CN1064859C - 气液接触器和湿式烟道气脱硫系统 - Google Patents
气液接触器和湿式烟道气脱硫系统 Download PDFInfo
- Publication number
- CN1064859C CN1064859C CN951181416A CN95118141A CN1064859C CN 1064859 C CN1064859 C CN 1064859C CN 951181416 A CN951181416 A CN 951181416A CN 95118141 A CN95118141 A CN 95118141A CN 1064859 C CN1064859 C CN 1064859C
- Authority
- CN
- China
- Prior art keywords
- stirring rod
- jar
- nozzle
- gas
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 51
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000003546 flue gas Substances 0.000 title claims abstract description 18
- 238000006477 desulfuration reaction Methods 0.000 title abstract description 6
- 230000023556 desulfurization Effects 0.000 title abstract description 5
- 239000002002 slurry Substances 0.000 claims abstract description 50
- 239000007789 gas Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 69
- 239000007787 solid Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 16
- 230000008021 deposition Effects 0.000 claims description 14
- 238000010521 absorption reaction Methods 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 5
- 239000002912 waste gas Substances 0.000 claims description 4
- 229940043430 calcium compound Drugs 0.000 claims description 3
- 150000001674 calcium compounds Chemical class 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 12
- 239000010440 gypsum Substances 0.000 description 8
- 229910052602 gypsum Inorganic materials 0.000 description 8
- 230000009183 running Effects 0.000 description 7
- 230000008439 repair process Effects 0.000 description 5
- 235000019738 Limestone Nutrition 0.000 description 4
- 239000006028 limestone Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 201000002282 venous insufficiency Diseases 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/504—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/80—Semi-solid phase processes, i.e. by using slurries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
- B01F23/23313—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements through a separate conduit substantially parallel with the stirrer axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
- B01F23/23314—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements through a hollow stirrer element
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/10—Maintenance of mixers
- B01F35/145—Washing or cleaning mixers not provided for in other groups in this subclass; Inhibiting build-up of material on machine parts using other means
- B01F35/1452—Washing or cleaning mixers not provided for in other groups in this subclass; Inhibiting build-up of material on machine parts using other means using fluids
- B01F35/1453—Washing or cleaning mixers not provided for in other groups in this subclass; Inhibiting build-up of material on machine parts using other means using fluids by means of jets of fluid, e.g. air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
- B01F23/23311—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements through a hollow stirrer axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2336—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer
- B01F23/23362—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer the gas being introduced under the stirrer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP273216/94 | 1994-11-08 | ||
| JP27321694A JP3170158B2 (ja) | 1994-11-08 | 1994-11-08 | 気液接触装置及び湿式排煙脱硫装置 |
| JP273216/1994 | 1994-11-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1131580A CN1131580A (zh) | 1996-09-25 |
| CN1064859C true CN1064859C (zh) | 2001-04-25 |
Family
ID=17524728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN951181416A Expired - Fee Related CN1064859C (zh) | 1994-11-08 | 1995-10-31 | 气液接触器和湿式烟道气脱硫系统 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5641460A (OSRAM) |
| EP (1) | EP0711590B1 (OSRAM) |
| JP (1) | JP3170158B2 (OSRAM) |
| KR (1) | KR0147183B1 (OSRAM) |
| CN (1) | CN1064859C (OSRAM) |
| DK (1) | DK0711590T3 (OSRAM) |
| ES (1) | ES2158059T3 (OSRAM) |
| PL (2) | PL181041B1 (OSRAM) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5878675A (en) * | 1995-10-13 | 1999-03-09 | Mitsubishi Jukogyo Kabushiki Kaisha | Flue gas desulfurizer, boiler equipment and thermal electric power generation equipment |
| JP3068452B2 (ja) * | 1996-02-06 | 2000-07-24 | 三菱重工業株式会社 | 湿式排煙脱硫装置 |
| JP3382778B2 (ja) * | 1996-06-04 | 2003-03-04 | 三菱重工業株式会社 | 気液接触装置 |
| TW402520B (en) * | 1997-11-05 | 2000-08-21 | Mitsubishi Heavy Ind Ltd | Wet flue gas desulfurizer and oxygen-containing gas blowing device for use therein |
