CN106479690A - A kind of alkalescence foam cleaner and preparation method thereof - Google Patents

A kind of alkalescence foam cleaner and preparation method thereof Download PDF

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CN106479690A
CN106479690A CN201510550870.0A CN201510550870A CN106479690A CN 106479690 A CN106479690 A CN 106479690A CN 201510550870 A CN201510550870 A CN 201510550870A CN 106479690 A CN106479690 A CN 106479690A
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sodium
foam
alkalescence
combinations
foam cleaner
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CN106479690B (en
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张朋丽
李旭东
刘爱玲
孟小宾
吕晓静
付春香
张晓鹏
徐晓然
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Tianjin Ringpu Bio Technology Co Ltd
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Tianjin Ringpu Bio Technology Co Ltd
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Abstract

The invention discloses a kind of alkalescence foam cleaner and preparation method thereof, each constituent mass percent by volume of the alkalescence foam cleaner is:Degreasing agent 10%-20%;Foam stabilizer 3%-13%;Bactericide 1%-5%;Builder 3%-9%;Cosolvent 10%-20%;PH adjusting agent 1%-3%;Balance of deionized water.Foam cleaner pH value range of the present invention is 8.5-13.5, is suitable for removing organic dirt;Degreasing agent, foam stabilizer can penetrate into the internal dissolved fat of biomembrane, protein etc.;Bactericide is killed the bacterium that hides inside biomembrane, so as to weaken the adhesion between biomembrane and object, quickly peels off and remove the stain in fixed-site.Cleaning agent of the present invention is used for cleaning livestock and poultry farm and equipment, while with bactericidal action, making follow-up sterilizing operation effect more notable.Cleaning agent of the present invention presses 1:50~1:After 200 dilutions, sprayed using special foam gun.

Description

A kind of alkalescence foam cleaner and preparation method thereof
Technical field
The present invention relates to a kind of chemical cleaner, more particularly to a kind of alkalescence foam cleaner and preparation method thereof.
Background technology
With modernization, the popularization of intensive culture technology, the requirement to administrative skill level, feeding environment condition is also increasingly improved.Want to make livestock and poultry play maximum production performance, it is necessary to follow the Biosecurity system principle of thought centered on strict isolation, cleaning, sterilization and epidemic prevention in the whole production cycle all the time.By taking broiler breeding as an example, large-scale at present, scale livestock farming all starts to start with and carry out self-management, or even employ the mechanism that keeps a public place clean from cleaning, sterilization consciously, carries out periodic maintenance by special cleaning, sterilizing equipment decontaminating apparatus.But deliver the ratio that the middle-size and small-size raiser less than 50,000 still accounts for the whole nation nearly 95% year for sale, they are as aquaculture cost is limited, confession selects product irregular, even if having by environment maintenance, reduce the pathogenetic consciousness of biological epidemic disease, it is also difficult to inexpensive, environmental protection is filtered out from domestic market, effective special cleaning class product.Reason focuses primarily upon at following 2 points:First in livestock and poultry farm and the fluid product itself of equipment cleaning few, focusing primarily upon the rare imported product of some high prices at present such as, Dupont in prior artPlus, Denmark Vitfoss Danclean etc.;Second domestic market is irregular, and, still in the budding stage, large quantities of product applicabilities are not strong for like product, be from derived from other industry;Separately there is fraction product based on sterilizing, supplemented by cleaning, can not only accomplish basic cleaning, also so that the effect of sterilization is had a greatly reduced quality.
