CN106479149A - A kind of Composite Coatings aluminium film - Google Patents

A kind of Composite Coatings aluminium film Download PDF

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Publication number
CN106479149A
CN106479149A CN201610895379.6A CN201610895379A CN106479149A CN 106479149 A CN106479149 A CN 106479149A CN 201610895379 A CN201610895379 A CN 201610895379A CN 106479149 A CN106479149 A CN 106479149A
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CN
China
Prior art keywords
parts
poly
acid
diester
ester
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Pending
Application number
CN201610895379.6A
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Chinese (zh)
Inventor
李建萍
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WUXI SANDI SPECIAL MACROMOLECULE MATERIALS Co Ltd
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WUXI SANDI SPECIAL MACROMOLECULE MATERIALS Co Ltd
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Priority to CN201610895379.6A priority Critical patent/CN106479149A/en
Publication of CN106479149A publication Critical patent/CN106479149A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2369/00Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of Composite Coatings aluminium film, including:Film base layer and aluminium coated, described film base layer are made up of following components:Isopropyl myristate, β (3,4 dihydroxy phenyls) α hydracrylic acid isopropyl ester, dihexyl sebacate, poly- carbonic acid 1,2 propylene diesters, poly- butanedioic acid fourth diester and citric acid three (2 propyl group heptan) ester, the weight content of its each component is:34 ~ 48 parts of isopropyl myristate, β (3,4 dihydroxy phenyls) 16 ~ 33 parts of α hydracrylic acid isopropyl ester, 10 ~ 22 parts of dihexyl sebacate, 15 ~ 29 parts of 1,2 propylene diester of poly- carbonic acid, 9 ~ 21 parts of poly- butanedioic acid fourth diester and citric acid three (2 propyl group heptan) 38 ~ 50 parts of ester.By the way, the back side of inventive film base layer is difficult scratch, and tensile resistance is excellent.

Description

A kind of Composite Coatings aluminium film
Technical field
The present invention relates to aluminizer field, more particularly to a kind of Composite Coatings aluminium film.
Background technology
Aluminizer is that the one kind formed in the very thin metallic aluminium of Plastic film surface plating last layer using special process is multiple Flexible packing material is closed, the processing method of most common of which, when number vacuum evaporated aluminium method, is exactly to pass through high temperature under high vacuum state By metallic aluminium fusing evaporation, the steam precipitation of aluminium is made to be stacked in Plastic film surface, so that Plastic film surface has gold Category gloss.As it had both had the characteristic of plastic sheeting, and the characteristic with metal, it is a kind of inexpensive attractive in appearance, function admirable, reality With the strong packaging material of property, therefore, aluminizer has been widely used in the packaging of the products such as food, medicine, chemical industry, such as The packaging of fast food, tealeaves, coffee and cosmetics.
The application of aluminizer is more and more extensive, has had become as the very universal a kind of packing timber of application in Flexible-Packaging Industry Material.The species of aluminizer is a lot, applies most aluminizers to be mainly polyester aluminizer at present(VMPET)With CPP aluminizer (VMCPP), polyester aluminizer(VMPET)The intermediate layer of composite packaging is typically used as, as its outward appearance is beautiful, in high-grade packaging Application is most, the such as packaging bag such as milk powder, tealeaves.CPP aluminizer(VMCPP)The hot sealing layer of composite packaging is typically used as, is usually used in Common pot foods(Such as biscuit)Packaging.
However, the back side of the film base layer of the aluminizer for using at present easily abrades, and tensile resistance is poor.
Content of the invention
The present invention solves the technical problem of providing a kind of Composite Coatings aluminium film, the back side of film base layer is difficult scratch, And tensile resistance is excellent.
For solving above-mentioned technical problem, one aspect of the present invention is:A kind of Composite Coatings aluminium film is provided, including:Film Base layer and aluminium coated, described film base layer are made up of following components:Isopropyl myristate, β-(3,4- dihydroxy phenyl)- α-hydracrylate isopropyl ester, dihexyl sebacate, poly-carbonic acid 1,2-propylene diester, poly- butanedioic acid fourth diester and three (2- of citric acid Propyl group heptan) ester, the weight content of its each component is:34 ~ 48 parts of isopropyl myristate, β-(3,4- dihydroxy phenyl)-Alpha-hydroxy 16 ~ 33 parts of isopropyl propionate, 10 ~ 22 parts of dihexyl sebacate, 15 ~ 29 parts of poly-carbonic acid 1,2-propylene diester, poly- butanedioic acid fourth two 9 ~ 21 parts of ester and citric acid three (2- propyl group heptan) 38 ~ 50 parts of ester.
In a preferred embodiment of the present invention, described β-(3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester Weight content is 18 ~ 30 parts.
In a preferred embodiment of the present invention, the weight content of described poly- carbonic acid 1,2- propylene diester is 17 ~ 29 parts.
In a preferred embodiment of the present invention, the weight content of described poly- butanedioic acid fourth diester is 11 ~ 21 parts.
The invention has the beneficial effects as follows:The back side of inventive film base layer is difficult scratch, and tensile resistance is excellent.
Specific embodiment
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection Enclose.
Embodiment 1
A kind of Composite Coatings aluminium film, including:Film base layer and aluminium coated, described film base layer are made up of following components:Tetradecylic acid Isopropyl ester, β-(3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, dihexyl sebacate, poly-carbonic acid 1,2-propylene diester, poly- Butanedioic acid fourth diester and citric acid three (2- propyl group heptan) ester, the weight content of its each component is:34 parts of isopropyl myristate, β- 18 parts of (3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, 10 parts of dihexyl sebacate, poly-carbonic acid 1,2-propylene diester 17 Part, 11 parts of poly- butanedioic acid fourth diester and citric acid three (2- propyl group heptan) 38 parts of ester.
Embodiment 2
A kind of Composite Coatings aluminium film, including:Film base layer and aluminium coated, described film base layer are made up of following components:Tetradecylic acid Isopropyl ester, β-(3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, dihexyl sebacate, poly-carbonic acid 1,2-propylene diester, poly- Butanedioic acid fourth diester and citric acid three (2- propyl group heptan) ester, the weight content of its each component is:48 parts of isopropyl myristate, β- 30 parts of (3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, 22 parts of dihexyl sebacate, poly-carbonic acid 1,2-propylene diester 29 Part, 21 parts of poly- butanedioic acid fourth diester and citric acid three (2- propyl group heptan) 50 parts of ester.
Embodiment 3
A kind of Composite Coatings aluminium film, including:Film base layer and aluminium coated, described film base layer are made up of following components:Tetradecylic acid Isopropyl ester, β-(3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, dihexyl sebacate, poly-carbonic acid 1,2-propylene diester, poly- Butanedioic acid fourth diester and citric acid three (2- propyl group heptan) ester, the weight content of its each component is:41 parts of isopropyl myristate, β- 24 parts of (3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, 16 parts of dihexyl sebacate, poly-carbonic acid 1,2-propylene diester 23 Part, 16 parts of poly- butanedioic acid fourth diester and citric acid three (2- propyl group heptan) 44 parts of ester.
The beneficial effect of Composite Coatings aluminium film of the present invention is:The back side of inventive film base layer is difficult scratch, and stretch-proof Function admirable.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, every using this Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (4)

