CN106495499A - The preparation method of anti-oxidation safety glass and the glass made using the method - Google Patents
The preparation method of anti-oxidation safety glass and the glass made using the method Download PDFInfo
- Publication number
- CN106495499A CN106495499A CN201610921001.9A CN201610921001A CN106495499A CN 106495499 A CN106495499 A CN 106495499A CN 201610921001 A CN201610921001 A CN 201610921001A CN 106495499 A CN106495499 A CN 106495499A
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- CN
- China
- Prior art keywords
- layer
- coating
- glass layer
- toughened glass
- glass
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
Abstract
The invention discloses a kind of preparation method of anti-oxidation safety glass, comprises the following steps：S1：Synthesis composite coated layer：Using silicone coupling agents in alcohol solvent surface coating modification nano-zinc sulfide crystal, formed composite coated layer material；S2：Surface coating modification is carried out to coating layer material：The coating layer material that step S1 is made is dispersed in the organic solvent containing coupling agent, using ultrasonic wave/ball-milling method to surface coating modification；S3：Spray coating layer：The coating layer material produced in step S2 is coated in by white glass surface, dry solidification using spraying or roller coating technology；S4：Bonding toughened glass layer：Toughened glass layer is set on white glass, compound antioxidation coating is located between toughened glass layer and white glass layer, between white glass layer and toughened glass layer, is formed cavity；S5：Filling inert gas.The present invention is by adopting hollow perfusion inert gas, and internally arranges coat, during as structures such as kitchen appliance control panels, plays oxidation-protective effect.
Description
Technical field
The present invention relates to a kind of preparation method of anti-oxidation safety glass and the glass made using the method.
Background technology
Luminescent glass is typically with inorganic fluorescent material and is mixed with high temperature glaze, is obtained after high-temperature heat treatment.The night
Light glass can resistance to acids and bases be good, ageing-resistant performance is good, face is difficult for drop-off, but easily oxidation occurs, affects which to use, with
When, strength of glass is not high, and when using for the occasion such as household electrical appliance or electric appliance for bathroom, service life is limited.
Content of the invention
It is an object of the invention to provide a kind of preparation method of anti-oxidation safety glass and the glass made using the method
Glass, by the structure using hollow perfusion inert gas, and internally arranges coat, as kitchen appliance control panel
During etc. structure, oxidation-protective effect can be played.
The present invention is achieved through the following technical solutions：
A kind of preparation method of anti-oxidation safety glass, comprises the following steps：
S1：Synthesis composite coated layer：Using silicone coupling agents in alcohol solvent surface coating modification nano-zinc sulfide
Crystal, forms composite coated layer material；
S2：Surface coating modification is carried out to coating layer material：The coating layer material that step S1 is made is dispersed in containing coupling
In the organic solvent of agent, using ultrasonic wave/ball-milling method to surface coating modification, by modified coating layer material and silica
Colloidal sol mixes, and forms mixing coat；
S3：Spray coating layer：The coating layer material produced in step S2 is coated in by white glass using spraying or roller coating technology
Glass surface, dry solidification form compound antioxidation coating；
S4：Bonding toughened glass layer：Toughened glass layer is set on white glass, makes compound antioxidation coating be located at safety glass
Between layer and white glass layer, cavity between white glass layer and toughened glass layer, is formed；
S5：Filling inert gas：The cavity that step S4 is produced is closed, and in empty intra-bladder instillation inert gas, is filled
By cavities seals after the completion of gas.
Further, for the present invention is better achieved, the nano-zinc sulfide in described step S1 is to utilize Hydrothermal Synthesiss
Method or precipitation method synthesis.
Further, for the present invention is better achieved, the modified coupling agent in described step S2 is KH-550, KH-
560th, KH-570 one or more be mixed to form.
Further, for the present invention is better achieved, the inert gas in described step S5 is helium or neon or argon
Gas.
The invention also discloses a kind of anti-oxidation safety glass, includes white glass layer, compound antioxidation coating, tempering glass successively
Glass layer, is filled with inert gas between described compound antioxidation coating and described toughened glass layer, in described white glass layer
Edge is provided with PVC sealants and described toughened glass layer between, in described white glass layer and described tempering glass
Glass layer outer ledge is provided with sealing strip.
