CN106489990A - Application of the ozonized surfactant in chicken cultivation - Google Patents
Application of the ozonized surfactant in chicken cultivation Download PDFInfo
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- CN106489990A CN106489990A CN201610936262.8A CN201610936262A CN106489990A CN 106489990 A CN106489990 A CN 106489990A CN 201610936262 A CN201610936262 A CN 201610936262A CN 106489990 A CN106489990 A CN 106489990A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
-
- A—HUMAN NECESSITIES
- A22—BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
- A22C—PROCESSING MEAT, POULTRY, OR FISH
- A22C21/00—Processing poultry
- A22C21/0061—Cleaning or disinfecting poultry
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B4/00—General methods for preserving meat, sausages, fish or fish products
- A23B4/06—Freezing; Subsequent thawing; Cooling
- A23B4/08—Freezing; Subsequent thawing; Cooling with addition of chemicals or treatment with chemicals before or during cooling, e.g. in the form of an ice coating or frozen block
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61D—VETERINARY INSTRUMENTS, IMPLEMENTS, TOOLS, OR METHODS
- A61D7/00—Devices or methods for introducing solid, liquid, or gaseous remedies or other materials into or onto the bodies of animals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L11/00—Methods specially adapted for refuse
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
- A61L9/145—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes air-liquid contact processes, e.g. scrubbing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Abstract
The present invention relates to application of the ozonized surfactant in chicken cultivation, apply the ozonized surfactant on an empty stomach drinking-water and dilute with water hen house, keeper, chicken body, breeding facility, empty gas and water, excrement are carried out disinfection with deodorant, for improving chicken to newcastle disease, Bursal Disease, chicken pox, bird flu, chicken coccidiasis, FAV disease, infectious rhinitis of fowl, Escherichia coli, salmonella, pasteurellosis, horse Garrick, the immunity of infective bronchitis and premunition, promote chicken to enter growth and lay eggs, it is ensured that the health of chicken.
Description
Technical field
The present invention relates to poultry farming field, and in particular to one kind being capable of, promotion chicken growth deodorant to coop sterilizing, product
Egg, improves the ozonized surfactant of chicken resistance against diseases.
Background technology
Surfactant refers to the material that just can significantly reduce solvent table and tension force with extremely low concentration.Its molecular structure
The characteristics of having common, i.e. molecule are all that the hydrophilic group two parts by nonpolar hydrophobic group with polarity are constituted, and with chemical bond
Be connected, organized assembles can be formed in certain density surfactant solution, change the surface state of system.This kind of point
Sub not only hydrophilic but also oleophylic, so that produce wetting or dewetting, emulsification or breakdown of emulsion, dispersion or cohesion, foaming or froth breaking and solubilising
Deng series of properties, there is important application at the aspect such as civilian and industrial.At present, various new surfactant is received extensively
General concern, including the aliphatic acid derived with natural animal-plant oil as development of raw materials novel surfactant（See Ge Hong,
Sun Lingxin, Wang Jun write《The progress of research work regarding surfactants derived from fatty acids》, daily chemical industry, 2004,3（34）：
176-180）；Nontoxic and not sensitization biosurfactant（See that left-handed crystal, Wang Xuechuan are write《Biosurfactant should
With》, chemical industry and engineering technology, 2005,（26）：23-27）, green surfactant to ecological environmental nonpollution（See Lee
Write Wenan《The application of green surfactant and progress》, Agriculture of Anhui science, 2007,35（19）：5691-
5692）With with high surface, low critical micelle concentration, unique viscosity characteristicses new type of Gemini surfactant（See king
Gorgeous write《The preparation of new type amphoteric ionic Gemini surface active and performance study》2010）.
In ozonisation series of products, ozonisation olive oil, sunflower oil and soybean oil are used for cotton-padded mattress as antiseptic, deodorant
The topical drug of the treating for skin disease such as sore and ulcer has been listed.Above-mentioned oil why is selected, unsaturation therein is because
Content of fatty acid is higher.Ozone molecule can occur addition reaction with unsaturated olefin double bond, generate ozonide.Unsaturated bond
Number is more, and ozonization is more susceptible to, and more with the amount of ozone addition, and addition product can carry the number of ozone molecule
Mesh is also more.
But above vegetable oil itself yet suffers from inherent shortcoming.As vegetable oil is the mixture containing Multiple components,
Its constituent can be because of aspects such as the place of production, weather conditions and processing technologys different and different, therefore, it is difficult to prepare have constant
The ozonisation vegetable oil of quality.Be additionally, since in crude vegetal containing antioxidant material, well imagine the antioxidant material with
Ozone competition and then the generation of interference ozonide.Furthermore, the profile due to ozonizing vegetable oil (for example, ozonizes olive
Oil) it is a kind of grease, it is used for outward the body part of position (for example, colony house and tank) and the mammal being spontaneously wet out by water (for example,
Hoof and skin) upper when be ostracised, therefore can not equably be coated with or be sprayed on object, become obstruction in practical application.
The interior environment of body is also water environment, ozone and surfactant generation addition reaction, generates ozonized surfactant, can
It is effectively increased the concentration that ozone enters blood.If again ozone, unrighted acid and unsaturated surfactant three can be mixed
Close and addition reaction occurs, just the advantage of three can be combined together, it is also possible to carry more ozone and enter body.
For improving the quality and safety of livestock products, oneself disables antibioticses additive in the world.Recent domestic scholar
Research shows that ozone has suppression pathogen, strengthens immunologic function, improves body resistance against diseases, promotes the function of growth of animals or poultry.
Present invention application in chicken cultivation has two methods：One is that ozonized surfactant is drunk water on an empty stomach, strengthens immunologic function, carries
High body resistance against diseases, promotes growth of animals or poultry；Two be by ozonized surfactant clear water dilute, spray to need sterilization and
Where deodorant, germ, bacterium in house are killed therewith, the foreign odor that it can also be distributed with fecaluria decompose reaction and deodorant.
