CN106496906A - A kind of weather-proof decorating film and preparation method - Google Patents
A kind of weather-proof decorating film and preparation method Download PDFInfo
- Publication number
- CN106496906A CN106496906A CN201510562494.7A CN201510562494A CN106496906A CN 106496906 A CN106496906 A CN 106496906A CN 201510562494 A CN201510562494 A CN 201510562494A CN 106496906 A CN106496906 A CN 106496906A
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- weather
- decorating film
- asa
- pvc
- pmma
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- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 21
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 17
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 17
- 239000002033 PVDF binder Substances 0.000 claims abstract description 15
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims abstract description 15
- 239000002131 composite material Substances 0.000 claims abstract description 12
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 claims abstract description 11
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 11
- 238000005520 cutting process Methods 0.000 claims abstract description 9
- 238000001125 extrusion Methods 0.000 claims abstract description 9
- 238000003490 calendering Methods 0.000 claims abstract description 7
- 238000007766 curtain coating Methods 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 230000007613 environmental effect Effects 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 238000004804 winding Methods 0.000 abstract description 3
- 206010039424 Salivary hypersecretion Diseases 0.000 abstract description 2
- 208000008630 Sialorrhea Diseases 0.000 abstract description 2
- 238000010096 film blowing Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000009826 distribution Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 8
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 238000005034 decoration Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention relates to a kind of weather-proof decorating film and preparation method, the composition material of the weather-proof decorating film is one or more of ASA, PVDF, PMMA and PVC, and each composition material presses layer distribution.The preparation method of the weather-proof decorating film, comprises the steps:Raw material drying, extrusion, calendering, curtain coating, press polish, blown film, cutting edge and winding.Compared to the prior art, weather-proof decorating film of the present invention pass through by ASA and PVDF PMMA PVC co-extrusions, processed using calendering, sialorrhea, film blowing method, not only reduce production cost, and the weather-proof decorating film for preparing is difficult layering, decorative pattern true to nature, damage resistant, good weatherability.
Description
Technical field
The present invention relates to furnishing fields, more particularly to a kind of weather-proof decorating film and preparation method.
Background technology
As global economy and the fast development of science and technology, the quality of life of people are improved constantly, the use of home decoration material is also more and more extensive.Wherein decorative plastic film is used widely in a lot of fields with its cheap cost
At present, it is usually PVC film to be particularly metal material decoration protecting film used above in ornament materials, and this film is made up of PVC bottoms, printing layer and PMMA surface layers, but due to its complex structure and expensive, does not obtain the wide promotion and application that sends out.Through constantly research and test, it is found that ASA and PMMA materials are respectively provided with preferable weatherability and stable mechanical property, therefore decorating film field is referred to, at present conventional technology be using PVC and PMMA PVDF is direct bonding forms, due to the restriction of simple physical bonds, cause to find after these decorating films are using a period of time, door and window occurs the typical catabiosis such as flavescence, graying, air slaking, layering.
Content of the invention
The present invention exactly in order to solve the above problems, overcomes the problems of existing decorating film, the present invention to provide a kind of weather-proof decorating film and preparation method to meet demand.
To achieve these goals, technical scheme is as follows:
A kind of weather-proof decorating film, the composition material of the weather-proof decorating film are one or more of ASA, PVDF, PMMA, PVC, and percentage thickness shared by each composition material is:
A kind of weather-proof decorating film, composition material ASA, PVDF, PMMA, PVC storied placement.This is the most typical place for being different from the blending method that commonly use on Vehicles Collected from Market.
A kind of preparation method of weather-proof decorating film, comprises the steps:
(1) raw material drying:ASA, PVDF, PMMA and PVC are dried under 80~90 DEG C of environmental conditions 3~5h respectively;
(2) extrude:By dried material respectively under 185~230 DEG C of environmental conditions, by two or three extruder co-extrusions;
(3) calendering, curtain coating, press polish, blown film;50-110 DEG C of roller temperature, linear velocity 5-20 m/min;
(4) cutting disc cutting edge;
(5) wind, 500-1000 rice/volume.
Particularly, before preparation process (2) extrusion, composition material ASA, PVDF, PMMA, PVC are mixed according to a certain percentage.
The invention has the beneficial effects as follows:As ASA has the mechanical properties such as good weatherability, chemical resistance, by ASA materials being introduced in conventional PVC decorative Film, not only greatly reduce production cost, and significantly improve the weatherability of decorating film.By by ASA and PVDF PMMA PVC co-extrusions, processed using calendering, sialorrhea, film blowing method, prepared weather-proof decorating film is difficult to be layered, decorative pattern is true to nature, damage resistant, and cementability is good.