1. a kind of Composite Coatings aluminium film, it is characterised in that include:Film base layer and aluminium coated, described film base layer is by with the following group Divide and make:Isopropyl myristate, β-(3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, dihexyl sebacate, poly- carbonic acid 1,2- propylene diester, poly- butanedioic acid fourth diester and citric acid three (2- propyl group heptan) ester, the weight content of its each component is:Tetradecylic acid is different 34 ~ 48 parts of propyl ester, β -16 ~ 33 parts of (3,4- dihydroxy phenyl)-α-hydracrylate isopropyl ester, 10 ~ 22 parts of dihexyl sebacate, 15 ~ 29 parts of poly-carbonic acid 1,2-propylene diester, 9 ~ 21 parts of poly- butanedioic acid fourth diester and citric acid three (2- propyl group heptan) 38 ~ 50 parts of ester.
2. Composite Coatings aluminium film according to claim 1, it is characterised in that described β-(3,4- dihydroxy phenyl)-α-hydroxyl The weight content of base isopropyl propionate is 18 ~ 30 parts.
3. Composite Coatings aluminium film according to claim 1, it is characterised in that the weight of described poly- carbonic acid 1,2- propylene diester contains Measure as 17 ~ 29 parts.
4. Composite Coatings aluminium film according to claim 1, it is characterised in that the weight content of described poly- butanedioic acid fourth diester For 11 ~ 21 parts.
CN201610895379.6A 2016-10-14 2016-10-14 A kind of Composite Coatings aluminium film Pending CN106479149A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610895379.6A CN106479149A (en) 2016-10-14 2016-10-14 A kind of Composite Coatings aluminium film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610895379.6A CN106479149A (en) 2016-10-14 2016-10-14 A kind of Composite Coatings aluminium film

Publications (1)

Publication Number Publication Date
CN106479149A true CN106479149A (en) 2017-03-08

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2524919Y (en) * 2002-02-09 2002-12-11 福州佳通第一塑料有限公司 PVC aluminium coating film
CN101402817A (en) * 2008-11-14 2009-04-08 上海维凯化学品有限公司 Environment-friendly holography aluminising transfer paint, preparation and uses thereof
CN102416741A (en) * 2011-09-29 2012-04-18 江苏立霸实业股份有限公司 Environment-friendly PET (polyethylene terephthalate)-PBS (polybutadiene styrene) bright film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2524919Y (en) * 2002-02-09 2002-12-11 福州佳通第一塑料有限公司 PVC aluminium coating film
CN101402817A (en) * 2008-11-14 2009-04-08 上海维凯化学品有限公司 Environment-friendly holography aluminising transfer paint, preparation and uses thereof
CN102416741A (en) * 2011-09-29 2012-04-18 江苏立霸实业股份有限公司 Environment-friendly PET (polyethylene terephthalate)-PBS (polybutadiene styrene) bright film

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Application publication date: 20170308

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