Drinking water disinfection to chicken, is that ozonized surfactant is dissolved in water, can kill the microorganism in water.Ozone disinfection is same
When kill body surface various bacteriums and virus, reach diseases prevention purpose.Chicken house sewage is processed simultaneously with ozonized surfactant
Carry out disinfection, deodorant, decolourize, also degradable with the harmful toxic matter that goes in eliminating water, such as phenol, cyanide, sulfide, nitro compound
The metal ion such as thing, organophosphorus pesticide, alkylbenzenesulfonate, lignin and iron, zinc, manganese, mercury.Large intestine bar in sewage
Bacterium, carcinogen equally have kills the notable function of removing, and is effectively improved exceeded BOD, COD.Live on ozonisation surface
Property agent can pass through purify air of spraying, stink that ozone is produced by the rapid decomposable chicken house of its strong oxidation performance and other smells
Material, such as ammonia, hydrogen sulfide, phenol, amine substance etc..Ozone is removed peculiar smell in air and is that it can be with the composition for producing peculiar smell
Generation chemical reaction, generates the material of other frees from extraneous odour.
Develop animal husbandry to transforming agricultural production, increase farmers' income, improve national economy level and strengthen the whole people
Fitness is significant.Developing Modern Livestock Husbandry must walk the road of scale, standardization and the marketization, it is desirable to have innovation and
Applicable green scientific culture technology.Avian disease becomes the outstanding problem for hindering aquaculture development with veterinary drug, antibiotic residue.
Often there are multiple diseases in livestock and poultry in feeding process, only chicken disease just has kind more than 50, particularly runs into disastrous popular disease
Disease, often leads to livestock and poultry mortality, suffers heavy losses.At present, common multiple containing chemical composition in prevention of damage by disease and treatment
Veterinary drug and antibiotic, improper use can cause animal products medicine residual exceeded, affect eater healthy and domestic and international market
Developing and development.Ozonized surfactant is a kind of strong oxidizer, with wide spectrum, efficiently, quick and do not stay the only of dead angle
Special bactericidal action.Ozone in finite concentration, in the time, to fungi, virus and multiple germ killing rates such as bacterium up to 99.9%～
100%, its sterilization effect is recognized the world over.Ozonization sterilization technology is by domestic and international application to numerous areas, effect
Well.Ozonized surfactant technology shows unique effect in terms of disinfectant anti-epidemic.Ozone permeates into colony house in the short time
The infectious germs such as virus, bacterium, fungi and parasite type are killed in each corner, moment, effectively prevent breathing problem
Infection and propagation, while eliminating peculiar smell, improve environment.Ozone technology processes drinking water and can purify water, and reduces or prevents livestock and poultry
Enterogastric diseases occur, and improve immunity of livestock, the green meat of production, egg, milk deli.
Content of the invention
It is an object of the invention to by ozonized surfactant to hen house, keeper, chicken body, breeding facility, sky
Gas and water, excrement are sterilized and deodorant, and apply ozonized surfactant to drink water on an empty stomach, for improving the immunity and premunition of chicken,
And the health for promoting to grow and ensure chicken.
Present invention relates particularly to surfactant include amphoteric surfactant with least one olefinic double bond,
The hydrophobic base section of nonionic surfactant, cationic surfactant and anion surfactant, Shuangzi（Gemini）
Surfactant connection base section, biosurfactant and green surfactant.
The surfactant of selection is the amphoteric surfactant with least one olefinic double bond, selected from unsaturated hydrocarbons
The monosubstituted and polysubstituted empgen BB of base, the monosubstituted and polysubstituted Cocoamidopropyl betaine of unsaturated alkyl, no
The monosubstituted and polysubstituted dodecyl hydroxypropyl sulfobetaines of saturated hydrocarbyl, the monosubstituted and polysubstituted fatty acyl of unsaturated alkyl
The monosubstituted and polysubstituted two phosphorous base glycine betaine of glycerine of amine CAB, unsaturated alkyl, unsaturated alkyl are monosubstituted and many
Replace the third hydroxyl sulfo betaine of lauramide, monosubstituted and polysubstituted the third weight ratio of the lauramide beet of unsaturated alkyl
Alkali, N, bis- (2- hydroxyls of N- dihydroxy ethyl-N- ethyl unsaturated fatty acid ester glycine betaines and N- ethyl unsaturated fatty acid ester-N, N-
Ethyl) -3-（2- hydroxypropyls）Sulfate ammonium salt, cocoyl both sexes unsaturated fatty acid salt, N- (2- fatty acid amides) ethyl imido
Unsaturated fat acid disodium and N-（2- fatty acid amides) ethyl-N, in N- tri- [3,3- (2- hydroxyls) propylsultaine] ammonia disodium salt
Any one, two kinds and two or more mixing.
The surfactant of selection is the nonionic surfactant with least one olefinic double bond, selected from unsaturation
Polyoxyethylene carboxylate, unsaturated fatty alcohol APEO, unsaturated fat phenol polyethenoxy ether, polyoxyethylene are unsaturated
Fatty acid amide, propane diols unsaturated fatty acid ester, pentaerythrite unsaturated fatty acid ester, glycerine unsaturated fatty acid ester, poly- sweet
Oily unsaturated fatty acid ester, sorbitan unsaturated fatty acid ester, polyoxyethylene sorbitol acid anhydride unsaturated fatty acid ester, sweet
Dew sugar alcohol unsaturated fatty acid ester, sucrose unsaturated fatty acid ester, polyethylene glycol unsaturated alkyl ether and polypropylene glycol are unsaturated
In the nonionic surfactant with least one olefinic double bond such as alkyl ether any one, two kinds and two or more mixed
Close.
The surfactant of selection is the anion surfactant with least one olefinic double bond, is selected from insatiable hunger
In soap, unsaturated fatty alcohol sulfuric acid, alpha-sulfo unsaturated fatty acid ester, olefin sulphates and alkene sulfonate
Any one, two kinds and two or more mixing.
The surfactant of selection is the cationic surfactant with least one olefinic double bond, selected from unsaturation
The monosubstituted leptodactyline of aliphatic group, two substituted dimethyl ammonium salt of unsaturated aliphatic hydrocarbyl moiety, unsaturated aliphatic hydrocarbyl moiety are monosubstituted
The monosubstituted amine acylate of dimethyl benzyl ammonium salt, unsaturated aliphatic hydrocarbyl moiety, two replacement amine acylate of unsaturated aliphatic hydrocarbyl moiety
With any one in the cationic surfactant in N- methyl diethanolamine unsaturated fatty acid ester hydrochlorides, two kinds and
Two or more mixing.
