical solutions:A kind of above-mentioned perfumed soap with skin effect is clear Clean dose with the preparation method of the conjugate of continuous class, comprise the steps:
(1)The preparation of polyurethane prepolymer A:According to weight proportion weigh stearic alcohol ether, epoxide, antiseptic, into perfumery Matter B and colour former B, mixing and stirring are obtained polyurethane prepolymer A;
(2)The preparation of polyurethane prepolymer B:MDI polyalcohol pre-polymerization is weighed according to weight proportion Thing, methyl diphenylene diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer or many benzene of polymethylene Quito isocyanates polyol prepolymer, stirs, and polyurethane prepolymer B is obtained;
(3)The preparation of bathing class polyurethane:By step(1)Obtained polyurethane prepolymer A and step(2)Obtained polyurethane is pre- Polymers B compares 1.5-3.5 according to weight:1 ratio is well mixed, and carries out foamable reaction, and bathing class polyurethane is obtained;
(4)The preparation of perfumed soap cleaning agent:Higher fatty acids sodium, functional component are weighed according to weight proportion, into Studies of The Aromatic Substances A and quality Substance A, mixing and stirring are obtained perfumed soap cleaning agent;
(5)The preparation of the conjugate of perfumed soap cleaning agent and bathing class polyurethane:By step(4)Obtained perfumed soap cleaning agent is according to weight Amount compares 6-10:1 ratio is dissolved into step(3)In obtained bathing class polyurethane, mixture is obtained, mould is added mixture to Cooling shaping in tool, is obtained the conjugate with the perfumed soap cleaning agent with bathing class polyurethane of skin effect.
The beneficial effects of the present invention is:The present invention perfumed soap cleaning agent, with oil of dispelling dispel dirt, anti-acne, moisten, maintenance, The skin-care effects such as anti-oxidant, whitening, nontoxic to skin non-stimulated.
Perfumed soap cleaning agent of the invention and the conjugate of continuous class, continuous class are bathing class polyurethane, bathing class polyurethane and perfume Soap cleaning agent combines, and is convenient for people to use, and can improve the clean rate of skin epidermis, is suitable for various skin and uses, and can reach clear The double effectses of clean and nursing skin.
Preparation method of the invention is simple to operate, the pollution of low cost, preparation process is few, is conducive to batch production and protection ring Border.
Specific embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of perfumed soap cleaning agent with skin effect, including the raw material of following weight portion:
80 parts of higher fatty acids sodium
2 parts of functional component
Into 0.2 part of Studies of The Aromatic Substances A
0.2 part of colour former A.
The higher fatty acids sodium is odium stearate.
The functional component is ginseng extract, Flos Pelargonii Hortori, licorice, Honegsukle flower P.E, narra Essential oil or flores aurantii essential oil.
Described into Studies of The Aromatic Substances A be thyme essential oil;The colour former A is rose glycosides, carrotene.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, by perfumed soap cleaning agent and continuous class according to weight Than 6:1 ratio is obtained.
The continuous class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to Weight compares 1.5:1 ratio is obtained.
The polyurethane prepolymer A includes the raw material of following weight portion:
0.5 part of stearic alcohol ether
1 part of epoxide
1 part of antiseptic
Into 0.2 part of Studies of The Aromatic Substances B
0.2 part of colour former B.
The stearic alcohol ether is cetearyl alcohol alcohol ether;The epoxide is oxirane;The antiseptic is benzene first Sour sodium.
Described into Studies of The Aromatic Substances B be lily essential oil;The colour former B is alkermes, tomato red.
The polyurethane prepolymer B is MDI polyol prepolymer.