| DE29909312U1 (de) * | 1999-05-27 | 1999-08-12 | Ekato Rühr- und Mischtechnik GmbH, 79650 Schopfheim | Rührwerk |
| KR100489292B1 (ko) * | 2003-07-08 | 2005-05-17 | 한국전력공사 | 가스층 다공판형 배연 탈황 장치 |
| US8540219B2 (en) | 2007-03-16 | 2013-09-24 | Alstom Technology Ltd | System and method for preventing scaling in a flue gas desulphurization system |
| KR101147702B1 (ko) | 2011-12-14 | 2012-05-23 | 주식회사 오투 | 나노버블 발생장치를 이용한 탈취탑 |
| US9028762B2 (en) | 2012-07-30 | 2015-05-12 | Mitsubishi Hitachi Power Systems, Ltd. | Wet type exhaust gas desulfurization apparatus |
| JP5582213B1 (ja) * | 2013-03-28 | 2014-09-03 | 大日本印刷株式会社 | フィラーの浄化方法及び装置 |
| CN103566748B (zh) * | 2013-11-21 | 2015-06-17 | 航天环境工程有限公司 | 烧结机搅拌式湿式排烟脱硫装置 |
| CN103657275B (zh) * | 2013-12-11 | 2016-02-10 | 北京中能诺泰节能环保技术有限责任公司 | 双重烟气净化工艺及其净化系统 |
| CN107754585A (zh) * | 2017-10-13 | 2018-03-06 | 华电电力科学研究院 | 一种用于电厂的废气脱硫脱硝净化过滤装置及过滤方法 |
| US11065576B2 (en) * | 2018-01-19 | 2021-07-20 | Doosan Heavy Industries & Construction Co., Ltd. | Wet flue gas desulfurization apparatus |
| CN109364709B (zh) * | 2018-11-29 | 2021-09-21 | 山西永硕新材料科技有限公司 | 一种炼钢炉废气处理工艺 |
| CN112808143B (zh) * | 2021-01-29 | 2025-04-15 | 广州文冲船舶修造有限公司 | 一种脱硫系统用药剂防沉淀系统以及药剂沉淀监测方法 |
| CN113509808A (zh) * | 2021-07-05 | 2021-10-19 | 沈阳环境科学研究院 | 一种危险废物焚烧处置烟气重金属吸附装置 |
| CN114130182B (zh) * | 2021-11-24 | 2023-08-29 | 华能山东发电有限公司众泰电厂 | 一种用于火力发电厂的脱硫吸收塔氧化风输送装置 |
| CN115624855B (zh) * | 2022-10-26 | 2023-10-10 | 汇舸(南通)环保设备有限公司 | 一种高效脱硫塔 |
| CN120733539B (zh) * | 2025-07-22 | 2025-12-30 | 辽宁亚禾营养科技有限责任公司 | 一种生物饲料发酵罐尾气处理装置 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0369876A1 (en) * | 1988-11-14 | 1990-05-23 | Mitsubishi Jukogyo Kabushiki Kaisha | Gas-liquid contacting method |
| US5106603A (en) * | 1991-05-24 | 1992-04-21 | Freeport-Mcmoran Inc. | Method for removing sulfur dioxide from gas streams |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2584391A (en) * | 1947-03-29 | 1952-02-05 | Universal Oil Prod Co | Apparatus for effecting fluidized contact between solid particles and fluid mediums |
| JPS5511045A (en) * | 1978-07-11 | 1980-01-25 | Mitsubishi Heavy Ind Ltd | Exhaust gas processing method |
| US4431608A (en) * | 1981-04-15 | 1984-02-14 | Osaka Gas Company | Gas purification system |
| DE3227187C1 (de) * | 1982-07-21 | 1988-12-01 | Gottfried Bischoff Bau kompl. Gasreinigungs- und Wasserrückkühlanlagen GmbH & Co KG, 4300 Essen | Waschturm fuer eine Anlage zur Entschwefelung von Rauchgas |
| US4587112A (en) * | 1985-06-20 | 1986-05-06 | General Electric Company | Effluent gas desulfurization with conversion to gypsum of large particle size |
| DE3751095T2 (de) * | 1986-05-12 | 1995-10-19 | Mitsubishi Heavy Ind Ltd | Apparat zum Behandeln einer Lösung oder einer Aufschlämmung. |
| US5160707A (en) * | 1989-08-25 | 1992-11-03 | Washington Suburban Sanitary Commission | Methods of and apparatus for removing odors from process airstreams |
| JP2691041B2 (ja) * | 1990-02-14 | 1997-12-17 | 三菱重工業株式会社 | フライアッシュを含む吸収液スラリーの処理方法 |
-
1994
- 1994-11-08 JP JP27321694A patent/JP3170158B2/ja not_active Expired - Lifetime
-
1995
- 1995-09-27 US US08/534,866 patent/US5641460A/en not_active Expired - Lifetime
- 1995-10-10 ES ES95610049T patent/ES2158059T3/es not_active Expired - Lifetime
- 1995-10-10 EP EP95610049A patent/EP0711590B1/en not_active Expired - Lifetime
- 1995-10-10 DK DK95610049T patent/DK0711590T3/da active
- 1995-10-31 PL PL95311195A patent/PL181041B1/pl not_active IP Right Cessation
- 1995-10-31 CN CN951181416A patent/CN1064859C/zh not_active Expired - Fee Related
- 1995-10-31 PL PL95338946A patent/PL180969B1/pl not_active IP Right Cessation
- 1995-11-08 KR KR1019950040189A patent/KR0147183B1/ko not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0369876A1 (en) * | 1988-11-14 | 1990-05-23 | Mitsubishi Jukogyo Kabushiki Kaisha | Gas-liquid contacting method |
| US5106603A (en) * | 1991-05-24 | 1992-04-21 | Freeport-Mcmoran Inc. | Method for removing sulfur dioxide from gas streams |
Also Published As
| Publication number | Publication date |
|---|---|
| KR0147183B1 (ko) | 1998-08-17 |
| ES2158059T3 (es) | 2001-09-01 |
| KR960016948A (ko) | 1996-06-17 |
| EP0711590A3 (OSRAM) | 1996-06-05 |
| EP0711590A2 (en) | 1996-05-15 |
| CN1131580A (zh) | 1996-09-25 |
| PL180969B1 (pl) | 2001-05-31 |
| US5641460A (en) | 1997-06-24 |
| PL181041B1 (pl) | 2001-05-31 |
| JP3170158B2 (ja) | 2001-05-28 |
| PL311195A1 (en) | 1996-05-13 |
| DK0711590T3 (da) | 2001-09-24 |
| EP0711590B1 (en) | 2001-05-30 |
| JPH08131753A (ja) | 1996-05-28 |
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