The surfactant of selection is the Shuangzi with least one olefinic double bond（Gemini）Surfactant, is selected from
Hydrophobic base section and connection base section have the Shuangzi of at least one olefinic double bond（Gemini）Any in surfactant
A kind of, two kinds and two or more mixing.
The surfactant of selection is the biosurfactant with least one olefinic double bond, selected from unsaturated lipid
Fat alkyl her subtilin, red moss enzyme of the monosubstituted and polysubstituted mannose of unsaturated aliphatic hydrocarbyl moiety monosubstituted and polysubstituted
The monosubstituted and polysubstituted Pseudomonas fluorescence metabolin of fat, unsaturated aliphatic hydrocarbyl moiety, unsaturated aliphatic hydrocarbyl moiety monosubstituted and
The monosubstituted and polysubstituted Lactobacillus acidophilus' metabolin of polysubstituted Bacillus acidi lactici metabolin, unsaturated aliphatic hydrocarbyl moiety, insatiable hunger
In monosubstituted with aliphatic group and polysubstituted yeast Bacillus acidi lactici any one, two kinds and two or more mixing.
The surfactant of selection is the green surfactant with least one olefinic double bond, selected from unsaturated lipid
The monosubstituted and polysubstituted triethanolamine quaternary ammonium salt of fat alkyl, alpha-sulfo unsaturated fatty acid methyl ester, unsaturated aliphatic hydrocarbyl moiety phosphorus
The monosubstituted and polysubstituted amino acid pattern of acid esters, unsaturated aliphatic hydrocarbyl moiety, the monosubstituted and polysubstituted glycine betaine of unsaturated aliphatic hydrocarbyl moiety
The monosubstituted and polysubstituted imidazoles fundamental mode of type, unsaturated aliphatic hydrocarbyl moiety, the monosubstituted and polysubstituted many glycosides of unsaturated aliphatic hydrocarbyl moiety, insatiable hunger
In monosubstituted with aliphatic group and polysubstituted glucose amide and sucrose unsaturated fat acid amide any one, two kinds and two kinds
Mixed above.
The surfactant of selection is mixed with unrighted acid, is formed mixture, is ozonized by addition ozone
Surfactant.Wherein unrighted acid is selected from crotonic acid, nutmeg oleic acid, palmitoleic acid, oleic acid, antiform oleic acid, castor-oil plant
The monounsaturated fatty acids such as oleic acid, erucic acid, cetoleic acid, nervonic acid.Polyunsaturated fatty acid is referred to
The unrighted acid of hydro carbons double bond, including linoleic acid（Unsaturated dienoic acid）, leukotrienes and eleostearic acid（Unsaturated trienic acid）, ten
Eight carbon tetraenoic acids and arachidonic acid（Unsaturated tetraenoic acid）, eicosapentaenoic acid and clupanodonic acid（Unsaturated pentaene
Acid）, DHA（Unsaturated acid）.Meanwhile, unrighted acid including but not limited to has 6～26 carbon originals
Son and 1～6 olefinic double bond.Surfactant according to claims 1 to 10, selects in above-mentioned surfactant
Any one, two kinds and two or more mixed, ozonized surfactant is obtained by addition ozone.
For reaching above-mentioned purpose, the technical solution used in the present invention will be carried out with reference to following Making programme and embodiment
Simple declaration.
1st, ozone gas are prepared.
2nd, ozonized surfactant is prepared.
3rd, ozonized surfactant and monounsaturated fatty acids mixture are prepared.
4th, ozonized surfactant and polyunsaturated fatty acid mixture are prepared.
5th, ozonisation polyoxyethylene sorbitan monooleate improves chicken immunity, premunition and promotes the work of chicken growth
With.
6th, ozonisation polyoxyethylene sorbitan monooleate is sterilized（Poison）And deodorizing capability.
7th, prevention of the ozonisation polyoxyethylene sorbitan monooleate to chicken disease.
Specific embodiment
Prepared by the ozonisation polyoxyethylene sorbitan monooleate of embodiment 1
1st, ozone gas are prepared.The present invention prepares ozone gas using medical oxygen by ozone generator.
Selected from the DRO3-A type ozone machines that Xi'an Derun Bio-Technology Co., Ltd. designs production（Power 55W）.
2nd, preparing ozonisation polyoxyethylene sorbitan monooleate whole process need be carried out at 20～25 DEG C, it is ensured that
Ozonisation polyoxyethylene sorbitan monooleate will not occur pyrolytic reaction.
3rd, polyoxyethylene sorbitan monooleate 3kg is inserted in reactor；Ozone is with 150m3/ h flow velocitys are added,
Total reaction time is 20 hours.After reaction terminates, residual air is inactivated.
4th, it is 40 mg/L to obtain ozonizing ozone concentration in polyoxyethylene sorbitan monooleate, and 25 DEG C can be stablized
Preserve ten months.
Prepared by the ozonisation sucrose unsaturated fatty acid ester quaternary ammonium salt of embodiment 2
1st, ozone gas are prepared.The present invention prepares ozone gas using medical oxygen by ozone generator.
Selected from the DRO3-A type ozone machines that Xi'an Derun Bio-Technology Co., Ltd. designs production（Power 55W）.
2nd, preparing ozonisation sucrose unsaturated fatty acid ester quaternary ammonium salt whole process need be carried out at 20～25 DEG C, it is ensured that smelly
Oxidation sucrose unsaturated fatty acid ester quaternary ammonium salt will not occur pyrolytic reaction.
3rd, sucrose unsaturated fatty acid ester quaternary ammonium salt 3kg is inserted in reactor；Ozone is with 150m3/ h flow velocitys are added, always
Reaction time is 20 hours.After reaction terminates, residual air is inactivated.
4th, it is 40 mg/L to obtain ozonizing ozone concentration in sucrose unsaturated fatty acid ester quaternary ammonium salt, and 25 DEG C stably can be protected
Deposit ten months.