A kind of perfumed soap cleaning agent with skin effect and the preparation method of the conjugate of continuous class, comprise the steps:
(1)The preparation of polyurethane prepolymer A:According to weight proportion weigh stearic alcohol ether, epoxide, antiseptic, into perfumery Matter B and colour former B, mixing and stirring are obtained polyurethane prepolymer A;
(2)The preparation of polyurethane prepolymer B:MDI polyalcohol pre-polymerization is weighed according to weight proportion Thing, stirs, and polyurethane prepolymer B is obtained;
(3)The preparation of bathing class polyurethane:By step(1)Obtained polyurethane prepolymer A and step(2)Obtained polyurethane is pre- Polymers B compares 1.5 according to weight:1 ratio is well mixed, and carries out foamable reaction, and bathing class polyurethane is obtained;
(4)The preparation of perfumed soap cleaning agent:Higher fatty acids sodium, functional component are weighed according to weight proportion, into Studies of The Aromatic Substances A and quality Substance A, mixing and stirring are obtained perfumed soap cleaning agent;
(5)The preparation of the conjugate of perfumed soap cleaning agent and continuous class:By step(4)Obtained perfumed soap cleaning agent compares 6 according to weight:1 Ratio be dissolved into step(3)In obtained bathing class polyurethane, mixture is obtained, is added mixture in mould and is cooled to Type, is obtained the conjugate with the perfumed soap cleaning agent with continuous class of skin effect.
Embodiment 2
The present embodiment is with the difference of above-described embodiment 1:
A kind of perfumed soap cleaning agent with skin effect, including the raw material of following weight portion:
90 parts of higher fatty acids sodium
4 parts of functional component
Into 0.5 part of Studies of The Aromatic Substances A
0.5 part of colour former A.
The higher fatty acids sodium is linolenic acid sodium.
The functional component is tea tree extract, Herba Lysimachiae foenumgraeci extract, Fructus Cucumidis sativi extract, lemon extract, Yoghourt extraction Thing, Peppermint essential oil or cinnamon essential oil.
Described into Studies of The Aromatic Substances A be thyme essential oil;The colour former A is turmeric.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, by perfumed soap cleaning agent and continuous class according to weight Than 7:1 ratio is obtained.
The continuous class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to Weight compares 2:1 ratio is obtained.
The polyurethane prepolymer A includes the raw material of following weight portion:
0.8 part of stearic alcohol ether
3 parts of epoxide
3 parts of antiseptic
Into 0.5 part of Studies of The Aromatic Substances B
0.5 part of colour former B.
The stearic alcohol ether is cetearyl alcohol alcohol ether -20.;The epoxide is expoxy propane;The antiseptic is Sodium Benzoate.
Described into Studies of The Aromatic Substances B be refined jasmine oil;The colour former B is chlorophyll.
The polyurethane prepolymer B is MDI polyol prepolymer.
A kind of preparation method of the conjugate of perfumed soap cleaning agent with skin effect and continuous class, the step(2)In, press MDI polyol prepolymer is weighed according to weight proportion, is stirred, polyurethane prepolymer B is obtained;
The step(3)In, by step(1)Obtained polyurethane prepolymer A and step(2)Obtained polyurethane prepolymer B is pressed Compare 2 according to weight:1 ratio is well mixed, and carries out foamable reaction, and bathing class polyurethane is obtained;
The step(5)In, by step(4)Obtained perfumed soap cleaning agent compares 7 according to weight:1 ratio is dissolved into step(3)System In the bathing class polyurethane for obtaining, mixture is obtained, cooling shaping in mould is added mixture to, be obtained and there is skin effect Perfumed soap cleaning agent and the conjugate of continuous class.
Embodiment 3
The present embodiment is with the difference of above-described embodiment 1:
A kind of perfumed soap cleaning agent with skin effect, including the raw material of following weight portion:
100 parts of higher fatty acids sodium
6 parts of functional component
Into 1.0 parts of Studies of The Aromatic Substances A
1.0 parts of colour former A.
The higher fatty acids sodium is palmitoleic acid sodium.
The functional component is that marine alga, bamboo charcoal, aloe, vitamin E, green-tea extract, tea tree ethereal oil or rose are extracted Thing.
Described into Studies of The Aromatic Substances A be Lavender;The colour former A is balsamine glycosides.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, by perfumed soap cleaning agent and continuous class according to weight Than 8:1 ratio is obtained.
The continuous class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to Weight compares 2.5:1 ratio is obtained.