Specific embodiment
Below in conjunction with the embodiment of the present invention; clear, complete description is carried out to the specific embodiment of the invention; obviously; the embodiment is only a part of embodiment of the invention; rather than whole embodiments; embodiments of the invention are based on, the other embodiment obtained under the premise of creative work is not made by those skilled in the art is all the scope of protection of the invention.
Embodiment 1
Composition material is come ASA and PVC and dries 3~5h under 80~90 DEG C of environmental conditions in case follow-up co-extrusion by the first step respectively;
Second step, by dried after ASA and PVC mix according to a certain percentage, above 1 layer of ASA spread one layer of PVC after continue tiling 1 layer of ASA, respectively under 185~230 DEG C of environmental conditions, by two extruderses co-extrusion;
The section bar of coextrusion is sequentially passed through the operations such as calendering, curtain coating, press polish, blown film, wherein 100 DEG C of roller temperature, 20 ms/min of linear velocity by the 3rd step;
4th step, cutting disc cutting edge;
5th step, winding:500-1000 rice/volume.
Embodiment 2
Composition material is come ASA, PVDF, PMMA and PVC and dries 3~5h under 80~90 DEG C of environmental conditions by the first step respectively;
Second step, by dried after ASA, PVDF, PMMA and PVC mix according to a certain percentage, specially 3 layers ASA, 1 layer of PVC, 1 layer of PMMA and 1 layer of PVDF, respectively under 185~230 DEG C of environmental conditions, by two or three extruder co-extrusions;
The section bar of coextrusion is sequentially passed through the operations such as calendering, curtain coating, press polish, blown film, wherein 110 DEG C of roller temperature, 15 ms/min of linear velocity by the 3rd step;
4th step, cutting disc cutting edge;
5th step, winding:500-1000 rice/volume.
The above is presently preferred embodiments of the present invention; it should be understood by those skilled in the art that; the present invention is not restricted to the described embodiments; merely illustrating the principles of the invention described in above-described embodiment and description; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements are both fallen within the scope of patent protection of the present invention.
Claims (4)
1. a kind of weather-proof decorating film, it is characterised in that one or more for ASA, PVDF, PMMA, PVC of the composition material of the weather-proof decorating film, percentage thickness shared by each composition material is:
.
2. a kind of weather-proof decorating film according to claim 1, it is characterised in that composition material ASA, PVDF, PMMA, PVC storied placement.
3. a kind of preparation method of weather-proof decorating film, it is characterised in that comprise the steps:
(1) raw material drying:ASA, PVDF, PMMA, PVC are dried under 80~90 DEG C of environmental conditions 3~5h respectively;
(2) extrude:By dried material respectively under 185~230 DEG C of environmental conditions, by two or three extruder co-extrusions;
(3) calendering, curtain coating, press polish:50-110 DEG C of roller temperature;Linear velocity 5-20 m/min;
(4) cutting disc cutting edge;
(5) wind.
4. the preparation method of a kind of weather-proof decorating film according to claim 2, it is characterised in that before preparation process (2) is extruded, composition material ASA, PVDF, PMMA, PVC are mixed according to a certain percentage.