The ozonisation polyoxyethylene sorbitan monooleate of embodiment 3 and the preparation of oleic acid mixture
1st, ozone gas are prepared.The present invention prepares ozone gas using medical oxygen by ozone generator.
Selected from the DRO3-A type ozone machines that Xi'an Derun Bio-Technology Co., Ltd. designs production（Power 55W）.
2nd, prepare ozonisation polyoxyethylene sorbitan monooleate and oleic acid mixture whole process need 20～
25 DEG C are carried out, it is ensured that ozonisation polyoxyethylene sorbitan monooleate and oleic acid mixture will not occur pyrolytic reaction.
3rd, polyoxyethylene sorbitan monooleate 1.5kg and oleic acid 1.5kg are inserted in reactor；Ozone is with 150m3/
H flow velocitys are added, and total reaction time is 20 hours.After reaction terminates, residual air is inactivated.
4th, it is 50mg/L to obtain ozonizing ozone concentration in polyoxyethylene sorbitan monooleate and oleic acid, and 25 DEG C can
Stably preserve ten months.
The ozonisation polyoxyethylene sorbitan monooleate of embodiment 4 and the preparation of linoleic acid mixture
1st, ozone gas are prepared.The present invention prepares ozone gas using medical oxygen by ozone generator.
Selected from the DRO3-A type ozone machines that Xi'an Derun Bio-Technology Co., Ltd. designs production（Power 55W）.
2nd, prepare ozonisation polyoxyethylene sorbitan monooleate and linoleic acid mixture whole process need be 20
～25 DEG C are carried out, it is ensured that it is anti-that ozonisation polyoxyethylene sorbitan monooleate and linoleic acid mixture will not occur pyrolysis
Should.
3rd, polyoxyethylene sorbitan monooleate 1.5kg and linoleic acid 1.5kg are respectively implanted in reactor, are mixed,
Ozone is with 150m3/ h flow velocitys are added, and total reaction time is 20 hours.After reaction terminates, residual air is inactivated.
4th, it is 60 mg/L to obtain ozonizing ozone concentration in polyoxyethylene sorbitan monooleate and linoleic acid, 25
DEG C stably can preserve ten months.
The ozonisation polyoxyethylene sorbitan monooleate disinfecting, deodorizing of embodiment 5 improve chicken immunity, premunition and
Promote the effect of chicken growth
1 materials and methods
1.1 test process
Colony house, drinking water, livestock and poultry body itself and human activity in infecting the germ of livestock and poultry body essentially from feeding environment, for
Pathogen transmission source application ozonisation polyoxyethylene sorbitan monooleate.Test address is selected in Xianyang Yangling District and supports
Grow test site.
(1), colony house disinfecting, deodorizing method:Will ozonisation polyoxyethylene sorbitan monooleate dilute with water concentration
0.5%, by spraying ozonisation polyoxyethylene sorbitan monooleate to each corner on colony house ground.Usually by every
Individual hen house uniformly sprinkles ozonisation polyoxyethylene sorbitan monooleate, by ozonizing polyoxyethylene sorbitol acid anhydride list
The gas reaction of bacterium and generation in oleate and chicken manure, to reduce in hen house distributing for ammonia and hydrogen sulfide in excrement, so as to
Reduce hen house stink, kill various harmful levels of pathogens, purify feeding environment, prevent the infection and propagation of breathing problem.Improve chicken
House environment, it is to avoid chicken mass-sending disease, it is ensured that the production performance of chicken.
(2), drinking water disinfection:Gastrointestinal tract of livestock and fowls disease is infected essentially from drinking-water and feed, and water sterilization is particularly important.
Drinking water is available for livestock and poultry to drink by 0.1% ozonisation polyoxyethylene sorbitan monooleate process 20min.
(3), sanitizing the carcass is raiseeed:Ozonisation polyoxyethylene sorbitan monooleate daily with 0.1% is empty to colony house
Between sterilize while, chicken body surface is also carried out sterilizing, effect is significant.
(4), the sterilization of breeding facility:All utensils by feeding（Such as chicken coop, bed, incubator, tank, hopper）, work
Person works' clothes etc. are regular with 0.5% ozonisation polyoxyethylene sorbitan monooleate with utensils such as livestock and poultry close contacts
Spray disinfectant is carried out, prevents external germ incoming.
(5), processed chicken house excrement and carried out disinfection, removed with 0.5% ozonisation polyoxyethylene sorbitan monooleate
Smelly, decolourize, degraded and remove excrement in harmful toxic matter, such as phenol, cyanide, sulfide, nitro compound, organophosphorus pesticide,
The metal ion such as alkylbenzenesulfonate, lignin and iron, zinc, manganese, mercury.Escherichia coli, carcinogen in killing excrement, make
Exceeded BOD, COD is effectively improved.
(6), purify air：Hen house is sprayed with 0.1% ozonisation polyoxyethylene sorbitan monooleate, strong by which
Stink and the material of other smells that the rapid decomposable chicken house of oxidation susceptibility is produced, such as ammonia, hydrogen sulfide, phenol, amine substance
Deng.Ozone is removed peculiar smell in air and is that it can occur chemical reaction with the composition for producing peculiar smell, generates the thing of other frees from extraneous odour
Matter.
(7), meat processing combine：Meat packing enterprise directly applies 0.1% ozonisation polyoxyethylene sorbitan monooleate pair
The live chickens that butchers carry out taking a shower, clean, and can kill the germ of various pollutions, virus on live chickens body.Trunk is applied in chilling room
With 0.01% ozonisation polyoxyethylene sorbitan monooleate, the very bad peculiar smell of chilling room is eliminated；It is suspended on chilling room
Inside do not go mouldy, optimize the quality of meat；Meat surface becomes slightly to dry, and strengthens feeling of freshness, reduces weight loss.
(8), the disinfecting, deodorizing of discarded object：Excrement in hen house is the significant risk microorganism for causing colibacillosis to propagate
Source, the hygienic state for controlling excrement can significantly reduce the incidence of alimentary canal epidemic disease.With 0.5% ozonisation polyoxyethylene
Sugar alcohol acid anhydride monoleate is sprayed onto excrement and coprodaecum, and the organic odor gas such as ammonia in poultry house can be decomposed into by these oxidants
Less harmless molecule, deodorizing effect are excellent.Especially the pathogenic microorganism and animal defecation of spacer screen surface attachment are produced
Microbial aerosol have strong kill effect, to preventing colibacillosis important in inhibiting.