" a kind of fat melting, sterilization one agent and preparation method, using method (CN 104164312A;Publication date:On November 26th, 2014) " key component be glutaraldehyde 5%-15%;Sulfonic acid 10%-20%;AES 10%-20%;Cocoanut fatty acid diethanolamide 2%-5%;Lauryl sodium sulfate 5%-10%;Glycerine 15%-25%;Tween-80 6%-12%, balance of water, orientate a kind of chemosterilant as, the main bactericidal action by glutaraldehyde and the fat melting of surfactant are acted on, and play the effect of sterilization of keeping a public place clean.Defect is:One is that the presence of disinfectant glutaraldehyde determines that invention pH is up to 8.5-9.5, and the invention dilutes 100 times and uses, the environment of weakly acidic pH, is unfavorable for that surfactant gives full play to cleaning action;Two be dirt in livestock and poultry farm typically based on the organic matters such as excrement, food-residue, sewage, disinfecting drug is consumed by substantial amounts of organic matter, can seriously be reduced the activity to pathogenic microorganism, and then can not possibly be reached the Expected Results of sterilization.
Content of the invention
Present invention aim at the technology vacancy in domestic plant's environment cleaner special market is solved the problems, such as, a kind of decontamination is provided efficiently, green harmless, alkaline foam cleaner cheap and easy to get and preparation method thereof.
The present invention is adopted the following technical scheme that for achieving the above object:
A kind of alkalescence foam cleaner, its raw material include following component:
The degreasing agent, foam stabilizer be in terms of active ingredient actual content.
One or more combinations in Sulfonates of the degreasing agent in surfactant, alcohol ethers, alkyl phenol ethers.Wherein Sulfonates is selected from, but not limited to, one or more compositions in neopelex, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, fatty acid methyl ester ethoxylate sodium sulfonate;Alcohol ethers are selected from, but not limited to, model O-7, O-8, one or more compositions in O-9, O-10, O-15, O-20, O-30;Alkyl phenol ethers is selected from, but not limited to, model OP-10, NP-8, one or more compositions in NP-9, NP-10, NP-12, NP-15, NP-20.
One or more combinations of the foam stabilizer in metal carboxylate, APG class and oxidation amine.Wherein metal carboxylate is selected from, but not limited to, one or more compositions in triethanolamine oleate, AEO carboxylic acid sodium, oleoyl amino carboxylic acid sodium;APG class is selected from, but not limited to, one or more compositions in the APG of model APG0814, APG10, APG08, APG06, APG0810, APG1214;Oxidation amine is selected from, but not limited to, one or more compositions in cocamidopropyl propyl amide amine oxide, DDAO, dodecanamide propyl amine oxide, two polyoxyethylene groups ether amine oxide of myristyl, dimethyl orthoresol amine oxide, dimethyl benzene sulfonamide acidic group propyl group amine oxide.
The bactericide is selected from, but not limited to, one or more compositions in triclocarban, PCMX, iodo propinyl ammonia butyl formate;Builder is selected from, but not limited to, one or more compositions in sodium carbonate, sodium metasilicate, laminated crystal of sodium disilicate, sodium metasilicate, sodium sulphate, disodium ethylene diamine tetraacetate, Sodium Polyacrylate;Cosolvent is selected from, but not limited to, one or more compositions in ethanol, glycerine, propane diols, polyethylene glycol.
The pH adjusting agent is selected from, but not limited to, one or more compositions in NaOH, sodium carbonate, sodium citrate, potassium hydroxide, potassium carbonate.
Used as the further prioritization scheme of the present invention, the alkalescence foam cleaner, by mass percentage, its raw material includes following component:
Used as the further prioritization scheme of the present invention, the pH value of alkalescence foam cleaner is between 11.5-12.5 as mentioned above, is adjusted with the sodium hydroxide solution of 10mol/L.
The cleaning, the alkaline foam cleaner preparation method of sterilization one, comprise the following steps:
(1), the deionized water for accounting for output 25% is added in Agitation Tank;
(2), the sodium carbonate for accounting for output 2%, the sodium metasilicate for accounting for output 6% are slowly added in Agitation Tank, and 50-60 DEG C is heated to, stir to being completely dissolved, constitute A liquid of the present invention;
(3), by the AEO carboxylic acid for accounting for output 7%, the fatty acid methyl ester ethoxylate sodium sulfonate for accounting for output 15% and the Macrogol 600 that output 15% is dissolved with triclocarban (1.5%) is accounted for, in Agitation Tank, it is stirred at room temperature and mixes, constitutes B liquid of the present invention;
(4), B liquid is poured in Agitation Tank and merges with A liquid, plus deionized water is to output, and be stirred well to uniform;
(5), room temperature is cooled to, and the sodium hydroxide solution for adding 10mol/L adjusts pH value in right amount for, between 11.5-12.5, obtaining final product alkaline foam cleaner.