The polyurethane prepolymer A includes the raw material of following weight portion:
1.0 parts of stearic alcohol ether
5 parts of epoxide
1.0 parts of antiseptic
1.0 parts of colour former B.
The stearic alcohol ether is polyoxyethylene stearyl alcohol ether;The epoxide is epoxy resin;The antiseptic is Jia Landan.
Described into Studies of The Aromatic Substances B be Rosa Damascana;The colour former B is carthamic acid.
The polyurethane prepolymer B is methyl diphenylene diisocyanate polyol prepolymer.
A kind of preparation method of the conjugate of perfumed soap cleaning agent with skin effect and continuous class, the step(2)In, press Methyl diphenylene diisocyanate polyol prepolymer is weighed according to weight proportion, is stirred, polyurethane prepolymer B is obtained;
The step(3)In, by step(1)Obtained polyurethane prepolymer A and step(2)Obtained polyurethane prepolymer B is pressed Compare 2.5 according to weight:1 ratio is well mixed, and carries out foamable reaction, and bathing class polyurethane is obtained;
The step(5)In, by step(4)Obtained perfumed soap cleaning agent compares 8 according to weight:1 ratio is dissolved into step(3)System In the bathing class polyurethane for obtaining, mixture is obtained, cooling shaping in mould is added mixture to, be obtained and there is skin effect Perfumed soap cleaning agent and the conjugate of continuous class.
Embodiment 4
The present embodiment is with the difference of above-described embodiment 1:
A kind of perfumed soap cleaning agent with skin effect, including the raw material of following weight portion:
110 parts of higher fatty acids sodium
8 parts of functional component
Into 1.5 parts of Studies of The Aromatic Substances A
1.5 parts of colour former A.
The higher fatty acids sodium is sodium laurate.
The functional component is Geranium Essential, Bergamot, asarum flower essential oil, polyphenol powde essential oil, yulan essential oil, bell Lenzin oil or Rosemary Oil.
Described into Studies of The Aromatic Substances A be sandalwood essential oil;The colour former A is sunset yellow.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, by perfumed soap cleaning agent and continuous class according to weight Than 9:1 ratio is obtained.
The continuous class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to Weight compares 3:1 ratio is obtained.
The polyurethane prepolymer A includes the raw material of following weight portion:
1.2 parts of stearic alcohol ether
7 parts of epoxide
7 parts of antiseptic
Into 1.5 parts of Studies of The Aromatic Substances B
1.5 parts of colour former B.
The stearic alcohol ether is PPG-15 tristearin alcohol ethers;The epoxide is epoxychloropropane;The antiseptic is Outstanding horse BP antiseptics.
Described into Studies of The Aromatic Substances B be osmanthus essential oil;The colour former B is lemon yellow.
The polyurethane prepolymer B is toluene di-isocyanate(TDI) polyol prepolymer.
A kind of preparation method of the conjugate of perfumed soap cleaning agent with skin effect and continuous class, the step(2)In, press Toluene di-isocyanate(TDI) polyol prepolymer is weighed according to weight proportion, is stirred, polyurethane prepolymer B is obtained;
The step(3)In, by step(1)Obtained polyurethane prepolymer A and step(2)Obtained polyurethane prepolymer B is pressed Compare 3 according to weight:1 ratio is well mixed, and carries out foamable reaction, and bathing class polyurethane is obtained;
The step(5)In, by step(4)Obtained perfumed soap cleaning agent compares 9 according to weight:1 ratio is dissolved into step(3)System In the bathing class polyurethane for obtaining, mixture is obtained, cooling shaping in mould is added mixture to, be obtained and there is skin effect Perfumed soap cleaning agent and the conjugate of continuous class.
Embodiment 5
The present embodiment is with the difference of above-described embodiment 1:
A kind of perfumed soap cleaning agent with skin effect, including the raw material of following weight portion:
120 parts of higher fatty acids sodium
10 parts of functional component
Into 2 parts of Studies of The Aromatic Substances A
2 parts of colour former A.
The higher fatty acids sodium is linolenic acid sodium.