Priority Applications (1)
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CN201510562494.7A CN106496906A (en) | 2015-09-08 | 2015-09-08 | A kind of weather-proof decorating film and preparation method |
Applications Claiming Priority (1)
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CN201510562494.7A CN106496906A (en) | 2015-09-08 | 2015-09-08 | A kind of weather-proof decorating film and preparation method |
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Publication Number | Publication Date |
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CN106496906A true CN106496906A (en) | 2017-03-15 |
Family
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Family Applications (1)
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CN201510562494.7A Pending CN106496906A (en) | 2015-09-08 | 2015-09-08 | A kind of weather-proof decorating film and preparation method |
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CN (1) | CN106496906A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108659443A (en) * | 2018-05-23 | 2018-10-16 | 芜湖创科新材料科技有限公司 | A kind of automobile decoration film preparation technique of good light stability |
CN108724876A (en) * | 2018-05-23 | 2018-11-02 | 芜湖创科新材料科技有限公司 | A kind of automobile composite decoration film preparation process |
CN108822460A (en) * | 2018-05-17 | 2018-11-16 | 芜湖创科新材料科技有限公司 | A kind of high bright and clean automobile decoration film preparation technique |
CN109422991A (en) * | 2017-08-28 | 2019-03-05 | 永清三利橡塑材料有限公司 | A kind of high abrasion has the function of clean surfaces ASA/PMMA mixture and preparation method thereof |
CN112339370A (en) * | 2020-10-28 | 2021-02-09 | 嘉兴高正新材料科技股份有限公司 | A kind of composite film of EPDM rubber and polyvinylidene fluoride and preparation method thereof |
CN114290778A (en) * | 2021-12-28 | 2022-04-08 | 山东结力新材料科技有限公司 | High-weather-resistance POE decorative composite film and manufacturing method thereof |
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WO2004029151A1 (en) * | 2002-09-20 | 2004-04-08 | Basf Aktiengesellschaft | Mixtures of propellant-free microgranulates |
CN101203404A (en) * | 2005-05-20 | 2008-06-18 | 聚科内饰有限公司 | Process for the manufacture of interior trim parts comprising defined surfaces and/or defined color profiles and articles obtained therefrom |
CN101746035A (en) * | 2009-12-30 | 2010-06-23 | 王远孔 | Method for producing decorative film coextrusion compound profile |
US20140010993A1 (en) * | 2012-07-04 | 2014-01-09 | Etansi Inc. | Decoration film and method for manufacturing decorated article |
CN104479256A (en) * | 2014-12-31 | 2015-04-01 | 江阴市向阳科技有限公司 | Preparation method of high-performance composite decorative film |
CN104647856A (en) * | 2015-03-05 | 2015-05-27 | 天津透明墙科技有限公司 | Method and equipment for gluing ASA and PMMA alloy decorative films |
CN205112576U (en) * | 2015-07-20 | 2016-03-30 | 苏州洛瑞卡新材料科技有限公司 | Modified plastics complex film |
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2015
- 2015-09-08 CN CN201510562494.7A patent/CN106496906A/en active Pending
Patent Citations (7)
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WO2004029151A1 (en) * | 2002-09-20 | 2004-04-08 | Basf Aktiengesellschaft | Mixtures of propellant-free microgranulates |
CN101203404A (en) * | 2005-05-20 | 2008-06-18 | 聚科内饰有限公司 | Process for the manufacture of interior trim parts comprising defined surfaces and/or defined color profiles and articles obtained therefrom |
CN101746035A (en) * | 2009-12-30 | 2010-06-23 | 王远孔 | Method for producing decorative film coextrusion compound profile |
US20140010993A1 (en) * | 2012-07-04 | 2014-01-09 | Etansi Inc. | Decoration film and method for manufacturing decorated article |
CN104479256A (en) * | 2014-12-31 | 2015-04-01 | 江阴市向阳科技有限公司 | Preparation method of high-performance composite decorative film |
CN104647856A (en) * | 2015-03-05 | 2015-05-27 | 天津透明墙科技有限公司 | Method and equipment for gluing ASA and PMMA alloy decorative films |
CN205112576U (en) * | 2015-07-20 | 2016-03-30 | 苏州洛瑞卡新材料科技有限公司 | Modified plastics complex film |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109422991A (en) * | 2017-08-28 | 2019-03-05 | 永清三利橡塑材料有限公司 | A kind of high abrasion has the function of clean surfaces ASA/PMMA mixture and preparation method thereof |
CN108822460A (en) * | 2018-05-17 | 2018-11-16 | 芜湖创科新材料科技有限公司 | A kind of high bright and clean automobile decoration film preparation technique |
CN108659443A (en) * | 2018-05-23 | 2018-10-16 | 芜湖创科新材料科技有限公司 | A kind of automobile decoration film preparation technique of good light stability |
CN108724876A (en) * | 2018-05-23 | 2018-11-02 | 芜湖创科新材料科技有限公司 | A kind of automobile composite decoration film preparation process |
CN112339370A (en) * | 2020-10-28 | 2021-02-09 | 嘉兴高正新材料科技股份有限公司 | A kind of composite film of EPDM rubber and polyvinylidene fluoride and preparation method thereof |
CN112339370B (en) * | 2020-10-28 | 2023-12-08 | 嘉兴高正新材料科技股份有限公司 | Composite membrane of ethylene propylene diene monomer and polyvinylidene fluoride and preparation method thereof |
CN114290778A (en) * | 2021-12-28 | 2022-04-08 | 山东结力新材料科技有限公司 | High-weather-resistance POE decorative composite film and manufacturing method thereof |
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Application publication date: 20170315 |