The using method of cleaning agent of the present invention is:
Surface smut is rinsed out with clear water first, continue water spray 5 minutes afterwards, water penetration is made to surface of wall 3mm;Then, by 1:50~1:200 prepare solution, and this alkaline foam cleaner is sprayed after body surface, per square metre of 200~300ml, 15-20 minute, clean with high pressure clean water, complete cleaning.Spray effect is carried out more preferably using special foam gun, for intractable spot, after being flushed, you can be 1 in the ratio of cleaning agent and water:10 join liquid, are wiped with towel adhesional wetting, thoroughly can clean.
Present invention cleaning mechanism is as follows:
1st, due to the presence of degreasing agent, product of the present invention is enabled to penetrate into the internal dissolved fat of biomembrane, the presence of bactericide is killed the part bacterium that hides inside biomembrane, so that the adhesion between biomembrane and object dies down, removing (referring to Figure of description 1) is quickly stripped.
2nd, the thalline packing in exposed liposome, by the effect of the bactericide in product of the present invention with bactericidal action so as to which quick death, such as table 1 below are the BA data of product embodiments of the present invention.
The specifically used concentration of the product of the present invention of table 1 and sterilizing time as shown in the table:
Present embodiments can apply to following place:Poultry, pouity dwelling place interior walls, mist line surface, waterline surface, net bed, ground.Cultivation equipment, the cleaning-sterilizing of utensil.Incubator, animal delivery room, milking parlour, food factory, slaughterhouse etc..
2 cleaning agent consumption of table and cleaning time
The optimal case of product of the present invention is sprayed using special foam gun, is cleaned sterilization to spot, germ, such as can also be prepared 1 nothing Special Equipment:100~1:400 this product solution (depending on pollution level), are uniformly sprayed on surface to be cleaned, every square metre of 500ml using common sprayer.After effect 15~20 minutes, rinsed well with high pressure clear water.
The present invention has decontamination grease removal ability; product enters dissolving, saponified fat inside biomembrane; remove nutrient source and the protective of pathogenic microorganism; the presence of bactericide is killed the bacterium that hides inside biomembrane; so that the adhesion between biomembrane and object dies down; it is stripped removing, final purification animal house, the milk Room, obstetric table, the hatching Room and various cultivation equipments.This product is sprayed in wall or body surface by special implement so as to foam, and long-time is covered, and deep layer is penetrated into inside grease, albumen dirt, thoroughly eliminates stupid stain, and the long-term place for killing scale raising further occupies cause of disease, reaches the purpose of cleaning.
The purport of the present invention is that as healthy and safe cultivation and provides optimal decontamination, cleaning supplies, and rationally effective measures.
The invention has the beneficial effects as follows:
(1) due to containing degreasing agent in product of the present invention, therefore, product of the present invention can dissolve, saponification and chyle fat;Peelable surface to be cleaned or even the organic-biological film in corner;Quickly disappear fat melting plastid, removes thalline nutrient source and protective.
(2) foam adhesion is strong, so that product of the present invention can be covered for a long time in article surface in vertical wall, smooth tube adhesive surface firmly, for a long time.
(3) with stable anti-interference, hard water resistance, low temperature is effective.
(4) by removing the energy supply source (liposome) of pathogenic microorganism and killing the double action of pathogenic microorganism, deep purifying environment place occupies cause of disease.
(5) without phosphorus formula, environmental protection;Without heavy metal, safe, can people and animals share;
(6) non-corrosiveness, extends the service life of hardware.