The present invention compared with prior art, has the advantages that：
(1) present invention is aoxidized by using coating modification fluorescent material, can effectively suppress all-sulphide phosphor；
(2) present invention is by adopting nano silicon, you can as binding agent, can simultaneously serve as protective agent, put
Put zinc sulphide oxidized；
(3) present invention can further avoid internal painting by cementing out the air in cavity using inert gas
Coating is oxidized, meanwhile, the intensity of entirety can be improved, oxidation proof propertiess are improved.
Description of the drawings
In order to be illustrated more clearly that the technical scheme of the embodiment of the present invention, below by to be used attached needed for embodiment
Figure is briefly described, it will be appreciated that the following drawings illustrate only certain embodiments of the present invention, and it is right to be therefore not construed as
The restriction of scope, for those of ordinary skill in the art, on the premise of not paying creative work, can be with according to this
A little accompanying drawings obtain other related accompanying drawings.
Fig. 1 is 2 overall structure diagram of the embodiment of the present invention.
Wherein：101. white glass layers, 102. compound antioxidation coatings, 103. toughened glass layers, 104. inert gases,
105.PVC sealants, 106. sealing strips.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment, but embodiments of the present invention are not limited to
This.
Embodiment 1：
A kind of preparation method of anti-oxidation safety glass, comprises the following steps：
S1：Synthesis composite coated layer：Using silicone coupling agents in alcohol solvent surface coating modification nano-zinc sulfide
Crystal, forms composite coated layer material；
S2：Surface coating modification is carried out to coating layer material：The coating layer material that step S1 is made is dispersed in containing coupling
In the organic solvent of agent, using ultrasonic wave/ball-milling method to surface coating modification, by modified coating layer material and silica
Colloidal sol mixes, and forms mixing coat；
S3：Spray coating layer：The coating layer material produced in step S2 is coated in by white glass using spraying or roller coating technology
Glass surface, dry solidification form compound antioxidation coating；
S4：Bonding toughened glass layer：Toughened glass layer is set on white glass, makes compound antioxidation coating be located at safety glass
Between layer and white glass layer, cavity between white glass layer and toughened glass layer, is formed；
S5：Filling inert gas：The cavity that step S4 is produced is closed, and in empty intra-bladder instillation inert gas, is filled
By cavities seals after the completion of gas.
Preferably, in the present embodiment, the nano-zinc sulfide in described step S1 is using hydrothermal synthesis method or the precipitation method
Synthesis.
Preferably, in the present embodiment, the modified coupling agent in described step S2 is KH-550, KH-560, KH-570 mono-
Kind or several be mixed to form.
Preferably, in the present embodiment, the inert gas in described step S5 is helium or neon or argon gas.
Embodiment 2：
As shown in figure 1, the present embodiment is on the basis of embodiment 1, a kind of anti-oxidation safety glass is also disclosed, is wrapped successively
Include white glass layer 101, compound antioxidation coating 102, toughened glass layer 103, described compound antioxidation coating 102 and described tempering
Inert gas 104, side between described white glass layer 101 and described toughened glass layer 103 is filled between glassy layer 103
Edge position is provided with PVC sealants 105, arranges in described white glass layer 101 and described 103 outer ledge of toughened glass layer
There is sealing strip 106.
Embodiment 3：
The present embodiment prepares zinc sulfide crystal using Hydrothermal Synthesiss on the basis of embodiment 1, and zinc sulfide crystal is disperseed
In the alcohol solvent containing KH-550, drying is stirred, promote surface coating modification, modified after cure using ultrasonic wave with ball-milling method
Zinc is mixed with silicon dioxide gel, is coated in white glass surface using spraying coating process, and safety glass is bonded in white glass surface,
Make safety glass cavity be formed with white glass surface, PVC sealings are set on the inside of safety glass with the opposite face edge of white glass
Layer, seals internal cavities, then to empty intra-bladder instillation helium, makes the air in helium replacement cavity, then by PVC sealants
Fully seal, again safety glass and white glass edge seal are got up using sealing strip.