2 results and analysis
The generation of 2.1 effective control livestock and poultries, improves survival rate
Successively to supply examination chicken (public young including Broiler chicks, miscellaneous chicken and laying hen) more than 8000 amount to 15 times repeat test, should
With the ozonisation polyoxyethylene sorbitan monooleate of concentration 0.5% to hen house, drinking water, chicken body, breeding facility and excreta
Carry out disinfection sterilizing, does not use any medicine and antibiotic, epidemic disease never occurred during testing every time.Indivedual chickens
When there is slight symptom, " Contingency Hospital " is set in hen house, morbidity chicken is concentrated in together, increases hen house disinfection of drinking water
Number.0.5% ozonisation polyoxyethylene sorbitan monooleate is notable to cecal coccidiosis and mycoplasmosis therapeutic effect.Examination
The survival rate for testing group chicken is stable 98% or so, and control group is 82%～93%.Poultry 10,000 laying hens of family Liu Yi are divided to two houses for Fugu
Raise (often giving up 5,000), wherein one house is routinely raised using ozonisation polyoxyethylene sorbitan monooleate, another house
Support.Ozonisation polyoxyethylene sorbitan monooleate breeding house, during whole raising is not used any chemicals, does not have
Have and disease occurred, laying rate is up to 97%, and the chicken coccidiasis incidence 35% of conventinal breeding house, laying rate is less than 71%.
2.2 promote the development of livestock birds health normal growth, deliver for sale in advance.
The feeding meat chick test of ozonisation polyoxyethylene sorbitan monooleate ozone technology, is divided into concentration 0.5% smelly
Oxidation polyoxyethylene sorbitan monooleate is to chicken coop air sterilization+drinking-water+ground sterilization test group, ozonisation polyoxy
With 1PPM concentration empty stomach drinking-water group and conventinal breeding control group, tested chicken breed is Ai Wei to ethene sorbitan monooleate
Cause, its growing state are shown in Table 1.
The impact that the ozonisation polyoxyethylene sorbitan monooleate of table 1 is developed to broiler growth（g）
Table 1 is illustrated, from raising the 3rd week, ozonisation polyoxyethylene sorbitan monooleate is sterilized and drinking-water treatment group ratio
Control group growth and development of chickens is substantially accelerated, and raises the 7th week, and two groups of tested chickens ozonize polyoxyethylene sorbitol by only quality is claimed
Averagely single chicken of the sterilization of alcohol acid anhydride monoleate and drinking-water treatment group increases 332.88g and 406.39g (p than control group quality respectively
0.01), feedstuff-meat ratio reduces by 4.2% and 4.4% to ＜ respectively, can deliver 4～5d in advance for sale.
2.3 ozonisation polyoxyethylene sorbitan monooleates are sterilized（Poison）And deodorizing capability
The inhibitory effect test of ozonisation polyoxyethylene sorbitan monooleate.
1.1 experimental condition.
By reagent:The embodiment of the present invention 1 ozonizes polyoxyethylene sorbitan monooleate product.
Comparison medicine:Hundred bacterium disappear (Biocid), and Pfizer Inc. produces, and dark brown liquid, plastics are canned.
1.2 plant for examination bacterium (poison):
Bacterium:Staphylococcus aureus, Escherichia coli, salmonella typhimurium, waxy bud pole bacterium, avian pasteurella multocida, thread
Mycoplasma goat subspecies, above bacterial strain through biochemical reactions and the Antigen Identification of morphological feature, cultural character and system, and
Screen through inoculation experiments animal, it was demonstrated that with the genus and species characteristic and preferable pathogenicity.
Virus:
A. newcastle disease virus:The lyophilized strong poison of F48E8, China Institute of Veterinary Drug Control are supplied;
B. CSFV:The weak poison of rabbitization, the lyophilized poison of F486, China Institute of Veterinary Drug Control are supplied;
Above seed culture of viruses is passing through corresponding animal used as test, after malicious valency is qualified after measured, for testing.
1.3 experimental animals, culture medium and reagent:
1) animal:
Small white mouse:20 grams or so healthy Kunming white mouses;
Rabbit:1.8～2.5kg healthy rabbits;
Chicken:11 monthly ages nonimmune healthy chicken;
Chicken embryo:10 ages in days health live chickens embryo;
2) culture medium:
Nutrient broth, martin's bouillon, standard agar flat board, Martin's agar plate, KM Mycoplasma culture mediums etc.;
3) diluent:
PBS, sterile saline, deionized water.
2nd, test method.
Depending on every experimental condition is according to test objective:Trial drug is 10min to the bacteria time, to virus
The deactivation time is 8～1Omin;Test temperature refers to and is room temperature (25 ± 4 DEG C).
3rd, result of the test
3.1 fungistatic effect:
2 ozonisation polyoxyethylene sorbitan monooleates be the results are shown in Table to various bacterium（Poison）The minimum fungistatic effect of strain
（MIC）
| Bacterium（Poison）Kind | Ozonisation polyoxyethylene sorbitan monooleate | Hundred bacterium disappear | The comparison that ozonisation polyoxyethylene sorbitan monooleate and hundred bacterium disappear |
| Staphylococcus aureus | 1:8000 | 1:2000 | 4 times |
| Escherichia coli | 1:8000 | 1:2000 | 4 times |
| Salmonella typhimurium | 1:8000 | 1:2000 | 2 times |
| Bud pole bacterium | 1:12000 | 1:4000 | 3 times |
| Avian pasteurella multocida | 1:8000 | 1:2000 | 4 times |
| Mycoplasma mycoides | 1:8000 | 1:2000 | 4 times |
| Newcastle disease virus | 1:2000 | 1:200 | 10 times |
| CSFV | 1:630 | 1:90 | 7 times |
Result of the test shows, ozonisation polyoxyethylene sorbitan monooleate to staphylococcus aureus, avian pasteurella multocida,
Mycoplasma mycoides and colibacillary minimum inhibitory concentration are 4 times that hundred bacterium disappear, and the minimum inhibitory concentration to remaining 2 kinds of bacterium is equal
2～3 times disappeared for hundred bacterium, and 10 times and 7 times that hundred bacterium disappear are respectively to the inhibition of two-strain, there is good suppression thin
Bacterium and the effect of virus.