Description of the drawings
Fig. 1, different cleaning agent emulsifying effectiveness figure (be running water from left to right successively, the emulsifying effectiveness figure of inventive embodiments one described in patent CN 104164312A and the embodiment of the present invention one under working concentration to lanolin;
The foam wall built-up design sketch of Fig. 2, the embodiment of the present invention one on pipeline and drinking trough.
The cleaning performance figure of Fig. 3, a pair of pipeline of the embodiment of the present invention and drinking trough.
Specific embodiment
For making the object, technical solutions and advantages of the present invention clearer, below clear, complete description is carried out to the technical scheme in the present invention, it is clear that described embodiment is a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, belong to the scope of protection of the invention.Following embodiment all adjusts pH value of the reset and subtract foam cleaner of the present invention in preparation process with NaOH.
Embodiment one:
A kind of alkalescence foam cleaner, based on quality is thrown in, often prepares 5000ml, and its raw material composition is as follows:
Preparation method:
(1), the deionized water of 1250g is added in Agitation Tank;
(2), 100g sodium carbonate, 300g sodium metasilicate are slowly added in Agitation Tank, and 50-60 DEG C is heated to, stir to being completely dissolved, be A liquid;
(3), 1071g fatty acid methyl ester ethoxylate sodium sulfonate (70%), 398g AEO carboxylic acid (88%) and 750g are dissolved with the Macrogol 600 of triclocarban (75g), in Agitation Tank, it is stirred at room temperature and mixes as B liquid;
(4), B liquid is poured into and merges in A liquid Agitation Tank therewith, plus deionized water is to output, and be stirred well to uniform;
(5), room temperature is cooled to, and the sodium hydroxide solution for adding 10mol/L adjusts pH value in right amount for, between 11.5-12.5, obtaining alkaline foam cleaner.
Embodiment two:
A kind of alkalescence foam cleaner, based on quality is thrown in, often prepares 5000ml, and its raw material composition is as follows:
Preparation method:
(1), the deionized water of 1500g is added in Agitation Tank;
(2), 150g potassium hydroxide, 450g disodium ethylene diamine tetraacetate are slowly added in Agitation Tank, and 50-60 DEG C is heated to, stir to being completely dissolved, be A liquid;
(3), 500g OP-10,100g triethanolamine oleate, 167g DDAO and 1000g are dissolved with the glycerine of PCMX (250g), in Agitation Tank, are stirred at room temperature and mix, be B liquid;
(4), B liquid is poured into and merges in A liquid Agitation Tank therewith, plus deionized water is to 5000ml, and be stirred well to uniform;
(5), room temperature is cooled to, and the sodium hydroxide solution for adding 10M adjusts pH value in right amount for, between 12.5-13.5, obtaining final product.
Embodiment three:
A kind of alkalescence foam cleaner, based on quality is thrown in, often prepares 5000ml, and its raw material composition is as follows:
Preparation method:
(1), the deionized water of 1000g is added in Agitation Tank;
(2), 50g sodium citrate, 150g Sodium Polyacrylate are slowly added in Agitation Tank, and 50-60 DEG C is heated to, stir to being completely dissolved, constitute A liquid of the present invention;
(3) the dodecanamide propyl amine oxide of the APG 0814 (50%), 834g of O-9,800g of 1000g and 500g are dissolved with the PEG400 of triclocarban (50g), in Agitation Tank, it is stirred at room temperature and mixes, constitutes B liquid of the present invention;
(4), B liquid is poured into and merges in A liquid Agitation Tank therewith, plus deionized water is to 5000ml, and be stirred well to uniform;
(5), room temperature is cooled to, and the sodium hydroxide solution for adding 10mol/L adjusts pH value in right amount for, between 8.5-9.5, obtaining final product.