The functional component is Pogostemon cablin essential, needle juniper essential oil, eucalyptus quintessence oil, Salvia japonica essential oil, myrrh essential oil, Yilan Essential oil or bigarabe leaf essential oil.
Described into Studies of The Aromatic Substances A be clove oil;The colour former A is blueberry extract.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, by perfumed soap cleaning agent and continuous class according to weight Than 10:1 ratio is obtained.
The continuous class be bathing class polyurethane, bathing class polyurethane by polyurethane prepolymer A and polyurethane prepolymer B according to Weight compares 3.5:1 ratio is obtained.
The polyurethane prepolymer A includes the raw material of following weight portion:
1.5 parts of stearic alcohol ether
10 parts of epoxide
10 parts of antiseptic
Into 2 parts of Studies of The Aromatic Substances B
2 parts of colour former B.
The stearic alcohol ether is PPG-15 tristearin alcohol ethers;The epoxide is epoxychloropropane;The antiseptic is Iodo propinyl ammonia butyl formate.
Described into Studies of The Aromatic Substances B be yulan essential oil;The colour former B is blueberry extract.
The polyurethane prepolymer B is poly methylene poly phenyl poly isocyanate polyol prepolymer.
A kind of preparation method of the conjugate of perfumed soap cleaning agent with skin effect and continuous class, the step(2)In, press Poly methylene poly phenyl poly isocyanate polyol prepolymer is weighed according to weight proportion, is stirred, polyurethane prepolymer is obtained B;
The step(3)In, by step(1)Obtained polyurethane prepolymer A and step(2)Obtained polyurethane prepolymer B is pressed Compare 3.5 according to weight:1 ratio is well mixed, and carries out foamable reaction, and bathing class polyurethane is obtained;
The step(5)In, by step(4)Obtained perfumed soap cleaning agent compares 10 according to weight:1 ratio is dissolved into step(3) In obtained bathing class polyurethane, mixture is obtained, add mixture to cooling shaping in mould, be obtained and there is skin effect Perfumed soap cleaning agent and continuous class conjugate.
Embodiment 6
The present embodiment is with the difference of above-described embodiment 1:
A kind of perfumed soap cleaning agent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate and hard Resin acid sodium compares 2.4 with weight:2.2:The mixture of 1 composition.
Described is to compare 1.5 by thyme essential oil, Lavender and cloves essence with weight into Studies of The Aromatic Substances A:2.0:1 composition Mixture;The colour former A is to compare 1.4 by rose glycosides, carrotene and balsamine glycosides with weight:3.2:The mixing of 1 composition Thing.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, the stearic alcohol ether is by cetostearyl alcohol Ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether compares 1.4 with weight:1.2:The mixture of 1 composition;The epoxy compound Thing is to compare 1.5 by oxirane, expoxy propane and epoxy resin with weight:2.0:The mixture of 1 composition;The antiseptic be by Outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia butyl formate compare 0.8 with weight:2.2:The mixture of 1 composition.
Described is to compare 1.5 by Rosa Damascana, refined jasmine oil and osmanthus essential oil with weight into Studies of The Aromatic Substances B:2.0:1 composition mixed Compound;The colour former B is to compare 1.4 by carthamic acid, lemon yellow and blueberry extract with weight:3.2:The mixture of 1 composition.
The polyurethane prepolymer B is that MDI polyol prepolymer, diphenyl methane two are different Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol Prepolymer compares 1.5 with weight:2.0:The mixture of 1 composition.
Embodiment 7
The present embodiment is with the difference of above-described embodiment 2:
A kind of perfumed soap cleaning agent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate and hard Resin acid sodium compares 2.6 with weight:2.0:The mixture of 1 composition.
Described is to compare 1.7 by thyme essential oil, Lavender and cloves essence with weight into Studies of The Aromatic Substances A:1.7:1 composition Mixture;The colour former A is to compare 1.6 by rose glycosides, carrotene and balsamine glycosides with weight:3.0:The mixing of 1 composition Thing.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, the stearic alcohol ether is by cetostearyl alcohol Ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether compares 1.6 with weight:1.1:The mixture of 1 composition;The epoxy compound Thing is to compare 1.7 by oxirane, expoxy propane and epoxy resin with weight:1.8:The mixture of 1 composition;The antiseptic be by Outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia butyl formate compare 0.9 with weight:2.0:The mixture of 1 composition.
