CN108822460A - A kind of high bright and clean automobile decoration film preparation technique - Google Patents

A kind of high bright and clean automobile decoration film preparation technique Download PDF

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Publication number
CN108822460A
CN108822460A CN201810474794.3A CN201810474794A CN108822460A CN 108822460 A CN108822460 A CN 108822460A CN 201810474794 A CN201810474794 A CN 201810474794A CN 108822460 A CN108822460 A CN 108822460A
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China
Prior art keywords
parts
film preparation
high bright
preparation technique
automobile decoration
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Pending
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CN201810474794.3A
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Chinese (zh)
Inventor
汪淼
俞洋
李昆明
庄莉莉
黄小军
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Wuhu Creates A New Mstar Technology Ltd
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Wuhu Creates A New Mstar Technology Ltd
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Priority to CN201810474794.3A priority Critical patent/CN108822460A/en
Publication of CN108822460A publication Critical patent/CN108822460A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/18Homopolymers or copolymers of tetrafluoroethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/16Solid spheres
    • C08K7/18Solid spheres inorganic
    • C08K7/20Glass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The present invention relates to decorating film preparation technical field, especially a kind of high bright and clean automobile decoration film preparation technique includes the following steps:Step 1:Ingredient:PMMA40-50 parts, 40-50 parts of ASA rubber powder, 2-3 parts of toughener, 1-2.5 parts of release agent, 1-2 parts of ultraviolet absorbing agent, 2-3 parts of plasticizer, 1.5-2 parts of adhesive, 2-3 parts of polytetrafluoroethylene (PTFE), 1.5-2.5 parts of dioctyl phthalate, 1-1.5 parts of glass microballoon are taken, the above number is parts by weight;Step 2:Mixing;Step 3:Mixing:Mixture in step 2 is delivered to mixer, mixing time 15-20 minutes, 160-170 DEG C of smelting temperature;Step 4:Squeeze filtering;Step 5:Twin-screw extrusion, then calendering, embossing, traction, cooling, trimming, batch, finished product packing.This product not only contributes to the cleaning of car body surface dirt, and has certain cushion performance, can protect car body surface, reflective function is good.