Example IV:
A kind of alkalescence foam cleaner, based on quality is thrown in, often prepares 5000ml, and its raw material composition is as follows:
Preparation method:
(1), the deionized water of 1000g is added in Agitation Tank;
(2), 50g NaOH, 150g sodium sulphate are slowly added in Agitation Tank, and 50-60 DEG C is heated to, stir to being completely dissolved, be A liquid;
(3), 924g α-sodium olefin sulfonate (92%), 500g oleoyl amino carboxylic acid sodium (40%), two polyoxyethylene groups ether amine oxide (30%) of myristyl of 500g and 500g are dissolved with the propane diols of iodo propinyl ammonia butyl formate (50g), in Agitation Tank, it is stirred at room temperature and mixes, is B liquid;
(4), B liquid is poured into and merges in A liquid Agitation Tank therewith, plus deionized water is to 5000ml, and be stirred well to uniform;
(5) room temperature, is cooled to, and is added 10mol/L sodium hydroxide solution and pH value is adjusted in right amount for, between 9.5-10.5, obtaining final product.
Embodiment five:
A kind of cleaning, the alkaline foam cleaner of sterilization one, based on quality is thrown in, often prepare 5000ml, and its raw material composition is as follows:
Preparation method:
(1), the deionized water of 1250g is added in Agitation Tank;
(2), 150g potassium carbonate, 450g laminated crystal of sodium disilicate are slowly added in Agitation Tank, and 50-60 DEG C is heated to, stir to being completely dissolved, constitute A liquid of the present invention;
(3), 600g DBSA, 600g APG 0810 (50%), 667g dodecanamide propyl amine oxide (30%) and 1000g are dissolved with the ethanol of PCMX (50g), in Agitation Tank, it is stirred at room temperature and mixes, constitutes B liquid of the present invention;
(4), B liquid is poured into and merges in A liquid Agitation Tank therewith, plus deionized water is to 5000ml, and stir;
(5) room temperature, is cooled to, and is added 10mol/L sodium hydroxide solution and pH value is adjusted in right amount for, between 10.5-11.5, obtaining final product.
Finally it should be noted that:Above example only in order to technical scheme to be described, rather than a limitation;Although being described in detail to the present invention with reference to the foregoing embodiments, it will be understood by those within the art that:Which still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent to which part technical characteristic;And these modifications or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (8)

1. a kind of alkalescence foam cleaner, it is characterised in that component contained by described alkaline foam cleaner and quality shared by each component Percent by volume is as follows:
The degreasing agent, foam stabilizer be in terms of active ingredient actual content.
2. according to claim 1 a kind of alkalescence foam cleaner, it is characterised in that the degreasing agent be selected from Sulfonates, alcohol One or more combinations in ethers, alkyl phenol ethers;The Sulfonates is DBSA, α-thiazolinyl sulphur One or more combinations in sour sodium, methyl sodiosul foaliphatate, fatty acid methyl ester ethoxylate sodium sulfonate, described Alcohol ethers are one or more combinations in O-7, O-8, O-9, O-10, O-15, O-20, O-30;The alkyl Phenolic ether class is one or more combinations in OP-10, NP-8, NP-9, NP-10, NP-12, NP-15, NP-20.
3. according to claim 1 a kind of alkalescence foam cleaner, it is characterised in that foam stabilizer selected from metal carboxylate, alkyl sugar One or more combinations in glycoside, oxidation amine;The metal carboxylate is triethanolamine oleate, fatty alcohol polyoxy second In alkene ether carboxylic acid sodium, oleoyl amino carboxylic acid sodium one or more combination, APG class be APG0814, APG10, One or more combinations in APG08, APG06, APG0810, APG1214, the oxidation amine is coconut oleoyl amine third Base amine oxide, DDAO, dodecanamide propyl amine oxide, two polyoxyethylene groups ether oxygen of myristyl Change one or more combinations in amine, dimethyl orthoresol amine oxide, dimethyl benzene sulfonamide acidic group propyl group amine oxide.
4. a kind of alkalescence foam cleaner according to claim 1, it is characterised in that the bactericide is selected from triclocarban, right One or more combinations between chlorine in xylenol, iodo propinyl ammonia butyl formate.
5. according to claim 1 a kind of alkalescence foam cleaner, it is characterised in that described builder be selected from sodium carbonate, silicon One kind in sour sodium, laminated crystal of sodium disilicate, sodium metasilicate, sodium sulphate, disodium ethylene diamine tetraacetate, Sodium Polyacrylate Or more than one combinations.