3.2 ozonisation polyoxyethylene sorbitan monooleate inactivation of virus tests:
Ozonisation polyoxyethylene sorbitan monooleate is shown in Table 3 to the inactivating efficacy of newcastle disease virus and CSFV.
Table 3 ozonizes polyoxyethylene sorbitan monooleate to newcastle disease virus and the inactivating efficacy of CSFV
Summary items result of the test, it was demonstrated that ozonisation polyoxyethylene sorbitan monooleate be a kind of efficiently, wide spectrum,
Strongly, safety, at a temperature of 25 ± 4 DEG C apply new disinfectant, can be widely used in various environment, livestock and poultry body surface, colony house,
The sterilization of aquatic products (such as fishpond), production equipment, forage grass and feed, various apparatus, drinking-water, excrement etc., chicken epidemic prevention and control, medical treatment and
The aspects such as public health have good value and wide application prospect.
4th, disinfection effect test of the polyoxyethylene sorbitan monooleate to chicken drinking water is ozonized
Table 4 ozonizes disinfection effect test of the polyoxyethylene sorbitan monooleate to chicken drinking water
Respectively 4 parts of water in hen house drinking device is offerd medicine 10 minutes, every part of 1000mL is divided into four groups, first group is control group, no
Dosing, second and third, four groups be separately added into final concentration 0.1%, 0.2%, 0.5% disinfectant.Per group is sampled 2, every lOmL.By institute
Sample thief dilutes 0.1 times and 0.O1 times respectively.
Sample 0.5mL after by dilution is added in the empty plate of sterilizing, adds 45～50 DEG C of plain agar culture medium,
After 37 DEG C of incubator cultures 24 hours, bacterium colony is counted, 4 are the results are shown in Table.
From table 4, it can be seen that ozonisation polyoxyethylene sorbitan monooleate is fine to chicken disinfection of drinking water effect, respectively
The bacteriostasis rate of concentration is all up 100%.
2.4 eliminate raising peculiar smell, effectively purify feeding environment
The foul smell main component produced in livestock and poultry colony house is ammonia and hydrogen sulfide, these pernicious gas severe contamination feeding environments,
Livestock and poultry are affected normally to grow healthy with staff, ozonisation polyoxyethylene sorbitan monooleate can
Fast decoupled harmful substance, purifies feeding environment.It is divided into the ozonisation polyoxyethylene sorbitan monooleate pair of concentration 0.5%
Chicken coop air sterilization+drinking-water+ground sterilization test group and control group.Using HL-209 ammonias detector and 40RATTLEZ sulphur
Change hydrogen detector, determine 10 point NH in breeding house respectively3And H2S gas concentrations.The average NH of test group37.2×10- 3mg/L、
H2S 4.2×10- 3Mg/L, the average NH of control group335.9×10- 3mg/L、H2S 10.2×10- 3mg/L.Test group is more than control
Group NH3And H2S concentration is low, and the concentration of control group is 4.99 times and 2.43 times (being shown in Table 5) of test group concentration.
NH in 5 fowl raising of table house3And H2S measured values（10- 3mg/L）
2.5 improve chicken panel antibodies level, strengthen immunity
The application ozonisation polyoxyethylene sorbitan monooleate of concentration 0.5% is to chicken coop air sterilization+drinking-water+ground sterilization
, with the concentration empty stomach drinking-water group of 1PPM and control group, ozone enters for test group and ozonisation polyoxyethylene sorbitan monooleate
After entering chicken body, with activation entirely immune effect, so as to enhance immunity and antibody horizontal.
(1), newcastle disease (ND) hemagglutination test (HI)：Ozonisation polyoxyethylene sorbitan monooleate sterilizing test
Group, ozonisation polyoxyethylene sorbitan monooleate water drinking test group and control group are through Xibei Univ. of Agricultural ＆ Forest Science ＆ Technology animal doctor
Institute's blood sampling carries out newcastle disease hemagglutination-inhibition test, the results are shown in Table 6.
Table 6 ozonizes polyoxyethylene sorbitan monooleate to newcastle disease (ND) hemagglutination-inhibition test (HI)
Affect
Table 6 illustrates that the HI mean values for ozonizing polyoxyethylene sorbitan monooleate sterilization group ND are 512, are control groups
3.03 times of mean value 168.9, ozonize polyoxyethylene sorbitan monooleate drinking-water group ND HI mean values be
630.34, it is compare cell mean 168.9 3.73 times, test group antibody horizontal is consistent, and control group antibody horizontal is irregular not
Together.Show that chicken, in feeding process, is acted on by ozone, the premunition of newcastle disease is strengthened.
(2) Bursal Disease (IBD) agar gel diffusion test (AGP) testing result, ozonizes polyoxyethylene
Sugar alcohol acid anhydride monoleate sterilization group positive rate is 86.7%, and control group is 73.3%；Ozonisation polyoxyethylene sorbitol acid anhydride list oil
Acid esters drinking-water group positive rate is 100%.Show that chicken, in feeding process, is acted on by ozone, the premunition of the bursa of farbricius is increased
By force.
Table 7 Bursal Disease (IBD) agar gel diffusion test (AGP)
2.6 egg productions are stable, and quality is improved
Using ozonisation polyoxyethylene sorbitan monooleate ozone technology disinfectant anti-epidemic and raising laying hen, laying hen can be ensured
Healthy growth and development, steadily in the long term 97% or so, egg is uniform in size, soft egg is few, has improved quality for laying rate.
Determine according to test, ozonize polyoxyethylene sorbitan monooleate group egg thickness of the shell and ratio, carry than control group respectively
High 0.36mm and 0.0035, yolk CIE level time is higher by 1.14.
