CN106479744A - A kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and preparation method thereof - Google Patents

A kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and preparation method thereof Download PDF

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Publication number
CN106479744A
CN106479744A CN201610832354.1A CN201610832354A CN106479744A CN 106479744 A CN106479744 A CN 106479744A CN 201610832354 A CN201610832354 A CN 201610832354A CN 106479744 A CN106479744 A CN 106479744A
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parts
efficiency
friendlyhigh
water
environment
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田恒良
贺凯
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Jaingsu Tianliang Daily Necessities Co Ltd
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Jaingsu Tianliang Daily Necessities Co Ltd
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Priority to CN201610832354.1A priority Critical patent/CN106479744A/en
Publication of CN106479744A publication Critical patent/CN106479744A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • C11D3/2013Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/32Amides; Substituted amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3726Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to a kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and preparation method thereof, its composition is counted as follows by weight:5 10 parts of amine oxide, 12 22 parts of anti-static liquid, 18 parts of ethylenediamine tetra-acetic acid, 35 parts of sodium alkyl sulfate, 4 12 parts of guar gum, 6 15 parts of coconut oil diethanol amide, 15 parts of azodicarbonamide, 10 15 parts of Sodium Benzoate, 26 parts of oleic acid, 15 parts of sorbierite, 80 120 parts of water, easy to use, low cost, Low-foam and easily are rinsed, are saved water and energy, environmental protection, while also quick, time saving and energy saving with strong detergency, washing.