Described is to compare 1.7 by Rosa Damascana, refined jasmine oil and osmanthus essential oil with weight into Studies of The Aromatic Substances B:1.8:1 composition mixed Compound;The colour former B is to compare 1.6 by carthamic acid, lemon yellow and blueberry extract with weight:3.0:The mixture of 1 composition.
The polyurethane prepolymer B is that MDI polyol prepolymer, diphenyl methane two are different Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol Prepolymer compares 1.8 with weight:1.7:The mixture of 1 composition.
Embodiment 8
The present embodiment is with the difference of above-described embodiment 3:
A kind of perfumed soap cleaning agent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate and hard Resin acid sodium compares 2.8 with weight:1.8:The mixture of 1 composition.
Described is to compare 2.0 by thyme essential oil, Lavender and cloves essence with weight into Studies of The Aromatic Substances A:1.5:1 composition Mixture;The colour former A is to compare 1.8 by rose glycosides, carrotene and balsamine glycosides with weight:2.8:The mixing of 1 composition Thing.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, the stearic alcohol ether is by cetostearyl alcohol Ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether compares 1.8 with weight:1.0:The mixture of 1 composition;The epoxy compound Thing is to compare 2.0 by oxirane, expoxy propane and epoxy resin with weight:1.5:The mixture of 1 composition;The antiseptic be by Outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia butyl formate compare 1.0 with weight:1.8:The mixture of 1 composition.
Described is to compare 2.0 by Rosa Damascana, refined jasmine oil and osmanthus essential oil with weight into Studies of The Aromatic Substances B:1.5:1 composition mixed Compound;The colour former B is to compare 1.8 by carthamic acid, lemon yellow and blueberry extract with weight:2.8:The mixture of 1 composition.
The polyurethane prepolymer B is that MDI polyol prepolymer, diphenyl methane two are different Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol Prepolymer compares 2.0 with weight:1.5:The mixture of 1 composition.
Embodiment 9
The present embodiment is with the difference of above-described embodiment 4:
A kind of perfumed soap cleaning agent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate and hard Resin acid sodium compares 3.0 with weight:1.6:The mixture of 1 composition.
Described is to compare 2.3 by thyme essential oil, Lavender and cloves essence with weight into Studies of The Aromatic Substances A:1.3:1 composition Mixture;The colour former A is to compare 2.0 by rose glycosides, carrotene and balsamine glycosides with weight:2.6:The mixing of 1 composition Thing.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, the stearic alcohol ether is by cetostearyl alcohol Ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether compares 2.0 with weight:0.9:The mixture of 1 composition;The epoxy compound Thing is to compare 2.3 by oxirane, expoxy propane and epoxy resin with weight:1.2:The mixture of 1 composition;The antiseptic be by Outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia butyl formate compare 1.1 with weight:1.6:The mixture of 1 composition.
Described is to compare 2.3 by Rosa Damascana, refined jasmine oil and osmanthus essential oil with weight into Studies of The Aromatic Substances B:1.2:1 composition mixed Compound;The colour former B is to compare 2.0 by carthamic acid, lemon yellow and blueberry extract with weight:2.6:The mixture of 1 composition.
The polyurethane prepolymer B is that MDI polyol prepolymer, diphenyl methane two are different Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol Prepolymer compares 2.2 with weight:1.3:The mixture of 1 composition.
Embodiment 10
The present embodiment is with the difference of above-described embodiment 5:
A kind of perfumed soap cleaning agent with skin effect, the higher fatty acids sodium are by palmitoleic acid sodium, sodium laurate and hard Resin acid sodium compares 3.2 with weight:1.4:The mixture of 1 composition.