6. according to claim 1 a kind of alkalescence foam cleaner, it is characterised in that described cosolvent selected from ethanol, glycerine, One or more combinations in propane diols, PEG400, Macrogol 600.
7. according to claim 1 a kind of alkalescence foam cleaner, it is characterised in that described pH adjusting agent be selected from hydroxide One or more combinations in sodium, sodium carbonate, sodium citrate, potassium hydroxide, potassium carbonate, alkaline foam cleaner PH value is 8.5-13.5, adjusts pH value with the sodium hydroxide solution of 10mol/L after the completion of preparation.
8. a kind of alkalescence foam cleaner preparation method, it is characterised in that comprise the following steps:
(1), the deionized water for accounting for output 20-30% is added in Agitation Tank;
(2), the pH adjusting agent for accounting for output 1%-3%, the builder for accounting for output 3%-9% are slowly added in Agitation Tank, And 50-60 DEG C is heated to, stir to being completely dissolved, be A liquid;
(3) degreasing agent of output 10%-20%, the foam stabilizer of 3%-13%, will be accounted for and accounts for being dissolved with for output 10%-20% and kill The cosolvent of microbial inoculum, in Agitation Tank, is stirred at room temperature and mixes, and is B liquid;
(4), B liquid is poured into and merges in A liquid Agitation Tank therewith, plus deionized water is to output, and be stirred well to uniform;
(5), room temperature is cooled to, and the sodium hydroxide solution for adding 10mol/L adjusts pH value in right amount between 8.5-13.5, Obtain alkaline foam cleaner.
CN201510550870.0A 2015-09-01 2015-09-01 A kind of alkalinity foam cleaner and preparation method thereof Active CN106479690B (en)

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CN107338121A (en) * 2017-08-04 2017-11-10 北京长江脉医药科技有限责任公司 Dairy processing instruments alkaline cleaning composition and preparation method thereof
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CN112961739A (en) * 2021-02-23 2021-06-15 湖南广安动物保健品有限公司 Efficient foam cleaning disinfectant special for farm
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CN115305159A (en) * 2022-05-24 2022-11-08 西安优露清科技股份有限公司 Hard surface cleaning composition and preparation method thereof
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CN105925395B (en) * 2016-05-19 2018-08-17 山东信得科技股份有限公司 A kind of foam cleaning agent for animals and preparation method thereof
CN105925395A (en) * 2016-05-19 2016-09-07 山东信得科技股份有限公司 Veterinary foam cleaning agent and preparation method thereof
CN107338121A (en) * 2017-08-04 2017-11-10 北京长江脉医药科技有限责任公司 Dairy processing instruments alkaline cleaning composition and preparation method thereof
CN107338121B (en) * 2017-08-04 2020-06-26 北京长江脉医药科技有限责任公司 Alkaline cleaning composition for dairy processing equipment and preparation method thereof
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CN109266451A (en) * 2018-11-12 2019-01-25 河南华美万邦清洗技术有限公司 A kind of farm's foam cleaning agent
CN111925873A (en) * 2020-08-18 2020-11-13 四川恒通动保生物科技有限公司 Alkaline foam cleaning agent for farm and preparation method thereof
CN112961739A (en) * 2021-02-23 2021-06-15 湖南广安动物保健品有限公司 Efficient foam cleaning disinfectant special for farm
CN113943613A (en) * 2021-11-08 2022-01-18 河南华美万邦生物科技集团有限公司 Foam cleaning agent for farm
CN115305159A (en) * 2022-05-24 2022-11-08 西安优露清科技股份有限公司 Hard surface cleaning composition and preparation method thereof
CN115305159B (en) * 2022-05-24 2024-05-07 西安优露清科技股份有限公司 Hard surface washing composition and preparation method thereof
CN115368973A (en) * 2022-08-11 2022-11-22 亿能(天津)健康产业发展有限公司 Foam type invisible car cover installation liquid

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