Description

A kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and preparation method thereof
Technical field
The present invention relates to household chemicals technical field, and in particular to a kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and its preparation side Method.
Background technology
Liquid detergent is people's regular supplies when padded equipment thing is washed in daily life, with apparatus and process is simple, low production cost, section Can environmental protection, product is easy to use, dissolving is rapid, alkalescence is low, the unique advantage such as gentleer to fabric and skin.Adjusted according to market Discovery is looked into, consumer feels that foam is many, difficult rinsed clean when using liquid detergent, generally, on worry clothing, have residual.This be by Add less in current traditional liquid detergent surface-active contents height, builder, cause many hardly possiblies of foam to rinse, money of not only wasting water Source, increases laundry cost, can also cause large-scale water pollution, be unfavorable for energy-saving and emission-reduction and environmental protection.
Content of the invention
The present invention proposes a kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and preparation method thereof for the problems referred to above, easy to use, become This low, Low-foam and easily is rinsed, is saved water and energy, environmental protection, while also quick, time saving and energy saving with strong detergency, washing.
Specific technical scheme is as follows:
A kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent, its composition are counted as follows by weight:
Amine oxide 5-10 part,
Anti-static liquid 12-22 part,
Ethylenediamine tetra-acetic acid 1-8 part,
Sodium alkyl sulfate 3-5 part,
Guar gum 4-12 part,
Coconut oil diethanol amide 6-15 part,
Azodicarbonamide 1-5 part,
Sodium Benzoate 10-15 part,
Oleic acid 2-6 part,
Sorbierite 1-5 part,
Water 80-120 part.
A kind of above-mentioned Environment-friendlyhigh-efficiency high-efficiency laundry detergent, wherein, the composition of the anti-static liquid is counted as follows by weight:
Polyethylene glycol 8-15 part,
Dodecanol 1-8 part,
Polyurethane 3-10 part,
Acetone 1-4 part,
Calcium carbonate 0.5-3 part,
Hydrogen peroxide 2-6 part,
Softened water 5-12 part.
A kind of preparation method of above-mentioned Environment-friendlyhigh-efficiency high-efficiency laundry detergent, its preparation method are as follows:
(1) anti-static liquid is prepared:Counted polyethylene glycol 8-15 part, dodecanol 1-8 part, polyurethane 3-10 by weight Part, acetone 1-4 part, calcium carbonate 0.5-3 part, hydrogen peroxide 2-6 part, softened water 5-12 part mix and blend 10-20min at normal temperatures;
(2) count amine oxide 5-10 part, anti-static liquid 12-22 part, ethylenediamine tetra-acetic acid 1-8 part, fat by weight Alcohol sodium sulphate 3-5 part, guar gum 4-12 part, coconut oil diethanol amide 6-15 part, azodicarbonamide 1-5 part, Sodium Benzoate 10-15 part, oleic acid 2-6 part, sorbierite 1-5 part, water 80-120 part stir 30-60min at a temperature of 30-50 DEG C.
Beneficial effects of the present invention are:
The Liquid laundry composition of the present invention, easy to use, low cost, Low-foam and easily are rinsed, are saved water and energy, environmental protection, with When also have strong detergency, wash quick, time saving and energy saving.
Specific embodiment
For making technical scheme become apparent from clearly, below the present invention is described further, any to this The technical characteristic of inventive technique scheme carries out the scheme that equivalencing and conventional reasoning draw and each falls within the scope of the present invention.
Embodiment one
A kind of preparation method of Environment-friendlyhigh-efficiency high-efficiency laundry detergent, its preparation method are as follows:
(1) anti-static liquid is prepared:Counted 12 parts of polyethylene glycol, 4 parts of dodecanol, 6 parts of polyurethane, acetone by weight 2 parts, 2 parts of calcium carbonate, 3.5 parts of hydrogen peroxide, 8 parts of softened water mix and blend 15min at normal temperatures;
(2) count 7 parts of amine oxide, 18 parts of anti-static liquid, 4 parts of ethylenediamine tetra-acetic acid, sodium alkyl sulfate 4 by weight Part, 8 parts of guar gum, 10 parts of coconut oil diethanol amide, 3 parts of azodicarbonamide, 12 parts of Sodium Benzoate, 4 parts of oleic acid, sorbierite 3 parts, 100 parts of water stir 50min at a temperature of 30-50 DEG C.
Embodiment two
A kind of preparation method of Environment-friendlyhigh-efficiency high-efficiency laundry detergent, its preparation method are as follows:
(1) anti-static liquid is prepared:Counted 10 parts of polyethylene glycol, 6 parts of dodecanol, 8 parts of polyurethane, acetone by weight 3.2 parts, 2.1 parts of calcium carbonate, 4.6 parts of hydrogen peroxide, 10 parts of softened water mix and blend 15min at normal temperatures;
(2) count 8 parts of amine oxide, 14 parts of anti-static liquid, 3 parts of ethylenediamine tetra-acetic acid, sodium alkyl sulfate by weight 3.2 parts, 5 parts of guar gum, 12 parts of coconut oil diethanol amide, 2 parts of azodicarbonamide, 13.5 parts of Sodium Benzoate, 3 parts of oleic acid, 2 parts of sorbierite, 90 parts of water stir 40min at a temperature of 35 DEG C.
Embodiment three
A kind of preparation method of Environment-friendlyhigh-efficiency high-efficiency laundry detergent, its preparation method are as follows:
(1) anti-static liquid is prepared:Counted 8 parts of polyethylene glycol, 1 part of dodecanol, 3 parts of polyurethane, acetone 1 by weight Part, 0.5 part of calcium carbonate, 2 parts of hydrogen peroxide, 5 parts of softened water mix and blend 10min at normal temperatures;
(2) count 5 parts of amine oxide, 12 parts of anti-static liquid, 1 part of ethylenediamine tetra-acetic acid, sodium alkyl sulfate 3 by weight Part, 4 parts of guar gum, 6 parts of coconut oil diethanol amide, 1 part of azodicarbonamide, 10 parts of Sodium Benzoate, 2 parts of oleic acid, sorbierite 1 Part, 80 parts of water stir 30min at a temperature of 30 DEG C.
Example IV
A kind of preparation method of strong Environment-friendlyhigh-efficiency high-efficiency laundry detergent, its preparation method are as follows:
(1) anti-static liquid is prepared:Count by weight by 15 parts of polyethylene glycol, 8 parts of dodecanol, 10 parts of polyurethane, third 4 parts of ketone, 3 parts of calcium carbonate, 6 parts of hydrogen peroxide, 12 parts of softened water mix and blend 20min at normal temperatures;
(2) count 10 parts of amine oxide, 22 parts of anti-static liquid, 8 parts of ethylenediamine tetra-acetic acid, sodium alkyl sulfate by weight 5 parts, 12 parts of guar gum, 15 parts of coconut oil diethanol amide, 5 parts of azodicarbonamide, 15 parts of Sodium Benzoate, 6 parts of oleic acid, sorb 5 parts of alcohol, 120 parts of water stir 60min at a temperature of 50 DEG C.
The present invention is had the advantage that for compared with similar products:
(1) to have Low-foam and easily rinsability for the Liquid laundry composition of the present invention.Machine washing test show, the liquid detergent of the present invention Only need rinsing following twice just can rinse completely, and commercially available prod at least needs to rinse three times, and some need to float four times even Five times could rinses, show using this patent liquid detergent time saving and energy saving, water saving save money, water saving reach more than 50%.
(2) Liquid laundry composition of the present invention has the natural green feature of environmental protection.Not only can fast degraded biologically, with environment Friendly;And gentle safety, not stimulating skin, not damaging laundry, natural safety is more healthy.
(3) Liquid laundry composition of the present invention and meanwhile have hard water resistance good, decontamination speed is fast, clean effect is good, and save time province The advantage of power.
(4) the Liquid laundry composition low cost of the present invention, cost performance are high.
(5) Liquid laundry composition of the present invention has good economic benefit and social benefit.Especially water-deficient area, As the continuous exhaustion of water resource, the price of domestic water will rise steadily, the cleaning product for therefore developing water saving seems non- Often important, and the Future Consumption demand of " green, low-carbon (LC), environmental protection ".