Ozonisation polyoxyethylene sorbitan monooleate ozone technology test show in the application practical economy,
Ecological and social benefit.Cultivation risk and cost reduce, and raiser's output value is improved, revenue growth.As a result illustrate, ozonize polyoxy
Thoroughly, chicken disease is reduced ethene sorbitan monooleate ozone technology disinfectant anti-epidemic, and survival rate is improved.Can particularly prevent
The generation of popular, catastrophic chicken disease and prevalence, reduce cultivation risk, economic loss are reduced or avoided.Application ozonisation
After polyoxyethylene sorbitan monooleate ozone technology, medication is reduced, and cost reduces.Test shows, using ozonisation polyoxy
Ethene sorbitan monooleate ozone technology raises meat, laying hen, and diseases prevention medication reduces 70%, and drug cost reduces by 66.7%.
Chicken is conducive to healthy growth and development, quality under the conditions of using ozonisation polyoxyethylene sorbitan monooleate ozone technology
Increase.Broiler chicks are tested, and when delivering for sale, ozone group single chicken weight average than control group increases.Improve food conversion ratio, save
Feed.Green meat, egg product can be produced using ozonisation polyoxyethylene sorbitan monooleate ozone technology, market is smooth
Pin, the output value are improved.Both harmful levels of pathogens in air killed, but the pernicious gas such as decomposable asymmetric choice net ammonia, hydrogen sulfide, purifying aquaculture ring
Border;Oxygen is decomposed into while sterilization again, and noresidue is polluted;Reduce the consumption of chemicals and antibiotic, it is to avoid to environment
Secondary pollution;Harmful substance, organic agricultural chemicals and detergent in decomposition water etc., can purify water.Using ozonisation polyoxy second
Alkene sorbitan monooleate ozone technology raises livestock and poultry, and the green meat of production, egg product, to building a Harmonious Society with reality
Meaning.
Embodiment 6 ozonizes prevention of the polyoxyethylene sorbitan monooleate to chicken disease
Ozonisation polyoxyethylene sorbitan monooleate can also prevent infectious rhinitis of fowl, Escherichia coli, salmonella, bar
Family name's bacillosis, horse Garrick, infective bronchitis, chicken pox, bird flu, FAV disease and coccidia etc..In Xianyang, Shanxi province city
Yang Ling chicken houses, carry out ozonizing polyoxyethylene sorbitan monooleate to infectious rhinitis of fowl, Escherichia coli, Salmonella
The immune protection effectiveness test of the vaccines such as bacterium, pasteurellosis, horse Garrick, infective bronchitis, chicken pox, bird flu, and right
FAV disease and the prevention of global-worm illness.Drunk with the ozonisation polyoxyethylene sorbitan monooleate of 1PPM concentration on an empty stomach
Water, can significantly improve the protection of vaccine, and strengthen opposing of the chicken to adenopathy viral disease and global-worm illness, can be used in above-mentioned disease
The preventing and treating of disease（It is shown in Table 8）.
Table 8 ozonizes testing result of the polyoxyethylene sorbitan monooleate to vaccine immunity Vaccine effectiveness
| Group | Test chicken (only) | Attack poison amount (108Individual bacterium) | Die of illness (only) | Protective rate (%) |
| Infectious rhinitis of fowl | 10 | 104Individual LD50 | 0 | 100 |
| Escherichia coli | 10 | 104Individual LD50 | 0 | 100 |
| Salmonella | 10 | 104Individual LD50 | 0 | 100 |
| Pasteurellosis | 10 | 104Individual LD50 | 0 | 100 |
| Horse Garrick | 10 | 104Individual LD50 | 1 | 90 |
| Infective bronchitis | 10 | 104Individual LD50 | 0 | 100 |
| Chicken pox | 10 | 104Individual LD50 | 0 | 100 |
| Bird flu | 10 | 104Individual LD50 | 0 | 100 |
| FAV disease | 10 | 104Individual LD50 | 0 | 100 |
| Coccidia | 10 | 104Individual LD50 | 1 | 90 |
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Any modification, equivalent and improvement for being made within principle etc., should be included within the scope of the present invention.
Claims (11)
1. application of a kind of ozonized surfactant in chicken cultivation, it is characterised in that by amphoteric surfactant, non-
The hydrophobic base section of ionic surface active agent, cationic surfactant and anion surfactant, Shuangzi（Gemini）Table
There is in face activating agent connection base section, biosurfactant, green surfactant the table of at least one olefinic double bond
Face activating agent addition ozone obtains ozonized surfactant, and obtained ozonized surfactant dilute with water is applied to
To hen house, keeper, chicken body, breeding facility, empty gas and water, the sterilization of excrement and deodorant, and application ozonized surfactant is empty
Abdomen is drunk water, for improving the immunity and premunition of chicken, and the health for promoting to grow and ensure chicken.
2. application of a kind of ozonized surfactant in chicken cultivation, it is characterised in that by amphoteric surfactant, non-
The hydrophobic base section of ionic surface active agent, cationic surfactant and anion surfactant, Shuangzi（Gemini）Table
There is in face activating agent connection base section, biosurfactant, green surfactant the table of at least one olefinic double bond
Face activating agent addition ozone obtains ozonized surfactant, and obtained ozonized surfactant is drunk water and dilute with water on an empty stomach
Release hen house, keeper, chicken body, breeding facility, empty gas and water, excrement are carried out disinfection with deodorant, for improving chicken to chicken new city
Epidemic disease, Bursal Disease, chicken pox, bird flu, chicken coccidiasis, FAV disease, infectious rhinitis of fowl, Escherichia coli, sand
Door Salmonella, pasteurellosis, horse Garrick, the immunity of infective bronchitis and premunition.
3. ozonized surfactant according to claims 1 to 2, it is characterised in that the hydrophobic base section has extremely
The surfactant of a few olefinic double bond is the amphoteric surface that there is at least one olefinic double bond selected from hydrophobic base section
There is the nonionic surfactant of at least one olefinic double bond, hydrophobic base section to have at least for activating agent, hydrophobic base section
The anion surfactant of one olefinic double bond and hydrophobic base section have the cation form of at least one olefinic double bond
In the activating agent of face any one, two kinds and two or more mixing.