The preferred embodiments of the present invention are the foregoing is only, the present invention is not limited to, for the skill of this area
For art personnel, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, made any repair
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (5)
1. a kind of preparation method of anti-oxidation safety glass, it is characterised in that：Comprise the following steps：
S1：Synthesis composite coated layer：Using silicone coupling agents in alcohol solvent surface coating modification nano-zinc sulfide crystal,
Form composite coated layer material；
S2：Surface coating modification is carried out to coating layer material：The coating layer material that step S1 is made is dispersed in containing coupling agent
In organic solvent, using ultrasonic wave/ball-milling method to surface coating modification, by modified coating layer material and silicon dioxide gel
Mixing, forms mixing coat；
S3：Spray coating layer：The coating layer material produced in step S2 is coated in by white glass table using spraying or roller coating technology
Face, dry solidification form compound antioxidation coating；
S4：Bonding toughened glass layer：On white glass, toughened glass layer is set, make compound antioxidation coating be located at toughened glass layer and
Between white glass layer, cavity between white glass layer and toughened glass layer, is formed；
S5：Filling inert gas：The cavity that step S4 is produced is closed, and in empty intra-bladder instillation inert gas, has been inflated
Into after by cavities seals.
2. the preparation method of a kind of anti-oxidation safety glass according to claim 1, it is characterised in that：Described step S1
In nano-zinc sulfide be to be synthesized using hydrothermal synthesis method or the precipitation method.
3. the preparation method of a kind of anti-oxidation safety glass according to claim 1, it is characterised in that：Described step S2
In modified coupling agent be KH-550, KH-560, KH-570 one or more be mixed to form.
4. the preparation method of a kind of anti-oxidation safety glass according to claim 1, it is characterised in that：Described step S5
In inert gas be helium or neon or argon gas.
5. a kind of anti-oxidation safety glass, it is characterised in that：Include successively white glass layer (101), compound antioxidation coating (102),
Toughened glass layer (103), is filled with inertia between described compound antioxidation coating (102) and described toughened glass layer (103)
Gas (104), between described white glass layer (101) and described toughened glass layer (103), to be provided with PVC close for edge
Sealing (105), is provided with sealing strip in described white glass layer (101) and described toughened glass layer (103) outer ledge
(106).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610921001.9A CN106495499A (en) | 2016-10-21 | 2016-10-21 | The preparation method of anti-oxidation safety glass and the glass made using the method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610921001.9A CN106495499A (en) | 2016-10-21 | 2016-10-21 | The preparation method of anti-oxidation safety glass and the glass made using the method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106495499A true CN106495499A (en) | 2017-03-15 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610921001.9A Pending CN106495499A (en) | 2016-10-21 | 2016-10-21 | The preparation method of anti-oxidation safety glass and the glass made using the method |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201420055Y (en) * | 2009-06-02 | 2010-03-10 | 董新芳 | Low-radiation fireproof hollow glass |
| CN203890237U (en) * | 2014-04-12 | 2014-10-22 | 重庆福威工贸有限公司 | Hollow decorative glass |
| CN204296148U (en) * | 2014-12-04 | 2015-04-29 | 广西远大玻璃节能科技股份有限公司 | A kind of toughened glass |
| CN105172265A (en) * | 2015-07-31 | 2015-12-23 | 芜湖真空科技有限公司 | Glass structure |
| WO2016032885A1 (en) * | 2014-08-25 | 2016-03-03 | Corning Incorporated | Sealed device and methods for making the same |
| CN105500843A (en) * | 2014-10-20 | 2016-04-20 | 张云德 | Hollow anti-UV wear-resistant hydrophobic glass |
| CN105751628A (en) * | 2016-04-25 | 2016-07-13 | 江苏齐光玻璃科技有限公司 | Glass |
-
2016
- 2016-10-21 CN CN201610921001.9A patent/CN106495499A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201420055Y (en) * | 2009-06-02 | 2010-03-10 | 董新芳 | Low-radiation fireproof hollow glass |
| CN203890237U (en) * | 2014-04-12 | 2014-10-22 | 重庆福威工贸有限公司 | Hollow decorative glass |
| WO2016032885A1 (en) * | 2014-08-25 | 2016-03-03 | Corning Incorporated | Sealed device and methods for making the same |
| CN105500843A (en) * | 2014-10-20 | 2016-04-20 | 张云德 | Hollow anti-UV wear-resistant hydrophobic glass |
| CN204296148U (en) * | 2014-12-04 | 2015-04-29 | 广西远大玻璃节能科技股份有限公司 | A kind of toughened glass |
| CN105172265A (en) * | 2015-07-31 | 2015-12-23 | 芜湖真空科技有限公司 | Glass structure |
| CN105751628A (en) * | 2016-04-25 | 2016-07-13 | 江苏齐光玻璃科技有限公司 | Glass |
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Application publication date: 20170315 |
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