Described is to compare 2.5 by thyme essential oil, Lavender and cloves essence with weight into Studies of The Aromatic Substances A:1.0:1 composition Mixture;The colour former A is to compare 2.2 by rose glycosides, carrotene and balsamine glycosides with weight:2.4:The mixing of 1 composition Thing.
A kind of perfumed soap cleaning agent with skin effect and the conjugate of continuous class, the stearic alcohol ether is by cetostearyl alcohol Ether, polyoxyethylene stearyl alcohol ether and PPG-15 tristearin alcohol ether compares 2.2 with weight:0.8:The mixture of 1 composition;The epoxy compound Thing is to compare 2.5 by oxirane, expoxy propane and epoxy resin with weight:1.0:The mixture of 1 composition;The antiseptic be by Outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia butyl formate compare 1.2 with weight:1.4:The mixture of 1 composition.
Described is to compare 2.5 by Rosa Damascana, refined jasmine oil and osmanthus essential oil with weight into Studies of The Aromatic Substances B:1.0:1 composition mixed Compound;The colour former B is to compare 2.2 by carthamic acid, lemon yellow and blueberry extract with weight:2.4:The mixture of 1 composition.
The polyurethane prepolymer B is that MDI polyol prepolymer, diphenyl methane two are different Cyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyalcohol Prepolymer compares 2.5 with weight:1.0:The mixture of 1 composition.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with alternate manner, On the premise of without departing from present inventive concept, any obvious replacement is within protection scope of the present invention.

Claims (10)

1. a kind of perfumed soap cleaning agent with skin effect, it is characterised in that:The perfumed soap cleaning agent includes following weight portion Raw material:
Higher fatty acids sodium 80-120 parts
Functional component 1-10 parts
Into Studies of The Aromatic Substances A 0.2-2 parts
Colour former A 0.2-2 parts.
2. a kind of perfumed soap cleaning agent with skin effect according to claim 1, it is characterised in that:The higher aliphatic Sour sodium is at least one in palmitoleic acid sodium, sodium laurate, odium stearate and linolenic acid sodium.
3. a kind of perfumed soap cleaning agent with skin effect according to claim 1, it is characterised in that:The functional component Carry for marine alga, bamboo charcoal, aloe, vitamin E, green-tea extract, ginseng extract, Flos Pelargonii Hortori, tea tree extract, Radix Glycyrrhizae Take thing, Honegsukle flower P.E, Flos Rosae Rugosae extract, Herba Lysimachiae foenumgraeci extract, Fructus Cucumidis sativi extract, lemon extract, Yoghourt extract, Tea tree ethereal oil, Peppermint essential oil, narra essential oil, flores aurantii essential oil, cinnamon essential oil, Pogostemon cablin essential, needle juniper essential oil, You Jiali essences Oil, Salvia japonica essential oil, myrrh essential oil, Cananga odorata quintessence oil, bigarabe leaf essential oil, Geranium Essential, Bergamot, asarum flower essential oil, At least one in polyphenol powde essential oil, yulan essential oil, lily of the valley essential oil and Rosemary Oil.
4. a kind of perfumed soap cleaning agent with skin effect according to claim 1, it is characterised in that:Described into Studies of The Aromatic Substances A is at least one in thyme essential oil, Lavender, sandalwood essential oil and clove oil;The colour former A is rose At least one in glycosides, carrotene, turmeric, balsamine glycosides, sunset yellow and blueberry extract.
5. the conjugate of a kind of perfumed soap cleaning agent with skin effect and continuous class, it is characterised in that:The conjugate will by right The perfumed soap cleaning agent described in any one of 1-4 and continuous class is asked to compare 6-10 according to weight:1 ratio is obtained.
6. the conjugate of a kind of perfumed soap cleaning agent with skin effect according to claim 5 and continuous class, its feature exist In:The continuous class is bathing class polyurethane, and bathing class polyurethane is by polyurethane prepolymer A and polyurethane prepolymer B according to weight Compare 1.5-3.5:1 ratio is obtained;
The polyurethane prepolymer A includes the raw material of following weight portion:
Stearic alcohol ether 0.5-1.5 parts
Epoxide 1-10 parts
Antiseptic 1-10 parts
Into Studies of The Aromatic Substances B 0.2-2 parts
Colour former B 0.2-2 parts.