Claims (3)

1. a kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent, it is characterized by, its composition is counted as follows by weight:
Amine oxide 5-10 part,
Anti-static liquid 12-22 part,
Ethylenediamine tetra-acetic acid 1-8 part,
Sodium alkyl sulfate 3-5 part,
Guar gum 4-12 part,
Coconut oil diethanol amide 6-15 part,
Azodicarbonamide 1-5 part,
Sodium Benzoate 10-15 part,
Oleic acid 2-6 part,
Sorbierite 1-5 part,
Water 80-120 part.
2. a kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent as claimed in claim 1, it is characterized by, the composition of the anti-static liquid is pressed Parts by weight meter is as follows:
Polyethylene glycol 8-15 part,
Dodecanol 1-8 part,
Polyurethane 3-10 part,
Acetone 1-4 part,
Calcium carbonate 0.5-3 part,
Hydrogen peroxide 2-6 part,
Softened water 5-12 part.
3. a kind of preparation method of Environment-friendlyhigh-efficiency high-efficiency laundry detergent, it is characterized by, its preparation method is as follows:
(1) anti-static liquid is prepared:Counted polyethylene glycol, dodecanol, polyurethane, acetone, calcium carbonate, dioxygen by weight Water, softened water mix and blend 10-20min at normal temperatures;
(2) count amine oxide, anti-static liquid, ethylenediamine tetra-acetic acid, sodium alkyl sulfate, guar gum, coconut oil by weight Diglycollic amide, azodicarbonamide, Sodium Benzoate, oleic acid, sorbierite, water stir 30-60min at a temperature of 30-50 DEG C ?.
CN201610832354.1A 2016-09-19 2016-09-19 A kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and preparation method thereof Pending CN106479744A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610832354.1A CN106479744A (en) 2016-09-19 2016-09-19 A kind of Environment-friendlyhigh-efficiency high-efficiency laundry detergent and preparation method thereof

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1070422A (en) * 1991-09-11 1993-03-31 蔡葵 High-efficiency multipurpose liquid detergent
CN101372648A (en) * 2008-09-24 2009-02-25 北京洛娃日化有限公司 Low foam laundry liquid
CN101760354A (en) * 2009-12-31 2010-06-30 周福铎 Anti-static liquid laundry detergent
CN103710167A (en) * 2013-12-27 2014-04-09 威莱(广州)日用品有限公司 Liquid laundry detergent for infants and preparation method thereof
CN103992886A (en) * 2014-06-17 2014-08-20 陈建宝 Clothes washing agent
CN104818135A (en) * 2015-04-30 2015-08-05 青岛德翕拓创高新技术有限公司 Long-acting anti-static detergent
CN105296179A (en) * 2015-11-19 2016-02-03 吴庆春 Soap-based environment-friendly laundry detergent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1070422A (en) * 1991-09-11 1993-03-31 蔡葵 High-efficiency multipurpose liquid detergent
CN101372648A (en) * 2008-09-24 2009-02-25 北京洛娃日化有限公司 Low foam laundry liquid
CN101760354A (en) * 2009-12-31 2010-06-30 周福铎 Anti-static liquid laundry detergent
CN103710167A (en) * 2013-12-27 2014-04-09 威莱(广州)日用品有限公司 Liquid laundry detergent for infants and preparation method thereof
CN103992886A (en) * 2014-06-17 2014-08-20 陈建宝 Clothes washing agent
CN104818135A (en) * 2015-04-30 2015-08-05 青岛德翕拓创高新技术有限公司 Long-acting anti-static detergent
CN105296179A (en) * 2015-11-19 2016-02-03 吴庆春 Soap-based environment-friendly laundry detergent

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
徐宝财编著: "《日用化学品—性能、制备、配方》", 31 October 2007 *
梅自强主编: "《纺织辞典》", 31 January 2007 *
裘炳毅等: "《现代化妆品科学与技术(下册)》", 31 March 2016 *

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