4. ozonized surfactant according to claims 1 to 2, it is characterised in that the hydrophobic base section has extremely
The amphoteric surfactant of a few olefinic double bond, selected from the monosubstituted and polysubstituted empgen BB of unsaturated alkyl,
The monosubstituted and polysubstituted dodecyl hydroxyl of the monosubstituted and polysubstituted Cocoamidopropyl betaine of unsaturated alkyl, unsaturated alkyl
The monosubstituted and polysubstituted fattyamidopropyl betaine of propylsultaine glycine betaine, unsaturated alkyl, unsaturated alkyl monosubstituted and
Monosubstituted and polysubstituted the third hydroxyl sulfo betaine of lauramide of two phosphorous base glycine betaine of polysubstituted glycerine, unsaturated alkyl, no
Monosubstituted and polysubstituted the third hydroxyl sulfo betaine of lauramide of saturated hydrocarbyl, N, N- dihydroxy ethyl-N- ethyl unsaturated fats
Acid esters glycine betaine, N- ethyl unsaturated fatty acid ester-N, N- bis- (2- ethoxys) -3-（2- hydroxypropyls）Sulfate ammonium salt, cocounut oil
Base both sexes unsaturated fatty acid salt, N- (2- fatty acid amides) ethyl imido unsaturated fat acid disodiums and N-（2- fatty acid amides) second
In base-N, N- tri- [3,3- (2- hydroxyls) propylsultaine] ammonia disodium salt any one, two kinds and two or more mixing.
5. ozonized surfactant according to claims 1 to 2, it is characterised in that the hydrophobic base section has extremely
The nonionic surfactant of a few olefinic double bond, gathers selected from unrighted acid polyoxyethylene ester, unsaturated fatty alcohol
Oxygen vinethene, unsaturated fat phenol polyethenoxy ether, polyoxyethylene unsaturated fat acid amides, propane diols unsaturated fatty acid ester,
Pentaerythrite unsaturated fatty acid ester, glycerine unsaturated fatty acid ester, polyglycereol unsaturated fatty acid ester, sorbitan insatiable hunger
Unsaturated with fatty acid ester, polyoxyethylene sorbitol acid anhydride unsaturated fatty acid ester, mannitol unsaturated fatty acid ester, sucrose
In fatty acid ester, polyethylene glycol unsaturated alkyl ether and polypropylene glycol unsaturated alkyl ether any one, two kinds and two kinds with
Upper mixing.
6. ozonized surfactant according to claims 1 to 2, it is characterised in that the hydrophobic base section has extremely
The anion surfactant of a few olefinic double bond, selected from unsaturated fatty acid salt, unsaturated fatty alcohol sulfuric acid, α-
In sulfo group unsaturated fatty acid ester, olefin sulphates and alkene sulfonate any one, two kinds and two or more mixing.
7. ozonized surfactant according to claims 1 to 2, it is characterised in that the hydrophobic base section has extremely
The cationic surfactant of a few olefinic double bond, is selected from the monosubstituted leptodactyline of unsaturated aliphatic hydrocarbyl moiety, insatiable hunger
With two substituted dimethyl ammonium salt of aliphatic group, the monosubstituted dimethyl benzyl ammonium salt of unsaturated aliphatic hydrocarbyl moiety, unsaturated aliphatic hydrocarbyl moiety
Monosubstituted amine acylate, two replacement amine acylate of unsaturated aliphatic hydrocarbyl moiety and N- methyl diethanolamine unrighted acids
In ester hydrochloride any one, two kinds and two or more mixing.
8. ozonized surfactant according to claims 1 to 2, it is characterised in that the hydrophobic base section and connection
Base section has the Shuangzi of at least one olefinic double bond（Gemini）In surfactant any one, two kinds and two kinds with
Upper mixing.
9. ozonized surfactant according to claims 1 to 2, it is characterised in that the biosurfactant is extremely
Monosubstituted and polysubstituted sweet selected from unsaturated aliphatic hydrocarbyl moiety her subtilin monosubstituted and polysubstituted, unsaturated aliphatic hydrocarbyl moiety less
Reveal the monosubstituted and polysubstituted Pseudomonas fluorescence metabolin of sugared red moss enzyme fat, unsaturated aliphatic hydrocarbyl moiety, unsaturated aliphatic hydrocarbyl moiety
The monosubstituted and polysubstituted Lactobacillus acidophilus' metabolin of monosubstituted and polysubstituted Bacillus acidi lactici metabolin, unsaturated aliphatic hydrocarbyl moiety,
In the monosubstituted and polysubstituted yeast Bacillus acidi lactici of unsaturated aliphatic hydrocarbyl moiety any one, two kinds and two or more mixing.
10. ozonized surfactant according to claims 1 to 2, it is characterised in that the green surfactant is extremely
Unsaturated aliphatic hydrocarbyl moiety single or multiple substituted triethanolamine quaternary ammonium salt, alpha-sulfo unsaturated fatty acid methyl ester, unsaturation are selected from less
Aliphatic group phosphate, unsaturated aliphatic hydrocarbyl moiety list and polysubstituted amino acid pattern, unsaturated aliphatic hydrocarbyl moiety list and polysubstituted beet
Alkaline, unsaturated aliphatic hydrocarbyl moiety list and polysubstituted imidazoles fundamental mode, unsaturated aliphatic hydrocarbyl moiety list and polysubstituted many glycosides, unsaturated fat
Live on the green surface that alkyl list and the unsaturated aliphatic hydrocarbyl moiety such as polysubstituted glucose amide and sucrose unsaturated fat acid amide replace
In property agent any one, two kinds and two or more mixing.
11. ozonized surfactants according to claims 1 to 10, it is characterised in that be selected from crotonic acid, nutmeg
Oleic acid, palmitoleic acid, oleic acid, antiform oleic acid, castor oil acid, erucic acid, cetoleic acid, nervonic acid, linoleic acid（Unsaturated diene
Acid）, leukotrienes and eleostearic acid（Unsaturated trienic acid）, parinaric acid and arachidonic acid（Unsaturated tetraenoic acid）, 20 carbon
Five olefin(e) acid and clupanodonic acid（Unsaturated five olefin(e) acid）, DHA（Unsaturated acid）In at least have one
In the unrighted acid of individual olefinic double bond any one, two kinds and two or more mixing, by electrophilic addition ozone, obtain
To the ozonized surfactant containing ozonisation unrighted acid.
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