Description

A kind of high bright and clean automobile decoration film preparation technique
Technical field
The present invention relates to decorating film preparation technical field more particularly to a kind of high bright and clean automobile decoration film preparation techniques.
Background technique
The composition of New-energy electric vehicle, New-energy electric vehicle includes:It is driven by electricity and control system, driving force is driven Etc. mechanical systems, complete the equipments etc. of assigned tasks.
It is driven by electricity and control system is the core of electric car, and be different from the maximum difference of internal-combustion engines vehicle. It is driven by electricity and control system is made of the speed-regulating control device etc. of drive motor, power supply and motor.Electric car its His device is substantially identical as internal-combustion engines vehicle.
With the development of society, the components such as household electrical appliance, automobile, mobile phone all largely use plastic part, incrustation Requirement it is higher and higher.Currently, plastic part surface metallization decoration is using plating, vacuum deposition process and hot transfer foil.Plating Technique production environment is poor, unfavorable to workers ' health, and to the more demanding of plastic part, many fields no longer use.Vacuum Depositing operation makes fast progress in film applications in recent years, but higher to the processing charges of molding plastic.And transfer film adds for dry method Work technique is good for the environment, it can be achieved that a variety of decorative effects, is suitable for the components such as most of household electrical appliances, automobile, mobile phone.
Present people can select to cover one layer of decorating film in outer surface of automobile after buying automobile, on the one hand for automobile On the other hand beauty plays the role of protecting car body, present decorating film function is very single, foulant sticks in car surface or When on person's general decor film, cleaning is very difficult, and general car owner is rinsed using giant, and high pressure water flow can make car body At certain destruction.
Summary of the invention
The purpose of the present invention is to solve the difficult cleaning of disadvantages of bodywork surface dirt in the prior art, and one proposed The high bright and clean automobile decoration film preparation technique of kind.
To achieve the goals above, present invention employs following technical solutions:
A kind of high bright and clean automobile decoration film preparation technique is designed, is included the following steps:
Step 1:Ingredient:Take PMMA40-50 parts, 40-50 parts of ASA rubber powder, 2-3 parts of toughener, 1-2.5 parts of release agent, purple 1-2 parts of ultraviolet absorbers, 2-3 parts of plasticizer, 1.5-2 parts of adhesive, 2-3 parts of polytetrafluoroethylene (PTFE), dioctyl phthalate 1.5-2.5 parts, 1-1.5 parts of glass microballoon, the above number is parts by weight;
Step 2:Mixing:By toughener, release agent, ultraviolet absorbing agent, plasticizer, adhesive, polytetrafluoroethylene (PTFE), neighbour Dioctyl phthalate, glass microballoon, which are put into mechanical agitator, to be stirred 5-7 minutes, then mixes PMMA, ASA rubber powder with more than It closes object to be mixed, stir 10-15 minutes, the above whipping temp is 100-105 DEG C;
Step 3:Mixing:Mixture in step 2 is delivered to mixer, mixing time 15-20 minutes, smelting temperature 160-170℃;
Step 4:Squeeze filtering;
Step 5:Twin-screw extrusion, then calendering, embossing, traction, cooling, trimming, batch, finished product packing.
Preferably, the toughener is acrylate, and the plasticizer is titanate esters, described adhesive is titanate esters coupling Agent.
Preferably, in step 4, filtration temperature is 155-160 DEG C.
Preferably, the double screw extruder squeezes out silicon carbide:One 200-220 DEG C of area, 220-240 DEG C of 2nd area, 3rd area 240-250 DEG C, 245-255 DEG C of discharge port.
Preferably, calender uses tri-roll press machine.
Preferably, cooling using air-cooled.
A kind of high bright and clean automobile decoration film preparation technique proposed by the present invention, beneficial effect are:It is added in this product poly- Tetrafluoroethene, dioctyl phthalate guarantee the smooth colleague of product film, enhance the adhesive strength between raw material, while this It is added with glass microballoon in product, increases the reflective function of product film, increases the security performance of vehicle at night traveling.
Specific embodiment
The technical solution in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment is only It is only a part of the embodiment of the present invention, instead of all the embodiments.
A kind of high bright and clean automobile decoration film preparation technique, includes the following steps:
Step 1:Ingredient:Take PMMA40-50 kilograms, 40-50 kilograms of ASA rubber powder, 2-3 kilograms of toughener, release agent 1- 2.5 kilograms, 1-2 kilograms of ultraviolet absorbing agent, 2-3 kilograms of plasticizer, 1.5-2 kilograms of adhesive, 2-3 kilograms of polytetrafluoroethylene (PTFE), 1.5-2.5 kilograms of dioctyl phthalate, 1-1.5 kilograms of glass microballoon, the toughener are acrylate, the plasticizer It is titanate coupling agent for titanate esters, described adhesive;
Step 2:Mixing:By toughener, release agent, ultraviolet absorbing agent, plasticizer, adhesive, polytetrafluoroethylene (PTFE), neighbour Dioctyl phthalate, glass microballoon, which are put into mechanical agitator, to be stirred 5-7 minutes, then mixes PMMA, ASA rubber powder with more than It closes object to be mixed, stir 10-15 minutes, the above whipping temp is 100-105 DEG C;
Step 3:Mixing:Mixture in step 2 is delivered to mixer, mixing time 15-20 minutes, smelting temperature 160-170℃;
Step 4:Filtering is squeezed, filtration temperature is 155-160 DEG C;
Step 5:Twin-screw extrusion, then calendering, embossing, traction, cooling, trimming, batch, finished product packing, double spiral shells Bar extruder squeezes out silicon carbide:One 200-220 DEG C of area, 220-240 DEG C of 2nd area, 240-250 DEG C of 3rd area, discharge port 245-255 DEG C, calender uses tri-roll press machine, cooling using air-cooled.
Above data surface:This product decorating film not only contributes to the cleaning of car body surface dirt, and has centainly Cushion performance can protect car body surface.
After the completion of cleaning, under sunlight irradiation, the car body reflective function of this product covering is splendid.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of high bright and clean automobile decoration film preparation technique, which is characterized in that include the following steps:
Step 1:Ingredient:Take PMMA40-50 parts, 40-50 parts of ASA rubber powder, 2-3 parts of toughener, 1-2.5 parts of release agent, ultraviolet light 1-2 parts of absorbent, 2-3 parts of plasticizer, 1.5-2 parts of adhesive, 2-3 parts of polytetrafluoroethylene (PTFE), dioctyl phthalate 1.5-2.5 Part, 1-1.5 parts of glass microballoon, the above number is parts by weight;
Step 2:Mixing:By toughener, release agent, ultraviolet absorbing agent, plasticizer, adhesive, polytetrafluoroethylene (PTFE), adjacent benzene two Formic acid dioctyl ester, glass microballoon are put into mechanical agitator and stir 5-7 minutes, then by PMMA, ASA rubber powder and the above mixture It is mixed, is stirred 10-15 minutes, the above whipping temp is 100-105 DEG C;
Step 3:Mixing:Mixture in step 2 is delivered to mixer, mixing time 15-20 minutes, smelting temperature 160- 170℃;
Step 4:Squeeze filtering;
Step 5:Twin-screw extrusion, then calendering, embossing, traction, cooling, trimming, batch, finished product packing.
2. a kind of high bright and clean automobile decoration film preparation technique according to claim 1, which is characterized in that the toughener is Acrylate, the plasticizer is titanate esters, described adhesive is titanate coupling agent.
3. a kind of high bright and clean automobile decoration film preparation technique according to claim 1, which is characterized in that in step 4, mistake Filtering temperature is 155-160 DEG C.
4. a kind of high bright and clean automobile decoration film preparation technique according to claim 1, which is characterized in that the twin-screw squeezes Machine squeezes out silicon carbide out:One 200-220 DEG C of area, 220-240 DEG C of 2nd area, 240-250 DEG C of 3rd area, 245-255 DEG C of discharge port.
5. a kind of high bright and clean automobile decoration film preparation technique according to claim 1, which is characterized in that calender uses three Roll calendar.
6. a kind of high bright and clean automobile decoration film preparation technique according to claim 1, which is characterized in that cooling to use wind It is cold.
CN201810474794.3A 2018-05-17 2018-05-17 A kind of high bright and clean automobile decoration film preparation technique Pending CN108822460A (en)