7. the conjugate of a kind of perfumed soap cleaning agent with skin effect according to claim 6 and continuous class, its feature exist In:The stearic alcohol ether is cetearyl alcohol alcohol ether, cetearyl alcohol alcohol ether -20, polyoxyethylene stearyl alcohol ether and PPG-15 stearyl alcohols At least one in ether;The epoxide be oxirane, expoxy propane, epoxy resin and epoxychloropropane at least A kind of;The antiseptic is at least in Sodium Benzoate, outstanding horse BP antiseptics, Jia Landan and iodo propinyl ammonia butyl formate Kind.
8. the conjugate of a kind of perfumed soap cleaning agent with skin effect according to claim 6 and continuous class, its feature exist In:Described into Studies of The Aromatic Substances B be Rosa Damascana, refined jasmine oil, lily essential oil, osmanthus essential oil and yulan essential oil at least one; The colour former B is at least one in alkermes, tomato red, chlorophyll, carthamic acid, lemon yellow and blueberry extract.
9. the conjugate of a kind of perfumed soap cleaning agent with skin effect according to claim 6 and continuous class, its feature exist In:The polyurethane prepolymer B is MDI polyol prepolymer, methyl diphenylene diisocyanate Polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer and poly methylene poly phenyl poly isocyanate polyol prepolymer In at least one.
10. a kind of perfumed soap cleaning agent with skin effect as described in any one of claim 6-9 and the conjugate of continuous class Preparation method, it is characterised in that:Comprise the steps:
(1)The preparation of polyurethane prepolymer A:According to weight proportion weigh stearic alcohol ether, epoxide, antiseptic, into perfumery Matter B and colour former B, mixing and stirring are obtained polyurethane prepolymer A;
(2)The preparation of polyurethane prepolymer B:MDI polyalcohol pre-polymerization is weighed according to weight proportion Thing, methyl diphenylene diisocyanate polyol prepolymer, toluene di-isocyanate(TDI) polyol prepolymer or many benzene of polymethylene Quito isocyanates polyol prepolymer, stirs, and polyurethane prepolymer B is obtained;
(3)The preparation of bathing class polyurethane:By step(1)Obtained polyurethane prepolymer A and step(2)Obtained polyurethane is pre- Polymers B compares 1.5-3.5 according to weight:1 ratio is well mixed, and carries out foamable reaction, and bathing class polyurethane is obtained;
(4)The preparation of perfumed soap cleaning agent:Higher fatty acids sodium, functional component are weighed according to weight proportion, into Studies of The Aromatic Substances A and quality Substance A, mixing and stirring are obtained perfumed soap cleaning agent;
(5)The preparation of the conjugate of perfumed soap cleaning agent and bathing class polyurethane:By step(4)Obtained perfumed soap cleaning agent is according to weight Amount compares 6-10:1 ratio is dissolved into step(3)In obtained bathing class polyurethane, mixture is obtained, mould is added mixture to Cooling shaping in tool, is obtained the conjugate with the perfumed soap cleaning agent with bathing class polyurethane of skin effect.
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CN102453224A (en) * 2011-07-15 2012-05-16 上海高裕海绵制品有限公司 Technology for producing sponge from plant oil polyether
CN202786200U (en) * 2012-08-17 2013-03-13 郑裕集 Sponge soap
CN104762145A (en) * 2015-04-17 2015-07-08 谢松芬 Antipruritic toilet soap containing shrubby sophora extract

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CN102453224A (en) * 2011-07-15 2012-05-16 上海高裕海绵制品有限公司 Technology for producing sponge from plant oil polyether
CN202786200U (en) * 2012-08-17 2013-03-13 郑裕集 Sponge soap
CN104762145A (en) * 2015-04-17 2015-07-08 谢松芬 Antipruritic toilet soap containing shrubby sophora extract

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CN115418283A (en) * 2022-07-05 2022-12-02 济宁医学院 Skin-care liquid soap and preparation method thereof

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