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Application Number Priority Date Filing Date Title
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104479256A (en) * 2014-12-31 2015-04-01 江阴市向阳科技有限公司 Preparation method of high-performance composite decorative film
CN104672737A (en) * 2015-02-12 2015-06-03 深圳毅彩鸿翔新材料科技有限公司 Weather-resistance ASA-based composite material, co-extruded plastic product and plastic product
CN106188927A (en) * 2016-08-10 2016-12-07 深圳毅彩鸿翔新材料科技有限公司 Uvioresistant weatherability ASA resin, coextruded plastic goods, thin film and goods
CN106496906A (en) * 2015-09-08 2017-03-15 苏州洛瑞卡新材料科技有限公司 A kind of weather-proof decorating film and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104479256A (en) * 2014-12-31 2015-04-01 江阴市向阳科技有限公司 Preparation method of high-performance composite decorative film
CN104672737A (en) * 2015-02-12 2015-06-03 深圳毅彩鸿翔新材料科技有限公司 Weather-resistance ASA-based composite material, co-extruded plastic product and plastic product
CN106496906A (en) * 2015-09-08 2017-03-15 苏州洛瑞卡新材料科技有限公司 A kind of weather-proof decorating film and preparation method
CN106188927A (en) * 2016-08-10 2016-12-07 深圳毅彩鸿翔新材料科技有限公司 Uvioresistant weatherability ASA resin, coextruded plastic goods, thin film and goods

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Application publication date: 20181116